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1. 发明授权

US4632963A Halogenated butyl rubber 失效
公开(公告)号：US4632963A
公开(公告)日：1986-12-30
申请号：US597187
申请日：1984-04-05
申请人： Irwin J. Gardner , James V. Fusco , Neil F. Newman , Ronald C. Kowalski , William M. Davis , Francis P. Baldwin
发明人： Irwin J. Gardner , James V. Fusco , Neil F. Newman , Ronald C. Kowalski , William M. Davis , Francis P. Baldwin
IPC分类号： C08L23/28 , C08F8/00 , C08F8/18 , C08F8/20 , C08F8/48 , C08L1/00 , C08L21/00 , C08L23/00 , C08L23/26 , C08L27/00 , C08L101/00 , C08F8/22
CPC分类号： C08F8/18 , C08F8/48
摘要： An improved halogenated butyl rubber wherein the polymer has a conjugated diene content of less than 0.25 mole % and a halogen content of at least 0.6 wt. %; at least 20 mole % of the halogen being in a primary allylic configuration.

2. 发明授权

US5087674A Acid scavenged polymer halogenation 失效
标题翻译：酸清除聚合物卤化
公开(公告)号：US5087674A
公开(公告)日：1992-02-11
申请号：US595915
申请日：1990-10-11
申请人： Irwin J. Gardner , James V. Fusco , Neil F. Newman , Ronald C. Kowalski , William M. Davis
发明人： Irwin J. Gardner , James V. Fusco , Neil F. Newman , Ronald C. Kowalski , William M. Davis
IPC分类号： C08F8/20
CPC分类号： C08F8/20
摘要： A process for halogenating polymers by contacting a polymer either in solution or in bulk with a halogenating agent in the presence of an acid scavenger. Halogenated polymer, e.g., butyl rubber, with a particular structure is obtained and the product suffers less molecular weight loss. Combinations of acid scavengers can also be used and the scavenger can be dispersed in the polymer prior to halogenation and/or added to the reaction zone during halogenation.
摘要翻译：一种通过在酸清除剂存在下使聚合物在溶液中或大量与卤化剂接触来使聚合物卤化的方法。获得具有特定结构的卤化聚合物，例如丁基橡胶，并且产物的分子量损失较小。酸清除剂的组合也可以使用，并且清除剂可以在卤化之前分散在聚合物中和/或在卤化过程中加入到反应区中。

3. 发明授权

US4703091A Halogenated butyl rubber 失效
标题翻译：卤化丁基橡胶
公开(公告)号：US4703091A
公开(公告)日：1987-10-27
申请号：US933655
申请日：1986-11-21
申请人： Irwin J. Gardner , James V. Fusco , Neil F. Newman , Ronald C. Kowalski , William M. Davis , Francis P. Baldwin
发明人： Irwin J. Gardner , James V. Fusco , Neil F. Newman , Ronald C. Kowalski , William M. Davis , Francis P. Baldwin
IPC分类号： C08F8/18 , C08F8/48 , C08F8/20
CPC分类号： C08F8/18 , C08F8/48 , Y10S156/91
摘要： An improved halogenated butyl rubber wherein the polymer has a conjugated diene content of less than 0.25 mole % and a halogen content of at least 0.6 wt. %; at least 20 mole % of the halogen being in a primary allylic configuration.
摘要翻译：一种改进的卤化丁基橡胶，其中聚合物的共轭二烯含量小于0.25摩尔％，卤素含量至少为0.6重量％。％; 至少20摩尔％的卤素是初级烯丙基构型。

4. 发明授权

US4650832A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4650832A
公开(公告)日：1987-03-17
申请号：US788425
申请日：1985-10-17
申请人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Zisis A. Foroulis , Francis P. Baldwin
发明人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Zisis A. Foroulis , Francis P. Baldwin
IPC分类号： C08F8/20 , C08F8/22
CPC分类号： C08F8/20
摘要： In a process for the continuous halogenation of polymers by contacting polymer and halogenating agent in a continuous flow device in which means are provided for disengaging reaction by-products and unreacted halogenating agent from the reaction mixture, by deforming and disrupting the halogenated polymer surface and injecting an inert and/or reactive gas into the halogenated polymers immediately after reaction thereby neutralizing the product. In a preferred embodiment the process is carried out in an extruder-reactor and an optional, supplementary inert and/or reactive gas scrubbing zone is included. The process is amenable to saturated and unsaturated polymers.
摘要翻译：在聚合物和卤化剂在连续流动装置中连续卤化聚合物的方法中，其中提供了用于使反应副产物和未反应的卤化剂从反应混合物中分离的方法，通过变形和破坏卤化聚合物表面并注入惰性和/或反应性气体在反应后立即进入卤代聚合物，从而中和产物。在优选的实施方案中，该方法在挤出机 - 反应器中进行，并且包括任选的补充的惰性和/或反应性气体洗涤区。该方法适用于饱和和不饱和聚合物。

5. 发明授权

US4554326A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4554326A
公开(公告)日：1985-11-19
申请号：US481320
申请日：1983-04-01
申请人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Z. Andrew Foroulis , Francis P. Baldwin
发明人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Z. Andrew Foroulis , Francis P. Baldwin
IPC分类号： C08F8/00 , C08C19/12 , C08F8/20 , C08F8/22
CPC分类号： C08F8/20 , C08C19/12
摘要： In a process for the continuous halogenation of polymers by contacting polymer and halogenating agent in a continuous flow device in which the polymer and halogenating agent are subjected to deformation during reaction and in which means are provided for disengaging reaction by-products and unreacted halogenating agent from the reaction mixture, a significant process improvement is realized by injecting an inert gas into the halogenated polymers immediately after reaction in order to neutralize the product. In a preferred embodiment the process is carried out in an extruder-reactor and an optional, supplementary inert gas scrubbing zone is included. The process is amenable to saturated and unsaturated polymers.
摘要翻译：在聚合物和卤化剂在连续流动装置中使聚合物和卤化剂在反应期间经受变形的连续卤化反应过程中，并且提供了用于使反应副产物和未反应的卤化剂从反应混合物中，通过在反应后立即向惰性气体中注入惰性气体以中和产物来实现显着的工艺改进。在优选的实施方案中，该方法在挤出机 - 反应器中进行，并且包括任选的补充惰性气体洗涤区。该方法适用于饱和和不饱和聚合物。

6. 发明授权

US4548995A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4548995A
公开(公告)日：1985-10-22
申请号：US651621
申请日：1984-09-17
申请人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Z. Andrew Foroulis , Francis P. Baldwin
发明人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Z. Andrew Foroulis , Francis P. Baldwin
IPC分类号： C08F8/00 , C08C19/12 , C08F8/20 , C08F8/22
CPC分类号： C08F8/20 , C08C19/12
摘要： In a process for the continuous halogenation of polymers by contacting polymer and halogenating agent in a continuous flow device in which means are provided for disengaging reaction by-products and unreacted halogenating agent from the reaction mixture, by deforming and disrupting the halogenated polymer surface and injecting an inert gas into the halogenated polymers immediately after reaction thereby neutralizing the product. In a preferred embodiment the process is carried out in an extruder-reactor and an optional, supplementary inert gas scrubbing zone is included. The process is amenable to saturated and unsaturated polymers.
摘要翻译：在聚合物和卤化剂在连续流动装置中连续卤化聚合物的方法中，其中提供了用于使反应副产物和未反应的卤化剂从反应混合物中分离的方法，通过变形和破坏卤化聚合物表面并注入在反应后立即将惰性气体引入卤化聚合物中，从而中和产物。在优选的实施方案中，该方法在挤出机 - 反应器中进行，并且包括任选的补充惰性气体洗涤区。该方法适用于饱和和不饱和聚合物。

7. 发明授权

US4563506A Extrusion process for preparing improved brominated butyl rubber 失效
标题翻译：制备改性溴化丁基橡胶的挤出方法
公开(公告)号：US4563506A
公开(公告)日：1986-01-07
申请号：US656664
申请日：1984-10-01
申请人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Zisis A. Foroulis , Francis P. Baldwin
发明人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Zisis A. Foroulis , Francis P. Baldwin
IPC分类号： C08F8/00 , C08C19/12 , C08F8/20 , C08F8/22
CPC分类号： C08F8/20 , C08C19/12
摘要： A process for the continuous bromination of butyl rubber polymer by contacting the polymer with a brominating agent in a continuous flow device in which means are provided for disengaging reaction by-products and unreacted halogenating agents from the reaction mixture, by deforming and disrupting the brominated polymer surface and injecting a neutralizing agent into the polymer immediately after reaction thereby neutralizing the polymer, comprising contacting a polymer substantially free of acid scavengers, with the brominating agent at elevated temperatures the bromination reaction being carried out in an acid atmosphere, thereby producing a polymer having a substantial fraction of the bromine in the primary allylic position.
摘要翻译：通过使连续流动装置中的聚合物与溴化剂接触来连续溴化丁基橡胶聚合物的方法，其中提供了用于通过使溴化聚合物变形和破坏从反应混合物中分离反应副产物和未反应的卤化剂表面，并且在反应后立即将中和剂注入聚合物中，由此中和聚合物，包括使基本上不含酸清除剂的聚合物与溴化剂在升高的温度下接触，溴酸反应在酸性气氛中进行，从而制备具有在主要烯丙基位置的大部分溴。

8. 发明授权

US4513116A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4513116A
公开(公告)日：1985-04-23
申请号：US481366
申请日：1983-04-01
申请人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Lewis Erwin
发明人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Lewis Erwin
IPC分类号： C08F8/00 , C08C19/12 , C08F8/20 , C08F8/22
CPC分类号： C08C19/12 , C08F8/20
摘要： Continuous halogenation of polymers is achieved by contacting polymer and halogenating agent in a continuous flow device in which the reactants are present as either co-continuous phases or wherein the halogenating agent is present as a continuous phase and the polymer is present as a discontinuous phase, the polymer is subjected to deformation during reaction and in which means are provided for disengaging reaction by-products and unreacted halogenating agent from the reaction mixture. In a preferred embodiment the polymer passes through three extruder-reactor zones under controlled conditions to achieve halogenation: feed, reaction (preferably vented), neutralization, and optionally a wash and exit zone. A continuous halogenating agent phase is achieved during reaction by avoiding complete filling of the reaction zone with polymer. Various halogenated polymers are produced, for example, halogenated linear low density polyethylene and halogenated butyl rubber.
摘要翻译：通过使聚合物和卤化剂在连续流动装置中接触来实现聚合物的连续卤化，其中反应物以共连续相存在，或者其中卤化剂作为连续相存在，并且聚合物以不连续相存在，聚合物在反应过程中变形，并且提供了用于使反应副产物和未反应的卤化剂从反应混合物中分离的装置。在优选的实施方案中，聚合物在受控条件下通过三个挤出机 - 反应器区域，以实现卤化：进料，反应（优选排气），中和，任选的洗涤和出口区。在反应期间通过避免用聚合物完全填充反应区而实现连续的卤化剂相。制备各种卤化聚合物，例如卤化线性低密度聚乙烯和卤化丁基橡胶。

9. 发明授权

US4384072A Process for the manufacture of halogenated elastomers 失效
标题翻译：制造卤化弹性体的方法
公开(公告)号：US4384072A
公开(公告)日：1983-05-17
申请号：US306882
申请日：1981-09-30
申请人： Neil F. Newman , Ronald C. Kowalski
发明人： Neil F. Newman , Ronald C. Kowalski
IPC分类号： C08F8/00 , C08C19/12 , C08C19/20 , C08F8/18 , C08F8/20 , C08F8/34 , C08F8/22
CPC分类号： C08F8/20 , C08C19/12 , Y02P20/143
摘要： Continuous halogenation of olefinically unsaturated rubber is achieved in an extruder - reactor employing reactants, conditions and design features directed to maximizing mixing and contact of the rubber with the halogenating agent and neutralizing agent while simultaneously minimizing side reactions and polymer degradation. The rubber passes through five extruder-reactor zones under controlled conditions to achieve halogenation: feed, reaction, neutralization, wash and exit. The halogenated rubber, for example, halogenated butyl rubber can be vulcanized in the absence of sulfur, e.g., with zinc oxide and stearic acid, and is useful in all applications where commercially available chlorinated and brominated rubbers are presently employed.
摘要翻译：在使用反应物的挤出机 - 反应器中实现烯属不饱和橡胶的连续卤化，条件和设计特征旨在使橡胶与卤化剂和中和剂的混合和接触最大化，同时最小化副反应和聚合物降解。橡胶在受控条件下通过五个挤出机 - 反应器区域以实现卤化：进料，反应，中和，洗涤和排出。卤化橡胶例如卤化丁基橡胶可以在不存在硫的情况下硫化，例如用氧化锌和硬脂酸硫化，并且可用于目前使用市售的氯化和溴化橡胶的所有应用中。

10. 发明授权

US4501859A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4501859A
公开(公告)日：1985-02-26
申请号：US481279
申请日：1983-04-01
申请人： Neil F. Newman , Ronald C. Kowalski
发明人： Neil F. Newman , Ronald C. Kowalski
IPC分类号： C08C19/12 , C08F8/20 , C08F8/22
CPC分类号： C08C19/12 , C08F8/20
摘要： Continuous halogenation of polymers is achieved in an extruder-reactor employing reactants, conditions and design features directed to maximizing mixing and contact of the polymer with the halogenating agent and neutralizing agent while simultaneously minimizing side reactions and polymer degradation. The polymer passes through three extruder-reactor zones under controlled conditions to achieve halogenation: feed, reaction, neutralization, and optionally a wash and exit zone. Various halogenated polymers are produced, for example, halogenated linear low density polyethylene and halogenated butyl rubber.
摘要翻译：聚合物的连续卤化在使用反应物的挤出机反应器中实现，条件和设计特征旨在使聚合物与卤化剂和中和剂的混合和接触最大化，同时最小化副反应和聚合物降解。聚合物在受控条件下通过三个挤出机 - 反应器区域，以实现卤化：进料，反应，中和，以及任选的洗涤和出口区域。制备各种卤化聚合物，例如卤化线性低密度聚乙烯和卤化丁基橡胶。

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