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1. 发明授权

US06812360B2 Process for preparing bis(fluoroaryl)boron derivatives 失效
标题翻译：制备双（氟化芳基）硼衍生物的方法
公开(公告)号：US06812360B2
公开(公告)日：2004-11-02
申请号：US10221029
申请日：2002-09-09
申请人： Ikuyo Ikeno , Hitoshi Mitsui , Toshiya Iida , Toshimitsu Moriguchi
发明人： Ikuyo Ikeno , Hitoshi Mitsui , Toshiya Iida , Toshimitsu Moriguchi
IPC分类号： C07F502
CPC分类号： C07F5/025 , C07F5/027
摘要： Bis(fluoroaryl)borane derivative is produced by reacting tris(fluoroaryl)borane with a compound, such as water, ethanol, ammonia and the like, in a hydrocarbon solvent at a molar ratio raging from 1:0.9 to 1:1.1. It is more preferable that the reaction is carried out while the hydrocarbon solvent is distilled off. It is more preferable that hydrocarbon solvent is substantially an aliphatic hydrocarbon solvent. With this arrangement, it is possible to provide a method for producing and isolating the bis(fluoroaryl)borane derivative of a high purity, with ease and at a low cost.

2. 发明授权

US06465668B2 Method for producing fluoroaryl metal compound 失效
标题翻译：氟芳基金属化合物的制备方法
公开(公告)号：US06465668B2
公开(公告)日：2002-10-15
申请号：US09993892
申请日：2001-11-27
申请人： Ikuyo Ikeno , Hitoshi Mitsui , Toshiya Iida , Toshimitsu Moriguchi
发明人： Ikuyo Ikeno , Hitoshi Mitsui , Toshiya Iida , Toshimitsu Moriguchi
IPC分类号： C07F722
CPC分类号： C07F7/2208
摘要： A method for easily and inexpensively producing and purifying a fluoroaryl metal compound such as bis(pentafluorophenyl)dialkyltin which is less colored and has no impurities is provided. Hydrocarbon magnesium halide is reacted with fluoroaryl halide in a solvent including an ether solvent so as to obtain fluoroaryl magnesium halide, which is then reacted with an organic metal compound so as to produce a fluoroaryl metal compound. Tin is more preferable as a metal atom included in the organic metal compound. As for the ether solvent, chain ether solvents are preferable, more specifically, diisopropyl ether, dibutyl ether, and t-butylmethyl ether are more preferable. Besides, it is preferable that magnesium halide, which is a by-product of the fluoroaryl metal compound, is precipitated and removed, or treated with an acid.
摘要翻译：提供了一种容易且廉价地生产和纯化氟代芳基金属化合物如双（五氟苯基）二烷基锡的方法，所述二（五氟苯基）二烷基锡颜色较少，没有杂质。碳氢化镁卤化物与氟芳基卤化物在包括醚溶剂的溶剂中反应，得到氟化芳基卤化镁，然后与有机金属化合物反应，生成氟芳基金属化合物。作为有机金属化合物中的金属原子，更优选锡。对于醚类溶剂，优选链状醚溶剂，更优选二异丙基醚，二丁基醚和叔丁基甲基醚。此外，优选将作为氟代芳基金属化合物的副产物的卤化镁沉淀除去，或用酸处理。

3. 发明授权

US06818785B2 Method for purifying fluoroaryl borane derivative and bis (fluoraryl) borane derivative 失效
标题翻译：氟芳基硼烷衍生物和双（氟芳基）硼烷衍生物的纯化方法
公开(公告)号：US06818785B2
公开(公告)日：2004-11-16
申请号：US10220635
申请日：2002-09-04
申请人： Ikuyo Ikeno , Hitoshi Mitsui , Toshiya Iida , Toshimitsu Moriguchi
发明人： Ikuyo Ikeno , Hitoshi Mitsui , Toshiya Iida , Toshimitsu Moriguchi
IPC分类号： C07F504
CPC分类号： C07F5/027
摘要： After a fluoroaryl borane derivative is precipitated from a solution containing the fluoroaryl borane derivative, a bis (fluoroaryl) borane derivative, and a hydrocarbon solvent and is subjected to first filtration so that the fluoroaryl borane derivative is isolated, a filtrate that has been obtained by the first filtration is cooled and the bis (fluoroaryl) borane derivative is separated and is subjected to second filtration so that the bis (fluoroaryl) borane derivative is isolated. In a case where the solution contains fluorobenzene, the solution is concentrated, so that the fluorobenzene is removed. Thus, it is possible to provide the high-purity fluoroaryl borane derivative and bis (fluoroaryl) borane derivative having no impurity with ease and at a low cost.
摘要翻译：氟化芳基硼烷衍生物从含有氟代芳基硼烷衍生物，双（氟化芳基）硼烷衍生物和烃溶剂的溶液中沉淀出来，并进行第一次过滤以分离出氟化芳基硼烷衍生物，得到的滤液由将第一次过滤冷却并分离双（氟化芳基）硼烷衍生物，并进行第二次过滤，从而分离双（氟化芳基）硼烷衍生物。在溶液含有氟苯的情况下，将溶液浓缩，以除去氟苯。因此，可以容易且低成本地提供不含杂质的高纯度氟代芳基硼烷衍生物和双（氟代芳基）硼烷衍生物。

4. 发明授权

US07205441B2 Method for producing tetrakis (fluoroaryl) borate-magnesium compound 有权
标题翻译：制备四（氟化芳基）硼酸镁化合物的方法
公开(公告)号：US07205441B2
公开(公告)日：2007-04-17
申请号：US10431613
申请日：2003-05-08
申请人： Ikuyo Ikeno , Toshimitsu Moriguchi , Hitoshi Mitsui , Toshiya Iida
发明人： Ikuyo Ikeno , Toshimitsu Moriguchi , Hitoshi Mitsui , Toshiya Iida
IPC分类号： C07F5/02
CPC分类号： C07F5/027
摘要： Fluoroaryl magnesium halide is reacted with a boron compound so that a molar ratio of the fluoroaryl magnesium halide to the boron compound is not less than 3.0 and not more than 3.7, so as to produce a tetrakis (fluoroaryl) borate.magnesium compound. With this method, there occurs no hydrogen fluoride which corrodes a producing apparatus and requires troublesome waste water treatment.
摘要翻译：氟芳基卤化镁与硼化合物反应，使得氟化芳基卤化镁与硼化合物的摩尔比不小于3.0且不大于3.7，以产生四（氟化芳基）硼酸镁化合物。通过这种方法，不会发生腐蚀生产装置的氟化氢，并且需要麻烦的废水处理。

5. 发明授权

US06509488B2 Method for purifying fluoroaryl metal compound 失效
公开(公告)号：US06509488B2
公开(公告)日：2003-01-21
申请号：US09993891
申请日：2001-11-27
申请人： Ikuyo Ikeno , Hitoshi Mitsui , Toshiya Iida , Toshimitsu Moriguchi
发明人： Ikuyo Ikeno , Hitoshi Mitsui , Toshiya Iida , Toshimitsu Moriguchi
IPC分类号： C07F722
CPC分类号： C07F7/2296
摘要： In a method for purifying a fluoroaryl metal compound of the present invention, magnesium halide is precipitated and removed from a solution containing the fluoroaryl metal compound, the magnesium halide, and an ether solvent. Or, the magnesium halide is removed by treating the solution with an acid. Examples of the method include: a method in which a solvent which has a boiling point higher than that of the ether solvent contained in the solution and which does not dissolve the magnesium halide is heated to a temperature higher than the boiling point of the ether solvent, then the ether solvent is distilled out with the solution being added to the solvent; and a method in which the solution and an aqueous solution containing an acid are mixed and stirred, then allowed to stand so as to be separated into an organic layer containing the fluoroaryl metal compound and an aqueous layer containing the magnesium halide and the acid. In this manner, a highly pure fluoroaryl metal compound having no impurities can be purified easily and inexpensively.

6. 发明申请

US20100249441A1 METHOD FOR PRODUCING FATTY ACID ALKYL ESTER AND/OR GLYCERIN 失效
标题翻译：生产脂肪酸乙酯和/或甘氨酸的方法
公开(公告)号：US20100249441A1
公开(公告)日：2010-09-30
申请号：US12739332
申请日：2007-10-31
申请人： Masanori Nonoguchi , Hiroko Izumi , Atsushi Tachibana , Tomoharu Oku , Toshimitsu Moriguchi , Takeo Akatsuka , Izuho Okada , Hideaki Tsuneki , Hironori Horie
发明人： Masanori Nonoguchi , Hiroko Izumi , Atsushi Tachibana , Tomoharu Oku , Toshimitsu Moriguchi , Takeo Akatsuka , Izuho Okada , Hideaki Tsuneki , Hironori Horie
IPC分类号： C07C67/03 , C07C27/02 , B01J8/02 , B01J8/04
CPC分类号： C11C3/003 , C07C67/03 , C10G2300/1011 , C10G2300/202 , C10L1/026 , Y02E50/13 , Y02P30/20 , C07C69/52
摘要： In the method of the present invention for producing fatty acid alkyl ester and/or glycerin, as a heat source for an alcohol refining step of refining alcohol from unreacted alcohol that remains without reacting in a first reaction step, at least a part of heat of the unreacted alcohol is used. This allows reducing costs in production of fatty acid alkyl ester and/or glycerin over a solid catalyst.
摘要翻译：在本发明的制备脂肪酸烷基酯和/或甘油的方法中，作为用于在第一反应步骤中保持不反应的未反应醇精炼醇的醇精制步骤的热源，至少一部分热量使用未反应的醇。这允许在固体催化剂上降低脂肪酸烷基酯和/或甘油的生产成本。

7. 发明申请

US20100113838A1 PROCESS FOR PRODUCING ACROLEIN 失效
标题翻译：生产ACROLEIN的方法
公开(公告)号：US20100113838A1
公开(公告)日：2010-05-06
申请号：US12451498
申请日：2008-05-15
申请人： Yoshitaka Arita , Tsukasa Takahashi , Masaki Okada , Toshimitsu Moriguchi
发明人： Yoshitaka Arita , Tsukasa Takahashi , Masaki Okada , Toshimitsu Moriguchi
IPC分类号： C07C45/00 , B01J27/18
CPC分类号： B01J37/036 , B01J27/1804 , B01J27/285 , B01J37/03 , C07C45/52 , Y02P20/584 , C07C47/22
摘要： There is provided a process for producing acrolein, which makes it possible to obtain acrolein in high yield by dehydration of glycerin. Glycerin is allowed to coexist with a catalyst containing a rare earth metal salt crystal of phosphoric acid, thereby dehydrating the glycerin, wherein the crystal is obtained by calcining a solid which is formed by allowing a liquid containing water and a hydroxide of the rare earth metal and/or a dehydration condensate of the hydroxide to contain phosphate ions.
摘要翻译：提供了制备丙烯醛的方法，其可以通过甘油脱水以高产率获得丙烯醛。甘油与含有磷酸稀土金属盐晶体的催化剂共存，从而使甘油脱水，其中通过煅烧通过使含有水的液体和稀土金属的氢氧化物形成的固体而获得的结晶和/或氢氧化物的脱水缩合物以含有磷酸根离子。

8. 发明授权

US08404887B2 Process for producing acrylic acid 失效
标题翻译：丙烯酸生产工艺
公开(公告)号：US08404887B2
公开(公告)日：2013-03-26
申请号：US13141325
申请日：2009-12-24
申请人： Toshimitsu Moriguchi , Yoshitaka Arita
发明人： Toshimitsu Moriguchi , Yoshitaka Arita
IPC分类号： C07C51/16 , C07C51/42 , C08F20/06
CPC分类号： B01J23/8885 , B01J20/261 , B01J21/063 , B01J21/066 , B01J23/002 , B01J23/06 , B01J27/16 , B01J35/0006 , B01J2523/00 , C07C51/235 , C07C51/43 , C07C57/04 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： A process for producing acrylic acid of the present invention comprises the step of conducting gas-phase oxidative dehydrogenation of a composition containing propionaldehyde using a solid catalyst containing molybdenum and vanadium as essential components, thereby obtaining acrylic acid. The obtained acrylic acid is preferably purified by crystallization, and a monomeric component containing the purified acrylic acid is polymerized to thereby give a hydrophilic resin such as an absorbent resin and a water-soluble resin.
摘要翻译：本发明的丙烯酸的制造方法包括使用含有钼和钒作为必要成分的固体催化剂进行含有丙醛的组合物的气相氧化脱氢的工序，得到丙烯酸。所得丙烯酸优选通过结晶进行纯化，并将含有纯化丙烯酸的单体组分聚合，从而得到亲水性树脂如吸水性树脂和水溶性树脂。

9. 发明授权

US07847131B2 Process for producing acrolein 失效
标题翻译：制备丙烯醛的方法
公开(公告)号：US07847131B2
公开(公告)日：2010-12-07
申请号：US12451498
申请日：2008-05-15
申请人： Yoshitaka Arita , Tsukasa Takahashi , Masaki Okada , Toshimitsu Moriguchi
发明人： Yoshitaka Arita , Tsukasa Takahashi , Masaki Okada , Toshimitsu Moriguchi
IPC分类号： C07C45/52
CPC分类号： B01J37/036 , B01J27/1804 , B01J27/285 , B01J37/03 , C07C45/52 , Y02P20/584 , C07C47/22
摘要： There is provided a process for producing acrolein, which makes it possible to obtain acrolein in high yield by dehydration of glycerin. Glycerin is allowed to coexist with a catalyst containing a rare earth metal salt crystal of phosphoric acid, thereby dehydrating the glycerin, wherein the crystal is obtained by calcining a solid which is formed by allowing a liquid containing water and a hydroxide of the rare earth metal and/or a dehydration condensate of the hydroxide to contain phosphate ions.
摘要翻译：提供了制备丙烯醛的方法，其可以通过甘油脱水以高产率获得丙烯醛。甘油与含有磷酸稀土金属盐晶体的催化剂共存，从而使甘油脱水，其中通过煅烧通过使含有水的液体和稀土金属的氢氧化物形成的固体而获得的结晶和/或氢氧化物的脱水缩合物以含有磷酸根离子。

10. 发明授权

US07605281B2 Method of production of fatty acid alkyl esters and/or glycerine and fatty acid alkyl ester-containing composition 失效
标题翻译：脂肪酸烷基酯和/或甘油和脂肪酸烷基酯组合物的生产方法
公开(公告)号：US07605281B2
公开(公告)日：2009-10-20
申请号：US10569979
申请日：2004-08-30
申请人： Tomoharu Oku , Masanori Nonoguchi , Toshimitsu Moriguchi
发明人： Tomoharu Oku , Masanori Nonoguchi , Toshimitsu Moriguchi
IPC分类号： C11C3/00
CPC分类号： B01J23/22 , B01J21/063 , B01J21/066 , B01J23/20 , B01J23/8472 , B01J35/002 , C11C3/003 , Y02E50/13
摘要： The method of producing fatty acid alkyl esters and/or glycerine of the present invention is a method of producing high-purity fatty acid alkyl esters and/or glycerine advantageously from the energy viewpoint while reducing the energy consumption of the production, and the products can be used in various fields of application, for example in biodiesel fuels, foods, cosmetics and pharmaceuticals.The above-mentioned method of producing fatty acid alkyl esters and/or glycerine by reacting a fat or oil with an alcohol using an insoluble solid catalyst in a reaction apparatus comprising at least one reactor, comprises (a) a step of obtaining low-boiling components removed liquid by removing low-boiling components or fraction from an effluent liquid of a reactor and (b) a step of separating the fatty acid alkyl esters and glycerine from the low-boiling components removed liquid, wherein an eluted active metal component of the insoluble solid catalyst in the effluent liquid of a reactor amounts to a level not higher than 1,000 ppm.
摘要翻译：本发明的脂肪酸烷基酯和/或甘油的制造方法是从能源角度有利地生产高纯度脂肪酸烷基酯和/或甘油的方法，同时降低生产的能量消耗，并且产品可以可用于各种应用领域，例如生物柴油燃料，食品，化妆品和药品。上述通过在包含至少一个反应器的反应装置中使用不溶性固体催化剂使脂肪或油与醇反应制备脂肪酸烷基酯和/或甘油的方法包括（a）获得低沸点组分通过从反应器的流出液中除去低沸点组分或部分来除去液体，和（b）从低沸点组分除去的液体中分离脂肪酸烷基酯和甘油的步骤，其中洗脱的活性金属组分反应器流出液中不溶性固体催化剂的含量不高于1,000ppm。

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