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    • 9. 发明申请
    • METHOD FOR SYNTHESIZING T-BUTYL (METH)ACRYLATE
    • 合成叔丁基(甲基)丙烯酸酯的方法
    • US20090012327A1
    • 2009-01-08
    • US11815664
    • 2006-02-06
    • Shigeho TanakaTohru EndohHaruki SatoToshihiro SatoKazutaka Inoue
    • Shigeho TanakaTohru EndohHaruki SatoToshihiro SatoKazutaka Inoue
    • C07C57/18
    • C07C67/04C07C69/54
    • Disclosed is a method for synthesizing t-butyl (meth)acrylate at low cost. Specifically, disclosed is a method for synthesizing a carboxylic acid ester by performing an addition reaction between isobutylene and (meth)acrylic acid in the presence of an acidic catalyst. This method includes the steps of: (A) performing a dehydration decomposition reaction of t-butyl alcohol in the presence of a first acidic catalyst; (B) obtaining crude isobutylene gas by separating at least water from a produced gas obtained in the step A; (C) absorbing the crude isobutylene gas in an absorption solvent containing (meth)acrylic acid; and (D) producing t-butyl (meth)acrylate by performing the addition reaction by bringing the absorption solvent which has absorbed the crude isobutylene gas into contact with a second acidic catalyst.
    • 公开了以低成本合成(甲基)丙烯酸叔丁酯的方法。 具体地,公开了通过在酸性催化剂的存在下进行异丁烯和(甲基)丙烯酸之间的加成反应来合成羧酸酯的方法。 该方法包括以下步骤:(A)在第一酸性催化剂的存在下进行叔丁醇的脱水分解反应; (B)通过从步骤A中获得的产生的气体中至少分离出水来获得粗异丁烯气体; (C)在含有(甲基)丙烯酸的吸收溶剂中吸收粗异丁烯气体; 和(D)通过使吸收了粗异丁烯气体的吸收溶剂与第二酸性催化剂接触进行加成反应来生产(甲基)丙烯酸叔丁酯。