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1. 发明授权

US4225412A Apparatus for separating neutral molecules using a bipolar membrane as a molecular sieve 失效
标题翻译：使用双极膜作为分子筛分离中性分子的装置
公开(公告)号：US4225412A
公开(公告)日：1980-09-30
申请号：US966196
申请日：1978-12-04
申请人： Howard Reiss
发明人： Howard Reiss
IPC分类号： A61F2/08 , B01D57/00 , B01D57/02 , B01D61/24 , B01D61/44 , C25B13/02 , C25B13/08 , H01G9/20 , H01M8/18 , H01M14/00
CPC分类号： H01M14/005 , A61F2/08 , B01D57/02 , B01D61/445 , B01D71/26 , H01G9/20 , H01M8/18 , A61F2002/0894 , B01D2315/06 , Y02E60/528
摘要： A monolithic bipolar membrane having elastic properties is immersed in a polar solvent or an electrolyte, such as water. An electric field is used to control the transfer rate of neutral or ionized molecules in solution in the electrolyte through the membrane in response to an applied external electromotive force. By adjusting the external electromotive force the membrane can be controlled to selectively pass one type of molecule while rejecting other molecules in solution. A separation between molecules of two or more materials in solution in the electrolyte can thus be achieved.
摘要翻译：将具有弹性的单片双极膜浸入极性溶剂或电解质如水中。电场用于响应于所施加的外部电动势来控制通过膜的电解质溶液中的中性或离子化分子的转移速率。通过调节外部电动势，可以控制膜选择性地通过一种分子，同时排除溶液中的其他分子。因此可以实现电解质溶液中两种或更多种材料的分子之间的分离。

2. 发明授权

US5358556A Membranes having selective permeability 失效
标题翻译：具有选择性渗透性的膜
公开(公告)号：US5358556A
公开(公告)日：1994-10-25
申请号：US988935
申请日：1993-02-25
申请人： Richard B. Kaner , Mark R. Anderson , Howard Reiss , Benjamin R. Mattes
发明人： Richard B. Kaner , Mark R. Anderson , Howard Reiss , Benjamin R. Mattes
IPC分类号： B01D71/60 , B01D53/22 , B01D67/00 , B01D69/02 , B01D71/72 , H01B1/12
CPC分类号： B01D67/0093 , B01D53/228 , B01D69/02 , B01D71/72 , H01B1/128 , Y02C10/10 , Y10S264/48 , Y10S264/62
摘要： Dopable, fully dense polymer membranes are used to form membranes having selective permeabilities. To improve selectivity, the membranes may be subjected to chemical or electrochemical treatment with electron donors or acceptors to alter the doping level of the polymer membrane, generally in a reversible fashion. This leads to significant changes in gas permeation rates relative to what is observed for the non-doped, fully dense polymers. This change in doping level of the polymer films can be precisely controlled by varying the concentration and nature of chemical dopants used. Desirable changes in permeation rates are achieved by a treatment which comprises a reversal doping of the polymeric material, followed by removal of the dopants (to provide an "undoped" polymer). Further addition of controlled amounts of at least one dopant species to the undoped polymer by a second, "redoping" procedure can still more dramatically change the permeability of large species, leading to particularly large separation factors.
摘要翻译：可掺杂的，完全致密的聚合物膜用于形成具有选择性渗透性的膜。为了提高选择性，膜可以用电子给体或受体进行化学或电化学处理，以改变聚合物膜的掺杂水平，通常以可逆的方式。这导致相对于未掺杂的，完全致密的聚合物观察到的气体渗透速率的显着变化。可以通过改变所用化学掺杂剂的浓度和性质来精确地控制聚合物膜的掺杂水平的这种变化。渗透速率的期望变化通过包括反向掺杂聚合物材料，然后除去掺杂剂（以提供“未掺杂的”聚合物）的处理来实现。通过第二个“重做”程序进一步向未掺杂的聚合物添加受控量的至少一种掺杂剂物质仍然可以更大地改变大物种的渗透性，导致特别大的分离因子。

3. 发明授权

US5096586A Membranes having selective permeability 失效
标题翻译：具有选择性渗透性的膜
公开(公告)号：US5096586A
公开(公告)日：1992-03-17
申请号：US573950
申请日：1990-08-28
申请人： Richard B. Kaner , Mark R. Anderson , Benjamin R. Mattes , Howard Reiss
发明人： Richard B. Kaner , Mark R. Anderson , Benjamin R. Mattes , Howard Reiss
IPC分类号： B01D71/60 , B01D53/22 , B01D67/00 , B01D69/02 , B01D71/72 , H01B1/12
CPC分类号： B01D67/0093 , B01D53/228 , B01D69/02 , B01D71/72 , H01B1/128 , Y02C10/10 , Y10S264/48 , Y10S264/62
摘要： Dopable, fully dense polymer membranes are used to form membranes having selective permeabilities. To improve selectivity, the membranes may be subjected to chemical or electrochemical treatment with electron donors or acceptors to alter the doping level of the polymer membrane, generally in a reversible fashion. This leads to significant changes in gas permeation rates relative to what is observed for the non-doped, fully dense polymers. This change in doping level of the polymer films can be precisely controlled by varying the concentration and nature of chemical dopants used. Desirable changes in permeation rates are achieved by a treatment which comprises a reversal doping of the polymeric material, followed by removal of the dopants (to provide an "undoped" polymer). Further addition of controlled amounts of at least one dopant species to the undoped polymer by a second, "redoping" procedure can still more dramatically change the permeability of large species, leading to particularly large separation factors.
摘要翻译：可掺杂的，完全致密的聚合物膜用于形成具有选择性渗透性的膜。为了提高选择性，膜可以用电子给体或受体进行化学或电化学处理，以改变聚合物膜的掺杂水平，通常以可逆的方式。这导致相对于未掺杂的，完全致密的聚合物观察到的气体渗透速率的显着变化。可以通过改变所用化学掺杂剂的浓度和性质来精确地控制聚合物膜的掺杂水平的这种变化。渗透速率的期望变化通过包括反向掺杂聚合物材料，然后除去掺杂剂（以提供“未掺杂的”聚合物）的处理来实现。通过第二个“重做”程序进一步向未掺杂的聚合物添加受控量的至少一种掺杂剂物质仍然可以更大地改变大物种的渗透性，导致特别大的分离因子。

4. 发明授权

US4354857A Method and apparatus for separating gas molecules using a bipolar membrane as a molecular sieve 失效
标题翻译：使用双极膜作为分子筛分离气体分子的方法和装置
公开(公告)号：US4354857A
公开(公告)日：1982-10-19
申请号：US230487
申请日：1981-02-02
申请人： Howard Reiss
发明人： Howard Reiss
IPC分类号： B01D53/22 , B01D53/32 , B01D59/12 , C01B23/00
CPC分类号： C01B23/00 , B01D53/22 , B01D53/323 , B01D59/12
摘要： A monolithic bipolar membrane having elastic properties is wetted with a polar solvent or an electrolyte, such as water. An electric field is used to control the transfer rate of gas molecules through the membrane in response to an applied external electromotive force. By adjusting the electromotive force the membrane can be controlled to selectively pass one type of molecule while rejecting other molecules. A separation between molecules of two or more materials can thus be achieved.
摘要翻译：具有弹性的单片双极膜用极性溶剂或诸如水的电解质润湿。使用电场来响应于所施加的外部电动势来控制通过膜的气体分子的传送速率。通过调节电动势，可以控制膜选择性地通过一种类型的分子，同时排斥其它分子。因此可以实现两种或更多种材料的分子之间的分离。

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