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1. 发明授权

US5096586A Membranes having selective permeability 失效
标题翻译：具有选择性渗透性的膜
公开(公告)号：US5096586A
公开(公告)日：1992-03-17
申请号：US573950
申请日：1990-08-28
申请人： Richard B. Kaner , Mark R. Anderson , Benjamin R. Mattes , Howard Reiss
发明人： Richard B. Kaner , Mark R. Anderson , Benjamin R. Mattes , Howard Reiss
IPC分类号： B01D71/60 , B01D53/22 , B01D67/00 , B01D69/02 , B01D71/72 , H01B1/12
CPC分类号： B01D67/0093 , B01D53/228 , B01D69/02 , B01D71/72 , H01B1/128 , Y02C10/10 , Y10S264/48 , Y10S264/62
摘要： Dopable, fully dense polymer membranes are used to form membranes having selective permeabilities. To improve selectivity, the membranes may be subjected to chemical or electrochemical treatment with electron donors or acceptors to alter the doping level of the polymer membrane, generally in a reversible fashion. This leads to significant changes in gas permeation rates relative to what is observed for the non-doped, fully dense polymers. This change in doping level of the polymer films can be precisely controlled by varying the concentration and nature of chemical dopants used. Desirable changes in permeation rates are achieved by a treatment which comprises a reversal doping of the polymeric material, followed by removal of the dopants (to provide an "undoped" polymer). Further addition of controlled amounts of at least one dopant species to the undoped polymer by a second, "redoping" procedure can still more dramatically change the permeability of large species, leading to particularly large separation factors.
摘要翻译：可掺杂的，完全致密的聚合物膜用于形成具有选择性渗透性的膜。为了提高选择性，膜可以用电子给体或受体进行化学或电化学处理，以改变聚合物膜的掺杂水平，通常以可逆的方式。这导致相对于未掺杂的，完全致密的聚合物观察到的气体渗透速率的显着变化。可以通过改变所用化学掺杂剂的浓度和性质来精确地控制聚合物膜的掺杂水平的这种变化。渗透速率的期望变化通过包括反向掺杂聚合物材料，然后除去掺杂剂（以提供“未掺杂的”聚合物）的处理来实现。通过第二个“重做”程序进一步向未掺杂的聚合物添加受控量的至少一种掺杂剂物质仍然可以更大地改变大物种的渗透性，导致特别大的分离因子。

2. 发明授权

US5358556A Membranes having selective permeability 失效
标题翻译：具有选择性渗透性的膜
公开(公告)号：US5358556A
公开(公告)日：1994-10-25
申请号：US988935
申请日：1993-02-25
申请人： Richard B. Kaner , Mark R. Anderson , Howard Reiss , Benjamin R. Mattes
发明人： Richard B. Kaner , Mark R. Anderson , Howard Reiss , Benjamin R. Mattes
IPC分类号： B01D71/60 , B01D53/22 , B01D67/00 , B01D69/02 , B01D71/72 , H01B1/12
CPC分类号： B01D67/0093 , B01D53/228 , B01D69/02 , B01D71/72 , H01B1/128 , Y02C10/10 , Y10S264/48 , Y10S264/62
摘要： Dopable, fully dense polymer membranes are used to form membranes having selective permeabilities. To improve selectivity, the membranes may be subjected to chemical or electrochemical treatment with electron donors or acceptors to alter the doping level of the polymer membrane, generally in a reversible fashion. This leads to significant changes in gas permeation rates relative to what is observed for the non-doped, fully dense polymers. This change in doping level of the polymer films can be precisely controlled by varying the concentration and nature of chemical dopants used. Desirable changes in permeation rates are achieved by a treatment which comprises a reversal doping of the polymeric material, followed by removal of the dopants (to provide an "undoped" polymer). Further addition of controlled amounts of at least one dopant species to the undoped polymer by a second, "redoping" procedure can still more dramatically change the permeability of large species, leading to particularly large separation factors.
摘要翻译：可掺杂的，完全致密的聚合物膜用于形成具有选择性渗透性的膜。为了提高选择性，膜可以用电子给体或受体进行化学或电化学处理，以改变聚合物膜的掺杂水平，通常以可逆的方式。这导致相对于未掺杂的，完全致密的聚合物观察到的气体渗透速率的显着变化。可以通过改变所用化学掺杂剂的浓度和性质来精确地控制聚合物膜的掺杂水平的这种变化。渗透速率的期望变化通过包括反向掺杂聚合物材料，然后除去掺杂剂（以提供“未掺杂的”聚合物）的处理来实现。通过第二个“重做”程序进一步向未掺杂的聚合物添加受控量的至少一种掺杂剂物质仍然可以更大地改变大物种的渗透性，导致特别大的分离因子。

3. 发明授权

US08425822B2 Spinning, doping, dedoping and redoping polyaniline fiber 失效
公开(公告)号：US08425822B2
公开(公告)日：2013-04-23
申请号：US13037178
申请日：2011-02-28
申请人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
发明人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
IPC分类号： D01D5/06 , D01F6/74 , H01B1/12
CPC分类号： C08L79/02 , C08G73/0266 , C08K5/42 , D01D5/06 , D01F6/74 , H01B1/128
摘要： A composition of matter suitable for spinning polyaniline fiber, a method for spinning electrically conductive polyaniline fiber, a method for exchanging dopants in polyaniline fibers, and methods for dedoping and redoping polyaniline fibers are described.

4. 发明申请

US20110266503A1 SPINNING, DOPING, DEDOPING AND REDOPING POLYANILINE FIBER 失效
标题翻译：旋转，掺杂，切割和缩小聚氨酯纤维
公开(公告)号：US20110266503A1
公开(公告)日：2011-11-03
申请号：US13037178
申请日：2011-02-28
申请人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
发明人： Benjamin R. Mattes , Phillip N. Adams , Dali Yang , Lori A. Brown , Andrei G. Fadeev , Ian D. Norris
IPC分类号： H01B1/12
CPC分类号： C08L79/02 , C08G73/0266 , C08K5/42 , D01D5/06 , D01F6/74 , H01B1/128
摘要： A composition of matter suitable for spinning polyaniline fiber, a method for spinning electrically conductive polyaniline fiber, a method for exchanging dopants in polyaniline fibers, and methods for dedoping and redoping polyaniline fibers are described.
摘要翻译：描述了适用于纺丝聚苯胺纤维的物质组合物，导电聚苯胺纤维的纺丝方法，聚苯胺纤维中的掺杂剂的交换方法以及聚苯胺纤维的去掺杂和重掺杂方法。

5. 发明授权

US06982514B1 Electrochemical devices incorporating high-conductivity conjugated polymers 失效
标题翻译：掺有高导电性共轭聚合物的电化学装置
公开(公告)号：US06982514B1
公开(公告)日：2006-01-03
申请号：US09863808
申请日：2001-05-22
申请人： Wen Lu , Elisabeth Smela , Benjamin R. Mattes , Philip N. Adams , Guido Zuccarello
发明人： Wen Lu , Elisabeth Smela , Benjamin R. Mattes , Philip N. Adams , Guido Zuccarello
IPC分类号： H02N11/00 , H02N2/00
CPC分类号： F03G7/005 , H01B1/127 , H01B1/128 , H02N11/006 , Y10S310/80
摘要： The present invention includes the preparation of highly conducting conjugated polymers and their use as electrochemical actuators, A typical electrochemical actuator comprises a highly conducting, conjugated polymer for the anode or the cathode, or for both the anode and the cathode; suitable conjugate polymers have a conductivity ≧100 S/cm. The material may have any form, including films and fibers. A preferred shape is a strip or a fiber, where the fiber can be solid or hollow, although any shape may be used. Before use, the material may be treated, for example, by immersion in an acid, in order to dope/protonate the material or to introduce anions or to exchange the anion in the polymer for another anion. Other materials may be incorporated in the polyaniline to increase its conductivity or to provide other benefits, such as increased strength. Useful conducting polymers include monomers of anilines, pyrroles, thiophenes, phenylene vinylenes, and derivatives thereof.
摘要翻译：本发明包括制备高导电性共轭聚合物及其作为电化学致动器的用途。典型的电化学致动器包括用于阳极或阴极或阳极和阴极的高导电共轭聚合物; 合适的共轭聚合物的导电率> 100S / cm。该材料可以具有任何形式，包括膜和纤维。优选的形状是条或纤维，其中纤维可以是固体或中空的，尽管可以使用任何形状。在使用之前，可以例如通过浸入酸中来处理材料，以便掺杂或质子化材料或引入阴离子或交换聚合物中的阴离子用于另一种阴离子。可以将其它材料引入聚苯胺中以增加其导电性或提供其它益处，例如增加的强度。有用的导电聚合物包括苯胺，吡咯，噻吩，亚苯基乙烯基单体及其衍生物。

6. 发明授权

US06667825B2 Stable conjugated polymer electrochromic devices incorporating ionic liquids 失效
公开(公告)号：US06667825B2
公开(公告)日：2003-12-23
申请号：US10037483
申请日：2002-01-03
申请人： Wen Lu , Benjamin R. Mattes , Andrei G. Fadeev , Baohua Qi
发明人： Wen Lu , Benjamin R. Mattes , Andrei G. Fadeev , Baohua Qi
IPC分类号： G02F115
CPC分类号： G02F1/15 , A61B2017/00398 , A61B2017/00871 , C08G61/02 , C08G61/10 , C08G61/12 , C08G61/123 , C09K9/02 , G02F1/155 , G02F2001/1515
摘要： Electrochemical synthesis of conjugated polymers in ionic liquids, achievement of electroactivity and electrochroism of conjugated polymers in ionic liquids, and the use of the resulting conjugated polymers for the fabrication of electrochromic devices incorporating ionic liquids as electrolytes are described.

7. 发明授权

US06123883A Method for preparing polyaniline fibers 失效
标题翻译：聚苯胺纤维的制备方法
公开(公告)号：US06123883A
公开(公告)日：2000-09-26
申请号：US334719
申请日：1999-06-16
申请人： Benjamin R. Mattes , Hsing-Lin Wang
发明人： Benjamin R. Mattes , Hsing-Lin Wang
IPC分类号： C08J5/18 , C08G73/00 , C08G73/02 , D01F6/26 , D01F6/76 , H01B1/12 , D01D5/06 , D01F1/09 , D01F6/96
CPC分类号： C08G73/0266 , D01F6/76 , H01B1/128
摘要： Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (>15% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.
摘要翻译：稳定的高分子量聚苯胺浓缩溶液。为了处理具有良好机械性能的高品质纤维和其它制品，已知所选聚合物的溶液浓度应在15-30％（w / w）的范围内。此外，期望使用与聚合物的溶解性质一致的最高分子量。然而，这种溶液固有地不稳定，可以在加工前形成凝胶。本发明描述了对聚合物溶液的加成凝胶抑制剂（GI），从而允许高分子量（（Mw）> 120,000和（Mn）> 30,000）翠绿亚胺碱的高浓度（> 15％（w / w）（EB）聚苯胺溶解。为了这个目的已经使用了仲胺，其浓度与可能用于其共溶剂作用的那些相比，其用量较小。所得到的溶液可用于产生优异的纤维，膜，涂层和其它物体，因为溶液在相当长的时间内是稳定的，并且GI以太小的浓度存在以引起聚合物劣化。证明发现有用的GI不能作为共溶剂，溶液的凝胶化时间与GI的浓度成正比。特别地，存在优选的GI浓度，如果超过，则导致所得制品的结构和电导率降低。溶液的加热显着提高了溶解度。

8. 发明授权

US5981695A Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom 失效
标题翻译：稳定的高分子量聚苯胺浓缩溶液及其制品
公开(公告)号：US5981695A
公开(公告)日：1999-11-09
申请号：US926338
申请日：1997-09-05
申请人： Benjamin R. Mattes , Hsing-Lin Wang
发明人： Benjamin R. Mattes , Hsing-Lin Wang
IPC分类号： C08J5/18 , C08G73/00 , C08G73/02 , D01F6/26 , D01F6/76 , H01B1/12 , C08J3/00
CPC分类号： C08G73/0266 , D01F6/76 , H01B1/128
摘要： Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (between 15% and 30% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.
摘要翻译：稳定的高分子量聚苯胺浓缩溶液。为了处理具有良好机械性能的高质量纤维和其它制品，已知所选聚合物的溶液浓度应在15-30％（w / w）的范围内。此外，期望使用与聚合物的溶解性质一致的最高分子量。然而，这种溶液固有地不稳定，可以在加工前形成凝胶。本发明描述了对聚合物溶液的添加凝胶抑制剂（GI），从而允许高分子量（（Mw）> 120,000和（Mn）> 30,000的高浓度（15％至30％（w / w））翠绿碱（EB）聚苯胺溶解。为了这个目的已经使用了仲胺，其浓度与可能用于其共溶剂作用的那些相比，其用量较小。所得到的溶液可用于产生优异的纤维，膜，涂层和其它物体，因为溶液在相当长的时间内是稳定的，并且GI以太小的浓度存在以引起聚合物劣化。证明发现有用的GI不能作为共溶剂，溶液的凝胶化时间与GI的浓度成正比。特别地，存在优选的GI浓度，如果超过，则导致所得制品的结构和电导率降低。溶液的加热显着提高了溶解度。

9. 发明授权

US07563484B2 Permeable polyaniline articles for gas separation 失效
标题翻译：用于气体分离的可渗透聚苯胺制品
公开(公告)号：US07563484B2
公开(公告)日：2009-07-21
申请号：US10953673
申请日：2004-09-28
申请人： Hsing-Lin Wang , Benjamin R. Mattes
发明人： Hsing-Lin Wang , Benjamin R. Mattes
IPC分类号： B05D3/02 , C08G73/06 , C08J3/00
CPC分类号： C08J3/09 , C08G73/0266 , C08J2379/02 , D01F6/76 , H01B1/128
摘要： Immersion precipitation of solutions having 15%-30% (w/w) and various molecular weights of the emeraldine base form of polyaniline in polar aprotic solvents are shown to form integrally skinned asymmetric membranes and fibers having skin layers
摘要翻译：显示在极性非质子溶剂中沉淀具有15％-30％（w / w）和各种分子量的聚苯胺的聚苯胺的溶液，形成整体表皮的不对称膜和具有<1μm厚的表层的纤维，其表现出改善气体输送速率同时保持良好的选择性。这些膜可以在制造后通过酸掺杂工艺进一步转化，以实现优异的渗透速率和特定气体分离的高选择性。在使用浓缩EB溶液之前，不可能形成整体表皮的非对称膜，因为在IP工艺过程中发现由<5％w / w聚苯胺溶液制成的膜和纤维分解。

10. 发明申请

US20090128168A1 MULTIFUNCTIONAL CONDUCTING POLYMER STRUCTURES 失效
标题翻译：多功能导电聚合物结构
公开(公告)号：US20090128168A1
公开(公告)日：2009-05-21
申请号：US12331010
申请日：2008-12-09
申请人： Baohua Qi , Benjamin R. Mattes
发明人： Baohua Qi , Benjamin R. Mattes
IPC分类号： G01R27/08
CPC分类号： H01B1/124
摘要： The present invention includes the use of conducting polymers as sensors in distributed sensing systems, as sensors and operating elements in multifunctional devices, and for conducting-polymer based multifunctional sensing fabrics suitable for monitoring humidity, breath, heart rate, blood (location of wounds), blood pressure, skin temperature, weight and movement, in a wearable, electronic embedded sensor system, as examples. A fabric comprising conducting polyaniline fibers that can be used to distribute energy for resistive heating as well as for sensing the fabric temperature is described as an example of a multifunctional sensing fabric.
摘要翻译：本发明包括使用导电聚合物作为分布式感测系统中的传感器，作为多功能装置中的传感器和操作元件，以及适于监测湿度，呼吸，心率，血液（伤口位置）的基于导电聚合物的多功能感测织物，，血压，皮肤温度，重量和运动，在可穿戴的电子嵌入式传感器系统中，作为示例。作为多功能传感织物的实例，描述了包括导电聚苯胺纤维的织物，其可用于分布用于电阻加热的能量以及感测织物温度。

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