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1. 发明授权

US06627761B2 Multifunctional carbonates and derivatives 有权
公开(公告)号：US06627761B2
公开(公告)日：2003-09-30
申请号：US09822914
申请日：2001-03-30
申请人： Howard P. Klein , David C. Alexander , Susan A. Woodrum , James R. Machac, Jr.
发明人： Howard P. Klein , David C. Alexander , Susan A. Woodrum , James R. Machac, Jr.
IPC分类号： C07D31710
CPC分类号： C07C269/02 , C07C271/24 , C07C2601/14 , C07D317/36 , C07C271/28
摘要： The present invention provides a more economical method of producing multifunctional carbonate resins. It overcomes the disadvantage of using relatively expensive starting material, such as polyglycidyl ethers, that have traditionally been used. The present invention makes use of readily available and inexpensive multi-isocyanate compounds reacted with organic carbonates that contain pendant hydroxyl groups to produce products that contain two or more carbonate functionalities. One form of the present invention is a method for preparing a carbonate urethane compound by reacting a carbonate containing compound that also contains a reactive hydroxyl group with a compound containing at least two isocyanate groups. The reaction is performed in a solvent and in the presence of a base.

2. 发明授权

US06596677B1 Propylene carbonate based cleaning compositions 有权
标题翻译：基于丙烯碳酸盐的清洁组合物
公开(公告)号：US06596677B1
公开(公告)日：2003-07-22
申请号：US09668961
申请日：2000-09-25
申请人： James R. Machac, Jr. , Susan A. Woodrum , Howard P. Klein , Edward T. Marquis
发明人： James R. Machac, Jr. , Susan A. Woodrum , Howard P. Klein , Edward T. Marquis
IPC分类号： C11D1700
CPC分类号： C11D7/3227 , C11D3/3947 , C11D7/263 , C11D7/265 , C11D7/266 , C11D7/5022
摘要： Propylene carbonate based cleaning compositions. The compositions comprise propylene carbonate, a glycol ether, water, and an acid activator. The compositions may optionally also comprise hydrogen peroxide. The present invention also provides for a method of removing a soil from a hard surface, wherein a cleaning composition comprising propylene carbonate, a glycol ether, water, and an acid activator is applied to the hard surface. After application of the cleaning composition, the soil is removed from the hard surface without the exertion of mechanical force.
摘要翻译：基于丙烯碳酸盐的清洁组合物。组合物包含碳酸亚丙酯，二醇醚，水和酸活化剂。组合物可以任选地还包含过氧化氢。本发明还提供了从硬表面去除污垢的方法，其中将包含碳酸亚丙酯，二醇醚，水和酸活化剂的清洁组合物施加到硬表面。施用清洁组合物后，土壤从硬表面去除而不产生机械力。

3. 发明授权

US06420327B1 Carbonate-based coating removers 失效
标题翻译：碳酸盐类涂料去除剂
公开(公告)号：US06420327B1
公开(公告)日：2002-07-16
申请号：US09634374
申请日：2000-08-09
申请人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum , Howard P. Klein
发明人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum , Howard P. Klein
IPC分类号： C11D339
CPC分类号： C11D3/2093 , C09D9/00 , C11D3/18 , C11D3/2006 , C11D3/201 , C11D3/2034 , C11D3/2037 , C11D3/3947
摘要： Coating remover compositions comprising an alkylene carbonate, hydrogen peroxide, water, a first alcohol, a second alcohol, and, optionally, pine oil that exhibit low toxicity. Further, a method of removing a coating from a surface. The method involves contacting a composition comprising an alkylene carbonate, hydrogen peroxide, water, a first alcohol, a second alcohol, and optionally, pine oil to a coated surface, and allowing the composition to contact the coated surface for a period of time, and under conditions effective to cause blistering of the coating. The compositions and method of the present invention are particularly suited for use with varnishes.
摘要翻译：包含显示低毒性的碳酸亚烷基酯，过氧化氢，水，第一醇，第二醇和任选的松油的涂层去除剂组合物。此外，从表面除去涂层的方法。该方法包括将包含碳酸亚烷基酯，过氧化氢，水，第一醇，第二醇和任选的松油的组合物接触到涂覆的表面，并使组合物与涂覆的表面接触一段时间，以及在有效引起涂层起泡的条件下。本发明的组合物和方法特别适用于清漆。

4. 发明授权

US06608012B2 Process and formulations to remove paint and primer coatings from thermoplastic polyolefin substrates 失效
公开(公告)号：US06608012B2
公开(公告)日：2003-08-19
申请号：US09843330
申请日：2001-04-26
申请人： James R. Machac, Jr. , Susan A. Woodrum , Howard P. Klein , Edward T. Marquis
发明人： James R. Machac, Jr. , Susan A. Woodrum , Howard P. Klein , Edward T. Marquis
IPC分类号： C11D344
CPC分类号： C09D9/005 , C11D7/261 , C11D7/263 , C11D7/264 , C11D7/3227 , C11D7/3281 , C11D7/34 , C11D11/0023 , C11D11/007
摘要： The present invention includes methods and compositions for the removal of coatings such as paint from surfaces. The methods of the present invention are typically conducted between about 45° C. and about 75° C., and the compositions typically contain a carbonate, a dibasic ester, a pyrrolidine, a mono-ester. The formulations of the present invention typically exhibit a high efficacy in the removal of paint while having a low level of toxicity.

5. 发明授权

US06833341B2 Paint stripping compositions 失效
标题翻译：涂漆组合物
公开(公告)号：US06833341B2
公开(公告)日：2004-12-21
申请号：US10223867
申请日：2002-08-20
申请人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum
发明人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum
IPC分类号： C09D900
CPC分类号： C11D3/2093 , C09D9/00 , C11D3/3947 , C11D3/43 , C11D7/263 , C11D7/264 , C11D7/266 , C11D7/5022
摘要： This invention concerns a composition useful as a paint remover, comprising: an organic carbonate, an alcohol, an activator, hydrogen peroxide, and water. The alcohol may be benzyl alcohol. The organic carbonate may be propylene carbonate, ethylene carbonate, or combination thereof. The activator may be an alkyl-substituted cycloalkane (naphthene), a soy oil, an alkyl soyate, or combination thereof.
摘要翻译：本发明涉及可用作除漆剂的组合物，其包含：有机碳酸酯，醇，活化剂，过氧化氢和水。醇可以是苄醇。有机碳酸酯可以是碳酸亚丙酯，碳酸亚乙酯或它们的组合。活化剂可以是烷基取代的环烷烃（环烷烃），大豆油，大豆油烷基酯或其组合。

6. 发明授权

US06482270B1 Paint and coating remover 失效
标题翻译：油漆和涂料去除剂
公开(公告)号：US06482270B1
公开(公告)日：2002-11-19
申请号：US09704001
申请日：2000-11-01
申请人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum , Katty Darragas
发明人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum , Katty Darragas
IPC分类号： C09D900
CPC分类号： C11D7/5009 , C09D9/005 , C11D7/263 , C11D7/264 , C11D7/266 , C11D7/34
摘要： A composition useful as a paint remover. The composition may include a carbonate, a dibasic ester and a mono-ester. The composition may also contain an organic sulfur-containing compound such as dimethyl sulfoxide (DMSO), a glycol ether, a ketone, or combination thereof. The composition may be used in a process for removing paint by applying it to a painted surface. The compositions have several important attributes, including low toxicity and high efficacy in removing paint and coatings.
摘要翻译：用作除漆剂的组合物。组合物可以包括碳酸酯，二元酯和单酯。组合物还可以含有有机含硫化合物如二甲基亚砜（DMSO），二醇醚，酮或其组合。该组合物可以用于通过将其施涂到涂漆表面上去除涂料的方法中。该组合物具有几个重要的特性，包括低毒性和高效去除油漆和涂料。

7. 发明授权

US06479445B1 Paint stripping compositions 失效
标题翻译：涂漆组合物
公开(公告)号：US06479445B1
公开(公告)日：2002-11-12
申请号：US09654439
申请日：2000-09-01
申请人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum
发明人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum
IPC分类号： C11D344
CPC分类号： C11D3/2093 , C09D9/00 , C11D3/3947 , C11D3/43 , C11D7/263 , C11D7/264 , C11D7/266 , C11D7/5022
摘要： This invention concerns a composition useful as a paint remover, comprising: an organic carbonate, an alcohol, an activator, hydrogen peroxide, and water. The alcohol may be benzyl alcohol. The organic carbonate may be propylene carbonate, ethylene carbonate, or combination thereof. The activator may be an alkyl-substituted cycloalkane (naphthene), a soy oil, an alkyl soyate, or combination thereof.
摘要翻译：本发明涉及可用作除漆剂的组合物，其包含：有机碳酸酯，醇，活化剂，过氧化氢和水。醇可以是苄醇。有机碳酸酯可以是碳酸亚丙酯，碳酸亚乙酯或它们的组合。活化剂可以是烷基取代的环烷烃（环烷烃），大豆油，大豆油烷基酯或其组合。

8. 发明授权

US06833345B2 Degreasing compositions 失效
标题翻译：脱脂成分
公开(公告)号：US06833345B2
公开(公告)日：2004-12-21
申请号：US10061536
申请日：2002-02-01
申请人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum
发明人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum
IPC分类号： C11D750
CPC分类号： C09D9/00 , C09D9/005 , C11D3/2093 , C11D3/3947 , C11D3/43 , C11D7/263 , C11D7/264 , C11D7/266 , C11D7/34 , C11D7/5009
摘要： A composition useful as a paint remover which may include a carbonate, a dibasic ester and a mono-ester. The paint stripping composition may also contain an organic sulfur-containing compound such as dimethyl sulfoxide (DMSO), a glycol ether, a ketone, or combination thereof. The composition may be used in a process for removing paint by applying it to a painted surface. A degreasing composition is also disclosed which may comprise a carbonate and a alkyl-substituted cyclo-alkane such as naphthene. The compositions have several important attributes, including low toxicity and high efficacy in removing paint and coatings.
摘要翻译：可用作除漆剂的组合物，其可以包括碳酸酯，二元酯和单酯。涂料剥离组合物还可以含有有机含硫化合物如二甲基亚砜（DMSO），二醇醚，酮或其组合。该组合物可以用于通过将其施涂到涂漆表面上去除涂料的方法中。还公开了可以包含碳酸酯和烷基取代的环烷烃如环烷烃的脱脂组合物。该组合物具有几个重要的特性，包括低毒性和高效去除油漆和涂料。

9. 发明授权

US06169061A Paint and coating remover 失效
标题翻译：油漆和涂料去除剂
公开(公告)号：US06169061A
公开(公告)日：2001-01-02
申请号：US09335596
申请日：1999-06-18
申请人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum
发明人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum
IPC分类号： C11D718
CPC分类号： C11D3/2093 , C09D9/00 , C11D3/3947 , C11D3/43 , C11D7/263 , C11D7/264
摘要： This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, his invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. Advantageously, the composition of this invention may include a dibasic ester (DBE).
摘要翻译：本发明涉及可用作除漆剂的组合物，其包括：碳酸亚烃酯如碳酸亚丙酯或碳酸亚乙酯，过氧化氢和水，以及任选的醇如苄醇。在另一个广泛的方面，他的发明涉及一种除去油漆的方法，其包括：将含有碳酸亚烷基酯，过氧化氢和水的组合物在有效引起油漆起泡或起泡的条件下，一段时间和在有条件的条件下涂覆到涂漆表面上。在另一个广泛的方面，本发明是一种可用作除漆剂的组合物，其包括：任选含有任选含有二醇醚的醇的碳酸二烷基酯，过氧化氢和水。在另一个广泛的方面，本发明是一种除去油漆的方法，其包括：将含有碳酸二烷基酯，过氧化氢和水的组合物在有效引起油漆起泡或起泡的条件下，一段时间和时间施加到涂漆表面上。有利地，本发明的组合物可以包括二元酯（DBE）。

10. 发明授权

US06673212B2 Polymerization-inhibited distillation 失效
标题翻译：聚合抑制蒸馏
公开(公告)号：US06673212B2
公开(公告)日：2004-01-06
申请号：US10127286
申请日：2002-04-22
申请人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum , Ralph M. DiGuilio , Mike W. McKinney
发明人： James R. Machac, Jr. , Edward T. Marquis , Susan A. Woodrum , Ralph M. DiGuilio , Mike W. McKinney
IPC分类号： B01D334
CPC分类号： C07D317/36 , B01D3/34 , C07D317/38 , Y10S203/11
摘要： Identified herein are inhibitors which may be added to the boiling pot portion of a distillation apparatus prior to or during the distillation of an alkylene carbonate. The inhibitors retard the occurrence of undesirable reactions of the alkylene carbonate with itself and impurities present in the pot, and hence greatly reduce or minimize the formation of undesirable by-products which otherwise tend to reduce overall yields of alkylene carbonate recovered by the distillation process. Higher distillation temperatures at higher pressures over the prior art are possible without attendant losses of significant amounts of recovered alkylene carbonate, which confers heretofore unseen flexibility in alkylene carbonate distillation.
摘要翻译：本文所述的是在碳酸亚烷基酯蒸馏之前或期间可以加入到蒸馏装置的沸腾锅部分的抑制剂。抑制剂阻碍碳酸亚烃酯本身和存在于罐中的杂质的不期望的反应的发生，因此大大减少或最小化不期望的副产物的形成，否则倾向于降低由蒸馏过程回收的碳酸亚烃酯的总产率。与现有技术相比，在较高压力下的较高蒸馏温度是可能的，而不需要大量回收的碳酸亚烃酯的损失，这在碳酸亚烷基酯蒸馏中赋予迄今未见的灵活性。

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