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1. 发明申请

US20120022309A1 METHOD FOR PRODUCING AROMATIC HYDROCARBON 审中-公开
标题翻译：生产芳香烃的方法
公开(公告)号：US20120022309A1
公开(公告)日：2012-01-26
申请号：US13146274
申请日：2010-01-15
申请人： Hongtao Ma , Yuji Ogawa
发明人： Hongtao Ma , Yuji Ogawa
IPC分类号： C07C2/76
CPC分类号： B01J38/10 , B01J29/48 , B01J29/90 , B01J2229/32 , B01J2229/42 , C07C2/76 , C07C2529/40 , C10G45/68 , C10G2400/30 , Y02P20/52 , Y02P20/584 , C07C15/04
摘要： [Object] To produce aromatic hydrocarbon stably for a long time maintaining a high aromatic hydrocarbon yield when the aromatic hydrocarbon is produced upon making a contact reaction between lower hydrocarbon and a catalyst.[Solving Means] In a method of producing aromatic hydrocarbon, including repeating a reaction step for obtaining aromatic hydrocarbon upon making a contact reaction between lower hydrocarbon and a catalyst and a regeneration step for regenerating the catalyst used in the reaction step, carbon dioxide in an amount of 0.33 to 1.6% by volume relative to an amount of the lower hydrocarbon is added to the lower hydrocarbon, in the reaction step.
摘要翻译：当在低级烃和催化剂之间进行接触反应制备芳族烃时，长时间稳定地制备芳族烃，保持高的芳族烃产率。 [解决方案]在制备芳族烃的方法中，包括在进行低级烃和催化剂之间的接触反应时重复进行芳烃的反应步骤和用于再生反应步骤中使用的催化剂的再生步骤，在反应步骤中相对于低级烃的量加入到低级烃中的量为0.33〜1.6体积％。

2. 发明申请

US20110288355A1 METHOD FOR PRODUCING AROMATIC HYDROCARBON AND APPARATUS FOR PRODUCING AROMATIC HYDROCARBON 有权
标题翻译：生产芳香烃的方法和制备芳香烃的装置
公开(公告)号：US20110288355A1
公开(公告)日：2011-11-24
申请号：US13146272
申请日：2010-01-15
申请人： Yuji Ogawa , Hongtao Ma
发明人： Yuji Ogawa , Hongtao Ma
IPC分类号： C07C15/04 , B01J8/00
CPC分类号： B01J38/10 , B01J29/48 , B01J29/90 , B01J2229/32 , B01J2229/42 , C07C2/76 , C07C2529/40 , C07C2529/70 , C10G45/68 , C10G45/70 , C10G45/72 , C10G2400/30 , Y02P20/52 , Y02P20/584 , C07C15/04
摘要： To economically regenerate a catalyst and to produce aromatic hydrocarbon stably for a long time maintaining a high aromatic hydrocarbon yield when the aromatic hydrocarbon is produced upon making a contact reaction between lower hydrocarbon and the catalyst.A method of producing aromatic hydrocarbon and an apparatus for producing aromatic hydrocarbon by repeating a reaction step for obtaining aromatic hydrocarbon upon making a contact reaction between lower hydrocarbon and a catalyst and a regeneration step for regenerating the catalyst used in the reaction step. Off-gas which is gas obtained by removing aromatic hydrocarbon produced in the reaction step from discharge gas passing through the reaction step is used as a regeneration gas in the regeneration step.
摘要翻译：为了经济地再生催化剂并长时间稳定地制备芳族烃，当在低级烃和催化剂之间进行接触反应时产生芳族烃时，保持高的芳族烃产率。通过重复在低级烃和催化剂之间进行接触反应获得芳族烃的反应步骤和用于再生反应步骤中使用的催化剂的再生步骤的芳族烃的制备方法和芳香族烃的制造装置。作为在再生工序中的再生气体，使用作为在反应工序中产生的芳香族烃的废气通过反应工序的排出气体而得到的废气。

3. 发明授权

US09358536B2 Method for producing aromatic hydrocarbon and apparatus for producing aromatic hydrocarbon 有权
标题翻译：芳香族烃的制造方法和芳香烃的制造装置
公开(公告)号：US09358536B2
公开(公告)日：2016-06-07
申请号：US13146272
申请日：2010-01-15
申请人： Yuji Ogawa , Hongtao Ma
发明人： Yuji Ogawa , Hongtao Ma
IPC分类号： C07C15/04 , C07C2/76 , B01J38/10 , B01J29/48 , B01J29/90 , C10G45/68 , C10G45/70 , C10G45/72
CPC分类号： B01J38/10 , B01J29/48 , B01J29/90 , B01J2229/32 , B01J2229/42 , C07C2/76 , C07C2529/40 , C07C2529/70 , C10G45/68 , C10G45/70 , C10G45/72 , C10G2400/30 , Y02P20/52 , Y02P20/584 , C07C15/04
摘要： To economically regenerate a catalyst and to produce aromatic hydrocarbon stably for a long time maintaining a high aromatic hydrocarbon yield when the aromatic hydrocarbon is produced upon making a contact reaction between lower hydrocarbon and the catalyst.A method of producing aromatic hydrocarbon and an apparatus for producing aromatic hydrocarbon by repeating a reaction step for obtaining aromatic hydrocarbon upon making a contact reaction between lower hydrocarbon and a catalyst and a regeneration step for regenerating the catalyst used in the reaction step. Off-gas which is gas obtained by removing aromatic hydrocarbon produced in the reaction step from discharge gas passing through the reaction step is used as a regeneration gas in the regeneration step.
摘要翻译：为了经济地再生催化剂并长时间稳定地制备芳族烃，当在低级烃和催化剂之间进行接触反应时产生芳族烃时，保持高的芳族烃产率。通过重复在低级烃和催化剂之间进行接触反应获得芳族烃的反应步骤和用于再生反应步骤中使用的催化剂的再生步骤的芳族烃的制备方法和芳香族烃的制造装置。作为在再生工序中的再生气体，使用作为在反应工序中产生的芳香族烃的废气通过反应工序的排出气体而得到的废气。

4. 发明申请

US20100137125A1 METHOD OF REGENERATING LOWER HYDROCARBON AROMATIZING CATALYST 有权
标题翻译：再生低碳氢化合物催化剂的方法
公开(公告)号：US20100137125A1
公开(公告)日：2010-06-03
申请号：US12594902
申请日：2008-03-17
申请人： Hongtao Ma , Yuji Ogawa
发明人： Hongtao Ma , Yuji Ogawa
IPC分类号： B01J38/10
CPC分类号： B01J29/48 , B01J27/22 , B01J27/28 , B01J29/90 , B01J37/0009 , B01J38/10 , B01J38/12 , B01J2229/12 , B01J2229/123 , B01J2229/18 , B01J2229/32 , B01J2229/42 , C07C2/76 , Y02P20/584 , C07C15/00
摘要： To improve stability of catalytic performance, an aromatizing catalyst for converting lower hydrocarbons into aromatic compounds is regenerated. A regeneration process of the aromatizing catalyst according to the present invention includes the steps of: (a) reacting the aromatizing catalyst with a hydrogen gas in an atmosphere containing the hydrogen gas after using the aromatizing catalyst in an aromatizing reaction for converting lower hydrocarbons into aromatic compounds; (b) decreasing a temperature of the atmosphere containing the hydrogen gas reacted with the aromatizing catalyst, by supplying one of an inert gas and a reducing gas to the atmosphere; (c) reacting the aromatizing catalyst reacted with this inert gas, with an oxidizing gas; and (d) reacting the aromatizing catalyst reacted with the oxidizing gas, with a reducing gas.
摘要翻译：为了提高催化性能的稳定性，再生了将低级烃转化为芳族化合物的芳构化催化剂。根据本发明的芳构化催化剂的再生方法包括以下步骤：（a）使芳构化催化剂在芳族化反应中将低级烃转化为芳族化合物后，使芳构化催化剂与含氢气氛中的氢气反应化合物（b）通过将惰性气体和还原气体中的一种供给到大气中，降低含有与芳构化催化剂反应的氢气的气氛的温度; （c）使与该惰性气体反应的芳构化催化剂与氧化气体反应; 和（d）使与氧化气体反应的芳构化催化剂与还原气体反应。

5. 发明授权

US08853480B2 Method for producing aromatic hydrocarbon 有权
标题翻译：芳烃生产方法
公开(公告)号：US08853480B2
公开(公告)日：2014-10-07
申请号：US13805756
申请日：2011-06-24
申请人： Yuji Ogawa , Hongtao Ma
发明人： Yuji Ogawa , Hongtao Ma
IPC分类号： C07C2/46 , C07C2/42 , C07C2/76
CPC分类号： C07C2/76 , C07C2529/48 , Y02P20/52 , Y02P20/584 , Y10S585/904 , C07C15/04
摘要： When producing an aromatic hydrocarbon by a contact reaction of a lower hydrocarbon with a catalyst, the aromatic hydrocarbon is produced stably for a long time while maintaining a high aromatic hydrocarbon yield. In a process for producing an aromatic hydrocarbon by being equipped with a reaction step for obtaining the aromatic hydrocarbon by a contact reaction of a lower hydrocarbon with a catalyst and a regeneration step for regenerating the catalyst used in this reaction step, and by repeating the reaction step and the regeneration step, yield of the aromatic hydrocarbon is calculated at constant intervals of time. A yield as the standard is set up from this calculated yield. Based on the change of yield relative to this standard, the regeneration time of the regeneration step is prolonged. A threshold value is set up in the change of yield. In case that the change of yield of the aromatic hydrocarbon has been lower than the threshold value in the reaction step, the regeneration time of the regeneration step is prolonged.
摘要翻译：当通过低级烃与催化剂的接触反应生产芳族烃时，长时间稳定地生产芳族烃，同时保持高的芳烃产率。在通过配置通过低级烃与催化剂的接触反应获得芳香族烃的反应步骤和用于再生该反应步骤中使用的催化剂的再生步骤的反应步骤的制备芳烃的方法中，步骤和再生步骤，芳香烃的产率以恒定的时间间隔计算。作为标准的收益率由该计算的收益率设定。基于相对于该标准的产量变化，再生步骤的再生时间延长。在产量变化中建立阈值。在反应步骤中芳族烃的收率变化低于阈值的情况下，再生步骤的再生时间延长。

6. 发明申请

US20130090506A1 METHOD FOR PRODUCING AROMATIC HYDROCARBON 有权
标题翻译：生产芳香烃的方法
公开(公告)号：US20130090506A1
公开(公告)日：2013-04-11
申请号：US13805756
申请日：2011-06-24
申请人： Yuji Ogawa , Hongtao Ma
发明人： Yuji Ogawa , Hongtao Ma
IPC分类号： C07C2/76
CPC分类号： C07C2/76 , C07C2529/48 , Y02P20/52 , Y02P20/584 , Y10S585/904 , C07C15/04
摘要： When producing an aromatic hydrocarbon by a contact reaction of a lower hydrocarbon with a catalyst, the aromatic hydrocarbon is produced stably for a long time while maintaining a high aromatic hydrocarbon yield.In a process for producing an aromatic hydrocarbon by being equipped with a reaction step for obtaining the aromatic hydrocarbon by a contact reaction of a lower hydrocarbon with a catalyst and a regeneration step for regenerating the catalyst used in this reaction step, and by repeating the reaction step and the regeneration step, yield of the aromatic hydrocarbon is calculated at constant intervals of time. A yield as the standard is set up from this calculated yield. Based on the change of yield relative to this standard, the regeneration time of the regeneration step is prolonged. A threshold value is set up in the change of yield. In case that the change of yield of the aromatic hydrocarbon has been lower than the threshold value in the reaction step, the regeneration time of the regeneration step is prolonged.
摘要翻译：当通过低级烃与催化剂的接触反应生产芳族烃时，长时间稳定地生产芳族烃，同时保持高的芳烃产率。在通过配置通过低级烃与催化剂的接触反应获得芳香族烃的反应步骤和用于再生该反应步骤中使用的催化剂的再生步骤的反应步骤的制备芳烃的方法中，步骤和再生步骤，芳香烃的产率以恒定的时间间隔计算。作为标准的收益率由该计算的收益率设定。基于相对于该标准的产量变化，再生步骤的再生时间延长。在产量变化中建立阈值。在反应步骤中芳族烃的收率变化低于阈值的情况下，再生步骤的再生时间延长。

7. 发明申请

US20110172478A1 CATALYST FOR AROMATIZATION OF LOWER HYDROCARBON, AND PROCESS FOR PRODUCTION OF AROMATIC COMPOUND 审中-公开
标题翻译：低碳氢化合物催化剂及芳香化合物生产方法
公开(公告)号：US20110172478A1
公开(公告)日：2011-07-14
申请号：US13058413
申请日：2009-06-18
申请人： Hongtao Ma , Yuji Ogawa
发明人： Hongtao Ma , Yuji Ogawa
IPC分类号： C07C2/00 , B01J21/06 , B01J29/48
CPC分类号： B01J29/48 , B01J35/0013 , B01J2229/186 , C07C2/76 , C07C2529/40 , C07C2529/48 , C07C15/00
摘要： [Object] To improve the yield of aromatic hydrocarbon and the stability of active life in a process for producing aromatic compound by using a lower hydrocarbon aromatization catalyst.[Solving Means] A lower hydrocarbon aromatization catalyst for producing aromatic compound under reaction of lower hydrocarbon has an average crystal diameter of not larger than 500 nm. A catalyst in which molybdenum is carried on ZSM-5 zeolite as metallosilicate is used as an example of the above-mentioned catalyst. Additionally, a process for producing aromatic compound upon contact of the above-mentioned catalyst with a reaction gas containing lower hydrocarbon is provided.
摘要翻译：通过使用低级烃芳构化催化剂，在芳族化合物的制造方法中提高芳香族烃的收率和活性寿命的稳定性。 [解决方案]用于在低级烃反应下制备芳族化合物的低级烃芳构化催化剂具有不大于500nm的平均晶体直径。使用钼作为金属硅酸盐的ZSM-5沸石载持的催化剂作为上述催化剂的实例。此外，提供了在与上述催化剂与含有低级烃的反应气体接触时制备芳族化合物的方法。

8. 发明申请

US20130012747A1 METHOD OF MANUFACTURE OF AROMATIC COMPOUND 审中-公开
标题翻译：芳香化合物的制备方法
公开(公告)号：US20130012747A1
公开(公告)日：2013-01-10
申请号：US13636257
申请日：2011-02-10
申请人： Hongtao Ma , Yo Yamamoto , Yuji Ogawa
发明人： Hongtao Ma , Yo Yamamoto , Yuji Ogawa
IPC分类号： C07C2/76 , C07C5/41
CPC分类号： B01J29/48 , B01J29/082 , B01J29/084 , B01J29/40 , B01J29/7038 , B01J29/83 , B01J29/90 , B01J38/02 , B01J38/10 , B01J2229/186 , C01B3/38 , C01B2203/0238 , C01B2203/0277 , C01B2203/1047 , C07C2/76 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/16 , C07C2523/02 , C07C2523/04 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2529/08 , C07C2529/16 , C07C2529/40 , C07C2529/48 , Y02P20/142 , Y02P20/52 , Y02P20/584 , C07C15/04 , C07C15/24
摘要： In manufacturing aromatic hydrocarbons by causing a contact reaction between a lower hydrocarbon and a catalyst, the aromatic hydrocarbons are stably produced over a long period of time while maintaining high aromatic hydrocarbon yields. The process includes a reaction process of initiating the contact reaction between the lower hydrocarbon and the catalyst thereby obtaining the aromatic hydrocarbons and hydrogen, and a regeneration process of regenerating the catalytic activity by bringing hydrogen into contact with the catalyst used in the reaction process. The reaction process and the regeneration process are repeated thereby producing the aromatic hydrocarbons and hydrogen. In the reaction process, carbon monoxide is added to the lower hydrocarbons and additionally a reaction temperature is set at higher than 800° C.
摘要翻译：在通过引入低级烃和催化剂之间的接触反应来制造芳族烃时，芳族烃在长时间内稳定地产生，同时保持高的芳族烃产率。该方法包括引发低级烃和催化剂之间的接触反应从而获得芳族烃和氢的反应过程，以及通过使氢与反应过程中使用的催化剂接触而再生催化活性的再生方法。重复反应过程和再生过程，从而产生芳烃和氢。在反应过程中，将一氧化碳加入到低级烃中，另外反应温度设定在高于800℃

9. 发明授权

US08735310B2 Method of regenerating lower hydrocarbon aromatizing catalyst 有权
标题翻译：再生低级烃芳构化催化剂的方法
公开(公告)号：US08735310B2
公开(公告)日：2014-05-27
申请号：US12594902
申请日：2008-03-17
申请人： Hongtao Ma , Yuji Ogawa
发明人： Hongtao Ma , Yuji Ogawa
IPC分类号： C07C15/02
CPC分类号： B01J29/48 , B01J27/22 , B01J27/28 , B01J29/90 , B01J37/0009 , B01J38/10 , B01J38/12 , B01J2229/12 , B01J2229/123 , B01J2229/18 , B01J2229/32 , B01J2229/42 , C07C2/76 , Y02P20/584 , C07C15/00
摘要： To improve stability of catalytic performance, an aromatizing catalyst for converting lower hydrocarbons into aromatic compounds is regenerated. A regeneration process of the aromatizing catalyst according to the present invention includes the steps of: (a) reacting the aromatizing catalyst with a hydrogen gas in an atmosphere containing the hydrogen gas after using the aromatizing catalyst in an aromatizing reaction for converting lower hydrocarbons into aromatic compounds; (b) decreasing a temperature of the atmosphere containing the hydrogen gas reacted with the aromatizing catalyst, by supplying one of an inert gas and a reducing gas to the atmosphere; (c) reacting the aromatizing catalyst reacted with this inert gas, with an oxidizing gas; and (d) reacting the aromatizing catalyst reacted with the oxidizing gas, with a reducing gas.
摘要翻译：为了提高催化性能的稳定性，再生了将低级烃转化为芳族化合物的芳构化催化剂。根据本发明的芳构化催化剂的再生方法包括以下步骤：（a）使芳构化催化剂在芳族化反应中将低级烃转化为芳族化合物后，使芳构化催化剂与含氢气氛中的氢气反应化合物（b）通过将惰性气体和还原气体中的一种供给到大气中，降低含有与芳构化催化剂反应的氢气的气氛的温度; （c）使与该惰性气体反应的芳构化催化剂与氧化气体反应; 和（d）使与氧化气体反应的芳构化催化剂与还原气体反应。

10. 发明授权

US08278237B2 Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds 有权
标题翻译：用于低级烃芳构化的催化剂和用于生产芳族化合物的方法
公开(公告)号：US08278237B2
公开(公告)日：2012-10-02
申请号：US12524029
申请日：2008-02-13
申请人： Shinichi Yamada , Tomohiro Yamada , Yuji Ogawa , Hirokazu Akiyama , Takuya Hatagishi
发明人： Shinichi Yamada , Tomohiro Yamada , Yuji Ogawa , Hirokazu Akiyama , Takuya Hatagishi
IPC分类号： B01J29/06 , C07C2/52 , C07C15/00
CPC分类号： C10G45/68 , B01J21/16 , B01J23/885 , B01J29/0308 , B01J29/041 , B01J29/076 , B01J29/40 , B01J29/48 , B01J29/7876 , B01J35/023 , B01J37/0201 , B01J37/088 , B01J37/18 , B01J2229/12 , B01J2229/123 , B01J2229/32 , B01J2229/40 , C01B3/40 , C01B2203/02 , C01B2203/1241 , C07C2/76 , C10G2400/30 , Y02P20/52 , C07C15/02
摘要： A catalyst for producing aromatic compounds from lower hydrocarbons while improving activity life stability of methane conversion rate; benzene formation rate; naphthalene formation rate; and total formation rate of benzene, toluene and xylene is formed by loading molybdenum and copper on metallo-silicate serving as a substrate and then calcining the metallo-silicate. When the catalyst is reacted with a reaction gas containing lower hydrocarbons and carbonic acid gas, aromatic compounds are produced. In order to obtain the catalyst, it is preferable that molybdenum and copper are loaded on zeolite formed of metallo-silicate after the zeolite is treated with a silane compound larger than a pore of the zeolite in diameter and having an amino group and a straight-chain hydrocarbon group, the amino group being able to selectively react with the zeolite at a Bronsted acid point of the zeolite. It is preferable that a loaded amount of molybdenum is within a range of from 2 to 12 wt. % based on total amount of the calcined catalyst while copper is loaded at a copper to molybdenum molar ratio of 0.01 to 0.8.
摘要翻译：一种用于从低级烃生产芳族化合物的催化剂，同时提高甲烷转化率的活性寿命稳定性; 苯形成率; 萘形成率; 苯，甲苯和二甲苯的总形成速率是通过将钼和铜负载在作为基底的金属硅酸盐上，然后煅烧金属硅酸盐而形成的。当催化剂与含有低级烃和碳酸气体的反应气体反应时，产生芳族化合物。为了得到催化剂，优选在沸石用直径大于沸石孔的硅烷化合物进行处理并具有氨基和直链状烷基的情况下，将钼和铜负载在由金属硅酸盐形成的沸石上，链烷烃基，该氨基能够在沸石的布朗斯台德酸点处与沸石选择性反应。钼的负载量优选在2〜12重量％的范围内。基于煅烧催化剂的总量的％，而铜以铜与钼的摩尔比为0.01至0.8。

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