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    • 2. 发明授权
    • Paint substitute film
    • 油漆替代胶片
    • US07320824B2
    • 2008-01-22
    • US10734297
    • 2003-12-15
    • Hitoshi OhganeKeisuke Kojima
    • Hitoshi OhganeKeisuke Kojima
    • B32B7/12C08K3/40
    • B32B27/08B32B27/20C08K3/08C08K3/40C09D5/36C09D7/61C09D7/69Y10T428/28
    • A paint substitute film 1 is provided which has an excellent property that permits universal application to a variety of components, for example to a complexly shaped component, without decreasing marketability of the component due to undesirable change in color. The paint substitute film 1 includes a color coat 3 which contains metallic pigments 5 and orientation inhibitors 6 for inhibiting orientation of the metallic pigments 5. When the paint substitute film 1 is bonded onto an exterior component of an automobile or the like, the paint substitute film 1 is drawn, but the orientation inhibitors 6 each serve as an obstacle to prevent the metallic pigments 5 from being uniformly oriented toward a direction parallel to the drawing direction. Accordingly, even after the paint substitute film 1 is drawn, rays of light incident on the film 1 diffuses upon reflection off the metallic pigments 5, and thus unfavorable alteration of color in the film 1 can be prevented.
    • 提供一种涂料替代膜1,其具有优异的性能,其允许通用地应用于各种部件,例如复合形状的部件,而不会由于不期望的颜色变化而降低部件的可销售性。 涂料替代膜1包括着色涂层3,其包含用于抑制金属颜料5的取向的金属颜料5和取向抑制剂6.当涂料替代膜1粘合到汽车等的外部组分上时,涂料替代物 拉伸膜1,但是取向抑制剂6各自作为阻止金属颜料5均匀地朝向与拉拔方向平行的方向的障碍。 因此,即使在涂料替代膜1被抽出之后,入射到膜1上的光线从金属颜料5反射而扩散,因此可以防止膜1中颜色的不利改变。
    • 4. 发明授权
    • Method for producing chlorinated hyperbranched polymer
    • 生产氯化超支化聚合物的方法
    • US09243084B2
    • 2016-01-26
    • US14003911
    • 2012-03-02
    • Hideo NagashimaKeisuke KojimaAkihiro TanakaKeisuke OdoiOsamu Uesugi
    • Hideo NagashimaKeisuke KojimaAkihiro TanakaKeisuke OdoiOsamu Uesugi
    • C08F8/20C08F8/18
    • C08F8/20C08F8/18C08G83/006
    • There is provided a novel production method of a chlorinated hyperbranched polymer that is optically stable and is capable of derivatizing the chlorinated hyperbranched polymer into various compounds. A production method of a chlorinated hyperbranched polymer for producing a chlorinated hyperbranched polymer of Formula (1): {where X is a chlorine atom; R1 is a hydrogen atom or a methyl group; and A1 is a phenylene-alkylene group, n is the number of repeating unit structures and is an integer of 2 to 100,000}, comprising the step of substituting a dithiocarbamate group of a hyperbranched polymer of Formula (3): (where R1, A1, and n are the same as defined in Formula (1); and each of R2 and R3 is a C1-5 alkyl group, a C1-5 hydroxyalkyl group, or a C7-12 arylalkyl group, or R2 and R3 optionally form a ring together with a nitrogen atom bonded to R2 and R3) with a chlorine atom using sulfuryl chloride.
    • 提供了一种光学稳定且能将氯化超支化聚合物衍生成各种化合物的氯化超支化聚合物的新型制备方法。 用于制备式(1)的氯化超支化聚合物的氯化超支化聚合物的制备方法:其中X是氯原子; R1是氢原子或甲基; A1是亚苯基 - 亚烷基,n是重复单元结构的数量,为2〜100,000的整数},包括用式(3)的超支化聚合物的二硫代氨基甲酸酯基取代的步骤:(其中R1,A1 和n与式(1)中所定义相同; R 2和R 3各自为C 1-5烷基,C 1-5羟基烷基或C 7-12芳烷基,或者R 2和R 3可任选地形成 与使用磺酰氯的氯原子与R2和R3键合的氮原子一起环。
    • 9. 发明申请
    • METHOD FOR PRODUCING CHLORINATED HYPERBRANCHED POLYMER
    • 生产氯化聚合物聚合物的方法
    • US20140073744A1
    • 2014-03-13
    • US14003911
    • 2012-03-02
    • Hideo NagashimaKeisuke KojimaAkihiro TanakaKeisuke OdoiOsamu Uesugi
    • Hideo NagashimaKeisuke KojimaAkihiro TanakaKeisuke OdoiOsamu Uesugi
    • C08F8/20
    • C08F8/20C08F8/18C08G83/006
    • There is provided a novel production method of a chlorinated hyperbranched polymer that is optically stable and is capable of derivatizing the chlorinated hyperbranched polymer into various compounds. A production method of a chlorinated hyperbranched polymer for producing a chlorinated hyperbranched polymer of Formula (1): {where X is a chlorine atom; R1 is a hydrogen atom or a methyl group; and A1 is a phenylene-alkylene group, n is the number of repeating unit structures and is an integer of 2 to 100,000}, comprising the step of substituting a dithiocarbamate group of a hyperbranched polymer of Formula (3): (where R1, A1, and n are the same as defined in Formula (1); and each of R2 and R3 is a C1-5 alkyl group, a C1-5 hydroxyalkyl group, or a C7-12 arylalkyl group, or R2 and R3 optionally form a ring together with a nitrogen atom bonded to R2 and R3) with a chlorine atom using sulfuryl chloride.
    • 提供了一种光学稳定且能将氯化超支化聚合物衍生成各种化合物的氯化超支化聚合物的新型制备方法。 用于制备式(1)的氯化超支化聚合物的氯化超支化聚合物的制备方法:其中X是氯原子; R1是氢原子或甲基; A1是亚苯基 - 亚烷基,n是重复单元结构的数量,为2〜100,000的整数},包括用式(3)的超支化聚合物的二硫代氨基甲酸酯基取代的步骤:(其中R1,A1 和n与式(1)中所定义相同; R 2和R 3各自为C 1-5烷基,C 1-5羟基烷基或C 7-12芳烷基,或者R 2和R 3可任选地形成 与使用磺酰氯的氯原子与R2和R3键合的氮原子一起环。