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    • 7. 发明申请
    • SOLID POLYMER ELECTROLYTE MEMBRANE AND FUEL CELL USING THE SAME
    • 固体聚合物电解质膜和使用它的燃料电池
    • US20140093792A1
    • 2014-04-03
    • US13957952
    • 2013-08-02
    • Hitachi, Ltd.
    • Yoshiyuki TAKAMORIAtsuhiko ONUMA
    • H01M8/10
    • H01M8/1044H01M2008/1095H01M2300/0082H01M2300/0088
    • A solid polymer electrolyte membrane is provided that is inexpensive, and is excellent in the ionic conductivity characteristics, the methanol crossover characteristics and the mechanical characteristics. The solid polymer electrolyte membrane contains a block copolymer A containing a hydrophilic segment having an ion exchange group and a hydrophobic segment, and a block copolymer B containing a hydrophilic segment having an ion exchange group and a hydrophobic segment and having a smaller ion exchange capacity than the block copolymer A, and has a structure where a region A having the block copolymer A agglomerated therein is dispersed in a matrix constituted by a region B having the block copolymer B agglomerated therein, with a microscopic phase-separated structure having a period of from 10 to 100 nm being formed in the region A and the region B.
    • 提供廉价的固体聚合物电解质膜,并且离子电导率特性,甲醇交叉特性和机械特性优异。 固体高分子电解质膜含有含有具有离子交换基团和疏水性链段的亲水性链段的嵌段共聚物A和含有离子交换基团和疏水性链段的离子交换容量小的离子交换容量的嵌段共聚物B, 嵌段共聚物A,并且具有将其中附聚有嵌段共聚物A的区域A分散在由嵌段共聚物B聚集的区域B构成的基质中的结构,其中微观相分离结构的周期为 在区域A和区域B中形成10至100nm。