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1. 发明授权

US5817165A Fluorine-containing polyimide gas separation membrane and method of manufacturing the same 失效
标题翻译：含氟聚酰亚胺气体分离膜及其制造方法
公开(公告)号：US5817165A
公开(公告)日：1998-10-06
申请号：US663509
申请日：1996-06-13
申请人： Hisao Hachisuka , Masatoshi Maeda , Kenichi Ikeda
发明人： Hisao Hachisuka , Masatoshi Maeda , Kenichi Ikeda
IPC分类号： B01D53/22 , B01D67/00 , B01D71/64 , C08G73/10
CPC分类号： C08G73/1064 , B01D53/228 , B01D67/0011 , B01D67/0013 , B01D71/64 , C08G73/1039 , B01D2323/30 , B01D2325/022 , B01D2325/026 , B01D2325/26 , Y10S55/05
摘要： A fluorine-containing polyimide gas separation membrane which is pinhole-free, uniform over a large area, and has a high permeability and a high separation factor .alpha. is provided. A polyimide resin is dissolved in at least one solvent selected from the group consisting of an organic solvent (A) or (B). The organic solvent (A) has a dielectric constant of 30 or less and a dipole moment of 3.0 D or less. The organic solvent (B) mainly contains an organic solvent having at least one ether bonding in the molecular unit. In the next step, the polyimide resin is dipped in a solvent (C) in order for desolvation. The solvent (C) does not dissolve the fluorine-containing polyimide resin while it is miscible with the organic solvent (A) or (B). As a result, an asymmetric gas separation membrane is formed. The fluorine-containing polyimide resin layer comprises a skin layer the thickness L.sub.1 thereof is about 40 nm and a sponge like layer the thickness L.sub.2 thereof is about 30 .mu.m. The membrane is formed on a supporter of, for example, a nonwoven cloth.
摘要翻译：提供了一种无孔无孔，大面积均匀，且具有高透过率和高分离因子α的含氟聚酰亚胺气体分离膜。将聚酰亚胺树脂溶解在选自有机溶剂（A）或（B）中的至少一种溶剂中。有机溶剂（A）的介电常数为30以下，偶极矩为3.0D以下。有机溶剂（B）主要含有在分子单元中具有至少一个醚键的有机溶剂。在下一步骤中，将聚酰亚胺树脂浸渍在溶剂（C）中以进行去溶剂化。溶剂（C）在与有机溶剂（A）或（B）可混溶时不溶解含氟聚酰亚胺树脂。结果，形成不对称气体分离膜。含氟聚酰亚胺树脂层的厚度L1约为40nm，海绵状层的厚度L2约为30μm。该膜形成在例如非织造布的支撑物上。

2. 发明授权

US5336409A Composite reverse osmosis membrane and novel acid chloride 失效
标题翻译：复合反渗透膜和新型酰氯
公开(公告)号：US5336409A
公开(公告)日：1994-08-09
申请号：US7763
申请日：1993-01-22
申请人： Hisao Hachisuka , Katsuhide Kojima , Yutaka Nakazono , Mitsuru Shimizu , Masahiko Hirose , Yasuo Kihara , Masatoshi Maeda , Hisashi Ikebata , Kenji Matsumoto
发明人： Hisao Hachisuka , Katsuhide Kojima , Yutaka Nakazono , Mitsuru Shimizu , Masahiko Hirose , Yasuo Kihara , Masatoshi Maeda , Hisashi Ikebata , Kenji Matsumoto
IPC分类号： B01D69/12 , B01D71/56 , C07C61/29 , C08G69/26
CPC分类号： C07C61/29 , B01D69/125 , B01D71/56 , C08G69/26
摘要： A composite reverse osmosis membrane comprising a thin membrane and a microporous supporting membrane supporting it, wherein said thin membrane mainly comprises a crosslinked polyamide comprising; (a) an amine component containing at least one member selected from the group consisting of substantially monomeric amine compounds each having at least two primary and/or secondary amino groups, and (b) an acid halide component containing at least one member selected from the group consisting of substantially monomeric cyclic acid halide compounds each having at least two acid halide groups and comprising at least two rings.
摘要翻译：一种复合反渗透膜，包括薄膜和支撑其的微孔支撑膜，其中所述薄膜主要包含交联聚酰胺，其包含：（a）含有至少一种选自基本上单体的胺化合物的胺成分，所述基本上单体胺化合物各自具有至少两个伯和/或仲氨基，和（b）含有至少一种选自由基本上单体的环状酰卤化合物组成，每个化合物具有至少两个酰卤基并且包含至少两个环。

3. 发明授权

US5510527A Acid chloride 失效
标题翻译：酰氯
公开(公告)号：US5510527A
公开(公告)日：1996-04-23
申请号：US202121
申请日：1994-02-25
申请人： Hisao Hachisuka , Katsuhide Kojima , Yutaka Nakazono , Masahiko Hirose , Yasuo Kihara , Masatoshi Maeda , Hisashi Ikebata , Kenji Matsumoto
发明人： Hisao Hachisuka , Katsuhide Kojima , Yutaka Nakazono , Masahiko Hirose , Yasuo Kihara , Masatoshi Maeda , Hisashi Ikebata , Kenji Matsumoto
IPC分类号： B01D69/12 , B01D71/56 , C07C61/29 , C08G69/26
CPC分类号： C07C61/29 , B01D69/125 , B01D71/56 , C08G69/26
摘要： An acid chloride, bicyclo 2,2,2!oct-7ene-(2.alpha.,3.beta.,5.alpha.,6.beta.)tetracarbonyl chloride (C.sub.12 H.sub.8 O.sub.4 Cl.sub.4) represented by the following formula: ##STR1##
摘要翻译：由下式表示的酰氯，双环[2,2,2]辛-7-烯 - （2α，3β，5α，6β）四羰基氯（C 12 H 8 O 4 Cl 4）

4. 发明授权

US5709733A Gas separation method 失效
标题翻译：气体分离法
公开(公告)号：US5709733A
公开(公告)日：1998-01-20
申请号：US654570
申请日：1996-05-29
申请人： Hisao Hachisuka , Kenichi Ikeda , Kenichi Inoue
发明人： Hisao Hachisuka , Kenichi Ikeda , Kenichi Inoue
IPC分类号： B01D53/22 , B01D69/02
CPC分类号： B01D53/228 , B01D2257/504 , Y02C10/10
摘要： A method of separating a gas, especially carbon dioxide, from a gas mixture of the gas and nitrogen at a low temperature of -20.degree. C. to 50.degree. C. using a gas separation membrane permeable to the gas, including the step of cooling the gas mixture using at least one cooling medium selected from the group consisting of liquefied petroleum gas and liquefied natural gas. The liquefied petroleum gas comprises at least one selected from the group consisting of propane gas and butane gas in an amount of more than 50 vol. %. The gas separation membrane has a CO.sub.2 permeation rate of 1.times.10.sup.-4 to 5.times.10.sup.-2 N cm.sup.3 /(cm.sup.2 cm Hg sec) at 25.degree. C. and a CO.sub.2 /N.sub.2 separation factor of 10 to 200 at 25.degree. C.
摘要翻译：一种使用可渗透气体的气体分离膜，在-20℃至50℃的低温下将气体，特别是二氧化碳从气体和氮气的气体混合物分离的方法，包括冷却步骤所述气体混合物使用选自由液化石油气和液化天然气组成的组中的至少一种冷却介质。液化石油气包含选自丙烷气体和丁烷气体中的至少一种，其量大于50体积％。％。气体分离膜在25℃下的CO 2渗透速率为1×10 -4〜5×10 -2 cm 3 /（cm 2·cm Hg·秒），25℃时的CO 2 / N 2分离系数为10〜200。

5. 发明授权

US06413425B1 Reverse osmosis composite membrane and reverse osmosis treatment method for water using the same 失效
标题翻译：反渗透复合膜和反渗透处理方法为水使用相同
公开(公告)号：US06413425B1
公开(公告)日：2002-07-02
申请号：US09055555
申请日：1998-04-06
申请人： Hisao Hachisuka , Kenichi Ikeda
发明人： Hisao Hachisuka , Kenichi Ikeda
IPC分类号： B01D7156
CPC分类号： B01D67/0088 , B01D69/00 , B01D69/125 , B01D71/56 , C02F1/441 , Y02A20/131
摘要： A reverse osmosis composite membrane comprises a sponge layer, and a separation layer formed on a surface of the sponge layer, wherein at least one substance selected from the group consisting of an electrically neutral organic substance and an electrically neutral polymer is present in the separation layer or a surface of the separation layer is coated with at least one substance selected from the group consisting of an electrically neutral organic substance and an electrically neutral polymer, and wherein the specific surface area of the layer in which the at least one substance is present or the separation layer before the surface coating is in the range of 2 to 1,000. The reverse osmosis composite membrane has a high salt rejection, a high water permeability, and a high fouling tolerance, and permits practical desalination at a relatively low pressure.
摘要翻译：反渗透复合膜包括海绵层和形成在海绵层的表面上的分离层，其中选自电中性有机物质和电中性聚合物的至少一种物质存在于分离层或者分离层的表面涂覆有选自电中性有机物质和电中性聚合物的至少一种物质，并且其中存在至少一种物质的层的比表面积或在表面涂布之前的分离层在2至1,000的范围内。反渗透复合膜具有高的拒水性，高透水性和高的耐污性，并且在相对低的压力下允许实际的脱盐。

6. 发明授权

US06177011B1 Composite reverse osmosis membrane having a separation layer with polyvinyl alcohol coating and method of reverse osmotic treatment of water using the same 失效
标题翻译：具有聚乙烯醇涂层分离层的复合反渗透膜和使用其的反渗透处理方法
公开(公告)号：US06177011B1
公开(公告)日：2001-01-23
申请号：US09077768
申请日：1998-06-03
申请人： Hisao Hachisuka , Kenichi Ikeda
发明人： Hisao Hachisuka , Kenichi Ikeda
IPC分类号： B01D6102
CPC分类号： B01D67/0088 , B01D69/125 , C02F1/441 , Y02A20/131
摘要： A reverse osmosis composite membrane that has a high salt rejection, a high water permeability, and a high fouling tolerance, and permits practical desalination at a relatively low pressure is provided by coating the surface of a reverse osmosis membrane of aromatic polyamide with polyvinyl alcohol (PVA), for example, and controlling the surface zeta potential of the separation layer within±10 mV at pH 6. This reverse osmosis composite membrane is electrically neutral and controls the electrical adsorption of membrane-fouling substances having a charge group present in water. Therefore, a high separation property can be maintained without fouling the membrane even if water containing a surfactant or a transition metal component is supplied as raw water.
摘要翻译：通过将芳香族聚酰胺的反渗透膜的表面用聚乙烯醇涂布，提供具有高的耐盐析性，高透水性和高耐污染性并且在相对低的压力下实现脱盐的反渗透复合膜（ PVA），并且在pH6下将分离层的表面ζ电位控制在±10mV内。该反渗透复合膜是电中性的，并且控制具有存在于水中的电荷基团的膜污染物质的电吸附。因此，即使供给含有表面活性剂或过渡金属成分的水作为原水，也可以保持高分离性，而不会使膜污染。

7. 发明授权

US5859182A Fluorine-containing polyquinazolone polymer and separation membrane using the same 失效
标题翻译：含氟聚喹唑酮聚合物和使用其的分离膜
公开(公告)号：US5859182A
公开(公告)日：1999-01-12
申请号：US803981
申请日：1997-02-21
申请人： Hisao Hachisuka , Kenichi Ikeda
发明人： Hisao Hachisuka , Kenichi Ikeda
IPC分类号： B01D71/62 , C08G73/06 , C08G73/24
CPC分类号： C08G73/0694 , B01D71/62
摘要： A fluorine-containing polyquinazolone polymer having a bisquinazolone unit represented by Formula 1 as the repeating unit is used for a gas separation membrane so that great chemical and heat resistance is provided. The membrane also has great permeability and effective separability, as well as excellent mechanical strength. ##STR1## where R.sub.1 indicates a tetravalent organic group, R.sub.2 respectively indicate an alkyl group or an aromatic group, R.sub.3 indicates a divalent organic group, and R.sub.1 and/or R.sub.3 indicates an organic group having at least one fluorine atom.
摘要翻译：将由式1表示的双喹唑酮单元作为重复单元的含氟聚喹唑酮聚合物用于气体分离膜，从而提供极好的耐化学性和耐热性。该膜还具有很好的渗透性和有效的可分离性，以及优异的机械强度。式1其中R1表示四价有机基团，R2分别表示烷基或芳基，R3表示二价有机基团，R 1和/或R 3表示具有至少一个氟原子的有机基团。

8. 发明授权

US6026968A Reverse osmosis composite membrane 失效
标题翻译：反渗透复合膜
公开(公告)号：US6026968A
公开(公告)日：2000-02-22
申请号：US855336
申请日：1997-05-13
申请人： Hisao Hachisuka , Kenichi Ikeda
发明人： Hisao Hachisuka , Kenichi Ikeda
IPC分类号： B01D67/00 , B01D69/12 , B01D71/56 , B01D71/68 , B01D29/00
CPC分类号： B01D67/0088 , B01D69/12 , B01D69/125 , B01D71/56 , B01D71/68
摘要： A reverse osmosis composite membrane comprising at least a porous support membrane layer and a separation layer, wherein a water-insoluble polymer layer having an anionic hydrophilic group formed on the surface of the separation layer is provided. Therefore, it has high anion property, high salt rejection, high water permeability, and chlorine tolerance, and can perform practical desalination under relatively low pressure.
摘要翻译：一种反渗透复合膜，其至少具有多孔性支持膜层和分离层，其中，在所述分离层的表面形成有具有阴离子性亲水基团的水不溶性聚合物层。因此，具有高阴离子性，高脱盐性，高透水性和耐氯性，可在相对较低的压力下进行实用的脱盐。

9. 发明授权

US5910357A Separation membrane and method of producing the same, and shape memory polymer composition 失效
标题翻译：分离膜及其制造方法，以及形状记忆聚合物组合物
公开(公告)号：US5910357A
公开(公告)日：1999-06-08
申请号：US889761
申请日：1997-07-10
申请人： Hisao Hachisuka , Yoshihiko Kondo , Kenichi Ikeda , Hitoshi Takano , Amane Mochizuki
发明人： Hisao Hachisuka , Yoshihiko Kondo , Kenichi Ikeda , Hitoshi Takano , Amane Mochizuki
IPC分类号： B01D39/16 , B01D69/02 , B01D71/54 , B01D39/00 , B01D39/14
CPC分类号： B01D69/02 , B01D39/1692 , B01D71/54 , Y10T428/249978
摘要： A separation membrane and a method of producing the membrane are provided. The membrane can control its permselectivity and its fouled pores can be easily washed by using the reversible shape change of the membrane. For this purpose, porous shape memory polymers are used for the separation membrane.
摘要翻译：提供分离膜和制造膜的方法。膜可以控制其选择性，并且可以通过使用膜的可逆形状来容易地洗涤其污染的孔。为此，多孔形状记忆聚合物用于分离膜。

10. 发明授权

US5811196A Laminated asymmetric membrane and method for manufacturing the same 失效
标题翻译：层压不对称膜及其制造方法
公开(公告)号：US5811196A
公开(公告)日：1998-09-22
申请号：US803982
申请日：1997-02-21
申请人： Hisao Hachisuka , Kenichi Ikeda
发明人： Hisao Hachisuka , Kenichi Ikeda
IPC分类号： B01D69/12 , B01D71/64 , B01D71/70 , C08G73/10 , C08G77/04 , D06N3/18 , D06N7/00 , B32B27/00
CPC分类号： B01D71/64 , B01D69/12 , Y10T428/31507 , Y10T428/31511 , Y10T428/31533 , Y10T428/3154 , Y10T428/31721 , Y10T428/31725
摘要： A laminated asymmetric membrane comprising first and second asymmetric membranes having different molecular structures, in which the first and second asymmetric membranes are laminated. Consequently, the laminated asymmetric membrane having the excellent property of the separation and permeability can be provided at a low cost. The laminated asymmetric membranes of the present invention is manufactured by the following steps: a film-forming dope (1) was prepared by synthesizing fluorine-containing polyimide having a repeating unit expressed by the following Chemical Formula by using diethylene glycol dimethyl ether as a solvent; a film-forming dope (2) was prepared by dissolving polysulfone in diethylene glycol dimethyl ether; the dope (2) from the resulted two dopes was cast on a polyester nonwoven cloth to a thickness of approximately 50 .mu.m by means of an applicator; the dope (1) was lap coated thereon to a thickness of 30 .mu.m; the dope (2) on which the dope (1) is coated was dipped in water as a solidifying solution at a temperature of 25.degree. C. for 5 minutes and in a water at a temperature of 20.degree. C. for one hour, thus forming a laminated asymmetric membrane. Chemical Formula ##STR1##
摘要翻译：一种层压的不对称膜，包括具有不同分子结构的第一和第二不对称膜，其中层压第一和第二不对称膜。因此，可以以低成本提供具有优异的分离性和渗透性的层压不对称膜。本发明的层压非对称膜通过以下步骤制造：通过使用二甘醇二甲醚作为溶剂合成具有由以下化学式表示的重复单元的含氟聚酰亚胺来制备成膜原液（1） ; 通过将聚砜溶解在二甘醇二甲醚中制备成膜原液（2）; 将所得到的两种涂料的涂料（2）通过涂布器浇铸在聚酯无纺布上至约50μm的厚度; 将涂布液（1）在其上铺上厚度为30μm; 将涂布液（1）的涂布液（2）作为固化液在25℃的温度下浸渍5分钟，在20℃的水中浸渍1小时，形成层压不对称膜。化学式 + TR

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