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    • 2. 发明授权
    • Vinyl chloride resin composition
    • 氯乙烯树脂组合物
    • US06204327B1
    • 2001-03-20
    • US09147076
    • 1999-04-27
    • Akira TakakiShinichi YauchiKoji YuiRiichi NishimuraKentaro Takesada
    • Akira TakakiShinichi YauchiKoji YuiRiichi NishimuraKentaro Takesada
    • C08L5104
    • C08L27/06C08L51/003C08L51/04C08L51/06C08L2666/24C08L2666/02
    • A vinyl chloride resin composition containing a graft copolymer A having an average particle diameter of at least 0.15 &mgr;m, prepared by polymerizing 50 to 90% of a solid matter of a rubber latex having a glass transition temperature of at most O° C., the rubber latex being prepared by polymerizing 50 to 100% of butadiene and/or alkyl acrylate, 0 to 40% of an aromatic vinyl monomer, 0 to 10% of a vinyl monomer and 0 to 5% of a polyfunctional monomer, with 10 to 50% of a mixture comprising 10 to 100% of an alkyl methacrylate, 0 to 90% of an aromatic vinyl monomer, 0 to 25% of a vinyl cyamide monomer and 0 to 20% of a vinyl monomer; a graft copolymer B having an average particle diameter of 0.05 to 0.13 &mgr;m, prepared by polymerizing 50 to 90% of the solid matter of the rubber latex with 10 to 50% of the mixture; and a vinyl chloride resin C; wherein the weight ratio of (copolymer A)/(copolymer B) is 50/50 to 90/15, and the weight ratio of (the total amount of copolymer A and copolymer B)/(vinyl chloride resin composition C) is 1/99 to 30/70; the composition being excellent in impact resistance and usable for the production of a pipe, a window frame and the like.
    • 一种氯乙烯树脂组合物,其含有平均粒径为0.15μm以上的接枝共聚物A,其通过聚合50〜90%的玻璃化转变温度为0℃以下的橡胶胶乳的固体成分, 橡胶胶乳通过将50至100%的丁二烯和/或丙烯酸烷基酯,0至40%的芳族乙烯基单体,0至10%的乙烯基单体和0至5%的多官能单体聚合而制备,其中10至50 %的包含10至100%的甲基丙烯酸烷基酯,0至90%的芳族乙烯基单体,0至25%的乙烯基酰胺单体和0至20%的乙烯基单体的混合物; 通过使10〜50%的混合物聚合50〜90%的橡胶胶乳固体成分而得到的平均粒径为0.05〜0.13μm的接枝共聚物B; 和氯乙烯树脂C; (共聚物A)/(共聚物B)的重量比为50/50〜90/15,(共聚物A和共聚物B的总量)/(氯乙烯树脂组合物C)的重量比为1 / 99至30/70; 该组合物的耐冲击性优异并且可用于制造管,窗框等。
    • 3. 发明申请
    • THERMOPLASTIC RESIN COMPOSITION AND MOLDED BODY THEREOF
    • 热塑性树脂组合物及其成型体
    • US20100286337A1
    • 2010-11-11
    • US12810919
    • 2008-12-25
    • Hirotsugu YamadaKoji Yui
    • Hirotsugu YamadaKoji Yui
    • C08L33/10
    • C08F290/00C08F265/00C08F265/06C08F290/068C08F293/005C08L27/06C08L51/003C08L53/00C09D153/00C08L2666/24C08L2666/02
    • A thermoplastic resin composition of the present invention capable of improving the strength and surface gloss of a molded article is comprising 100 parts by weight of a thermoplastic resin (a) and 0.5 to 30 parts by weight of a core-shell polymer composition (b), wherein the core-shell polymer composition (b) is obtained by polymerizing a shell-constituting component in the presence of a core obtained by polymerizing a core-constituting component, the core-constituting component contains 70% to 99.95% by weight of an alkyl acrylate having an alkyl group of 2 to 18 carbon atoms, 0.05% to 10% by weight of a polyfunctional monomer, and 0% to 20% by weight of a monomer copolymerizable with the alkyl acrylate and/or the polyfunctional monomer, the total amount of which is 100% by weight, the polyfunctional monomer is one or more selected from the group consisting of polypropylene glycol diacrylate and polypropylene glycol dimethacrylate, and the molecular weight of a component soluble in methyl ethyl ketone and insoluble in methanol of the core-shell polymer composition (b) is 500,000 or higher.
    • 能够提高成型体的强度和表面光泽度的本发明的热塑性树脂组合物包含100重量份的热塑性树脂(a)和0.5-30重量份的核 - 壳聚合物组合物(b) 其中,所述核 - 壳聚合物组合物(b)通过在通过聚合芯构成成分而获得的芯的存在下聚合壳组成成分而获得,所述芯构成成分含有70重量%〜99.95重量% 具有2至18个碳原子烷基的丙烯酸烷基酯,0.05至10重量%的多官能单体和0重量%至20重量%的可与丙烯酸烷基酯和/或多官能单体共聚的单体,总计 其量为100重量%,多官能单体是选自聚丙二醇二丙烯酸酯和聚丙二醇二甲基丙烯酸酯中的一种或多种,​​并且可溶于m的组分的分子量 乙基乙基酮,并且不溶于核 - 壳聚合物组合物(b)的甲醇为500,000以上。
    • 5. 发明授权
    • Polymerizable macromonomers and polymers prepared therefrom
    • 可聚合的大分子单体和由其制备的聚合物
    • US5830948A
    • 1998-11-03
    • US810465
    • 1997-02-28
    • Jean J.M. FrechetKoji Yui
    • Jean J.M. FrechetKoji Yui
    • A61K47/48C08F290/06C08G73/02C08G73/04C08G83/00C08L79/04C08G73/06
    • C08G83/005A61K47/48207C08F290/06C08G73/0233
    • Polyoxazolines having the structural formula: ##STR1## wherein R is phenylene or alkylene containing 2 to 18 carbon atoms, R.sup.2 is C.sub.1-4 alkyl and R.sub.1 is selected from the group consisting of C.sub.1-12 alkyl, vinyl, isopropylidene, pentafluoroethyl, phenyl, hydroxyphenyl which is optionally interrupted by up to 20 ethylene oxide groups, C.sub.1-2 -alkoxyphenyl which is optionally interrupted by up to 20 ethylene oxide groups and .paren open-st.CH.sub.2 CH.sub.2 --O.paren close-st..sub.r CH.sub.3 in which r ranges from 1-20, X is NH.sub.2 or OH, n ranges from 2 to 50 and m ranges from 0 to 50, wherein R.sub.1 is hydroxyphenyl optionally interrupted by up to 20 ethylene oxide groups only when X is NH.sub.2, are polymerizable to form hyperbranched polymers which have a number average molecular weight ranging from 5,000 to 150,000, a weight average molecular weight ranging from 5,500 to 5,000,000 and a polydispersity ranging from 1.1 to 300 and which are very polar and highly wettable and are useful as adhesives, biodegradable materials, biomaterials, carriers for chemicals, carriers for image contrast agents, coatings, components of blends, components of medical imaging formulations, crosslinkers, dispersants, drug carriers, imaging materials, resists for lighography, slow release agents, vectors for gene therapy, and viscosity modifiers.
    • 具有以下结构式的聚恶唑啉:其中R是亚苯基或含2至18个碳原子的亚烷基,R 2是C 1-4烷基,R 1选自C 1-12烷基,乙烯基,异亚丙基,五氟乙基 ,任选地被多达20个环氧乙烷基团间隔的苯基,羟基苯基,任选地被多达20个环氧乙烷基团间隔的C 1-2 - 烷氧基苯基和+545个CH 2 CH 2 -O + 546 rCH 3,其中r在1-20, X为NH 2或OH,n为2至50,m为0至50,其中R 1为仅在X为NH 2时任选地被至多20个环氧乙烷基团间隔的羟基苯基,可聚合形成数均分子量的超支化聚合物 分子量为5,000至150,000,重均分子量为5,500至5,000,000,多分散性为1.1至300,非极性和高度可湿性,可用作粘合剂,可生物降解材料,生物材料,载体 用于化学品,图像造影剂的载体,涂料,共混物组分,医学成像制剂的组分,交联剂,分散剂,药物载体,成像材料,用于光刻的抗蚀剂,缓释剂,用于基因治疗的载体和粘度调节剂。
    • 7. 发明申请
    • HAIRSPRAY
    • 头发
    • US20120076746A1
    • 2012-03-29
    • US13322789
    • 2010-05-25
    • Yoshimasa TateKoji YuiKeiko Ishii
    • Yoshimasa TateKoji YuiKeiko Ishii
    • A61K8/81A61Q5/04A61K8/898
    • C08F20/56A61K8/345A61K8/8158A61K2800/5424A61K2800/5426A61K2800/594A61Q5/065C08F220/10C08F220/56C08L33/26C08F220/34C08F2220/288
    • A hairspray which contains (A) to (C): (A) a cationic coating film-forming polymer, which is a copolymer containing monomers represented by formulae (1) to (4) (30 to 80% of (1), 2 to 50% of (2), 0 to 30% of (3), and 0 to 40% of (4)), or a copolymer including monomers represented by formulae (5) to (8) (30 to 80% of (5), 5 to 45% of (6), 2 to 30% of (7), and 0 to 30% of (8)): wherein R1, R4, R5, R12, and R21 are H or lower alkyl; R2, R3, R13, and R14 are H or C4-12 alkyl, or the like; R6, R16, R9, R10, R19, and R20 are lower alkylene; R7, R8, R17, R18, and R15 are lower alkyl; R11 is H, C1-10 alkyl or Ph; “a” is 0 or 1; “b” and “c” are 0 to 50; (B) an anionic coating film-forming polymer; and (C) a liquid solvent which has two or more OH and has a molecular weight of 62 to 1000, and wherein a mass ratio (B)/(A) is from 0.1 to 100.
    • 含有(A)〜(C)的发胶:(A)阳离子成膜性聚合物,其为含有式(1)〜(4)表示的单体的共聚物((1)的30〜80% (2)的50%,(3)的0〜30%和(4)的0〜40%),或包含式(5)〜(8)所示的单体的共聚物((5)〜(8)的30〜80% 5),(6)的5〜45%,(7)的2〜30%,(8)的0〜30%):其中,R 1,R 4,R 5,R 12和R 21为H或低级烷基; R2,R3,R13和R14是H或C4-12烷基等; R6,R16,R9,R10,R19和R20是低级亚烷基; R 7,R 8,R 17,R 18和R 15为低级烷基; R11为H,C1-10烷基或Ph; “a”为0或1; “b”和“c”为0〜50; (B)阴离子涂膜形成聚合物; 和(C)具有两个以上OH且分子量为62〜1000的液体溶剂,其中质量比(B)/(A)为0.1〜100。
    • 8. 发明申请
    • Thermoplastic Resin Composition and Process for Production Thereof
    • 热塑性树脂组合物及其制备方法
    • US20090137719A1
    • 2009-05-28
    • US12226563
    • 2007-04-18
    • Toshihiko KandaKoji YuiYusuke Aoki
    • Toshihiko KandaKoji YuiYusuke Aoki
    • C08L51/00
    • C08L27/06C08F279/02C08L5/04C08L33/06C08L51/003C08L51/04C08L101/00C08L2666/02C08L2666/24C08L2666/04
    • In order to provide a novel thermoplastic resin composition capable of exhibiting high impact resistance using an impact modifier having good dispersibility and can be isolated as a resin powder without coarsening and agglomeration, and a process for preparing the same, the invention provides a thermoplastic resin composition comprising a thermoplastic resin (a) and 0.5 to 20 parts by weight of a graft copolymer (b) comprising a butadiene-based rubbery polymer and a hard shell based on 100 parts by weight of the thermoplastic resin (a), wherein the composition further comprises 0.01 to 3.0 parts by weight of an aqueous polymer compound (c) having a property to form a physical gel, and 0.01 to 10 parts by weight of a processing aid (d), per 100 parts by weight of the graft copolymer (b), and a process for preparing the thermoplastic resin.
    • 为了提供一种能够使用具有良好分散性的抗冲击改性剂表现出高耐冲击性的新型热塑性树脂组合物及其制备方法,并且可以将其分离为树脂粉末而不会粗化和附聚,本发明提供一种热塑性树脂组合物 包含热塑性树脂(a)和基于100重量份热塑性树脂(a)的0.5至20重量份的包含丁二烯基橡胶状聚合物和硬壳的接枝共聚物(b),其中所述组合物进一步 相对于100重量份的接枝共聚物(b),含有0.01〜3.0重量份具有形成物理性凝胶性质的高分子化合物(c)和0.01〜10重量份的加工助剂(d) )和制备热塑性树脂的方法。
    • 10. 发明授权
    • Emulsion composition
    • 乳液组成
    • US07371715B2
    • 2008-05-13
    • US10790061
    • 2004-03-02
    • Koji YuiOsamu TakiguchiMasakazu SaseToshio Miyake
    • Koji YuiOsamu TakiguchiMasakazu SaseToshio Miyake
    • C11D3/37C11D17/08
    • C11D1/72C11D3/37C11D3/3788C11D17/0017
    • The invention relates to an emulsion composition, wherein an optically isotropic surfactant phase containing a nonionic surfactant (hereinafter the phase being referred to as the surfactant phase) is present as stable droplets in an aqueous solution phase containing an electrolytic salt (hereinafter the phase being referred to as the aqueous solution phase), the amount of the salt being such an amount that the aqueous solution phase is incompatible with the surfactant phase, with a polymer including a segment (a) having affinity with the aqueous solution phase and a segment (b) having affinity with the surfactant phase; and a liquid detergent composition containing the emulsion composition and inorganic builder particles dispersed in the emulsion composition.
    • 本发明涉及一种乳液组合物,其中含有非离子表面活性剂(以下称为表面活性剂相的相)的光学各向同性的表面活性剂相作为稳定的液滴在含有电解盐的水溶液相中存在(以下称为相 作为水溶液相),盐的量是这样的水溶液相与表面活性剂相不相容的量,以及包含与水溶液相具有亲和性的链段(a)的聚合物和片段(b )与表面活性剂相具有亲和性; 和含有分散在乳液组合物中的乳液组合物和无机助洗剂颗粒的液体洗涤剂组合物。