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1. 发明授权

US5147942A Thermoplastic resin composition 失效
公开(公告)号：US5147942A
公开(公告)日：1992-09-15
申请号：US476687
申请日：1990-02-08
申请人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Takeshi Sanada , Masahiro Kakugo
发明人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Takeshi Sanada , Masahiro Kakugo
IPC分类号： C08L51/00 , C08G65/48 , C08L51/06 , C08L53/00 , C08L67/00 , C08L71/00 , C08L71/12 , C08L75/00 , C08L77/00 , C08L81/00 , C08L101/00
CPC分类号： C08L71/12 , C08G65/485 , C08L77/00 , C08L67/00 , C08L71/00 , C08L75/00 , C08L81/00 , Y10S525/905
摘要： Disclosed is a thermoplastic resin composition improved in low-temperature impact resistance and processability which comprises:(A) 5-95% by weight of a polyamide resin which has a relative viscosity of 3.1-4.5 and has a ratio .alpha. of terminal amino group to terminal carboxyl group of 0

2. 发明授权

US4603174A Stretched polypropylene film 失效
标题翻译：拉伸聚丙烯薄膜
公开(公告)号：US4603174A
公开(公告)日：1986-07-29
申请号：US686865
申请日：1984-12-27
申请人： Tadayuki Okada , Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
发明人： Tadayuki Okada , Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
IPC分类号： B29C55/00 , B29C55/02 , B29K23/00 , B29L7/00 , C08J5/18 , C08L23/12 , C08L23/14 , C08L23/20 , C08L23/04
CPC分类号： C08J5/18 , C08L23/12 , C08L23/142 , C08J2323/10 , C08L23/20 , C08L2314/02 , Y10S428/91 , Y10T428/31913
摘要： A stretched polypropylene film having excellent see-through characteristics, which is prepared by stretching in at least one direction a polypropylene resin sheet containing 0.05 ppm to 10,000 ppm by weight of a 3-position branched .alpha.-olefin unit and/or a vinyl cycloalkane unit, each having at least 6 carbon atoms.
摘要翻译：一种拉伸聚丙烯薄膜，具有优异的透视特性，其通过至少一个方向拉伸含有0.05ppm至10,000ppm重量的3-位支链α-烯烃单元和/或乙烯基环烷烃单元的聚丙烯树脂板各自具有至少6个碳原子。

3. 发明授权

US4414373A Propylene-ethylene copolymer having improved stretchability 失效
标题翻译：具有改善的拉伸性的丙烯 - 乙烯共聚物
公开(公告)号：US4414373A
公开(公告)日：1983-11-08
申请号：US399146
申请日：1982-07-16
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
IPC分类号： C08F4/00 , C08F2/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/06 , C08F210/00 , C08F210/06 , C08F210/16
CPC分类号： C08F210/06
摘要： In a process for producing polypropylene comprising polymerizing propylene in the presence of hydrogen and a catalyst system comprising (A) titanium trichloride obtained by reducing titanium tetrachloride with an organoaluminum compound and reacting the reduced solid with an ether represented by the formula:R.sup.1 --O--R.sup.2wherein R.sup.1 and R.sup.2 are defined hereinbefore, and a halogen compound selected from the group consisting of (i) halogen or interhalogen compounds of the formula, X.sup.1 X.sup.2.sub.a (wherein X.sup.1, X.sup.2 and a are defined hereinbefore), (ii) titanium halides, and (iii) organic halogen compounds, simultaneously or successively and (B) an organoaluminum compound, the improvement which comprises supplying ethylene together with propylene to the polymerization system such that the ethylene concentration in the vapor phase of the system based on the total amount of propylene, ethylene and hydrogen in the vapor phase of the system is 0.15 to 1.5 mol % to obtain a propylene-ethylene copolymer having an ethylene content of from 0.1 to 1.0 wt % is disclosed. The propylene-ethylene copolymer is improved in stretchability.
摘要翻译：在制备聚丙烯的方法中，包括在氢气存在下聚合丙烯和催化剂体系，所述催化剂体系包含（A）通过用有机铝化合物还原四氯化钛获得的三氯化钛，并将还原的固体与由下式表示的醚反应：R1-O- 其中R 1和R 2如上定义，卤素化合物选自（ⅰ）卤素或下式的卤代化合物：X1X2a（其中X1，X2和a定义如前），（ⅱ）卤化钛和（iii）有机卤素化合物，同时或相继和（B）有机铝化合物，其改进包括将乙烯与丙烯一起供应到聚合体系中，使得基于丙烯总量的体系的气相中的乙烯浓度，系统的气相中的乙烯和氢为0.15〜1.5摩尔％，得到丙烯 - 乙烯共聚物公开了乙烯含量为0.1〜1.0重量％。丙烯 - 乙烯共聚物的拉伸性提高。

4. 发明授权

US4254237A Process for producing propylene-ethylene block copolymers 失效
标题翻译：制备丙烯 - 乙烯嵌段共聚物的方法
公开(公告)号：US4254237A
公开(公告)日：1981-03-03
申请号：US30523
申请日：1979-04-16
申请人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
发明人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
IPC分类号： C08F297/00 , C08F297/08
CPC分类号： C08F297/086
摘要： A process for producing propylene-ethylene block copolymers by a three-step polymerization technique using a stereoregular catalyst, characterized in that the first-step polymerization is carried out by supplying propylene alone or a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 6/94 or less, thereby polymerizing 60 to 95% by weight of the total polymerization amount, the second-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 15/85 to 79/21, thereby polymerizing 1 to 20% by weight of the total polymerization amount, and the third-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 50/50 to 89/11, thereby polymerizing 4 to 35% by weight of the total polymerization amount, with the ethylene/propylene reaction ratio in the third step made larger than that in the second step. Said process can give propylene-ethylene block copolymers markedly well balanced in impact strength, stiffness, transparency and impact blushing.
摘要翻译：一种通过使用立体规则催化剂的三步聚合技术制备丙烯 - 乙烯嵌段共聚物的方法，其特征在于第一步聚合是通过仅供应丙烯或丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比为6/94以下，由此聚合60〜95重量％的总聚合量，第二步聚合是通过供给丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比为15/85〜79 / 21，由此聚合1至20重量％的总聚合量，第三步聚合通过供应丙烯/乙烯混合物进行，使得乙烯/丙烯反应比为50/50至89/11，从而聚合4〜35重量％的总聚合量，第3步骤中的乙烯/丙烯反应比例大于第2步骤。所述方法可以使丙烯 - 乙烯嵌段共聚物在冲击强度，刚度，透明度和冲击冲刷中显着地平衡。

5. 发明授权

US5043408A Ethylene-aromatic vinyl compound alternating copolymer and process for the production thereof 失效
标题翻译：乙烯 - 芳族乙烯基化合物交替共聚物及其制备方法
公开(公告)号：US5043408A
公开(公告)日：1991-08-27
申请号：US538713
申请日：1990-06-15
申请人： Masahiro Kakugo , Tatsuya Miyatake , Koozi Mizunuma , Yoshio Yagi
发明人： Masahiro Kakugo , Tatsuya Miyatake , Koozi Mizunuma , Yoshio Yagi
IPC分类号： C08F4/609 , C08F210/02 , C08F212/04
CPC分类号： C08F212/04 , C08F210/02
摘要： Alternating copolymers having a high alternating degree and high isotacticity, which can be produced by copolymerizing ethylene and an aromatic vinyl monomer in the presence, as a catalyst, of a transition metal compound, aluminoxane and a specific organic compound having at least two hydroxyl groups.

6. 发明授权

US4696979A Process for producing propylene copolymer 失效
标题翻译：制备丙烯共聚物的方法
公开(公告)号：US4696979A
公开(公告)日：1987-09-29
申请号：US686864
申请日：1984-12-27
申请人： Akinobu Shiga , Masahiro Kakugo , Junpei Kozima , Kizuku Wakatsuki
发明人： Akinobu Shiga , Masahiro Kakugo , Junpei Kozima , Kizuku Wakatsuki
IPC分类号： C08L23/10 , C08L23/20 , C08L53/00 , C08L23/14
CPC分类号： C08L23/10 , C08L53/00 , C08L23/20
摘要： A process for producing a propylene copolymer having improved transparency and rigidity, which comprises carrying out (A) the polymerization of a vinyl cycloalkane having at least 6 carbon atoms and (B) the polymerization of propylene either alone or with ethylene in a multiplicity of steps in the presence of a catalyst system composed of a titanium compound and an organoaluminum compound. The content of the vinyl cycloalkane unit in the resulting copolymer is 0.05 to 10,000 weight ppm.
摘要翻译：一种制备具有改善的透明度和刚性的丙烯共聚物的方法，其包括进行（A）聚合具有至少6个碳原子的乙烯基环烷烃和（B）单独或与乙烯在多个步骤中聚合丙烯在由钛化合物和有机铝化合物组成的催化剂体系的存在下。所得共聚物中乙烯基环烷烃单元的含量为0.05至10,000重量ppm。

7. 发明授权

US4584239A Stretched multilayer polypropylene film 失效
标题翻译：拉伸多层聚丙烯薄膜
公开(公告)号：US4584239A
公开(公告)日：1986-04-22
申请号：US753846
申请日：1985-07-11
申请人： Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
发明人： Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
IPC分类号： B32B27/00 , B32B27/32 , C09J7/02 , C09J123/08 , C09J123/14
CPC分类号： C09J7/0242 , B32B27/32 , C09J123/0815 , C09J123/142 , Y10S428/91 , Y10T428/2826
摘要： A stretched multilayer polypropylene film is described, comprising a stretched crystalline polypropylene layer and a layer of a composition (Composition B) laminated on at least one side of said polypropylene layer, wherein the composition B comprises a homo- or copolymer composed mainly of ethylene, propylene or butene-1 and having a melting point of 150.degree. C. or less, and a vinylcycloalkane polymer in an amount of 0.05 wt ppm to 10 wt % calculated as a vinylcycloalkane unit. This multilayer film is greatly improved in optical properties such as excellent see-through properties without deteriorating its good heat sealability. Thus it is very useful for wrapping.
摘要翻译：描述了拉伸的多层聚丙烯薄膜，其包含拉伸的结晶聚丙烯层和层压在所述聚丙烯层的至少一侧上的组合物层（组合物B），其中组合物B包含主要由乙烯组成的均聚物或共聚物，丙烯或丁烯-1，熔点为150℃以下，乙烯基环烷烃聚合物的量为0.05重量％〜10重量％，以乙烯基环烷烃单元计算。这种多层膜在透光性方面优异的光学特性大大提高，而不会使其良好的热封性劣化。因此，它是非常有用的包装。

8. 发明授权

US4382065A Fluidized bed apparatus and method of using 失效
标题翻译：流化床装置及其使用方法
公开(公告)号：US4382065A
公开(公告)日：1983-05-03
申请号：US304871
申请日：1981-09-23
申请人： Akinobu Shiga , Masahiro Kakugo , Koji Yamada , Hajime Sadatoshi
发明人： Akinobu Shiga , Masahiro Kakugo , Koji Yamada , Hajime Sadatoshi
IPC分类号： B01J8/34 , B01J8/00 , B01J8/38 , C08F2/38 , C08F10/00 , F27B15/08
CPC分类号： B01J8/386 , B01J8/0065 , C08F10/00
摘要： In a fluidized bed apparatus intended to fluidize solid particles by means of ascending stream gas, the improvement for reducing solid particles entrained from the apparatus, which comprises placing an internal in a free board of the apparatus so that the projected area ratio is not less than 0.8, and the opening proportion to the free board cross-sectional area is within 0.3 to 0.9.
摘要翻译：在旨在通过上升气流使固体颗粒流化的流化床装置中，减少了从装置夹带的固体颗粒的改进，其包括将内部放置在装置的自由板中，使得投影面积比不小于 0.8，与自由板横截面积的开口比例在0.3〜0.9的范围内。

9. 发明授权

US4367322A Process for producing propylene copolymer 失效
标题翻译：制备丙烯共聚物的方法
公开(公告)号：US4367322A
公开(公告)日：1983-01-04
申请号：US291701
申请日：1981-08-10
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Akira Nunose , Masaharu Nishioka
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Akira Nunose , Masaharu Nishioka
IPC分类号： C08F4/64 , C08F210/06
CPC分类号： C08F210/06 , Y10S526/916
摘要： In a process for producing propylene copolymer containing about 80 to 99 mol % propylene and about 1 to 20 mol % ethylene and/or an .alpha.-olefin having 4 to 18 carbon atoms using a Ziegler-Natta catalyst, the improvement which comprises said Ziegler-Natta catalyst comprising:(A) titanium trichloride prepared by reducing titanium tetrachloride with an organoaluminum compound and activating the product; and(B) an organoaluminum compound;with the molar ratio of (B)/(A) being about 20 to 100.
摘要翻译：在使用齐格勒 - 纳塔催化剂的丙烯共聚物的制备方法中，所述丙烯共聚物含有约80-99摩尔％的丙烯和约1-20摩尔％的乙烯和/或具有4-18个碳原子的α-烯烃，其改进包括所述齐格勒 - 纳塔催化剂，其包含：（A）通过用有机铝化合物还原四氯化钛制备的三氯化钛并活化该产物; 和（B）有机铝化合物; （B）/（A）的摩尔比为约20至100。

10. 发明授权

US4355144A Process for producing a propylene-ethylene copolymer having improved stretchability 失效
标题翻译：制备具有改善的拉伸性的丙烯 - 乙烯共聚物的方法
公开(公告)号：US4355144A
公开(公告)日：1982-10-19
申请号：US257431
申请日：1981-04-24
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
IPC分类号： C08F4/00 , C08F2/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/06 , C08F210/00 , C08F210/06 , C08F210/16
CPC分类号： C08F210/06
摘要： In a process for producing polypropylene comprising polymerizing propylene in the presence of hydrogen and a catalyst system comprising (A) titanium trichloride obtained by reducing titanium tetrachloride with an organoaluminum compound and reacting the reduced solid with an ether represented by the formula:R.sup.1 -O-R.sup.2wherein R.sup.1 and R.sup.2 are defined hereinbefore, and a halogen compound selected from the group consisting of (i) halogen or interhalogen compounds of the formula, X.sup.1 X.sup.2.sub.a (wherein X.sup.1, X.sup.2 and a are defined hereinbefore), (ii) titanium halides, and (iii) organic halogen compounds, simultaneously or successively and (B) an organoaluminum compound, the improvement which comprises supplying ethylene together with propylene to the polymerization system such that the ethylene concentration in the vapor phase of the system based on the total amount of propylene, ethylene and hydrogen in the vapor phase of the system is 0.15 to 1.5 mol % to obtain a propylene-ethylene copolymer having an ethylene content of from 0.1 to 1.0 wt % is disclosed. The propylene-ethylene copolymer is improved in stretchability.
摘要翻译：在制备聚丙烯的方法中，包括在氢气存在下聚合丙烯和催化剂体系，所述催化剂体系包含（A）通过用有机铝化合物还原四氯化钛获得的三氯化钛，并将还原的固体与由下式表示的醚反应：R1-O- 其中R 1和R 2如上定义，卤素化合物选自（ⅰ）卤素或下式的卤代化合物：X1X2a（其中X1，X2和a定义如前），（ⅱ）卤化钛和（iii）有机卤素化合物，同时或相继和（B）有机铝化合物，其改进包括将乙烯与丙烯一起供应到聚合体系中，使得基于丙烯总量的体系的气相中的乙烯浓度，系统的气相中的乙烯和氢为0.15〜1.5摩尔％，得到丙烯 - 乙烯共聚物公开了乙烯含量为0.1〜1.0重量％。丙烯 - 乙烯共聚物的拉伸性提高。

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