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    • 4. 发明授权
    • Copolymer and top coating composition
    • 共聚物和顶涂组合物
    • US07781142B2
    • 2010-08-24
    • US11664296
    • 2005-09-28
    • Takashi ChibaToru KimuraTomohiro UtakaHiroki NakagawaHirokazu SakakibaraHiroshi Dougauchi
    • Takashi ChibaToru KimuraTomohiro UtakaHiroki NakagawaHirokazu SakakibaraHiroshi Dougauchi
    • G03F7/11C08F18/20C08F18/22
    • G03F7/11C08F220/18C08F220/26C08F220/38C08F228/00G03F7/2041
    • A resin composition for forming a top coat which can be formed on a photoresist film without causing intermixing with the photoresist film, can maintain a stable film coating which is not eluted into a medium during immersion lithography, does not impair pattern profiles during dry exposure (which is not immersion lithography), and can be easily dissolved in an alkaline developer. The resin is a copolymer which comprises at least one recurring unit (I) selected from the group consisting of a recurring unit having a group shown by the following formula (1), a recurring unit having a group shown by the following formula (2), and a recurring unit having a carboxyl group, and a recurring unit (II) having a sulfo group, the copolymer having a weight average molecular weight determined by gel permeation chromatography of 2,000 to 100,000, wherein at least one of R1 and R2 is a fluoroalkyl group having 1 to 4 carbon atoms and R3 in the formula (2) represents a fluoroalkyl group having 1 to 20 carbon atoms.
    • 用于形成表面涂层的树脂组合物可以形成在光致抗蚀剂膜上而不与光致抗蚀剂膜混合,可以保持在浸没光刻期间不溶于介质的稳定的膜涂层,在干燥曝光期间不损害图案轮廓( 这不是浸没式光刻法),并且可以容易地溶解在碱性显影剂中。 树脂是包含至少一种选自由下式(1)表示的基团的重复单元,由下式(2)表示的基团的重复单元)的重复单元(I)的共聚物, 和具有羧基的重复单元和具有磺基的重复单元(II),所述共聚物的重均分子量通过凝胶渗透色谱法测定为2,000〜100,000,其中R1和R2中的至少一个为 具有1至4个碳原子的氟代烷基和式(2)中的R 3表示具有1至20个碳原子的氟烷基。
    • 6. 发明申请
    • Copolymer and Top Coating Composition
    • 共聚物和顶部涂料组合物
    • US20080038661A1
    • 2008-02-14
    • US11664296
    • 2005-09-28
    • Takashi ChibaToru KimuraTomohiro UtakaHiroki NakagawaHirokazu SakakibaraHiroshi Dougauchi
    • Takashi ChibaToru KimuraTomohiro UtakaHiroki NakagawaHirokazu SakakibaraHiroshi Dougauchi
    • C08F12/30G03C1/73
    • G03F7/11C08F220/18C08F220/26C08F220/38C08F228/00G03F7/2041
    • A resin composition for forming a top coat which can be formed on a photoresist film without causing intermixing with the photoresist film, can maintain a stable film coating which is not eluted into a medium during immersion lithography, does not impair pattern profiles during dry exposure (which is not immersion lithography), and can be easily dissolved in an alkaline developer. The resin is a copolymer which comprises at least one recurring unit (I) selected from the group consisting of a recurring unit having a group shown by the following formula (1), a recurring unit having a group shown by the following formula (2), and a recurring unit having a carboxyl group, and a recurring unit (II) having a sulfo group, the copolymer having a weight average molecular weight determined by gel permeation chromatography of 2,000 to 100,000, wherein at least one of R1 and R2 is a fluoroalkyl group having 1 to 4 carbon atoms and R3 in the formula (2) represents a fluoroalkyl group having 1 to 20 carbon atoms.
    • 用于形成表面涂层的树脂组合物可以形成在光致抗蚀剂膜上而不与光致抗蚀剂膜混合,可以保持在浸没光刻期间不溶于介质的稳定的膜涂层,在干燥曝光期间不损害图案轮廓( 这不是浸没式光刻法),并且可以容易地溶解在碱性显影剂中。 树脂是包含至少一种选自由下式(1)表示的基团的重复单元,由下式(2)表示的基团的重复单元)的重复单元(I)的共聚物, 和具有羧基的重复单元和具有磺基的重复单元(II),所述共聚物的重均分子量通过凝胶渗透色谱法测定为2,000〜100,000,其中R 1〜 R 2是具有1〜4个碳原子的氟代烷基,式(2)中的R 3表示碳原子数1〜20的氟代烷基 。