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1. 发明授权

US09153757B2 Thermoplastic resin composition for reflective material, reflective plate, and light-emitting diode element 有权
标题翻译：用于反射材料，反射板和发光二极管元件的热塑性树脂组合物
公开(公告)号：US09153757B2
公开(公告)日：2015-10-06
申请号：US14236450
申请日：2012-07-31
申请人： Hideto Ogasawara , Takashi Hama , Kuniaki Kawabe , Hirotaka Kanaya , Nobuhiro Takizawa , Akinori Amano , Hiroki Ebata , Kan Komiya
发明人： Hideto Ogasawara , Takashi Hama , Kuniaki Kawabe , Hirotaka Kanaya , Nobuhiro Takizawa , Akinori Amano , Hiroki Ebata , Kan Komiya
IPC分类号： H01L33/00 , H01L33/60 , C08L67/02 , G02B1/04 , C08L51/06 , C08K3/22 , C08K3/26
CPC分类号： H01L33/60 , C08F255/10 , C08K3/22 , C08K7/08 , C08K2003/2241 , C08K2003/265 , C08L51/06 , C08L67/02 , C08L91/06 , G02B1/04 , C08L67/00 , C08L33/00 , C08F222/06
摘要： The purpose of the present invention is to provide a thermoplastic resin composition for a reflective material which has excellent mechanical strength, excellent heat resistance, excellent high reflectance, and excellent moldability, and which makes it possible to obtain a reflective plate with little decline in reflectance caused by heating. A first embodiment of this thermoplastic resin composition for a reflective material includes: a polyester resin (A) that has a melting point or glass transition temperature of 250° C. or higher and includes an alicyclic hydrocarbon structure; a thermoplastic resin (B) that has a polyolefin backbone and a functional group; a white pigment (C); and an inorganic filler (D); the thermoplastic resin (B) either including 0.1 to 1.8 wt % of a functional group unit (B1) that further includes a heteroatom, or further including an aromatic hydrocarbon structure (B2), and the limiting viscosity [η] being 0.04 to 1.0 dl/g.
摘要翻译：本发明的目的是提供一种机械强度优异，耐热性优异，高反射率优异，成型性优异的反射材料用热塑性树脂组合物，能够得到反射率几乎没有下降的反射板加热引起的用于反射材料的该热塑性树脂组合物的第一个实施方案包括：具有250℃或更高的熔点或玻璃化转变温度并包括脂环烃结构的聚酯树脂（A）具有聚烯烃主链和官能团的热塑性树脂（B）白色颜料（C）; 和无机填料（D）; 还含有杂原子的官能团单元（B1）的0.1〜1.8重量％，还包含芳香族烃结构（B2）的热塑性树脂（B）的特性粘度[ηe]为0.04〜1.0 dl / g。

2. 发明申请

US20140167091A1 THERMOPLASTIC RESIN COMPOSITION FOR REFLECTIVE MATERIAL, REFLECTIVE PLATE, AND LIGHT-EMITTING DIODE ELEMENT 有权
标题翻译：反射材料，反射板和发光二极管元件的热塑性树脂组合物
公开(公告)号：US20140167091A1
公开(公告)日：2014-06-19
申请号：US14236450
申请日：2012-07-31
申请人： Hideto Ogasawara , Takashi Hama , Kuniaki Kawabe , Hirotaka Kanaya , Nobuhiro Takizawa , Akinori Amano , Hiroki Ebata , Kan Komiya
发明人： Hideto Ogasawara , Takashi Hama , Kuniaki Kawabe , Hirotaka Kanaya , Nobuhiro Takizawa , Akinori Amano , Hiroki Ebata , Kan Komiya
IPC分类号： H01L33/60 , G02B1/04
CPC分类号： H01L33/60 , C08F255/10 , C08K3/22 , C08K7/08 , C08K2003/2241 , C08K2003/265 , C08L51/06 , C08L67/02 , C08L91/06 , G02B1/04 , C08L67/00 , C08L33/00 , C08F222/06
摘要： The purpose of the present invention is to provide a thermoplastic resin composition for a reflective material which has excellent mechanical strength, excellent heat resistance, excellent high reflectance, and excellent moldability, and which makes it possible to obtain a reflective plate with little decline in reflectance caused by heating. A first embodiment of this thermoplastic resin composition for a reflective material includes: a polyester resin (A) that has a melting point or glass transition temperature of 250° C. or higher and includes an alicyclic hydrocarbon structure; a thermoplastic resin (B) that has a polyolefin backbone and a functional group; a white pigment (C); and an inorganic filler (D); the thermoplastic resin (B) either including 0.1 to 1.8 wt % of a functional group unit (B1) that further includes a heteroatom, or further including an aromatic hydrocarbon structure (B2), and the limiting viscosity [η] being 0.04 to 1.0 dl/g.
摘要翻译：本发明的目的是提供一种机械强度优异，耐热性优异，高反射率优异，成型性优异的反射材料用热塑性树脂组合物，能够得到反射率几乎没有下降的反射板加热引起的用于反射材料的该热塑性树脂组合物的第一个实施方案包括：具有250℃或更高的熔点或玻璃化转变温度并包括脂环烃结构的聚酯树脂（A）具有聚烯烃主链和官能团的热塑性树脂（B）; 白色颜料（C）; 和无机填料（D）; 还含有杂原子的官能团单元（B1）的0.1〜1.8重量％，还包含芳香族烃结构（B2）的热塑性树脂（B）的特性粘度[ηe]为0.04〜1.0 dl / g。

3. 发明授权

US07605208B2 Process for producing thermoplastic resin composition 有权
标题翻译：热塑性树脂组合物的制造方法
公开(公告)号：US07605208B2
公开(公告)日：2009-10-20
申请号：US11589853
申请日：2006-10-31
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： C08J3/22
CPC分类号： C08J3/005 , C08J2323/02 , C08L23/06 , C08L23/10 , C08L91/08 , C08L101/00 , C08L2314/06 , C08L2666/06
摘要： The present invention provides a process for producing a thermoplastic resin composition comprising a polyolefin wax having good dispersibility for a thermoplastic resin, a molded product, which is excellent in physical properties such as blocking property and mechanical properties, from the thermoplastic resin composition and a process for producing the molded product.Specifically, a process for producing a thermoplastic resin composition comprises melt-kneading a mixture of a polyolefin wax (A) which has a passing ratio through a mesh having a sieve opening of 5.66 mmφ of 95% by weight or more, and a non-passing ratio through a mesh having a sieve opening of 2.00 mmφ of 95% by weight or more, and is in the particle form, and a thermoplastic resin (B), a molded product, which is excellent in physical properties such as blocking property and mechanical properties, obtained from the thermoplastic resin composition and a process for producing the molded product are provided.
摘要翻译：本发明提供一种热塑性树脂组合物的制造方法，该热塑性树脂组合物包含热塑性树脂具有良好分散性的聚烯烃蜡，热塑性树脂组合物的物理性能如机械性能优异的成型体，以及工序用于生产模制产品。具体而言，制造热塑性树脂组合物的方法包括将具有95重量％以上的筛孔5.66mmφ的筛网的通过率的聚烯烃蜡（A）的混合物熔融捏合，通孔比为2.00mmφ的筛孔为95重量％以上的筛网，为粒状，热塑性树脂（B），成型品，其物理性质如粘合性优异，提供从热塑性树脂组合物获得的机械性能和制造模塑产品的方法。

4. 发明申请

US20070100055A1 Process for producing thermoplastic resin composition 有权
标题翻译：热塑性树脂组合物的制造方法
公开(公告)号：US20070100055A1
公开(公告)日：2007-05-03
申请号：US11589853
申请日：2006-10-31
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： C08L91/08
CPC分类号： C08J3/005 , C08J2323/02 , C08L23/06 , C08L23/10 , C08L91/08 , C08L101/00 , C08L2314/06 , C08L2666/06
摘要： The present invention provides a process for producing a thermoplastic resin composition comprising a polyolefin wax having good dispersibility for a thermoplastic resin, a molded product, which is excellent in physical properties such as blocking property and mechanical properties, from the thermoplastic resin composition and a process for producing the molded product. Specifically, a process for producing a thermoplastic resin composition comprises melt-kneading a mixture of a polyolefin wax (A) which has a passing ratio through a mesh having a sieve opening of 5.66 mmφ of 95% by weight or more, and a non-passing ratio through a mesh having a sieve opening of 2.00 mmφ of 95% by weight or more, and is in the particle form, and a thermoplastic resin (B), a molded product, which is excellent in physical properties such as blocking property and mechanical properties, obtained from the thermoplastic resin composition and a process for producing the molded product are provided.
摘要翻译：本发明提供一种热塑性树脂组合物的制造方法，该热塑性树脂组合物包含热塑性树脂具有良好分散性的聚烯烃蜡，热塑性树脂组合物的物理性能如机械性能优异的成型体，以及工序用于生产模制产品。具体而言，制造热塑性树脂组合物的方法包括将具有95重量％以上的筛孔5.66mmφ的筛网的通过率的聚烯烃蜡（A）的混合物熔融捏合，通孔比为2.00mmφ的筛孔为95重量％以上的筛网，为粒状，热塑性树脂（B），成型品，其物理性质如粘合性优异，提供从热塑性树脂组合物获得的机械性能和制造模塑产品的方法。

5. 发明申请

US20130344273A1 MOLDED ARTICLE 有权
标题翻译：模制品
公开(公告)号：US20130344273A1
公开(公告)日：2013-12-26
申请号：US13980950
申请日：2012-01-18
申请人： Kaori Matoishi , Takuma Yano , Hiromasa Marubayashi , Naoki Tomoshige , Naoshi Nagai , Tamotsu Harada , Kuniaki Kawabe
发明人： Kaori Matoishi , Takuma Yano , Hiromasa Marubayashi , Naoki Tomoshige , Naoshi Nagai , Tamotsu Harada , Kuniaki Kawabe
IPC分类号： C08L23/26
CPC分类号： C08L23/26 , C08F8/42 , C08F10/00 , C08F110/02 , C08F2810/40 , C08L23/10 , C08L83/00 , C08L83/04 , C08L101/10 , C08L2312/08 , Y10T428/1397 , Y10T428/249921 , C08L51/06
摘要： A molded article formed of a composition including 100 parts by weight of at least one kind of resin selected from the group consisting of thermoplastic resins and thermosetting resins, and 0.01 parts by weight to 10,000 parts by weight of a silylated polyolefin, which is obtained by a reaction between a silicon-containing compound containing a structural unit represented by Formula (1) and a vinyl group-containing compound having a defined number average molecular weight, a derivative thereof, or a mixture of these, —Si(R1)H—Y1— (1) wherein R1 and Y1 are defined and with the proviso that the silylated polyolefin is not obtained by a reaction between a silicon-containing compound containing a structural unit represented by Formula (1) and having two or more SH groups per molecule and a compound having 2.0 or more vinyl groups on average per molecule as the vinyl group-containing compound.
摘要翻译：由包含100重量份的选自热塑性树脂和热固性树脂的至少一种树脂和0.01重量份至10,000重量份的甲硅烷基化聚烯烃的组合物形成的模塑制品，其通过包含式（1）表示的结构单元的含硅化合物和具有确定数均分子量的含乙烯基的化合物，其衍生物或它们的混合物之间的反应-Si（R1）H- Y 1 - （1）其中R1和Y1被定义，条件是甲硅烷基化聚烯烃不是通过含有由式（1）表示的结构单元的含硅化合物与每分子具有两个或更多个SH基团的反应而得到的和每分子平均具有2.0个以上乙烯基的化合物作为含乙烯基的化合物。

6. 发明申请

US20130052464A1 RESIN FINE POWDER CONSISTING OF 4-METHYL-1-PENTENE POLYMER, COMPOSITION CONTAINING SAME, AND PROCESS FOR PRODUCTION THEREOF 有权
标题翻译：含有4-甲基-1-丁烯聚合物的树脂粉末，含有它们的组合物及其生产方法
公开(公告)号：US20130052464A1
公开(公告)日：2013-02-28
申请号：US13643866
申请日：2011-02-08
申请人： Kuniaki Kawabe , Toshiyuki Itou , Mai Karihara , Kazutoshi Fujihara , Ryouichi Seki
发明人： Kuniaki Kawabe , Toshiyuki Itou , Mai Karihara , Kazutoshi Fujihara , Ryouichi Seki
IPC分类号： C08F10/14 , B02C19/06 , B22F1/00 , C09D11/00 , C04B35/64 , B22F3/20 , C04B35/00 , C09D123/20
CPC分类号： C08F110/14 , C04B38/0635 , C04B2111/00793 , C08J3/12 , C08J2323/20 , C08K3/08 , C08K3/34 , C08L23/20 , C09D7/61 , C09D11/033 , C09D11/102 , C09D11/106 , C09D123/20 , Y10T428/2982 , C08F2500/17 , C08F2500/18 , C08F2500/11 , C08F2500/24 , C04B35/00 , C04B38/0006
摘要： A resin fine powder which consists of a 4-methyl-1-pentene polymer that exhibits a limiting viscosity [η] of 1.0×10−2 to less than 3.0 dl/g as determined in decalin at 135° C. and which has a median particle diameter [D50] of 1.0×10−1 to 5.0×10 μm; and a composition which comprises the resin fine powder and at least one sinterable powder selected from the group consisting of metal powders and ceramic powders.
摘要翻译：由在135℃的萘烷中测定的显示特性粘度[η]为1.0×10-2〜小于3.0dl / g的4-甲基-1-戊烯类聚合物的树脂细粉末，中值粒径[D50]为1.0×10-1〜5.0×10μm; 以及包含树脂细粉和至少一种选自金属粉末和陶瓷粉末的可烧结粉末的组合物。

7. 发明授权

US08354470B2 Olefin polymer wax-containing resin composition 有权
标题翻译：烯烃聚合物含蜡树脂组合物
公开(公告)号：US08354470B2
公开(公告)日：2013-01-15
申请号：US12996963
申请日：2009-06-12
申请人： Mai Kurihara , Kuniaki Kawabe , Akinori Etoh , Toshiyuki Itou
发明人： Mai Kurihara , Kuniaki Kawabe , Akinori Etoh , Toshiyuki Itou
IPC分类号： C08L69/00 , C08L77/00
CPC分类号： C08L77/00 , C08L23/0823 , C08L45/00 , C08L69/00 , C08L91/06 , C08L101/00 , C08L2666/04 , C08L2666/06
摘要： Resin compositions of the invention contain an olefin polymer wax having higher heat resistance than achieved heretofore, high compatibility with resins and excellent mold-releasing properties.A resin composition (X) of the invention is obtained by blending a resin (A) having a melting point Tm of not less than 200° C. and an olefin polymer wax component (B), the olefin polymer wax component (B) including a cyclic olefin polymer wax (B-1) having structural units (a) and (b) described below, the cyclic olefin polymer wax (B-1) containing the structural units (b) at 0.05 to 50 mol % based on all the structural units in the polymer; (a) units derived from ethylene (b) units derived from a cyclic olefin.
摘要翻译：本发明的树脂组合物含有比迄今为止高的耐热性，与树脂的高相容性和优异的脱模性能的烯烃聚合物蜡。本发明的树脂组合物（X）通过将熔点Tm不低于200℃的树脂（A）和烯烃聚合物蜡组分（B），烯烃聚合物蜡组分（B），包括具有下述结构单元（a）和（b）的环状烯烃聚合物蜡（B-1），含有结构单元（b）的环状烯烃聚合物蜡（B-1）为0.05〜50摩尔％聚合物中的结构单元; （a）衍生自环烯烃的单元衍生自乙烯（b）。

8. 发明申请

US20070080483A1 Process for producing injection molded product 审中-公开
标题翻译：注塑产品生产工艺
公开(公告)号：US20070080483A1
公开(公告)日：2007-04-12
申请号：US11543901
申请日：2006-10-06
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： B29C45/00 , C08L91/08 , C08J3/22 , C08K5/01
CPC分类号： B29C45/0001 , B29K2105/0094 , C08K5/01 , C08L23/02 , C08L23/06 , C08L23/10 , C08L23/16 , C08L91/06 , C08L91/08 , C08L2205/03 , C08L2666/04 , C08L2666/06 , C08L2666/02
摘要： The present invention provides an injection molding process of a thermoplastic resin which is capable of thin molding or precision molding by improving injection moldability, particularly releasability or fluidity, without deteriorating the characteristics of the injection molded article of the thermoplastic resin. The process for producing an injection molded product comprises injection molding a mixture containing a thermoplastic resin and a polyolefin wax, wherein the mixture has L/L0≧1.05, the L being a flow length in the case where the mixture contains the polyolefin wax and the Lo being a flow length in the case where the mixture contains no polyolefin wax, the L and L0 being measured under the conditions of a mold temperature of 40° C. and a resin temperature, Tr, as determined by the following equation: Tr=¾×Tm+100(wherein Tm represents a melting temperature (° C.) of the thermoplastic resin), using a spiral flow mold having a thickness of 1 mm and a width of 10 mm.
摘要翻译：本发明提供一种热塑性树脂的注射成型方法，其能够通过提高注射成型性，特别是脱模性或流动性而能够进行薄型化或精密成型，而不会降低热塑性树脂的注塑制品的特性。制造注射成型制品的方法包括注射模塑含有热塑性树脂和聚烯烃蜡的混合物，其中混合物的L / L <0.01 / L = 1.05，L是在该情况下的流动长度其中混合物包含聚烯烃蜡，并且在混合物不含聚烯烃蜡的情况下Lo为流动长度，在模具温度为40℃的条件下测量L和L 0 和树脂温度Tr，由以下等式确定：<？in-line-formula description =“In-line Formulas”end =“lead”？> Tr =¾xTm+ 100 <？in-line-formula description （“In-line Formulas”end =“tail”？>（其中Tm表示热塑性树脂的熔融温度（℃）），使用厚度为1mm，宽度为10mm的螺旋流动模具。

9. 发明授权

US09260549B2 Resin fine powder consisting of 4-methyl-1-pentene polymer, composition containing same, and process for production thereof 有权
标题翻译：由4-甲基-1-戊烯聚合物，含有它们的组合物组成的树脂细粉末及其制造方法
公开(公告)号：US09260549B2
公开(公告)日：2016-02-16
申请号：US13643866
申请日：2011-02-08
申请人： Kuniaki Kawabe , Toshiyuki Itou , Mai Kurihara , Kazutoshi Fujihara , Ryouichi Seki
发明人： Kuniaki Kawabe , Toshiyuki Itou , Mai Kurihara , Kazutoshi Fujihara , Ryouichi Seki
IPC分类号： C08F110/14 , C04B38/06 , C08J3/12 , C09D7/12 , C09D11/102 , C09D123/20 , C08L23/20 , C04B111/00 , C08K3/08 , C08K3/34 , C09D11/033 , C09D11/106
CPC分类号： C08F110/14 , C04B38/0635 , C04B2111/00793 , C08J3/12 , C08J2323/20 , C08K3/08 , C08K3/34 , C08L23/20 , C09D7/61 , C09D11/033 , C09D11/102 , C09D11/106 , C09D123/20 , Y10T428/2982 , C08F2500/17 , C08F2500/18 , C08F2500/11 , C08F2500/24 , C04B35/00 , C04B38/0006
摘要： A resin fine powder which consists of a 4-methyl-1-pentene polymer that exhibits a limiting viscosity [η] of 1.0×10−2 to less than 3.0 dl/g as determined in decalin at 135° C. and which has a median particle diameter [D50] of 1.0×10−1 to 5.0×10 μm; and a composition which comprises the resin fine powder and at least one sinterable powder selected from the group consisting of metal powders and ceramic powders.
摘要翻译：由在135℃的萘烷中测定的显示特性粘度[η]为1.0×10-2〜小于3.0dl / g的4-甲基-1-戊烯类聚合物的树脂细粉末，中值粒径[D50]为1.0×10-1〜5.0×10μm; 以及包含树脂细粉和至少一种选自金属粉末和陶瓷粉末的可烧结粉末的组合物。

10. 发明授权

US08765872B2 4-methyl-1-pentene polymer, resin composition containing 4-methyl-1-pentene polymer, masterbatch thereof, and formed product thereof 有权
标题翻译： 4-甲基-1-戊烯聚合物，含有4-甲基-1-戊烯聚合物的树脂组合物，其母料及其成型产物
公开(公告)号：US08765872B2
公开(公告)日：2014-07-01
申请号：US12987510
申请日：2011-01-10
申请人： Kuniaki Kawabe , Masayoshi Sutou , Toshiyuki Itou , Mai Kurihara , Akinori Etoh , Shinichirou Asao , Kenji Sugimura , Hiroshi Hoya , Koji Matsunaga , Yoji Hayakawa , Kunihiko Mizumoto
发明人： Kuniaki Kawabe , Masayoshi Sutou , Toshiyuki Itou , Mai Kurihara , Akinori Etoh , Shinichirou Asao , Kenji Sugimura , Hiroshi Hoya , Koji Matsunaga , Yoji Hayakawa , Kunihiko Mizumoto
IPC分类号： C08L23/20 , C08L77/00 , C08L63/00 , C08F110/14 , C08F4/42 , C08F210/14
CPC分类号： C08F10/14 , C08F210/14 , C08J3/226 , C08J5/18 , C08J2323/02 , C08J2323/06 , C08J2323/12 , C08J2367/00 , C08J2369/00 , C08J2377/00 , C08J2377/02 , C08J2423/20 , C08L23/00 , C08L23/06 , C08L23/12 , C08L23/20 , C08L23/22 , C08L63/00 , C08L67/00 , C08L69/00 , C08L77/00 , C08L77/02 , C08L2310/00 , C08L2666/06 , C09J7/22 , C09J2423/006 , C09J2463/006 , C09J2467/006 , C09J2469/006 , C09J2477/006 , Y10T428/28 , C08F210/06 , C08F2500/12
摘要： [Object] To provide a resin composition with excellent mold releasability and blocking resistance.[Solution] A resin composition containing a 4-methyl-1-pentene polymer includes 0.01 to 10 parts by mass of a 4-methyl-1-pentene polymer (B) per 100 parts by mass of at least one resin (A) selected from the group consisting of thermoplastic resins and thermosetting resins, wherein the 4-methyl-1-pentene polymer (B) has (B1) an intrinsic viscosity [η] of 0.01 or more but less than 0.50 dl/g measured at 135° C. in a decalin solvent.
摘要翻译：提供具有优异的脱模性和抗粘连性的树脂组合物。 [解决方案]含有4-甲基-1-戊烯聚合物的树脂组合物，相对于所选择的至少一种树脂（A），相对于每100质量份的所述4-甲基-1-戊烯类聚合物（B），含有0.01〜10质量份的4-甲基-1-戊烯类聚合物由热塑性树脂和热固性树脂组成的组合物，其中4-甲基-1-戊烯聚合物（B）的特性粘度[ηe]为135°时测得的0.01或更大但小于0.50dl / g C.在十氢化萘溶剂中。

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