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1. 发明授权

US4386203A Halogen-containing s-triazines 失效
标题翻译：含卤素的s-三嗪
公开(公告)号：US4386203A
公开(公告)日：1983-05-31
申请号：US305857
申请日：1981-09-25
申请人： Herbert Naarmann , Klaus Penzien , Franz Brandstetter , Gerhard Lindenschmidt , Erhard Seiler
发明人： Herbert Naarmann , Klaus Penzien , Franz Brandstetter , Gerhard Lindenschmidt , Erhard Seiler
IPC分类号： C07D251/34 , C08K5/00 , C08K5/34 , C08K5/3477 , C08K5/3492 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C07D251/30
CPC分类号： C08K5/3492 , C07D251/34
摘要： Halogen-containing s-triazine compounds of the formula I ##STR1## where R is OH, R.sup.1, R.sup.2 or R.sup.3, R.sup.1 is ##STR2## where R.sup.4 is lower alkyl or lower haloalkyl, X is bromine or chlorine, k and n are 0 or integers from 1 to 5 and k+n is not more than 5, R.sup.2 is ##STR3## where R.sup.5 is lower alkyl or lower haloalkyl, Z is bromine or chlorine, s and p are 0 or integers from 1 to 4 and s+p is not more than 4, and R.sup.3 is ##STR4## where R, R.sup.5, Z, s and p have the above meanings. The compounds claimed are prepared by reacting cyanuric chloride with a phenol of the formula III ##STR5## and a benzene derivative of the formula IV ##STR6## in the presence of a base. The products thereby obtained are used for flameproofing thermoplastics, in particular styrene/acrylonitrile copolymers made impact-resistant with rubber (ABS resins).
摘要翻译：其中R是OH，R 1，R 2或R 3的R 1是其中R 4是低级烷基或低级卤代烷基，X是溴或氯的卤素含量的三嗪化合物，其中R是OH，R1，R2或R3，k和n是 0或1〜5的整数，k + n为5以下，R2为R5，其中R5为低级烷基或低级卤代烷基，Z为溴或氯，s为p，p为0或1〜4的整数，s为 + p不大于4，R3为，其中R，R5，Z，s和p具有上述含义。所要求的化合物通过在碱存在下使氰尿酰氯与式III的苯酚和式IV的苯衍生物反应来制备。由此获得的产品用于隔热热塑性塑料，特别是用橡胶（ABS树脂）制成抗冲击性的苯乙烯/丙烯腈共聚物。

2. 发明授权

US4360455A Preparation of mixtures of brominated polystyrenes and brominated aromatic compounds 失效
标题翻译：制备溴化聚苯乙烯和溴化芳族化合物的混合物
公开(公告)号：US4360455A
公开(公告)日：1982-11-23
申请号：US228368
申请日：1981-01-26
申请人： Gerhard Lindenschmidt , Wolfgang Schulte , Franz Brandstetter , Herbert Naarmann , Klaus Penzien
发明人： Gerhard Lindenschmidt , Wolfgang Schulte , Franz Brandstetter , Herbert Naarmann , Klaus Penzien
IPC分类号： C08F8/00 , C08F8/20 , C08K5/03 , C08K5/06 , C08L7/00 , C08L21/00 , C08L23/00 , C08L25/00 , C08L51/00 , C08L51/02 , C08L55/02 , C08L67/00 , C08L77/00 , C08L101/00 , C08L27/24
CPC分类号： C08K5/03 , C08K5/06 , C08L55/02
摘要： A mixture of brominated oligomeric polystyrenes, having a degree of polymerization of from 3 to 400, and low molecular weight brominated aromatic compounds of the diphenyl ether type is obtained by polymerizing the non-brominated starting materials, in a halohydrocarbon solvent, using a Lewis acid catalyst. The reaction mixture is then brominated and extracted with water to remove hydrogen bromide and catalyst, and the solvent and volatile constituents are separated from the product. The bromination is carried out at from -30.degree. C. to +130.degree. C. The final mixtures have a low melt viscosity and are therefore particularly suitable for incorporation, as a flameproofing agent, into thermoplastics.
摘要翻译：通过在卤代烃溶剂中使用路易斯酸聚合非溴化原料，得到聚合度为3〜400的溴化低聚聚苯乙烯和低分子量二苯醚型溴化芳香族化合物的混合物催化剂。然后将反应混合物溴化并用水萃取以除去溴化氢和催化剂，并将溶剂和挥发性成分与产物分离。溴化在-30℃至+ 130℃下进行。最终的混合物具有低的熔体粘度，因此特别适用于作为防火剂掺入热塑性塑料中。

3. 发明授权

US4585536A Ion exchange membranes consisting of pyrrole polymers 失效
标题翻译：由吡咯聚合物组成的离子交换膜
公开(公告)号：US4585536A
公开(公告)日：1986-04-29
申请号：US603241
申请日：1984-04-23
申请人： Hermann Puetter , Herbert Naarmann , Klaus Penzien
发明人： Hermann Puetter , Herbert Naarmann , Klaus Penzien
IPC分类号： H01M8/18 , B01D57/02 , B01D69/02 , B01J47/12 , C02F1/42 , C08J5/22 , C08L45/00 , C25B13/08 , G01N27/416 , H01M2/16 , H01M8/02 , H01M10/36
CPC分类号： B01D61/46 , B01D61/44 , B01D71/72 , C08J5/2256 , C25B13/08 , H01M10/36 , H01M2/1653 , C08J2379/06 , H01M2300/0005
摘要： Electrochemical processes for selectively separating ions in aqueous soltuion are carried out using apparatuses in which two or more different spaces are separated by means of ion exchange membranes, and the membrane material consists of electrochemically prepared pyrrole polymers. Such ion exchange membranes are used as proton and anion exchange membranes.
摘要翻译：使用其中两个或更多个不同空间通过离子交换膜分离的装置进行在水溶液中选择性分离离子的电化学方法，并且膜材料由电化学制备的吡咯聚合物组成。这种离子交换膜用作质子和阴离子交换膜。

4. 发明授权

US4418187A Preparation of electrically conductive polymers 失效
标题翻译：导电聚合物的制备
公开(公告)号：US4418187A
公开(公告)日：1983-11-29
申请号：US254258
申请日：1981-04-15
申请人： Volker Muench , Herbert Naarmann , Klaus Penzien
发明人： Volker Muench , Herbert Naarmann , Klaus Penzien
IPC分类号： C08F4/06 , C08F38/00 , H01L51/30 , C08F112/32 , C08F126/00 , C08F126/06 , C08F126/12
CPC分类号： H01L51/004 , C08F38/00 , H01L51/0042 , Y02E10/549
摘要： A process for the preparation of electrically conductive polymers by polymerizing acenaphthylene, N-vinyl-heterocyclics, eg. N-vinylcarbazole or N-vinylpyridine, or N,N-divinylaniline at from -80.degree. to +100.degree. C. in the presence of a cationtic catalyst, wherein from 1 to 50 percent by weight of an oxidizing Lewis acid, preferably FeCl.sub.3, FeBr.sub.3, SbCl.sub.5, SbF.sub.5, AsF.sub.5 or CF.sub.3 -SO.sub.3 H, or a combination of AlCl.sub.3 or TiCl.sub.4 with the said compounds or with CrO.sub.3 or OsO.sub.4 is used as the catalyst. In a preferred embodiment of the process, thin films of the monomers to be polymerized, applied to glass or to a polymeric base, preferably to a plastic film, are treated with gaseous SbCl.sub.5, SbF.sub.5 or AsF.sub.5. The conductive polymers obtained can be used in the electrical industry for the production of solar cells, for the conversion and fixing of radiation and for the production of electrical and magnetic switches, as well as for the antistatic treatment of plastics.
摘要翻译：通过聚合苊烯，N-乙烯基 - 杂环化合物制备导电聚合物的方法， N-乙烯基咔唑或N-乙烯基吡啶或N，N-二乙烯基苯胺，在-80℃至+ 100℃下，在阳离子催化剂存在下，其中1至50重量％的氧化路易斯酸，优选FeCl 3， FeBr 3，SbCl 5，SbF 5，AsF 5或CF 3 SO 3 H，或AlCl 3或TiCl 4与所述化合物或与CrO 3或OsO 4的组合用作催化剂。在该方法的优选实施方案中，将待聚合的单体的薄膜施加到玻璃上或聚合物基体上，优选用塑料膜，用气态SbCl 5，SbF 5或AsF 5处理。所得到的导电聚合物可用于电气工业中用于生产太阳能电池，用于辐射的转换和固定以及电气和磁性开关的生产以及用于塑料的抗静电处理。

5. 发明授权

US4360644A Preparation of electrically conductive polyaromatics 失效
标题翻译：导电多芳族化合物的制备
公开(公告)号：US4360644A
公开(公告)日：1982-11-23
申请号：US221731
申请日：1980-12-31
申请人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
发明人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
IPC分类号： C08K5/00 , C07C27/00 , C07C39/12 , C07C67/00 , C08K5/13 , C08L65/00 , C08L65/02 , C09K3/16 , H01B1/12 , H01L51/30 , H01L51/42 , C08G61/10 , C08L3/00
CPC分类号： H01B1/128 , C08L65/00 , C08L65/02 , C09K3/16 , H01L51/0035 , C08G2261/312 , H01L51/0052 , H01L51/42 , Y02E10/549
摘要： A process for the preparation of electrically conductive polyaromatics having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 15% by weight of an oxidizing Lewis acid, e.g. antimony pentafluoride or arsenic pentafluoride, or their NO.sup.+ - or NO.sub.2.sup.+ -salts, or a nitroaromatic, e.g. trinitrophenol or trinitrobenzenesulfonic acid, and/or a fluorine derivative, e.g. CF.sub.3 --COOH, or an acid, e.g. sulfuric acid, nitric acid or perchloric acid, is added to a polyaromatic, in the absence of moisture.
摘要翻译：一种制备电导率大于10-2S / cm的导电多芳族化合物的方法，其中按重量计0.5至15％的氧化性路易斯酸，例如，五氟化锑或五氟化砷，或它们的NO +或NO 2 +盐，或硝基芳族化合物。三硝基苯酚或三硝基苯磺酸，和/或氟衍生物。 CF 3 -COOH，或酸，例如。在没有水分的情况下，将硫酸，硝酸或高氯酸加入到多芳族化合物中。

6. 发明授权

US4344869A Preparation of electrically conductive hetero-poly-phenylenes 失效
标题翻译：导电异聚亚苯基的制备
公开(公告)号：US4344869A
公开(公告)日：1982-08-17
申请号：US237635
申请日：1981-02-24
申请人： Gerd Blinne , Herbert Naarmann , Klaus Penzien
发明人： Gerd Blinne , Herbert Naarmann , Klaus Penzien
IPC分类号： C08L71/00 , C08L81/00 , C08L85/00 , C09K3/16 , H01B1/12 , H01L51/30 , H01B1/00
CPC分类号： H01L51/0036 , C08L71/00 , C08L81/00 , C08L85/00 , C09K3/16 , H01B1/128 , H01L51/0035 , Y02E10/549
摘要： A process for the preparation of electrically conductive hetero-polyphenylenes, having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 35 percent by weight of a strong Lewis acid having a pk.sub.a of from -10 to +4, preferably AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ AsF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sub.2.sup.+BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid or 2,4,6-trinitrobenzoic acid, is added to a hetero-polyphenylene in the absence of moisture and of oxygen.
摘要翻译：具有导电性大于10-2S / cm的导电异聚亚苯基的制备方法，其中0.5至35重量％的pka为-10至+4的强路易斯酸，优选AsF5，SbF5 ，UF6，HClO4，NO + SbF6-，NO2 + SbF6-，NO + AsF6-，NO + PF6-，NO2 + PF6-，NO + BF4-，NO2 + BF4-，NO + ClO4-，（CF3）将2,4,6-三硝基苯酚，2,4,6-三硝基苯磺酸或2,4,6-三硝基苯甲酸加入到不存在水分和氧气的异亚苯基中。

7. 发明授权

US4049622A Self-extinguishing thermoplastic molding compositions 失效
标题翻译：自熄性热塑性成型组合物
公开(公告)号：US4049622A
公开(公告)日：1977-09-20
申请号：US715640
申请日：1976-08-18
申请人： Helmut Fleig , Helmut Hagen , Herbert Naarmann , Klaus Penzien
发明人： Helmut Fleig , Helmut Hagen , Herbert Naarmann , Klaus Penzien
IPC分类号： C08L25/00 , C08K5/17 , C08K5/34 , C08K5/46 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L101/00 , C08J9/00
CPC分类号： C08K5/46 , Y10S260/24 , Y10S521/907
摘要： Thermoplastic molding compositions based on styrene polymers contain, as a flameproofing agent, an organic bromine compound of the general formula ##STR1## where X is a hydrocarbon radical and n is 0 or 1. The compositions may be used for the manufacture of self-extinguishing moldings, e.g. foams.
摘要翻译：基于苯乙烯聚合物的热塑性模塑组合物含有作为防火剂的通式为“IMAGE”的有机溴化合物，其中X为烃基，n为0或1.该组合物可用于制造自熄性模制品，例如泡沫

8. 发明授权

US4560593A Deposition of metals on electrically conductive, polymeric carriers 失效
标题翻译：在导电的聚合物载体上沉积金属
公开(公告)号：US4560593A
公开(公告)日：1985-12-24
申请号：US662546
申请日：1984-10-19
申请人： Herbert Naarmann , Volker Munch , Klaus Penzien
发明人： Herbert Naarmann , Volker Munch , Klaus Penzien
IPC分类号： C23C14/14 , C23C18/16 , C23C18/31 , C23C18/34 , C23C18/38 , C23C18/44 , C23C18/52 , C25D5/56 , H05K3/18 , C23C3/02
CPC分类号： C23C18/52 , C25D5/56 , H05K3/181
摘要： A process for depositing metals onto electrically conductive, polymeric carriers, wherein a finely divided metal M having a standard potential E.sub.o of >-2 V is deposited, from a solution of a metal cation compound of the formula (I) ##EQU1## where M', L.sup.1, L.sup.2, L.sup.3, L.sup.4, l, m, n, o, and p are as defined in the claims, in an aprotic polar or non-polar solvent, onto a polymeric, electrically conductive carrier of the formula (II) ##EQU2## where M" is Li, Na, K, Rb or Cs,P is P=--CH--, --C.sub.6 H.sub.4 --, --C.sub.4 H.sub.2 S--, --C.sub.6 H.sub.4 S--, --C.sub.4 H.sub.2 O--, --C.sub.4 H.sub.2 NH-- --C.sub.6 H.sub.4 O-- or --C.sub.5 H.sub.3 N--y is from 0.001 to 0.6 andx is from 5 to 1,000, or onto a polymeric, electrically conductive carrier of the formula (III)[(P)(X).sub.y ].sub.x (III)whereP is one of the groups listed for formula (II), X is ClO.sub.4.sup..crclbar., AsF.sub.6.sup..crclbar., PF.sub.6.sup..crclbar., SbF.sub.6.sup..crclbar., BF.sub.4.sup..crclbar., HSO.sub.4.sup..crclbar., CF.sub.3 SO.sub.3.sup..crclbar. or Br.sup..crclbar.,y is from 0.001 to 0.6 andx is from 5 to 1,000, by reduction, preferably at from -100.degree. to +100.degree. C. The electrically conductive, polymeric systems can be employed in the electrical industry for the production of solar cells, for converting and fixing radiation, and for the production of electric and magnetic switches and electrical storage devices, and can also be used as heterogeneous catalysts and to provide an antistatic finish on plastics.
摘要翻译：一种将金属沉积在导电聚合物载体上的方法，其中从式（I）的化学式（I）的化学式（I）的化学物质中沉积出具有> -2V的标准电位Eo的细碎金属M（I ）其中M'，L1，L2，L3，L4，l，m，n，o和p如权利要求中所定义，在非质子传递极性或非极性溶剂中，（II）其中M“是Li，Na，K，Rb或Cs，P是P = -CH-，-C6H4-，-C4H2S-，-C6H4S-， -C 4 H 2 O-，-C 4 H 2 NH-C 6 H 4 O-或-C 5 H 3 N-y为0.001至0.6，x为5至1,000，或通式（III）[（P）（X）y）的聚合导电载体上 ] x（III）其中P是式（II）中所列的基团之一，X是ClO 4（ - ），AsF 6（ - ），PF 6（ - ），SbF 6（ - ），BF 4（ - ），HSO 4 ，CF 3 SO 3（ - ）或Br（ - ），y为0.001至0.6，x为5至1,000，通过还原，优选为-100至+ 100℃。可使用导电聚合体系在电气工业中用于生产太阳能电池，用于转换和固定辐射，以及用于生产电磁开关和蓄电装置，并且还可以用作非均相催化剂并在塑料上提供抗静电涂饰。

9. 发明授权

US4440693A Preparation of electrically conductive products 失效
标题翻译：导电产品的制备
公开(公告)号：US4440693A
公开(公告)日：1984-04-03
申请号：US327726
申请日：1981-12-04
申请人： Herbert Naarmann , Klaus Penzien , Volker Muench , Klaus-Dieter Franz
发明人： Herbert Naarmann , Klaus Penzien , Volker Muench , Klaus-Dieter Franz
IPC分类号： C08G79/00 , C08G79/14 , C08K5/00 , H01B1/12 , H01L51/30 , C07F1/08 , C07F15/02
CPC分类号： H01L51/0077 , C08G79/00 , C08G79/14 , C08K5/0091 , H01B1/12 , H01L51/0051 , H01L51/0052 , Y02E10/549
摘要： A process for the preparation of electrically conductive products which are stable to air and have conductivities greater than 1 .times.10.sup.-3 S/cm, by reacting a cation of a metal of group VII or VIII or of sub-group I of the periodic table with an organic chelating compound to give a metal chelate and oxidizing the latter to form a oxidized product, wherein the organic chelating compound is a 1,9-substituted phenalene of the formula I ##STR1## where X is O, NH, S, Se or Te and Y is OH, NH.sub.2 or SH. The electrically conductive products are useful for the production of solar cells, the conversion and fixing of radiation, the production of electrical and magnetic switches and the antistatic treatment of plastics.
摘要翻译：通过将元素周期表第VII族或第Ⅷ族金属或第1族元素的阳离子与阳离子的反应，通过使周期表第Ⅶ族或Ⅷ族金属的阳离子与一种有机螯合化合物，得到金属螯合物并将其氧化以形成氧化产物，其中有机螯合化合物是式I的1,9-取代的非那烯，其中X是O，NH，S，Se或 Te和Y是OH，NH2或SH。导电产品可用于生产太阳能电池，辐射的转换和固定，电气和磁性开关的生产以及塑料的抗静电处理。

10. 发明授权

US4395497A Preparation of electrically conductive soluble heteropolyphenylenes 失效
标题翻译：导电性可溶性多聚苯乙烯的制备
公开(公告)号：US4395497A
公开(公告)日：1983-07-26
申请号：US273688
申请日：1981-06-15
申请人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
发明人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
IPC分类号： C08G61/12 , C08L65/00 , H01B1/12 , H01L51/30 , C08L77/02
CPC分类号： H01B1/128 , C08G61/123 , C08L65/00 , H01B1/127 , H01L51/0035 , C08G2261/312 , Y02E10/549
摘要： A process for the preparation of electrically conductive heteropolyphenylenes, wherein from 0.5 to 5 per cent by weight of an activating additive is introduced, in the absence of moisture and of oxygen, into a heteropolyphenylene of the general formula ##STR1## where X is O, S, Se, SO or SO.sub.2 and Y has one of the meanings given for X or is NH, CH.sub.2, CO or C.sub.6 H.sub.4, and n is from 2 to 250. The activating additive is preferably one of the compounds AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, SbCl.sub.5, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid and 2,4,6-trinitrophenylcarboxylic acid, or is sodium, potassium, rubidium, cesium, calcium or barium or one of their amides, the latter being added, if appropriate, in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene. The conductive heteropolyphenylenes may be used in the electrical industry for the production of solar cells, for conversion and fixing of radiation and for the production of electrical and magnetic switches, or may be used for the antistatic treatment of plastics.
摘要翻译：一种用于制备导电杂多苯基苯的方法，其中将0.5-5重量％的活化添加剂在没有水分和氧气的情况下引入通式为“IMAGE”的杂多亚苯基，其中X为O， S，Se，SO或SO 2，Y具有对X给出的含义之一或为NH，CH 2，CO或C 6 H 4，n为2至250.活化添加剂优选为化合物AsF5，SbF5，UF6， HClO4，NO + SbF6-，NO2 + SbF6-，NO + PF6-，SbCl5，NO2 + PF6-，NO + BF4-，NO + ClO4-，（CF3）2SO4,2,4,6-三硝基苯酚，6-三硝基苯磺酸和2,4,6-三硝基苯基羧酸，或者是钠，钾，铷，铯，钙或钡或它们的酰胺之一，如果合适，将其加入四氢呋喃，二甲氧基乙二醇，蒽，萘或2-甲基苯乙烯。导电杂多亚苯基可用于电气工业中用于生产太阳能电池，用于辐射的转换和固定以及用于电气和磁性开关的生产，或可用于塑料的抗静电处理。

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