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    • 6. 发明授权
    • Polymer compositions having improved constancy of properties
    • 具有改善的性能恒定性的聚合物组合物
    • US06767962B2
    • 2004-07-27
    • US10206638
    • 2002-07-26
    • Herbert EichenauerVera BuchholzEckhard Wenz
    • Herbert EichenauerVera BuchholzEckhard Wenz
    • C08L5100
    • C08L51/04C08F279/02C08F279/04C08F285/00C08L25/12C08L35/00C08L55/02C08L2666/24C08L51/00C08L2666/02
    • A thermoplastic molding composition that contains a plurality of graft rubbers is disclosed. A first graft rubber is a product of emulsion polymerization of a mixture containing styrene and acrylonitrile in the presence of butadiene polymer latex (A) having an average particle diameter (d50) of 80 to 220 nm. An additional graft rubber is a product of emulsion polymerization of a mixture containing styrene and acrylonitrile in the presence of butadiene polymer latex (B) having an average particle diameter (d50) of 350 to 650 nm. The butadiene polymer latex (A) is the product of seed polymerization in which seed is butadiene polymer latex having a median particle diameter of 10 to 100 nm, and the butadiene polymer latex (B) is the product of agglomeration in which butadiene polymer latex (A) is the starting latex.
    • 公开了一种含有多个接枝橡胶的热塑性模塑组合物。 在平均粒径(d50)为80〜220nm的丁二烯聚合物胶乳(A)的存在下,第一接枝橡胶是含有苯乙烯和丙烯腈的混合物的乳液聚合的产物。 在平均粒径(d50)为350〜650nm的丁二烯聚合物胶乳(B)的存在下,另外的接枝橡胶是含有苯乙烯和丙烯腈的混合物的乳液聚合的产物。 丁二烯聚合物胶乳(A)是种子聚合的产物,其中种子是中值粒径为10-100nm的丁二烯聚合物胶乳,丁二烯聚合物胶乳(B)是其中丁二烯聚合物胶乳( A)是起始胶乳。