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1. 发明授权

US07473664B2 Formation of Ziegler-Natta catalyst 有权
标题翻译：齐格勒 - 纳塔催化剂的形成
公开(公告)号：US07473664B2
公开(公告)日：2009-01-06
申请号：US11474145
申请日：2006-06-23
申请人： Kayo Vizzini , David Knoeppel , Steven Gray , David Rauscher , Tim Coffy , Henry Enriquez
发明人： Kayo Vizzini , David Knoeppel , Steven Gray , David Rauscher , Tim Coffy , Henry Enriquez
IPC分类号： B01J37/22
CPC分类号： B01J31/122 , C08F10/02 , C08F110/02 , C08F4/6557 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F2500/24 , C08F2500/19
摘要： Methods of forming polyolefins and catalysts are described herein. Such methods generally include forming Ziegler-Natta catalyst compounds in the absence of one or more blended compounds typically used to form such catalyst.
摘要翻译：本文描述了形成聚烯烃和催化剂的方法。这样的方法通常包括在不存在通常用于形成这种催化剂的一种或多种共混化合物的情况下形成齐格勒 - 纳塔催化剂化合物。

2. 发明授权

US07655590B2 Ziegler-Natta catalyst for particle size control 失效
标题翻译：齐格勒 - 纳塔催化剂用于粒度控制
公开(公告)号：US07655590B2
公开(公告)日：2010-02-02
申请号：US12004814
申请日：2007-12-20
申请人： Henry Enriquez , Kayo Vizzini , Steven Gray
发明人： Henry Enriquez , Kayo Vizzini , Steven Gray
IPC分类号： B01J37/16 , B01J37/22
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6557 , C08F2500/24 , C08F2500/18 , C08F2500/12 , C08F2500/19 , C08F2500/07 , C08F2500/23 , C08F2500/04
摘要： Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product “A1”, contacting the solution of reaction product “A1” with a reducing agent to form a reduced reaction product “A2”, contacting reduced reaction product “A2” with a second agent to form a solid reaction product “A3”, contacting solid reaction product “A3” with a metal halide to form reaction product “B” and contacting reaction product “B” with an organoaluminum compound to form a catalyst component.
摘要翻译：本文描述了催化剂组分，形成催化剂组合物的方法，利用催化剂组合物的聚合方法和由此形成的聚合物。所述方法通常包括提供二烷氧基镁化合物，使二烷氧基镁化合物与第一试剂接触以形成反应产物“A1”的溶液，使反应产物“A1”的溶液与还原剂接触以形成还原反应产物 “A2”，将还原的反应产物“A2”与第二试剂接触以形成固体反应产物“A3”，使固体反应产物“A3”与金属卤化物接触以形成反应产物“B”并使反应产物“B” 与有机铝化合物形成催化剂组分。

3. 发明申请

US20090163680A1 Ziegler-Natta catalyst for particle size control 失效
标题翻译：齐格勒 - 纳塔催化剂用于粒度控制
公开(公告)号：US20090163680A1
公开(公告)日：2009-06-25
申请号：US12004814
申请日：2007-12-20
申请人： Henry Enriquez , Kayo Vizzini , Steven Gray
发明人： Henry Enriquez , Kayo Vizzini , Steven Gray
IPC分类号： C08F4/76
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6557 , C08F2500/24 , C08F2500/18 , C08F2500/12 , C08F2500/19 , C08F2500/07 , C08F2500/23 , C08F2500/04
摘要： Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product “A1”, contacting the solution of reaction product “A1” with a reducing agent to form a reduced reaction product “A2”, contacting reduced reaction product “A2” with a second agent to form a solid reaction product “A3”, contacting solid reaction product “A3” with a metal halide to form reaction product “B” and contacting reaction product “B” with an organoaluminum compound to form a catalyst component.
摘要翻译：本文描述了催化剂组分，形成催化剂组合物的方法，利用催化剂组合物的聚合方法和由此形成的聚合物。所述方法通常包括提供二烷氧基镁化合物，使二烷氧基镁化合物与第一试剂接触以形成反应产物“A1”的溶液，使反应产物“A1”的溶液与还原剂接触以形成还原反应产物 “A2”，将还原的反应产物“A2”与第二试剂接触以形成固体反应产物“A3”，使固体反应产物“A3”与金属卤化物接触以形成反应产物“B”并使反应产物“B” 与有机铝化合物形成催化剂组分。

4. 发明申请

US20070299224A1 Formation of Ziegler-Natta catalyst 有权
标题翻译：齐格勒 - 纳塔催化剂的形成
公开(公告)号：US20070299224A1
公开(公告)日：2007-12-27
申请号：US11474145
申请日：2006-06-23
申请人： Kayo Vizzini , David Knoeppel , Steven Gray , David Rauscher , Tim Coffy , Henry Enriquez
发明人： Kayo Vizzini , David Knoeppel , Steven Gray , David Rauscher , Tim Coffy , Henry Enriquez
IPC分类号： C08F4/44
CPC分类号： B01J31/122 , C08F10/02 , C08F110/02 , C08F4/6557 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F2500/24 , C08F2500/19
摘要： Methods of forming polyolefins and catalysts are described herein. Such methods generally include forming Ziegler-Natta catalyst compounds in the absence of one or more blended compounds typically used to form such catalyst.
摘要翻译：本文描述了形成聚烯烃和催化剂的方法。这样的方法通常包括在不存在通常用于形成这种催化剂的一种或多种共混化合物的情况下形成齐格勒 - 纳塔催化剂化合物。

5. 发明授权

US08063159B2 Process for controlling morphology of Ziegler-Natta catalysts 失效
标题翻译：控制齐格勒 - 纳塔催化剂形态的方法
公开(公告)号：US08063159B2
公开(公告)日：2011-11-22
申请号：US11778262
申请日：2007-07-16
申请人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
发明人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
IPC分类号： C08F4/00
CPC分类号： C08F10/00 , C08F210/16 , Y10T428/1345 , Y10T428/139 , C08F4/6546 , C08F4/6541
摘要： Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties.
摘要翻译：公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。其包括通过控制可溶性含镁催化剂前体的浓度来改变催化剂组分从包括可溶性镁的催化剂前体的催化剂合成溶液中的沉淀，其中催化剂组分的平均粒径增加，并且颗粒尺寸分布增加，可溶性含镁催化剂前体的浓度降低; 或沉淀剂，其中催化剂组分的平均粒度增加，并且随着沉淀剂浓度的增加，粒度分布增加。使用本发明能够改善催化剂的一致性，而不管生产规模如何，催化剂形态定制成所需的聚合物形态。新颖的催化剂组分可用于制备聚合物及其最终用途制品，具有期望的性能。

6. 发明申请

US20090023875A1 Process for Controlling Morphology of Ziegler-Natta Catalysts 失效
标题翻译：控制齐格勒 - 纳塔催化剂形态的方法
公开(公告)号：US20090023875A1
公开(公告)日：2009-01-22
申请号：US11778262
申请日：2007-07-16
申请人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
发明人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
IPC分类号： B01J37/03 , C08F4/12
CPC分类号： C08F10/00 , C08F210/16 , Y10T428/1345 , Y10T428/139 , C08F4/6546 , C08F4/6541
摘要： Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
摘要翻译：公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。其包括通过控制可溶性含镁催化剂前体的浓度来改变催化剂组分从包括可溶性镁的催化剂前体的催化剂合成溶液中的沉淀，其中催化剂组分的平均粒径增加，并且颗粒尺寸分布增加，可溶性含镁催化剂前体的浓度降低; 或沉淀剂，其中催化剂组分的平均粒度增加，并且随着沉淀剂浓度的增加，粒度分布增加。使用本发明能够改善催化剂的一致性，而不管生产规模如何，催化剂形态定制成所需的聚合物形态。新颖的催化剂组分可用于制备聚合物及其最终用途制品，具有期望的性能。要强调的是，该摘要被提供以符合要求摘要的规则，这将允许搜索者或其他读者快速确定技术公开的主题。提交它的理解是，它不会用于解释或限制权利要求的范围或含义。

7. 发明申请

US20120064268A1 Process for Controlling Morphology of Ziegler-Natta Catalysts 审中-公开
标题翻译：控制齐格勒 - 纳塔催化剂形态的方法
公开(公告)号：US20120064268A1
公开(公告)日：2012-03-15
申请号：US13272279
申请日：2011-10-13
申请人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
发明人： Kayo Vizzini , Henry Enriquez , Steven D. Gray , Tim J. Coffy , David W. Knoeppel
IPC分类号： B32B1/08 , C08F10/00 , B32B1/00 , C08F4/16
CPC分类号： C08F10/00 , C08F210/16 , Y10T428/1345 , Y10T428/139 , C08F4/6546 , C08F4/6541
摘要： Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. The process enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
摘要翻译：公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。该方法能够改善催化剂的一致性，而不管生产规模如何，催化剂形态定制成所需的聚合物形态。新颖的催化剂组分可用于制备聚合物及其最终用途制品，具有期望的性能。要强调的是，该摘要被提供以符合要求摘要的规则，这将允许搜索者或其他读者快速确定技术公开的主题。提交它的理解是，它不会用于解释或限制权利要求的范围或含义。

8. 发明授权

US07282546B2 Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations 有权
标题翻译：用于减少茂金属催化聚合中的生产问题的助催化剂
公开(公告)号：US07282546B2
公开(公告)日：2007-10-16
申请号：US11158454
申请日：2005-06-22
申请人： Steven Gray , Henry Enriquez , David Knoeppel
发明人： Steven Gray , Henry Enriquez , David Knoeppel
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/65927 , C08F210/16 , Y10S526/934 , C08F4/65912 , C08F210/14
摘要： Polyolefins may be prepared using a cocatalyst conforming to the formula: AIRz(Xz)nLzm wherein Rz is a linear or branched organic moiety having at least 5 carbons and Xz is a linear or branched organic moiety having at least 5 carbons or a heterocyclic moiety having at least 4 atoms and can be anionic or di-anionic. The aluminum complex may also be in the form of an adduct complex where Lz is a Lewis base and m=1-3. The cocatalyst Rz components are selected such that they do not react with water under polymerization conditions to form a species that is highly soluble in the polymerization diluent. Use of the specified cocatalyst reduces fouling during metallocene-catalyzed runs and “post-metallocene hangover” when the same production equipment is transitioned to non-metallocene catalyst runs using catalysts such as chromium.
摘要翻译：聚烯烃可以使用符合下列公式的助催化剂制备：<？in-line-formula description =“In-line formula”end =“lead”？>空气（X < ？？？？？z？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？其中R z是具有至少5个碳原子的直链或支链有机部分，X是具有至少5个碳原子的直链或支链有机部分或具有至少5个碳原子的杂环部分，至少4个原子，可以是阴离子或二阴离子。铝络合物也可以是加合物络合物的形式，其中L z是路易斯碱，m = 1-3。选择助催化剂R z z组分使得它们在聚合条件下不与水反应以形成高度可溶于聚合稀释剂的物质。使用特定的助催化剂可以减少金属茂催化运行期间的结垢和“后金属茂宿醉”，当相同的生产设备使用催化剂如铬转变为非茂金属催化剂运行时。

9. 发明申请

US20060293472A1 Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations 有权
标题翻译：用于减少茂金属催化聚合中的生产问题的助催化剂
公开(公告)号：US20060293472A1
公开(公告)日：2006-12-28
申请号：US11158454
申请日：2005-06-22
申请人： Steven Gray , Henry Enriquez , David Knoeppel
发明人： Steven Gray , Henry Enriquez , David Knoeppel
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/65927 , C08F210/16 , Y10S526/934 , C08F4/65912 , C08F210/14
摘要： Polyolefins may be prepared using a cocatalyst conforming to the formula: AIRz(Xz)nLzm wherein Rz is a linear or branched organic moiety having at least 5 carbons and Xz is a linear or branched organic moiety having at least 5 carbons or a heterocyclic moiety having at least 4 atoms and can be anionic or di-anionic. The aluminum complex may also be in the form of an adduct complex where Lz is a Lewis base and m=1-3. The cocatalyst Rz components are selected such that they do not react with water under polymerization conditions to form a species that is highly soluble in the polymerization diluent. Use of the specified cocatalyst reduces fouling during metallocene-catalyzed runs and “post-metallocene hangover” when the same production equipment is transitioned to non-metallocene catalyst runs using catalysts such as chromium.
摘要翻译：聚烯烃可以使用符合下列公式的助催化剂制备：<？in-line-formula description =“In-line formula”end =“lead”？>空气（X < ？？？？？z？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？？其中R z是具有至少5个碳原子的直链或支链有机部分，X是具有至少5个碳原子的直链或支链有机部分或具有至少5个碳原子的杂环部分，至少4个原子，可以是阴离子或二阴离子。铝络合物也可以是加合物络合物的形式，其中L z是路易斯碱，m = 1-3。选择助催化剂R z z组分使得它们在聚合条件下不与水反应以形成高度可溶于聚合稀释剂的物质。使用特定的助催化剂可以减少金属茂催化运行期间的结垢和“后金属茂宿醉”，当相同的生产设备使用催化剂如铬转变为非茂金属催化剂运行时。

10. 发明申请

US20050209094A1 Ziegler-natta catalyst for polyolefins 审中-公开
标题翻译：齐格勒 - 纳塔催化剂用于聚烯烃
公开(公告)号：US20050209094A1
公开(公告)日：2005-09-22
申请号：US11133685
申请日：2005-05-20
申请人： David Knoeppel , Tim Coffy , Henry Enriquez , Steven Gray
发明人： David Knoeppel , Tim Coffy , Henry Enriquez , Steven Gray
IPC分类号： C08F4/654 , B01J31/00 , B01J31/02 , C08F4/44 , C08F4/658 , C08F10/00 , C08F10/02 , C08F110/02
CPC分类号： B01J31/0212 , B01J2231/122 , B01J2531/31 , B01J2531/46 , C08F10/00 , C08F110/02 , C08F4/6557 , C08F2500/04 , C08F2500/12 , C08F4/6546 , C08F4/651 , C08F4/6567 , C08F2500/02 , C08F2500/23 , C08F2500/07 , C08F2500/18
摘要： A Ziegler-Natta type catalyst component can be produced by a process comprising contacting a magnesium dialkoxide compound with a halogenating agent to form a reaction product A, and contacting reaction product A with a first, second and third halogenating/titanating agents. Catalyst components, catalysts, catalyst systems, polyolefin, products made therewith, and methods of forming each are disclosed. The reaction products can be washed with a hydrocarbon solvent to reduce titanium species [Ti] content to less than about 100 mmol/L.
摘要翻译：齐格勒 - 纳塔型催化剂组分可以通过包括使二烷氧基镁化合物与卤化剂接触以形成反应产物A并使反应产物A与第一，第二和第三卤化/钛化剂接触的方法制备。公开了催化剂组分，催化剂，催化剂体系，聚烯烃，由其制备的产品，以及各自形成的方法。可以用烃溶剂洗涤反应产物以将钛物质[Ti]含量降低至小于约100mmol / L。

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