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    • 9. 发明申请
    • Production of bisphenol-A with reduced sulfur content
    • 生产具有降低硫含量的双酚A
    • US20050215833A1
    • 2005-09-29
    • US11043800
    • 2005-01-26
    • Rainer NeumannUlrich BlaschkeStefan Westernacher
    • Rainer NeumannUlrich BlaschkeStefan Westernacher
    • C07C37/20C07C37/82C07C37/84C07C39/16C08G64/06
    • C07C37/20C07C37/70C07C37/82C07C37/84C08G64/06C07C39/16
    • A process for the production of bisphenol-A having low concentration of sulphur is disclosed. The process comprise a) reacting phenol with acetone in the presence of a sulfonic acid ion exchanger to form a product mixture containing water, bisphenol-A/phenol adduct, phenol and sulfurous particles, and b) filtering the product mixture to separate the sulfurous particles to obtain a purified product mixture that contains water, phenol and bisphenol-A/phenol adduct. In one embodiment of the process further comprise distilling the purified product mixture to remove the water to obtain a first material system that contains said adduct and phenol, crystallizing the adduct, and removing the phenol by filtration using a filtering apparatus to obtain crystalline adduct. In a yet additional embodiment the process comprise crystallizing the purified product mixture to obtain a second material system that contains crystalline adduct, water and phenol and removing the phenol and water by filtration using a filtering apparatus to obtain crystalline adduct.
    • 公开了一种生产低浓度硫的双酚A的方法。 该方法包括a)在磺酸离子交换剂存在下使苯酚与丙酮反应,形成含有水,双酚A /苯酚加成物,苯酚和亚硫酸颗粒的产物混合物,和b)过滤产物混合物以分离出亚硫酸颗粒 以获得含有水,苯酚和双酚A /苯酚加合物的纯化产物混合物。 在该方法的一个实施方案中还包括蒸馏纯化的产物混合物以除去水以获得含有所述加合物和苯酚的第一材料体系,结晶加合物,并使用过滤装置通过过滤除去苯酚以获得结晶加合物。 在另外的实施方案中,该方法包括使纯化的产物混合物结晶以获得含有结晶加合物,水和苯酚的第二材料体系,并使用过滤装置通过过滤除去苯酚和水以获得结晶加合物。