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    • 3. 发明授权
    • Butadiene/sytrene block copolymers having an asymmetric structure, their
preparation and their use as molding materials
    • 具有不对称结构的丁二烯/ sytrene嵌段共聚物,其制备及其作为模塑材料的用途
    • US4891410A
    • 1990-01-02
    • US184068
    • 1988-04-20
    • Klaus BronstertDaniel WagnerHorst Schuch
    • Klaus BronstertDaniel WagnerHorst Schuch
    • C08F297/04
    • C08F297/04
    • In block copolymers of the general formula A--B--A' which have a molecular weight of less than 300,000 and consist of from 18 to 40% by weight of a vinylaromatic hydrocarbon and from 60 to 82% by weight of one or more partially or completely hydrogenated hydrocarbons and in which A and A' are each a polymer block of a vinylaromatic hydrocarbon and B is a polymer block of a diene hydrocarbon, the weight ratio of the polymer blocks A to A' is less than or equal to 1:5 and greater than 1:10 and the mean molecular weight of polymer block A is from 2,000 to 20,000 and that of the polymer block A' is from 10,000 to 110,000 and the molecular weight of the B block is not less than 18,000. The block copolymers are prepared by a process in which, in a first polymerization stage, the vinylaromatic hydrocarbon is completely polymerized to form the A or A' block, in the second polymerization stage the diene hydrocarbon is completely converted to form the B block and thereafter the second portion of the vinylaromatic hydrocarbon is polymerized on to form the A or A' block, the portion of a vinylaromatic compound for the preparation of the A' block being not less than five times, and not more than 10 times, the weight used to form the A block. The block copolymers are used for the preparation of molding materials.
    • 通式ABA'的嵌段共聚物,其分子量小于300,000,由18至40重量%的乙烯基芳族烃和60至82重量%的一种或多种部分或完全氢化的烃和 其中A和A'各自为乙烯基芳族烃的聚合物嵌段,B为二烯烃的聚合物嵌段,聚合物嵌段A与A'的重量比小于或等于1:5且大于1 10,聚合物嵌段A的平均分子量为2,000〜20,000,聚合物嵌段A'的平均分子量为10,000〜110,000,B嵌段的分子量为18000以上。 嵌段共聚物通过以下方法制备,其中在第一聚合阶段,乙烯基芳族烃完全聚合以形成A或A'嵌段,在第二聚合阶段中,二烯烃完全转化成B嵌段,此后 将乙烯基芳族烃的第二部分聚合形成A或A'嵌段,用于制备A'嵌段的乙烯基芳族化合物部分不小于所用重量的5倍,而不超过10倍 形成A块。 嵌段共聚物用于制备模塑材料。
    • 5. 发明授权
    • Thermoplatic molding materials
    • 热塑性成型材料
    • US5334658A
    • 1994-08-02
    • US991650
    • 1992-12-16
    • Uwe BlumensteinPeter KlaernerHorst SchuchHans-Michael Walter
    • Uwe BlumensteinPeter KlaernerHorst SchuchHans-Michael Walter
    • C08L51/04C08L25/06
    • C08L25/06C08L51/04
    • A thermoplastic molding material contains, based on the sum of A and B,A: from 75 to 97% by weight of a polystyrene A as a hard matrix andB: from 3 to 25% by weight of a particulate, elastomeric (co)polymer B based essentially on butadiene or its copolymers, in turn consisting of, based on B,B1: from 40 to 98% by weight of a (co)polymer B1 having a mean particle size of from 100 to 600 nm andB2: from 2 to 60% by weight of a particle blend B2 which in turn consists of, based on B2,B21: from 1 to 60% by weight of a (co)polymer B21 having a particle size of from 200 to 1,200 nm andB22: from 40 to 99% by weight of a (co)polymer B22 having a mean particle size of from 1,200 to 8,000 nm,(co)polymer B1 having an encapsulated-particle morphology and (co)polymers B21 and B22 having a cellular and/or coiled particle morphology.
    • 热塑性成型材料基于A和B的总和含有A:75至97重量%的作为硬质基质的聚苯乙烯A和B:3至25重量%的颗粒状弹性体(共) 聚合物B基本上基于丁二烯或其共聚物,反过来由B,B1组成:40至98重量%的平均粒径为100-600纳米的(共)聚合物B1,B2:来自 2至60重量%的颗粒共混物B2,其又由基于B2的B21组成:1至60重量%的粒度为200至1200nm的(共)聚合物B21和B22: 40〜99重量%的平均粒径为1200-8000nm的(共)聚合物B22,具有包封颗粒形态的(共)聚合物B1和具有细胞和/或细胞的(共)聚合物B21和B22, 或卷曲粒子形态。
    • 6. 发明授权
    • Process and apparatus for the parallel analysis of colloidal particles using field-flow fractionation
    • 使用场流分级技术平行分析胶体颗粒的方法和装置
    • US06562307B1
    • 2003-05-13
    • US09610944
    • 2000-07-06
    • Horst SchuchWolfgang Schrof
    • Horst SchuchWolfgang Schrof
    • B01D1104
    • G01N30/0005G01N2030/628G01N30/466
    • The present invention relates to an apparatus for the simultaneous analysis of at least two samples by the field-flow fractionation method, where the apparatus has at least the following elements: a) a source of a defined liquid stream, preferably a pump, b) at least two separation channels, each with at least one inlet and each with at least one outlet for passing the at least two samples through in each case one of the at least two separation channels, c) at least one controllable unit which is connected to the at least two separation channels via their at least one outlet each, and which can pass on the at least two samples, which can be passed through in each case one of the at least two separation channels, separately from one another to at least one unit downstream of the controllable unit.
    • 本发明涉及一种用于通过场流分级方法同时分析至少两个样品的装置,其中所述装置至少具有以下元件:a)限定液流源,优选泵,b) 至少两个分离通道,每个具有至少一个入口,每个具有至少一个出口,用于使所述至少两个样品在每种情况下通过所述至少两个分离通道中的一个; c)至少一个可控单元,其连接到 所述至少两个分离通道经由其至少一个出口各自并且可以在所述至少两个样品上通过,所述至少两个样品可以在所述至少两个分离通道中的每一个彼此分开地通过至少一个 单元在可控单元的下游。