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    • 1. 发明授权
    • Butadiene/sytrene block copolymers having an asymmetric structure, their
preparation and their use as molding materials
    • 具有不对称结构的丁二烯/ sytrene嵌段共聚物,其制备及其作为模塑材料的用途
    • US4891410A
    • 1990-01-02
    • US184068
    • 1988-04-20
    • Klaus BronstertDaniel WagnerHorst Schuch
    • Klaus BronstertDaniel WagnerHorst Schuch
    • C08F297/04
    • C08F297/04
    • In block copolymers of the general formula A--B--A' which have a molecular weight of less than 300,000 and consist of from 18 to 40% by weight of a vinylaromatic hydrocarbon and from 60 to 82% by weight of one or more partially or completely hydrogenated hydrocarbons and in which A and A' are each a polymer block of a vinylaromatic hydrocarbon and B is a polymer block of a diene hydrocarbon, the weight ratio of the polymer blocks A to A' is less than or equal to 1:5 and greater than 1:10 and the mean molecular weight of polymer block A is from 2,000 to 20,000 and that of the polymer block A' is from 10,000 to 110,000 and the molecular weight of the B block is not less than 18,000. The block copolymers are prepared by a process in which, in a first polymerization stage, the vinylaromatic hydrocarbon is completely polymerized to form the A or A' block, in the second polymerization stage the diene hydrocarbon is completely converted to form the B block and thereafter the second portion of the vinylaromatic hydrocarbon is polymerized on to form the A or A' block, the portion of a vinylaromatic compound for the preparation of the A' block being not less than five times, and not more than 10 times, the weight used to form the A block. The block copolymers are used for the preparation of molding materials.
    • 通式ABA'的嵌段共聚物,其分子量小于300,000,由18至40重量%的乙烯基芳族烃和60至82重量%的一种或多种部分或完全氢化的烃和 其中A和A'各自为乙烯基芳族烃的聚合物嵌段,B为二烯烃的聚合物嵌段,聚合物嵌段A与A'的重量比小于或等于1:5且大于1 10,聚合物嵌段A的平均分子量为2,000〜20,000,聚合物嵌段A'的平均分子量为10,000〜110,000,B嵌段的分子量为18000以上。 嵌段共聚物通过以下方法制备,其中在第一聚合阶段,乙烯基芳族烃完全聚合以形成A或A'嵌段,在第二聚合阶段中,二烯烃完全转化成B嵌段,此后 将乙烯基芳族烃的第二部分聚合形成A或A'嵌段,用于制备A'嵌段的乙烯基芳族化合物部分不小于所用重量的5倍,而不超过10倍 形成A块。 嵌段共聚物用于制备模塑材料。
    • 3. 发明授权
    • Polymers containing amino groups, their preparation and their use
    • 含有氨基的聚合物,其制备及其用途
    • US4791174A
    • 1988-12-13
    • US30487
    • 1987-03-27
    • Klaus BronstertDaniel Wagner
    • Klaus BronstertDaniel Wagner
    • C08F8/12C08F8/30C08F8/32
    • C08F8/32C08F8/30C08F2800/20
    • Homo- co- and/or block polymers which are modified with amino functional groups, are obtained from vinylaromatics and/or dienes and contain functional groups of the formulae (I) to (VI) ##STR1## where N is nitrogen, R.sup.1 and R.sup.4 are each hydrogen, alkyl, cycloalkyl or aryl, R.sup.2, R.sup.3 and R.sup.5 are each alkyl, cycloalkyl or aryl, Me is an alkali metal and A is an unsubstituted or substituted bridge which, in addition to carbon, may contain N or O members, a process for the preparation of the polymers from living anionically polymerized or alkali-metal-metallized homo-, co- and/or block copolymers from vinylaromatics and/or dienes, which are reacted with appropriate nitrogen compounds in the presence of a polar or nonpolar solvent, and the conversion of the polymers as claimed in claim 1 for the preparation of similar polymers by hydrolysis, alcoholysis and/or hydrogenation.
    • 用氨基官能团改性的同 - 和/或嵌段聚合物由乙烯基芳烃和/或二烯衍生得到,并含有式(I)至(VI)的官能团。 (VI)其中N为氮,R1和R4分别为氢,烷基,环烷基或芳基,R2,R3和R5分别为 烷基,环烷基或芳基,Me是碱金属,A是未被取代或取代的桥,除了碳之外,还可以含有N或O成员,由活性阴离子聚合或碱金属 - 在极性或非极性溶剂的存在下与适当的氮化合物反应的乙烯基芳族化合物和/或二烯的金属化的均聚物,共聚物和/或嵌段共聚物,以及权利要求1所述的聚合物的转化用于制备 类似的聚合物通过水解,醇解和/或氢化。
    • 6. 发明授权
    • Polymers with functional groups
    • 具有功能组合的聚合物
    • US5064907A
    • 1991-11-12
    • US576196
    • 1990-08-30
    • Klaus BronstertDaniel Wagner
    • Klaus BronstertDaniel Wagner
    • C08F8/02C08F8/30
    • C08F8/30
    • Modified homopolymer, random copolymers and/or block copolymers of aromatic vinyls and/or dienes contain functional groups of the general formula (I): ##STR1## where N is nitrogen, O is oxygen, Y is a substituted or unsubstituted bridge which besides carbon additionally contains N- or O-members, R is any desired organic radical, R.sup.1 is hydrogen, alkyl, cycloalkyl or aryl, and n is a whole number greater than or equal to 1, are prepared from living anionically polymerized or from alkali metallized homopolymers, random copolymers and/or block copolymers of aromatic vinyls and/or dienes which, reacted with organic nitrogen compounds, have a nitrogen-alkali metal bond by reaction of polymers of the general formula (II) in the presence of a polar or apolar solvent with compounds of the general formula (III) where Me is an alkali metal, X is halogen and Y, O, N, R, n and R.sup.1 (other than hydrogen) have the abovementioned meanings ##STR2##
    • 芳族乙烯基和/或二烯的改性均聚物,无规共聚物和/或嵌段共聚物含有通式(I)的官能团:其中N是氮,O是氧,Y是取代或未取代的桥 除碳外还含有N-或O-成员,R是任何所需的有机基团,R1是氢,烷基,环烷基或芳基,n是大于或等于1的整数,由阴离子聚合的活性或从 碱金属化均聚物,与有机氮化合物反应的芳族乙烯基和/或二烯的无规共聚物和/或嵌段共聚物通过在极性存在下通过通式(II)的聚合物反应而具有氮 - 碱金属键 或非极性溶剂,其中Me为碱金属,X为卤素且Y,O,N,R,n和R 1(除氢以外)具有通式(III)的化合物具有上述含义
    • 8. 发明授权
    • Online creation of panoramic augmented reality annotations on mobile platforms
    • 在移动平台上在线创建全景增强现实注释
    • US09204040B2
    • 2015-12-01
    • US13112329
    • 2011-05-20
    • Tobias Martin LanglotzDaniel WagnerAlessandro MulloniDieter Schmalstieg
    • Tobias Martin LanglotzDaniel WagnerAlessandro MulloniDieter Schmalstieg
    • H04N7/00H04N5/232
    • H04N5/23238
    • A mobile platform generates a panoramic map by rotating a camera and stores the panoramic map. The mobile platform performs a computer vision operation on the panoramic map while continuing to generate the panoramic map. The mobile platform may determine the location of the camera when the panoramic map is generated, produce an annotation on the panoramic map and transmit the determined location, annotation, and portion to a storage device. In another example, the mobile platform may receive an annotation, a portion of a source panoramic map associated with the annotation, and a location where the source panoramic map was generated. The mobile platform may compare the portion of the source panoramic map to the panoramic map to identify a position on the panoramic map that corresponds to the portion of the source panoramic map, and display the annotation based on the determined position on the panoramic map.
    • 移动平台通过旋转相机并存储全景地图来生成全景地图。 移动平台在全景地图上执行计算机视觉操作,同时继续生成全景地图。 当生成全景地图时,移动平台可以确定摄像机的位置,在全景地图上产生注释并将确定的位置,注释和部分发送到存储设备。 在另一示例中,移动平台可以接收注释,与注释相关联的源全景图的一部分,以及生成源全景图的位置。 移动平台可以将源全景地图的部分与全景地图进行比较,以识别全景地图上对应于源全景地图的该部分的位置,并且基于在全景地图上确定的位置来显示该注释。
    • 9. 发明授权
    • Styrol/butadiene block copolymer mixtures for shrink films
    • 用于收缩膜的苯乙烯/丁二烯嵌段共聚物混合物
    • US09090768B2
    • 2015-07-28
    • US11813742
    • 2005-12-31
    • Konrad KnollHelmut SteiningerMichael SchusterDaniel WagnerPeter Merkel
    • Konrad KnollHelmut SteiningerMichael SchusterDaniel WagnerPeter Merkel
    • C08L53/02
    • C08L53/02C08L2666/24
    • A mixture which comprises from 5 to 50% by weight of a block copolymer A, which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C.; from 95 to 50% by weight of a block copolymer B, which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C.; from 0 to 45% by weight of polystyrene or of a block copolymer C other than A and B; and from 0 to 6% by weight of a plasticizer; and its use for production of shrink films.
    • 包含5至50重量%的嵌段共聚物A的混合物,其包含一种或多种共聚物嵌段(B / S)A,每个共聚物嵌段(B / S)A由65至95重量%的乙烯基芳族单体和35至5重量% 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内; 95至50重量%的嵌段共聚物B,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种共聚物嵌段(B / S)B,每个共聚物嵌段(B / S)B由20至60重量%的乙烯基芳族 单体和80〜40重量%的二烯,玻璃化转变温度TgB在-70℃至0℃的范围内。 0至45重量%的聚苯乙烯或除A和B之外的嵌段共聚物C; 和0〜6重量%的增塑剂; 并用于生产收缩膜。