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1. 发明授权

US06245403B1 Writable and erasable high-density optical storage media 失效
标题翻译：可写和可擦除的高密度光存储介质
公开(公告)号：US06245403B1
公开(公告)日：2001-06-12
申请号：US09069266
申请日：1998-04-29
申请人： Heinz Spahni , Jin Mizuguchi , Beat Schmidhalter , Annemarie Wolleb , Jean-Luc Budry , Gérald Giller
发明人： Heinz Spahni , Jin Mizuguchi , Beat Schmidhalter , Annemarie Wolleb , Jean-Luc Budry , Gérald Giller
IPC分类号： B32B302
CPC分类号： C07D471/06 , C09B5/62 , G11B7/00455 , G11B7/0052 , G11B7/00552 , G11B7/006 , G11B7/244 , Y10S428/913 , Y10S430/146 , Y10T428/21
摘要： The invention relates to an optical storage medium comprising a substrate and a storage layer, wherein the storage layer comprises a compound of the formula (I) or (II) in which A and A′, independently of one another, are unsubstituted or mono- or di-halo-, -hydroxy-, —C1-C6alkyl-, —C1-C6alkoxy-, -cyano- or -nitro-substituted phenyl, pyridyl, pyrrolyl, imidazolyl, furyl or thienyl, which can, if desired, be fused to a benzene ring, are halide, tetrafluoroborate or unsubstituted or with one or more halogen substituted C1-C6alkane-sulfonate, benzenesulfonate, C1-C6alkylbenzenesulfonate, C1-C6alkylsulfate or di-C1-C6alkyl-phosphonate of N—C1-C6alkyl-pyridiniumyl, or are unsubstituted or mono- or di-hydroxy-substituted C2-C6alkyl or C2-C6alkenyl, whose chain may be uninterrupted or interrupted by one or two oxygen atoms, B and B′, independently of one another, are 2 H, S, S2 or SO2, and n and n′, independently of one another, are each a number from 1 to 4. The invention also relates to a process for the optical writing, storage, reading, modification or erasing of data at a wavelength of from 400 to 700 nm using a novel recording medium, to an optical recorder for the optical writing, modification or erasing of data using only continuous laser radiation or only modulated laser radiation, to a process for converting a compound of the formula (I) or (II) from a black form into a red form by mechanical force, and to new compounds of the formula (I) or (II).
摘要翻译：本发明涉及一种包括基材和存储层的光学存储介质，其中该储存层包含式（I）或（II）的化合物，其中A和A'彼此独立地为未取代的或单 - 或二卤代 - ， - 羟基 - ，-C 1 -C 6烷基 - ， - C 1 -C 6烷氧基 - ， - 氰基 - 或 - 硝基取代的苯基，吡啶基，吡咯基，咪唑基，呋喃基或噻吩基，如果需要，苯基环，卤素取代的C 1 -C 6烷基磺酸酯，苯磺酸酯，C 1 -C 6烷基苯磺酸酯，C 1 -C 6烷基硫酸酯或N-C 1 -C 6烷基 - 吡啶鎓基的二-C 1 -C 6烷基 - 膦酸酯，或未被取代的单或二羟基取代的C 2 -C 6烷基或C 2 -C 6烯基，其链可以不间断或被一个或两个氧原子间隔，B和B'彼此独立地为2 H，S， S2或SO2，n和n'彼此独立地为1至4的数。本发明还涉及一种pr 用于使用新颖的记录介质将波长为400至700nm的数据的光学写入，存储，读取，修改或擦除的光学记录到用于仅使用连续激光辐射的光学写入，修改或擦除数据的光学记录器，通过机械力将式（I）或（II）的化合物从黑色形式转化成红色的方法，以及式（I）或（II）的新化合物的方法。

2. 发明申请

US20080130474A1 Optical Recording Materials Having High Stroage Density 审中-公开
标题翻译：具有高剧烈密度的光学记录材料
公开(公告)号：US20080130474A1
公开(公告)日：2008-06-05
申请号：US10561392
申请日：2004-06-25
申请人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
发明人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
IPC分类号： G11B7/24 , B32B3/02
CPC分类号： G11B7/248 , C09B47/26
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I). For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 300 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density even at high speeds.
摘要翻译：本发明涉及一种光记录介质，其包括基底，记录层和任选的一个或多个反射层，其中记录层包含式（I）的化合物。关于进一步取代基的详细定义，参见说明书。特别是在300〜500nm的波长下进行记录和回放，例如使用蓝色激光。录音和播放质量极佳，即使在高速下也能保持较高的存储密度。

3. 发明申请

US20070172624A1 Optical recording materials writable using blue lasers 审中-公开
标题翻译：光学记录材料可使用蓝色激光器写入
公开(公告)号：US20070172624A1
公开(公告)日：2007-07-26
申请号：US10590021
申请日：2005-02-16
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
IPC分类号： B32B3/02
CPC分类号： G11B7/2492 , C09B47/045 , G11B7/2472 , G11B7/2475 , G11B7/2478 , G11B7/248 , G11B7/2534 , G11B7/259 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I) or a tautomeric or mesomeric form thereof, wherein G1 and G2 are each independently of the other C(R5) or N; M1 is a lanthanide or transition metal of groups 4 to 10; P is a phthalocyanino diradical; and R1 to R5 are substituents as defined in the description and the claims. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density.
摘要翻译：本发明涉及一种包括基底，记录层和任选的一个或多个反射层的光学记录介质，其中记录层包含式（I）化合物或其互变异构体或介导体形式，其中G 1， / SUB和G 2各自独立地为C（R 5 N）或N; M 1是第4至10族的镧系元素或过渡金属; P是酞菁双基; 和R 1至R 5是如说明书和权利要求书中所定义的取代基。记录和回放特别是在350至500nm的波长下进行，例如使用蓝色激光。录制和播放质量非常好，可以保持较高的存储密度。

4. 发明申请

US20050250942A1 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US20050250942A1
公开(公告)日：2005-11-10
申请号：US11169126
申请日：2005-06-28
申请人： Jurgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jurgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： B41M5/26 , C09B47/12 , C09B47/18 , C09B47/24 , C09B67/22 , G11B7/244 , G11B7/248 , G11B7/26 , C09B47/04 , G11B7/24
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要翻译：通过使包含两种酞菁的混合物A与茂金属衍生物在催化剂存在下反应获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质。

5. 发明授权

US07378221B2 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US07378221B2
公开(公告)日：2008-05-27
申请号：US11169126
申请日：2005-06-28
申请人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： C09B47/04 , G11B7/24
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要翻译：通过使包含两种酞菁的混合物A与茂金属衍生物在催化剂存在下反应获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质。

6. 发明授权

US07034148B2 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US07034148B2
公开(公告)日：2006-04-25
申请号：US10474634
申请日：2002-04-09
申请人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： C09B47/04 , C09B67/00 , C07D487/22
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines (I) and (II) with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media
摘要翻译：通过在催化剂存在下使包含两种酞菁（I）和（II）的混合物A与金属茂衍生物反应而获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质

7. 发明授权

US06399768B1 Metallocenyl-phthalocyanines 有权
标题翻译：金属茂 - 酞菁
公开(公告)号：US06399768B1
公开(公告)日：2002-06-04
申请号：US09365471
申请日：1999-08-02
申请人： Heinz Wolleb , Annemarie Wolleb , Beat Schmidhalter , Jean-Luc Budry
发明人： Heinz Wolleb , Annemarie Wolleb , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： G11B724
CPC分类号： C07F17/00 , C07F17/02 , C09B47/08 , C09B67/0035 , Y10S430/146 , Y10T428/12722 , Y10T428/21
摘要： There was found a metallocenyl-phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, in which at least one of the four phenyl rings of the phthalocyanine contains, bound via a bridge unit E, at least one metallocene radical as substituent, E being composed of a chain of at least two atoms or atom groups selected from the group consisting of —CH2—, —C(═O)—, —CH(C1-C4alkyl)—, —C(C1-C4alkyl)2—, —NH—, —S—, —O— and —CH═CH—, as well as mixtures of the novel compounds which comprise, inter alia, isomers, a process for the production, the use and recording media comprising the novel compounds.
摘要翻译：发现金属茂金属酞菁或其二价金属，氧化金属，卤素金属或羟基金属的金属络合物，其中酞菁的四个苯环中的至少一个含有通过桥单元E结合至少一个金属茂基团作为取代基，E由至少两个原子的链或选自-CH 2 - ， - C（= O） - ， - CH（C 1 -C 4烷基） - ， - C（C 1 -C 4烷基） 2-，-NH-，-S-，-O-和-CH = CH-，以及包含异构体的新化合物的混合物，制备方法，使用和记录介质，其包含新化合物。

8. 发明申请

US20080193700A1 Metal Chelates and Their Use in Optical Recording Media Having High Storage Capacity 审中-公开
标题翻译：金属螯合物及其在具有高存储容量的光记录介质中的应用
公开(公告)号：US20080193700A1
公开(公告)日：2008-08-14
申请号：US11579261
申请日：2005-04-25
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： B32B3/00 , C07D277/64 , C07D401/06 , C07F9/6541
CPC分类号： G11B7/246 , C07D277/64 , C07D277/84 , C07D417/06 , C07D513/04 , C07F17/02 , G11B7/2467 , G11B7/249 , G11B7/2492 , G11B7/2495 , G11B7/2534 , G11B7/259 , G11B2007/24612 , G11B2007/25706 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to novel optical recording media, which comprise particular novel metal chelates and have an excellent recording and playback quality, especially at a wavelength of from 300 to 500 nm.
摘要翻译：本发明涉及新颖的光学记录介质，其包含特别新颖的金属螯合物，并且具有优异的记录和回放质量，特别是在300-500nm的波长下。

9. 发明申请

US20060177621A1 O-coordinated metal chelates and their use in optical recording media having high storage capacity 审中-公开
标题翻译： O-配位金属螯合物及其在存储容量高的光记录介质中的应用
公开(公告)号：US20060177621A1
公开(公告)日：2006-08-10
申请号：US10565138
申请日：2004-07-12
申请人： Frank Bienewald , Jean-Luc Budry , Beat Schmidhalter , Annemarie Wolleb , Heinz Wolleb
发明人： Frank Bienewald , Jean-Luc Budry , Beat Schmidhalter , Annemarie Wolleb , Heinz Wolleb
IPC分类号： B32B3/02
CPC分类号： G11B7/246 , C07C225/14 , C07D207/20 , C07D209/12 , C07D209/34 , C07D211/86 , C07D213/69 , C07D233/48 , C07D235/30 , C07D239/62 , C07D239/66 , C07D263/14 , C07D277/64 , C07D277/82 , C07D309/32 , C07D309/38 , C07D319/06 , C07D403/06 , G11B7/247 , G11B7/249 , G11B7/2534 , G11B7/259
摘要： The invention relates to novel optical recording materials that comprise specific and in some cases novel diketone enamines or metal chelates thereof and that have excellent recording and playback quality especially at a wavelength of 350-500 nm. The invention accordingly relates to an optical recording medium comprising a substrate, a recording layer and optionally a reflecting layer, wherein the recording layer comprises a compound of formula (I), wherein M is hydrogen, aluminium or, preferably, a transition metal, which may in addition be coordinated with one or more further ligands and/or, for balancing out an excess charge, where applicable, may have an electrostatic interaction with one or more further ions inside or outside the coordination sphere, but M in formulae (Ib) and (Ic) is not hydrogen, Q is C—H, N or C—R6, it being possible for the stereochemistry of the C=Q double bond to be either E or Z. For the exact definitions of R1 to R6 reference should be made to the description. Also claimed are the novel compounds, especially tetracoordinated chelates, and a process for the preparation thereof.
摘要翻译：本发明涉及新颖的光学记录材料，其特别地包括新颖的二酮烯胺或其金属螯合物，并且具有优异的记录和回放质量，特别是在350-500nm的波长下。因此，本发明涉及一种包括基底，记录层和任选地反射层的光学记录介质，其中记录层包含式（I）化合物，其中M是氢，铝或优选的过渡金属，其中另外可以与一种或多种其它配位体配位和/或用于平衡过量电荷（如果适用的话）可能与配位球内部或外部的一种或多种其它离子具有静电相互作用，而式（Ib）和（Ic）不是氢，Q是CH，N或CR 6，C = Q双键的立体化学可以是E或Z。对于R的确切定义应当对说明书进行参考。还要求保护的是新化合物，特别是四配位螯合物，以及其制备方法。

10. 发明授权

US06790593B2 Metallocenyl-phthalocyanines 失效
标题翻译：金属茂 - 酞菁
公开(公告)号：US06790593B2
公开(公告)日：2004-09-14
申请号：US10037106
申请日：2001-10-22
申请人： Heinz Wolleb , Annemarie Wolleb , Beat Schmidhalter , Jean-Luc Budry
发明人： Heinz Wolleb , Annemarie Wolleb , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： G11B724
CPC分类号： C07F17/00 , C07F17/02 , C09B47/08 , C09B67/0035 , Y10S430/146 , Y10T428/12722 , Y10T428/21
摘要： There was found a metallocenyl-phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, in which at least one of the four phenyl rings of the phthalocyanine contains, bound via a bridge unit E, at least one metallocene radical as substituent, E being composed of a chain of at least two atoms or atom groups selected from the group consisting of —CH2—, —C(═O)—, —CH(C1-C4alkyl)—, —C(C1-C4alkyl)2—, —NH—, —S—, —O— and —CH═CH—, as well as mixtures of the novel compounds which comprise, inter alia, isomers, a process for the production, the use and recording media comprising the novel compounds.
摘要翻译：发现金属茂金属酞菁或其二价金属，氧化金属，卤素金属或羟基金属的金属络合物，其中酞菁的四个苯环中的至少一个含有通过桥单元E结合至少一个金属茂基团作为取代基，E由至少两个原子的链或选自-CH 2 - ， - C（= O） - ， - CH（C 1 -C 4烷基） - ， - C（C 1 -C 4烷基） 2-，-NH-，-S-，-O-和-CH = CH-，以及包含异构体的新化合物的混合物，制备方法，使用和记录介质，其包含新化合物。

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