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1. 发明申请

US20080130474A1 Optical Recording Materials Having High Stroage Density 审中-公开
标题翻译：具有高剧烈密度的光学记录材料
公开(公告)号：US20080130474A1
公开(公告)日：2008-06-05
申请号：US10561392
申请日：2004-06-25
申请人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
发明人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
IPC分类号： G11B7/24 , B32B3/02
CPC分类号： G11B7/248 , C09B47/26
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I). For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 300 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density even at high speeds.
摘要翻译：本发明涉及一种光记录介质，其包括基底，记录层和任选的一个或多个反射层，其中记录层包含式（I）的化合物。关于进一步取代基的详细定义，参见说明书。特别是在300〜500nm的波长下进行记录和回放，例如使用蓝色激光。录音和播放质量极佳，即使在高速下也能保持较高的存储密度。

2. 发明申请

US20070172624A1 Optical recording materials writable using blue lasers 审中-公开
标题翻译：光学记录材料可使用蓝色激光器写入
公开(公告)号：US20070172624A1
公开(公告)日：2007-07-26
申请号：US10590021
申请日：2005-02-16
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
IPC分类号： B32B3/02
CPC分类号： G11B7/2492 , C09B47/045 , G11B7/2472 , G11B7/2475 , G11B7/2478 , G11B7/248 , G11B7/2534 , G11B7/259 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I) or a tautomeric or mesomeric form thereof, wherein G1 and G2 are each independently of the other C(R5) or N; M1 is a lanthanide or transition metal of groups 4 to 10; P is a phthalocyanino diradical; and R1 to R5 are substituents as defined in the description and the claims. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density.
摘要翻译：本发明涉及一种包括基底，记录层和任选的一个或多个反射层的光学记录介质，其中记录层包含式（I）化合物或其互变异构体或介导体形式，其中G 1， / SUB和G 2各自独立地为C（R 5 N）或N; M 1是第4至10族的镧系元素或过渡金属; P是酞菁双基; 和R 1至R 5是如说明书和权利要求书中所定义的取代基。记录和回放特别是在350至500nm的波长下进行，例如使用蓝色激光。录制和播放质量非常好，可以保持较高的存储密度。

3. 发明申请

US20050250942A1 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US20050250942A1
公开(公告)日：2005-11-10
申请号：US11169126
申请日：2005-06-28
申请人： Jurgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jurgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： B41M5/26 , C09B47/12 , C09B47/18 , C09B47/24 , C09B67/22 , G11B7/244 , G11B7/248 , G11B7/26 , C09B47/04 , G11B7/24
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要翻译：通过使包含两种酞菁的混合物A与茂金属衍生物在催化剂存在下反应获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质。

4. 发明授权

US06399768B1 Metallocenyl-phthalocyanines 有权
标题翻译：金属茂 - 酞菁
公开(公告)号：US06399768B1
公开(公告)日：2002-06-04
申请号：US09365471
申请日：1999-08-02
申请人： Heinz Wolleb , Annemarie Wolleb , Beat Schmidhalter , Jean-Luc Budry
发明人： Heinz Wolleb , Annemarie Wolleb , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： G11B724
CPC分类号： C07F17/00 , C07F17/02 , C09B47/08 , C09B67/0035 , Y10S430/146 , Y10T428/12722 , Y10T428/21
摘要： There was found a metallocenyl-phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, in which at least one of the four phenyl rings of the phthalocyanine contains, bound via a bridge unit E, at least one metallocene radical as substituent, E being composed of a chain of at least two atoms or atom groups selected from the group consisting of —CH2—, —C(═O)—, —CH(C1-C4alkyl)—, —C(C1-C4alkyl)2—, —NH—, —S—, —O— and —CH═CH—, as well as mixtures of the novel compounds which comprise, inter alia, isomers, a process for the production, the use and recording media comprising the novel compounds.
摘要翻译：发现金属茂金属酞菁或其二价金属，氧化金属，卤素金属或羟基金属的金属络合物，其中酞菁的四个苯环中的至少一个含有通过桥单元E结合至少一个金属茂基团作为取代基，E由至少两个原子的链或选自-CH 2 - ， - C（= O） - ， - CH（C 1 -C 4烷基） - ， - C（C 1 -C 4烷基） 2-，-NH-，-S-，-O-和-CH = CH-，以及包含异构体的新化合物的混合物，制备方法，使用和记录介质，其包含新化合物。

5. 发明申请

US20080193700A1 Metal Chelates and Their Use in Optical Recording Media Having High Storage Capacity 审中-公开
标题翻译：金属螯合物及其在具有高存储容量的光记录介质中的应用
公开(公告)号：US20080193700A1
公开(公告)日：2008-08-14
申请号：US11579261
申请日：2005-04-25
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： B32B3/00 , C07D277/64 , C07D401/06 , C07F9/6541
CPC分类号： G11B7/246 , C07D277/64 , C07D277/84 , C07D417/06 , C07D513/04 , C07F17/02 , G11B7/2467 , G11B7/249 , G11B7/2492 , G11B7/2495 , G11B7/2534 , G11B7/259 , G11B2007/24612 , G11B2007/25706 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to novel optical recording media, which comprise particular novel metal chelates and have an excellent recording and playback quality, especially at a wavelength of from 300 to 500 nm.
摘要翻译：本发明涉及新颖的光学记录介质，其包含特别新颖的金属螯合物，并且具有优异的记录和回放质量，特别是在300-500nm的波长下。

6. 发明授权

US07378221B2 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US07378221B2
公开(公告)日：2008-05-27
申请号：US11169126
申请日：2005-06-28
申请人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： C09B47/04 , G11B7/24
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要翻译：通过使包含两种酞菁的混合物A与茂金属衍生物在催化剂存在下反应获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质。

7. 发明申请

US20060177621A1 O-coordinated metal chelates and their use in optical recording media having high storage capacity 审中-公开
标题翻译： O-配位金属螯合物及其在存储容量高的光记录介质中的应用
公开(公告)号：US20060177621A1
公开(公告)日：2006-08-10
申请号：US10565138
申请日：2004-07-12
申请人： Frank Bienewald , Jean-Luc Budry , Beat Schmidhalter , Annemarie Wolleb , Heinz Wolleb
发明人： Frank Bienewald , Jean-Luc Budry , Beat Schmidhalter , Annemarie Wolleb , Heinz Wolleb
IPC分类号： B32B3/02
CPC分类号： G11B7/246 , C07C225/14 , C07D207/20 , C07D209/12 , C07D209/34 , C07D211/86 , C07D213/69 , C07D233/48 , C07D235/30 , C07D239/62 , C07D239/66 , C07D263/14 , C07D277/64 , C07D277/82 , C07D309/32 , C07D309/38 , C07D319/06 , C07D403/06 , G11B7/247 , G11B7/249 , G11B7/2534 , G11B7/259
摘要： The invention relates to novel optical recording materials that comprise specific and in some cases novel diketone enamines or metal chelates thereof and that have excellent recording and playback quality especially at a wavelength of 350-500 nm. The invention accordingly relates to an optical recording medium comprising a substrate, a recording layer and optionally a reflecting layer, wherein the recording layer comprises a compound of formula (I), wherein M is hydrogen, aluminium or, preferably, a transition metal, which may in addition be coordinated with one or more further ligands and/or, for balancing out an excess charge, where applicable, may have an electrostatic interaction with one or more further ions inside or outside the coordination sphere, but M in formulae (Ib) and (Ic) is not hydrogen, Q is C—H, N or C—R6, it being possible for the stereochemistry of the C=Q double bond to be either E or Z. For the exact definitions of R1 to R6 reference should be made to the description. Also claimed are the novel compounds, especially tetracoordinated chelates, and a process for the preparation thereof.
摘要翻译：本发明涉及新颖的光学记录材料，其特别地包括新颖的二酮烯胺或其金属螯合物，并且具有优异的记录和回放质量，特别是在350-500nm的波长下。因此，本发明涉及一种包括基底，记录层和任选地反射层的光学记录介质，其中记录层包含式（I）化合物，其中M是氢，铝或优选的过渡金属，其中另外可以与一种或多种其它配位体配位和/或用于平衡过量电荷（如果适用的话）可能与配位球内部或外部的一种或多种其它离子具有静电相互作用，而式（Ib）和（Ic）不是氢，Q是CH，N或CR 6，C = Q双键的立体化学可以是E或Z。对于R的确切定义应当对说明书进行参考。还要求保护的是新化合物，特别是四配位螯合物，以及其制备方法。

8. 发明授权

US07034148B2 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US07034148B2
公开(公告)日：2006-04-25
申请号：US10474634
申请日：2002-04-09
申请人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： C09B47/04 , C09B67/00 , C07D487/22
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines (I) and (II) with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media
摘要翻译：通过在催化剂存在下使包含两种酞菁（I）和（II）的混合物A与金属茂衍生物反应而获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质

9. 发明授权

US06790593B2 Metallocenyl-phthalocyanines 失效
标题翻译：金属茂 - 酞菁
公开(公告)号：US06790593B2
公开(公告)日：2004-09-14
申请号：US10037106
申请日：2001-10-22
申请人： Heinz Wolleb , Annemarie Wolleb , Beat Schmidhalter , Jean-Luc Budry
发明人： Heinz Wolleb , Annemarie Wolleb , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： G11B724
CPC分类号： C07F17/00 , C07F17/02 , C09B47/08 , C09B67/0035 , Y10S430/146 , Y10T428/12722 , Y10T428/21
摘要： There was found a metallocenyl-phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, in which at least one of the four phenyl rings of the phthalocyanine contains, bound via a bridge unit E, at least one metallocene radical as substituent, E being composed of a chain of at least two atoms or atom groups selected from the group consisting of —CH2—, —C(═O)—, —CH(C1-C4alkyl)—, —C(C1-C4alkyl)2—, —NH—, —S—, —O— and —CH═CH—, as well as mixtures of the novel compounds which comprise, inter alia, isomers, a process for the production, the use and recording media comprising the novel compounds.
摘要翻译：发现金属茂金属酞菁或其二价金属，氧化金属，卤素金属或羟基金属的金属络合物，其中酞菁的四个苯环中的至少一个含有通过桥单元E结合至少一个金属茂基团作为取代基，E由至少两个原子的链或选自-CH 2 - ， - C（= O） - ， - CH（C 1 -C 4烷基） - ， - C（C 1 -C 4烷基） 2-，-NH-，-S-，-O-和-CH = CH-，以及包含异构体的新化合物的混合物，制备方法，使用和记录介质，其包含新化合物。

10. 发明授权

US5851621A High-capacity storage media 失效
标题翻译：大容量存储介质
公开(公告)号：US5851621A
公开(公告)日：1998-12-22
申请号：US842292
申请日：1997-04-23
申请人： Heinz Wolleb , Beat Schmidhalter , Jean-Luc Budry
发明人： Heinz Wolleb , Beat Schmidhalter , Jean-Luc Budry
IPC分类号： B41M5/26 , C07D311/82 , C07D491/16 , C09B11/28 , G11B7/244 , G11B7/246 , G11B7/249 , G11B7/253 , G11B7/2534 , G11B7/258 , B32B3/00
CPC分类号： G11B7/246 , C09B11/28 , G11B7/249 , G11B7/253 , G11B7/258 , G11B7/2534 , Y10S428/913 , Y10S430/146 , Y10T428/21 , Y10T428/31678
摘要： The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, which recording layer consists essentially of a dye of the formula (I), ##STR1## in which R.sub.1 and R.sub.6 are hydrogen or unsubstituted or substituted alkyl, alkenyl, alkynyl, aralkyl or aryl, R.sub.6 and R.sub.7 are unsubstituted or substituted alkyl, alkenyl, alkynyl, aralky or aryl, R.sub.3, R.sub.4, R.sub.8 and R.sub.9 are hydrogen, halogen, OR.sub.17, SR.sub.17, NR.sub.18 R.sub.19, NO.sub.2, alkyl, alkenyl or Alkynyl, R.sub.5 and R.sub.10 are hydrogen, halogen, OR.sub.17, SR.sub.17, NO.sub.2, NR.sub.18 R.sub.19 or unsubstituted or substituted alkyl, alkenyl, alkynyl or aralkyl, and R.sub.11 is hydrogen, (CH.sub.2).sub.1-10 COO.sup.-, (CH.sub.2).sub.1-10 COOR.sub.24, alkyl, alkenyl, alkynyl or unsubstituted or substituted aralkyl or aryl; Y is the anion of an inorganic, organic or organometallic acid, Z is a metal cation, ammonium cation or phosphonium cation, m, n and o are from 1 to 3, and p and q are from 0 to 4; and the stoichiometry of o, p and q is such as not to result in any excess positive or negative charge in the formula (I). The substituents can, if desired, be connected to one another in such a way, via a direct bond or via a bridge --O-- or --NR.sub.12 --, as to form additional five- or six-membered rings. The novel recording media are of high sensitivity and have good reproduction characteristics.
摘要翻译：本发明涉及一种光记录介质，其包括基板，反射层和记录层，该记录层基本上由式（I）的染料，其中R 1和R 6为氢或未取代的或取代的烷基，烯基，炔基，芳烷基或芳基，R6和R7是未取代的或取代的烷基，烯基，炔基，芳基或芳基，R3，R4，R8和R9分别是氢，卤素，OR17，SR17，NR18R19，，烯基或炔基，R 5和R 10是氢，卤素，OR 17，SR 17，NO 2，NR 18 R 19或未取代或取代的烷基，烯基，炔基或芳烷基，R 11是氢，（CH 2）1-10 COO-，（CH 2）烷基，烯基，炔基或未取代或取代的芳烷基或芳基; Y是无机，有机或有机金属酸的阴离子，Z是金属阳离子，铵阳离子或鏻阳离子，m，n和o为1至3，p和q为0至4; 并且o，p和q的化学计量比如在式（I）中不会导致任何过量的正电荷或负电荷。如果需要，取代基可以以这样的方式通过直接键或通过桥-O-或-NR 12 - 彼此连接，形成另外的五元或六元环。该新颖的记录介质具有高灵敏度和良好的再生特性。

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