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1. 发明授权

US4605809A Aluminosilicates and silica gels having a low content of transition elements, a process for their use in the conversion of methanol to olefins 失效
标题翻译：具有低含量过渡元素的硅铝酸盐和硅胶，其用于将甲醇转化为烯烃的方法
公开(公告)号：US4605809A
公开(公告)日：1986-08-12
申请号：US545957
申请日：1983-10-27
申请人： Heinz Litterer , Friedrich Wunder , Ernst I. Leupold , Herbert Baltes
发明人： Heinz Litterer , Friedrich Wunder , Ernst I. Leupold , Herbert Baltes
IPC分类号： B01J21/08 , B01J29/00 , B01J29/50 , B01J29/65 , B01J29/80 , C01B33/157 , C01B33/158 , C01B39/02 , C01B39/04 , C01B39/06 , C01B39/44 , C07C1/00 , C07C1/20 , C07C67/00 , C07C1/24
CPC分类号： C01B39/026 , B01J21/08 , B01J29/50 , B01J29/65 , C01B33/158 , C07C1/20 , C07C2521/08 , C07C2521/12 , Y10S502/52
摘要： The present invention relates to aluminosilicates and silica gels having a low content of transition elements, to a process for their manufacture and to their use as a catalysts or catalyst supports. Said aluminosilicates or silica gels are prepared by treating them with a solution of complexing agents at a temperature of from 70.degree. to 150.degree. C. The manufacture of low-molecular-weight olefins from methanol is one possible application field of said aluminosilicates, used as a catalyst.
摘要翻译：本发明涉及具有低含量过渡元素的硅铝酸盐和二氧化硅凝胶，涉及其制备方法及其作为催化剂或催化剂载体的用途。所述硅铝酸盐或硅胶通过在70至150℃的温度下用络合剂溶液处理制备。低分子量烯烃由甲醇制备是所述铝硅酸盐的一个可能的应用领域，用作催化剂

2. 发明授权

US4522800A Process for the production of a crystalline aluminosilicate zeolite 失效
标题翻译：用于生产结晶硅铝酸盐沸石的方法
公开(公告)号：US4522800A
公开(公告)日：1985-06-11
申请号：US491860
申请日：1983-05-05
申请人： Herbert Baltes , Heinz Litterer , Ernst I. Leupold , Friedrich Wunder
发明人： Herbert Baltes , Heinz Litterer , Ernst I. Leupold , Friedrich Wunder
IPC分类号： B01J29/00 , B01J29/70 , B01J29/89 , C01B39/04 , C01B39/30 , C07C1/00 , C07C1/20 , C07C11/02 , C07C67/00 , C01B33/20
CPC分类号： C01B39/305 , B01J29/70 , B01J29/89 , C07C1/20 , C07C2529/06 , Y02P30/42
摘要： A method for making crystalline aluminosilicate ZSM-34 zeolites, useful as catalysts for making C.sub.2 -C.sub.4 -olefins from methanol, from a reaction mixture containing silicon, aluminum, sodium, potassium, and an organic template compound which is (i) a salt of an ammonium compound of di-, tri-, or tetra-ethanolamine or (ii) a mixture of at least one of diethanolamine and triethanolamine with certain lower alkanols, lower alkylene diols, or lower alkyl iodides, sulfates, or p-toluenesulfonates.
摘要翻译：一种从含有硅，铝，钠，钾和有机模板化合物的反应混合物中制备可用作从甲醇制备C2-C4-烯烃的催化剂的结晶硅铝酸盐ZSM-34沸石的方法，其为（i）二，三或四乙醇胺的铵化合物或（ii）二乙醇胺和三乙醇胺中的至少一种与某些低级链烷醇，低级亚烷基二醇或低级烷基碘化物，硫酸盐或对甲苯磺酸盐的混合物。

3. 发明授权

US4481376A Process for the synthesis of lower olefins from methanol and/or dimethyl ether 失效
标题翻译：从甲醇和/或二甲醚合成低级烯烃的方法
公开(公告)号：US4481376A
公开(公告)日：1984-11-06
申请号：US465292
申请日：1983-02-09
申请人： Friedrich Wunder , Ernst I. Leupold , Heinz Litterer
发明人： Friedrich Wunder , Ernst I. Leupold , Heinz Litterer
IPC分类号： B01J21/06 , B01J21/16 , B01J29/50 , B01J29/80 , C07B61/00 , C07C1/00 , C07C1/20 , C07C67/00
CPC分类号： B01J21/066 , B01J21/06 , B01J29/50 , C07C1/20 , C07C2521/06 , C07C2521/12 , Y02P30/42
摘要： A method for the catalytic conversion of methanol and/or dimethyl ether to lower olefins with an aluminosilicate zeolite catalyst containing zirconium and/or hafnium together with manganese.
摘要翻译：一种用含有锆和/或铪以及锰的铝硅酸盐沸石催化剂将甲醇和/或二甲醚催化转化成低级烯烃的方法。

4. 发明授权

US5264094A Process for the preparation of fluorobenzenes 失效
标题翻译：制备氟苯的方法
公开(公告)号：US5264094A
公开(公告)日：1993-11-23
申请号：US849059
申请日：1992-04-24
申请人： Frank P. Sistig , Ernst I. Leupold , Heinz Litterer
发明人： Frank P. Sistig , Ernst I. Leupold , Heinz Litterer
IPC分类号： B01J31/24 , C07B37/06 , C07B61/00 , C07C17/361 , C07C25/13 , C07C37/62 , C07C201/12 , C07C205/11 , C07C205/12 , C07C17/33 , C07G13/00
CPC分类号： C07C201/12 , C07C17/361
摘要： Process for the preparation of fluorobenzenes having at least one hydrogen atom as ring substituent and, optionally, further substituents, which, independently of each other, can be chlorine, bromine, nitro, hydroxyl, C.sub.1 -C.sub.3 -alkoxy or C.sub.1 -C.sub.3 -alkyl, the number of nitro groups being not more than 2 and the number of hydroxyl groups and alkoxy groups being not more than 3 in each case, by heating the corresponding benzaldehydes, substituted by at least one flourine atom, in the presence of a catalyst, characterized in that the reaction product is immediately removed from the reaction zone.
摘要翻译： PCT No.PCT / EP90 / 01762 Sec。 371日期：1992年4月24日 102（e）日期1992年4月24日PCT 1990年10月18日PCT PCT。公开号WO91 / 06518 日期：1991年5月16日。具有至少一个氢原子作为环取代基的氟苯的制备方法和任选的另外的取代基，其彼此独立地可以是氯，溴，硝基，羟基，C 1 -C 3 - 烷氧基或C 1 -C 3 - 烷基，硝基数不超过2，羟基和烷氧基的数目在每种情况下不超过3，通过加热相应的由至少一个亮原子取代的苯甲醛，在催化剂的存在，其特征在于反应产物立即从反应区除去。

5. 发明授权

US4937395A Process for the preparation of fluorobenzenes 失效
标题翻译：制备氟苯的方法
公开(公告)号：US4937395A
公开(公告)日：1990-06-26
申请号：US379827
申请日：1989-07-14
申请人： Heinz Litterer , Hans J. Metz , Theodor Papenfuhs , Frank P. Sistig , Ernst I. Leupold
发明人： Heinz Litterer , Hans J. Metz , Theodor Papenfuhs , Frank P. Sistig , Ernst I. Leupold
IPC分类号： B01J29/06 , B01J29/40 , B01J29/65 , B01J29/83 , B01J29/85 , B01J29/89 , C07B61/00 , C07C17/00 , C07C17/361 , C07C25/13 , C07C67/00
CPC分类号： C07C17/361
摘要： A process for the preparation of fluorobenzenes of the formula I ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are equal or different and represent H, F, Cl or alkyl having from 1 to 3 carbon atoms, at least one of these radicals being fluorine, and S.sup.1 and S.sup.2 being equal or different and represent H or a group reducing the electron density at the benzene nucleus, which comprises subjecting a compound of the formula II ##STR2## in which R.sup.1, R.sup.2, R.sup.3, S.sup.1 and S.sup.2 have the aforementioned meaning to a decarbonylation at a zeolite catalyst.
摘要翻译：制备式I的氟苯（I）的方法，其中R 1，R 2和R 3相同或不同并且表示H，F，Cl或具有1至3个碳原子的烷基，这些基团中的至少一个是氟，S1和S2相同或不同，表示H或降低苯核的电子密度的基团，其包括使其中R 1，R 2，R 3，S 1（II）的式II化合物和S2具有上述对沸石催化剂脱碳的意义。

6. 发明授权

US5744010A Process for the preparation of the non-toxic salts of 6-methyl-3,4-dihydro-1,2,3-oxathiazin-4-one 2,2-dioxide and arrangement for carrying out this process 失效
标题翻译：制备6-甲基-3,4-二氢-1,2,3-氧杂噻嗪-4-酮2,2-二氧化物的无毒盐的方法和用于进行该方法的装置
公开(公告)号：US5744010A
公开(公告)日：1998-04-28
申请号：US302807
申请日：1995-06-19
申请人： Gunter Roscher , Heinz Litterer , Axel Engelmann , Wolf-Dietmar Kaufmann , Bernd Laugwitz , Hans-Dietmar Schnabel
发明人： Gunter Roscher , Heinz Litterer , Axel Engelmann , Wolf-Dietmar Kaufmann , Bernd Laugwitz , Hans-Dietmar Schnabel
IPC分类号： C07D291/06 , B01D11/00 , C07D291/00
CPC分类号： C07D291/06 , Y10S203/17
摘要： The invention relates to a process for the preparation of acesulfam salts by reaction of salts of amidosulfonic acid with diketene to give a salt of acetoacetamidosulfonic acid (I), ring closure by the action of at least about an equivalent amount of SO.sub.3, at least this ring closure reaction being carried out in the presence of a halogenated, aliphatic hydrocarbon as an inert solvent, treatment of the cyclization product with water and conversion of the resulting acesulfam-H (II) into the form of a non-toxic salt, which comprises, in the work-up by distillation of the resulting crude solvent, after removal of water and low-boilers and recovery of solvent sufficiently pure for reuse in the preparation of compounds (I) and/or (II), directly returning :he remaining, solvent-containing distillation residue, without further purification, into the system downstream of the reaction vessel for carrying out the ring closure reaction.
摘要翻译： PCT No.PCT / EP93 / 00606 Sec。 371日期：1995年6月19日 102（e）日期1995年6月19日PCT 1993年3月16日PCT公布。出版物WO93 / 19055 日期1993年9月30日本发明涉及通过酰胺磺酸与双烯酮的盐反应制备乙酰磺胺盐的方法，得到乙酰乙酰氨基磺酸（I）的盐，通过至少约等量的 SO 3，至少该闭环反应在卤化的脂族烃作为惰性溶剂的存在下进行，环化产物用水处理并将所得的乙酰胺-H（II）转化为非 - 其中包括在除去水和低沸点剂后，通过蒸馏所得的粗溶剂进行后处理和回收足够纯的用于制备化合物（I）和/或（II）的溶剂）直接返回：将剩余的含溶剂的蒸馏残余物不经进一步纯化进入反应容器下游的系统进行闭环反应。

7. 发明授权

US4480128A Process for the manufacture of o-toluidine and/or m-toluidine and/or p-toluidine 失效
标题翻译：邻甲苯胺和/或间甲苯胺和/或对甲苯胺的制备方法
公开(公告)号：US4480128A
公开(公告)日：1984-10-30
申请号：US484179
申请日：1983-04-12
申请人： Hans-J/u/ rgen Arpe , Heinz Litterer
发明人： Hans-J/u/ rgen Arpe , Heinz Litterer
IPC分类号： C07B61/00 , B01J21/00 , B01J29/40 , C07C67/00 , C07C209/00 , C07C209/64 , C07C209/68 , C07C209/86 , C07C211/47 , C07C85/26
CPC分类号： C07C209/68
摘要： The invention provides a process for the manufacture of o-toluidine and/or m-toluidine and/or p-toluidine, which comprises the two following steps (a) and (b):(a) treatment of a toluidine isomer mixture or of the not intended toluidine isomer or of one of the not intended toluidine isomers with an isomerization catalyst selected from the group of synthetic zeolites of the pentasil type,(b) isolation of the intended isomer or one of the intended isomers from the isomer mixture formed in step (a) by selective adsorption to a medium-pore or large-pore zeolite and subsequent desorption, furthermore discharge of the isolated isomer and recycling of the remaining isomer mixture to step (a).
摘要翻译：本发明提供了制备邻甲苯胺和/或间甲苯胺和/或对甲苯胺的方法，其包括以下两个步骤（a）和（b）：（a）处理甲苯胺异构体混合物或不需要的甲苯胺异构体或一种不需要的甲苯胺异构体，其中异构化催化剂选自pentasil类型的合成沸石，（b）从所形成的异构体混合物中分离出所需异构体或其中一种异构体步骤（a）通过选择性吸附到中孔或大孔沸石并随后解吸，此外排出分离的异构体并将剩余的异构体混合物再循环到步骤（a）。

8. 发明授权

US4931568A Process for the preparation of thiophene ethers 失效
标题翻译：制备噻吩醚的方法
公开(公告)号：US4931568A
公开(公告)日：1990-06-05
申请号：US308893
申请日：1989-02-09
申请人： Peter Wegener , Michael Feldhues , Heinz Litterer
发明人： Peter Wegener , Michael Feldhues , Heinz Litterer
IPC分类号： B01J27/053 , B01J31/02 , C07B61/00 , C07D333/32 , C07D333/72 , C07D333/78 , C07F9/6553 , H01B1/12
CPC分类号： C07F9/655345 , C07D333/32 , H01B1/127
摘要： Thiophene ethers having relatively large side chains can be easily obtained by reacting 2-, 3-, 2,3-, 2,4- or 3,4-C.sub.1 -C.sub.3 -alkoxythiophenes in the presence of an acid catalyst with a compound containing an OH group. The novel thiophene ethers are suitable as monomers for electrically conducting polymers.
摘要翻译：具有相对较大侧链的噻吩醚可以通过使2-，3-，2,3-，2,4-或3,4-C 1 -C 3 - 烷氧基噻吩在酸催化剂存在下与含有 OH组。新型噻吩醚适合用作导电聚合物的单体。

9. 发明授权

US4650915A Process for preparing p-chlorotoluene and/or m-chlorotoluene 失效
标题翻译：制备对氯甲苯和/或间氯甲苯的方法
公开(公告)号：US4650915A
公开(公告)日：1987-03-17
申请号：US764511
申请日：1985-08-09
申请人： Hans-Jurgen Arpe , Heinz Litterer , Norbert Mayer
发明人： Hans-Jurgen Arpe , Heinz Litterer , Norbert Mayer
IPC分类号： B01J20/18 , B01J23/00 , B01J29/08 , B01J29/18 , B01J29/40 , B01J29/70 , C07B61/00 , C07C17/00 , C07C17/12 , C07C17/358 , C07C17/38 , C07C17/389 , C07C17/395 , C07C25/02 , C07C67/00
CPC分类号： C07C25/02 , C07C17/358 , C07C17/389
摘要： The invention relates to a process for preparing p-chlorotoluene and/or m-chlorotoluene by ring-chlorination of toluene by using the following two pages (a) and (b) when further processing the toluene chlorination product composed of mixed isomers:(a) Isolation of p-chlorotoluene from a mixture of o-, m- and p-chlorotoluene by selective adsorption of p-chlorotoluene onto a mesoporous or macroporous zeolite and subsequent desorption of p-chlorotoluene(b) Treatment of an o-chlorotoluene-rich mixture of isomers with an isomerization catalyst.For the exclusive preparation of p-chlorotoluene first p-chlorotoluene is isolated and removed from the toluene chlorination product in stage (a). The remaining mixed isomers are then treated in stage (b) to increase their content of m- and p-isomers and then returned into stage (a).For the preparation of m-chlorotoluene and, if appropriate, additionally of p-chlorotoluene first the toluene chlorination product is treated in stage (b) to increase its content of m- and, if appropriate, p-isomer. p-Chlorotoluene is then isolated in stage (a) and returned to stage (b), or, if appropriate, removed. The remaining mixture essentially comprising o- and m-isomers is separated by distillation or adsorption and o-chlorotoluene is then returned into stage (b) and m-chlorotoluene is removed.
摘要翻译：本发明涉及通过使用以下两页（a）和（b）进一步处理由混合异构体组成的甲苯氯化产物时，通过甲苯的环氯化来制备对氯甲苯和/或间氯甲苯的方法：（a ）通过将对氯甲苯选择性吸附到介孔或大孔沸石上并随后对对氯甲苯的解吸，从邻 - ，间 - 和对 - 氯甲苯的混合物中分离对氯甲苯（b）处理富含邻氯甲苯异构体与异构化催化剂的混合物。对于专门制备对氯甲苯，首先在阶段（a）中从甲苯氯化产物中分离并除去对氯甲苯。然后在阶段（b）中处理剩余的混合异构体以增加它们的m-和p-异构体的含量，然后返回到阶段（a）。为了制备间氯甲苯，并且如果合适，另外还加入对氯甲苯，在步骤（b）中处理甲苯氯化产物，以增加其含量，如果合适，增加对异构体。然后在阶段（a）中分离出对 - 氯甲苯并返回到阶段（b），或者如果合适的话除去。通过蒸馏或吸附分离基本上含有O-和m-异构体的剩余混合物，然后将邻氯甲苯回到步骤（b）中，并除去间氯甲苯。

10. 发明授权

US5100520A Process for the preparation of thiophene derivatives 失效
标题翻译：制备噻吩衍生物的方法
公开(公告)号：US5100520A
公开(公告)日：1992-03-31
申请号：US474145
申请日：1990-02-02
申请人： Steffen Dapperheld , Michael Feldhues , Heinz Litterer , Frank P. Sistig , Peter Wegener
发明人： Steffen Dapperheld , Michael Feldhues , Heinz Litterer , Frank P. Sistig , Peter Wegener
IPC分类号： C25B3/00 , C07D333/08 , C07D333/10 , C07D333/28 , C25B3/04
CPC分类号： C07D333/10 , C07D333/08 , C07D333/28 , C25B3/04
摘要： Selectively dehalogenated thiophene derivatives are obtained from compounds of the formula II ##STR1## by an electrochemical reaction in a divided electrolysis cell in the presence of a suitable solvent, an onium compound or a compound which is converted into an onium compound in the electrolyte, and a conducting salt. Thiophene derivatives are important intermediates in the production of pharmaceuticals and plant protection agents.
摘要翻译：选择性脱卤噻吩衍生物通过在分解电解槽中的电化学反应在合适的溶剂，鎓化合物或在其中转化为鎓化合物的化合物的存在下，通过电化学反应从式II（II）的化合物获得电解质和导电盐。噻吩衍生物是药物和植物保护剂生产中的重要中间体。

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