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    • 2. 发明授权
    • Isolation of dimethyl 4,4'-biphenyldicarboxylate
    • 分离4,4'-联苯二羧酸二甲酯
    • US5397440A
    • 1995-03-14
    • US227058
    • 1994-04-13
    • Michael FreyUlrich HertensteinRainer Schaller
    • Michael FreyUlrich HertensteinRainer Schaller
    • C07C67/52C07C67/54C07C69/76B01D3/10B01D9/02
    • C07C67/52C07C67/54Y10S203/17
    • Process for isolating dimethyl 4,4'-biphenyldicarboxylate from residues of DMT production, which includes first distilling the residues at a pressure of at most 7 mbar at a boiler temperature from 200.degree. to 350.degree. C., subsequently treating the distillate which distills over in the range from 230.degree. to 270.degree. C. at a pressure of, for example, 0.2 mbar for from 10 to 60 minutes with 0.7 to 10 times the amount of an organic solvent at a temperature from 70.degree. to 180.degree. C., if required, separating the clear solution from undissolved components, cooling the removed clear solution to a temperature from 45.degree. to 65.degree. C. and allowing it to crystallize at this temperature, resulting in a suspension of dimethyl 4,4'-biphenyldicarboxylate crystals from which the crystals are isolated by washing one or more times with the same or a different solvent and by drying.
    • 从DMT生产的残留物中分离出4,4'-联苯二羧酸二甲酯的方法,其中包括首先在锅炉温度为200〜350℃下,以至多7毫巴的压力蒸馏残留物,然后处理蒸馏出的馏出物 在230℃至270℃的范围内,在例如0.2毫巴的压力下进行10至60分钟的压力,在70至180℃的温度下为0.7至10倍的有机溶剂, 如果需要,将澄清溶液与未溶解的组分分离,将除去的透明溶液冷却至45℃至65℃的温度,并使其在该温度下结晶,导致4,4'-联苯二羧酸二甲酯的晶体从 通过用相同或不同的溶剂洗涤一次或多次,并通过干燥将晶体分离出来。