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1. 发明授权

US5035987A Color photographic recording material containing a DIR coupler 失效
标题翻译：含有DIR耦合器的彩色照相记录材料
公开(公告)号：US5035987A
公开(公告)日：1991-07-30
申请号：US586516
申请日：1990-09-21
申请人： Heinrich Odenwalder , Thomas Kruger , Hans-Joachim Schumann
发明人： Heinrich Odenwalder , Thomas Kruger , Hans-Joachim Schumann
IPC分类号： C07D249/04 , C07D257/04 , C07D403/12 , C07D413/12 , C07D417/12 , C07D417/14 , C07D473/08 , C07D487/04 , C09K9/02 , G03C7/26 , G03C7/305 , G03C7/32 , G03C7/36
CPC分类号： G03C7/305 , C07D257/04 , C07D403/12 , C07D413/12 , C07D417/12 , C07D417/14
摘要： Where DIR couplers corresponding to formula I are used in color photographic silver halide materials, good edge effects and interimage effects are obtained. ##STR1## In formula (I), A represents halogen, --OR, --SR, --CN, --COR, --CONHR, --COOR, --SO.sub.2 R, --SO.sub.2 NHR, ##STR2## R represents alkyl, aralkyl, aryl or hetaryl; Q represents a substituent for compelting a 5- or 6-membered heterocyclic ring;D and E, which may be the same or different, represent substituents attached to the C atom of the C.dbd.N group by a C, O, S or N atom, including those substituents which, together with the C atom of the C.dbd.N group, complete a carbocyclic or heterocyclic ring;Y represents a group having a silver halide development inhibiting function which is releasable during color development.
摘要翻译：其中对应于式I的DIR成色剂用于彩色照相卤化银材料中，获得了良好的边缘效果和图像效果。（I）式（I）中，A表示卤素，-OR，-SR，-CN，-COR，-CONHR，-COOR，-SO2R，-SO2NHR，R表示烷基，芳烷基，芳基或杂芳基; Q表示用于强制5或6元杂环的取代基; D和E可以相同或不同，表示通过C，O，S或N原子连接到C = N基团的C原子的取代基，包括与C = O的C原子一起的那些取代基， N基团，完成碳环或杂环; Y表示具有卤化银显影抑制功能的基团，其在显色期间可释放。

2. 发明授权

US5021332A Color photographic recording material containing a DIR coupler 失效
标题翻译：含有DIR耦合器的彩色照相记录材料
公开(公告)号：US5021332A
公开(公告)日：1991-06-04
申请号：US528045
申请日：1990-05-23
申请人： Peter Bergthaller , Thomas Kruger , Hans Vetter , Heinrich Odenwalder
发明人： Peter Bergthaller , Thomas Kruger , Hans Vetter , Heinrich Odenwalder
IPC分类号： G03C7/26 , C07D403/06 , G03C7/305 , G03C7/32 , G03C7/392
CPC分类号： C07D403/06 , G03C7/30535 , Y10S430/158
摘要： Good edge effects and inter-image effects are obtained where DIR couplers corresponding to formula I are used in color photogrpahic silver halide materials. ##STR1## in which R.sup.1 is H, Cl, --CF.sub.3, alkoxy, sulfamoyl;R.sup.2 is H, Cl, alkyl, cycloalkyl, alkoxy, alkoxycarbonyl, carbamoyl;n is 0, 1 or 2;X is O or S;Y is a group with a silver halide development inhibiting function releasable during color development;Z is benzoyl, pivaloyl, carbamoyl or a quinazolin-4-on-2-yl group.
摘要翻译：获得良好的边缘效果和图像间效果，其中对应于式I的DIR成色剂用于彩色光致卤化银材料。（I）其中R1是H，Cl，-CF3，烷氧基，氨磺酰基; R2是H，Cl，烷基，环烷基，烷氧基，烷氧基羰基，氨基甲酰基; n为0,1或2; X是O或S; Y是具有在显色期间可释放的卤化银显影抑制功能的组; Z是苯甲酰基，新戊酰基，氨基甲酰基或喹唑啉-4-基-2-基。

3. 发明授权

US5021331A Color photographic recording material containing a DIR coupler 失效
标题翻译：含有DIR耦合器的彩色照相记录材料
公开(公告)号：US5021331A
公开(公告)日：1991-06-04
申请号：US528043
申请日：1990-05-23
申请人： Hans Vetter , Heinrich Odenwalder , Peter Bergthaller , Thomas Kruger
发明人： Hans Vetter , Heinrich Odenwalder , Peter Bergthaller , Thomas Kruger
IPC分类号： G03C7/305 , G03C7/32
CPC分类号： G03C7/305 , Y10S430/158
摘要： Highly active silver halide development inhibitors are released from DIR couplers corresponding to formula I during color development. Where DIR couplers are used in color photographic silver halide materials, high edge effects and high inter-image effects are obtained.A--(TIME).sub.n --Z IIn formula I,A is the residue of a coupler which couples with the oxidation product of a silver halide developing agent under the conditions of photographic development and, in doing so, releases a group corresponding to the following formula--(TIME).sub.n --ZTIME is a binding link which together with the group Z (a triazole ring) attached thereto is releases on reaction of the coupler with the oxidation product of a silver halide developing agent and which, in turn, releases the group Z with delay under the development conditions;n is 0 or 1;Z is a triazole ring corresponding to one of the following formulae ##STR1## R.sup.1 is alkylthio; R.sup.2 is H, alkyl, alkythio, aryl or a heterocyclic group; at least one of the substituents R.sup.1 and R.sup.2 contains at a distance of 2 to 4 atoms from the triazole ring a group --CO--OR.sup.3, --O--CO--OR.sup.3 or --O--CO--R.sup.3 hydrolyzable in aqueous alkali;R.sup.3 is alkyl, cycloalkyl or aryl.
摘要翻译：在显影期间，高活性卤化银显影抑制剂从对应于式I的DIR成色剂中释放出来。在彩色照相卤化银材料中使用DIR成色剂时，可获得高边缘效果和高图像效果。 A-（TIME）n-Z在式I中，A是在照相显影的条件下与卤化银显影剂的氧化产物偶联的成色剂的残基，并且在这样做时，释放相应于下列物质的基团式 - （TIME）nZ TIME是与连接到其上的组Z（三唑环）一起的结合链接，其与成色剂与卤化银显影剂的氧化产物反应释放，并且反过来释放基团 Z在发展条件下有延误; n为0或1; Z是对应于下式之一的三唑环：R 1是烷硫基; R2是H，烷基，链烯基，芳基或杂环基; 取代基R 1和R 2中的至少一个与三唑环在含水碱中可水解的基团-CO-OR3，-O-CO-OR3或-O-CO-R3的距离为2至4个原子; R3是烷基，环烷基或芳基。

4. 发明授权

US4310621A Photosensitive photographic material, a process for the production of photographic images, development baths and new hydroquinones 失效
标题翻译：感光照相材料，生产摄影图像的过程，开发浴和新的氢醌
公开(公告)号：US4310621A
公开(公告)日：1982-01-12
申请号：US217193
申请日：1980-12-16
申请人： Heinrich Odenwalder , Karl Frank , Reinhard Muller
发明人： Heinrich Odenwalder , Karl Frank , Reinhard Muller
IPC分类号： C07D249/12 , G03C5/30 , G03C7/305 , G03C1/06
CPC分类号： C07D249/12 , G03C5/3021 , G03C7/305 , G03C7/30541 , Y10S430/158 , Y10S430/16
摘要： New DIR-compounds of the formula ##STR1## are useful in photographic materials and processes.
摘要翻译：式（IMAGE）的新型DIR化合物在照相材料和方法中是有用的。

5. 发明授权

US6013428A Color photographic recording material having a 2-equivalent magenta coupler and a white coupler 失效
标题翻译：具有2-当量品红色耦合器和白色耦合器的彩色照相记录材料
公开(公告)号：US6013428A
公开(公告)日：2000-01-11
申请号：US891391
申请日：1997-07-11
申请人： Hans Langen , Heinrich Odenwalder , Uwe Dahlhaus
发明人： Hans Langen , Heinrich Odenwalder , Uwe Dahlhaus
IPC分类号： C07C69/757 , G03C7/30 , G03C7/392 , G03C7/333
CPC分类号： C07C69/757 , G03C7/3012 , G03C7/39232 , G03C7/39236
摘要： A colour photographic recording material having at least one red-sensitive silver halide emulsion layer which is associated with a cyan coupler, at least one green-sensitive silver halide emulsion layer which is associated with a magenta coupler, at least one blue-sensitive silver halide emulsion layer which is associated with a yellow coupler contains in at least one green-sensitive silver halide emulsion layer a 2-equivalent pyrazolone coupler and in a photosensitive or non-photosensitive layer a white coupler of the formula (I) ##STR1## in which X.sup.1 means an acyl residue derived from an aliphatic, cycloaliphatic or aromatic carboxylic or sulphonic acid, a carbonic acid semi-ester or a carbamic acid,Z means the residue required to complete a saturated or partially unsaturated 5- or 6-membered carbocyclic ring which is optionally substituted and/or provided with a further fused ring or ring system.The colour images produced using the recording material exhibit elevated storage stability without a subsequent increase in fog or a subsequent increase in colour density or spotting occurring during storage.
摘要翻译：一种彩色照相记录材料，其具有与青色成色剂相关联的至少一种感红卤化银乳剂层，与品红色成色剂相关的至少一种感绿卤化银乳剂层，至少一种蓝敏感卤化银与黄色成色剂相关联的乳剂层在至少一种感绿卤化银乳剂层中含有2-当量吡唑啉酮偶联剂，在光敏或非感光层中含有式（I）的白色偶联剂，其中X1表示衍生自脂族，脂环族或芳族羧酸或磺酸，碳酸半酯或氨基甲酸的酰基残基Z表示完成饱和或部分不饱和的5-或6-元碳环所需的残基，其任选被取代和/或设置有另外的稠环或环系统。使用记录材料产生的彩色图像表现出提高的储存稳定性，而不会随后增加雾度，或随后的颜色密度增加或储存期间发生斑点。

6. 发明授权

US5407789A Photographic recording material 失效
标题翻译：摄影记录材料
公开(公告)号：US5407789A
公开(公告)日：1995-04-18
申请号：US190686
申请日：1994-02-01
申请人： Heinrich Odenwalder , Hans hlschlager , Thomas Stetzer
发明人： Heinrich Odenwalder , Hans hlschlager , Thomas Stetzer
IPC分类号： G03C7/305 , C07D249/12 , C07D271/10 , C07D271/113 , C07D405/04 , C07D413/04 , G03C7/392 , G03C1/46
CPC分类号： C07D271/113 , C07D249/12 , C07D405/04 , C07D413/04 , G03C7/39228 , G03C7/39256 , G03C7/39272
摘要： A photographic recording material on a transparent support having at least one light-sensitive silver halide emulsion layer and optionally conventional interlayers and protective layers, characterized in that the photographic recording material contains, in at least one of the above-mentioned layers, a compound corresponding to formula I, II or III ##STR1## wherein R.sub.1 denotes an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryl group or an unsubstituted or substituted heterocyclic group,R2 denotes hydrogen, an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryl group or an unsubstituted or substituted alkylthio group,R.sub.3 denotes hydrogen or an unsubstituted or substituted alkyl group,R4 denotes an unsubstituted or substituted alkyl group, an unsubstituted or a substituted aryl group or an unsubstituted or substituted heterocyclic group,X denotes an alkylene group having 1 to 8 carbon atoms in which the carbon chain may be interrupted by oxygen or sulphur atoms, or it denotes an arylene group, andZ denotes hydrogen, a cation or a precursor compound thereof which is capable of releasing the mercapto compound non-imagewise in the course of development,is distinguished by excellent interimage and edge effects and by improved sharpness and graininess compared with conventional materials.
摘要翻译：在透明支撑体上的具有至少一个感光卤化银乳剂层和任选的常规中间层和保护层的照相记录材料，其特征在于，照相记录材料在至少一个上述层中含有相应的化合物其中R 1表示未取代或取代的烷基，未取代或取代的芳基或未取代或取代的杂环基，R 2表示氢，未取代或取代的烷基，未取代或取代的芳基或未取代或取代的烷硫基，R 3表示氢或未取代或取代的烷基，R 4表示未取代或取代的烷基，未取代或取代的芳基或未取代或取代的杂环基，X表示具有1至8个碳链可被中断的碳原子或者表示亚芳基，Z表示氢，可以在显影过程中非成像地释放巯基化合物的阳离子或其前体化合物，其特征在于优异的图像和边缘效果，通过与常规材料相比提高清晰度和颗粒度。

7. 发明授权

US5266449A Bleaching bath 失效
标题翻译：漂白浴
公开(公告)号：US5266449A
公开(公告)日：1993-11-30
申请号：US969490
申请日：1992-10-30
申请人： Christa Dacke , Heinrich Odenwalder , Hans Langen
发明人： Christa Dacke , Heinrich Odenwalder , Hans Langen
IPC分类号： C07D249/04 , C07D249/08 , G03C5/39 , G03C5/44 , G03C7/42 , G03C7/28
CPC分类号： G03C7/42
摘要： A bleaching bath for processing of a color photographic silver halide material which contains the ferric complex of alaninediacetic acid as the bleaching agent and in a dye-stabilizing amount a formaldehyde precursor of the formula ##STR1## wherein X and Y denote the residual atoms of a hetero aromatic 5- or 6-membered ring,yields color photographic images with excellent dye-stabilizing. In the atmosphere above the stabilizing bath no formaldehyde is detectable.
摘要翻译：一种用于加工彩色照相卤化银材料的漂白浴，其含有丙氨酸二乙酸的三元配合物作为漂白剂，并且在染料稳定量下具有式（I）的甲醛前体，其中X和Y表示残基杂芳族5-或6-元环的原子产生具有优异染料稳定性的彩色摄影图像。在稳定浴上方的气氛中，无法检测到甲醛。

8. 发明授权

US4897341A Color photographic recording material containing a dir-coupler 失效
标题翻译：含有双向耦合器的彩色照相记录材料
公开(公告)号：US4897341A
公开(公告)日：1990-01-30
申请号：US109762
申请日：1987-10-19
申请人： Heinrich Odenwalder , Hans Ohlschlager , Friedrich-Wilhelm Kunitz , Dirk Hubner
发明人： Heinrich Odenwalder , Hans Ohlschlager , Friedrich-Wilhelm Kunitz , Dirk Hubner
IPC分类号： G03C7/36 , G03C7/305
CPC分类号： G03C7/30535
摘要： Remarkably high inter-image and edge effects are obtained when DIR-Couplers corresponding to Formula I are added to multilayered color photographic recording materials, in particular to green sensitive or red sensitive layers. The sharpness and color reproduction may thereby be improved. ##STR1## R.sup.1 and R.sup.2 denote alkyl or an aromatic group, R.sup.3 denotes H, alkyl or acylamino,R.sup.4 denotes H or alkylR.sup.5 denotes alkyl, alkinyl, aryl, acyloxy, carbamoyl or a cyclic imido group andn has the value 0 or 1and the total number of carbon atoms in R.sup.3, R.sup.4 and R.sup.5 is greater than 3 but not greater than 11.
摘要翻译：当将对应于式I的DIR耦合器添加到多层彩色照相记录材料，特别是绿色敏感层或红色敏感层时，可获得非常高的图像间和边缘效应。从而可以提高清晰度和色彩再现。 R1和R2表示烷基或芳基，R3表示H，烷基或酰氨基，R4表示H或烷基R5表示烷基，炔基，芳基，酰氧基，氨基甲酰基或环状酰亚胺基，n的数值为0或 1，R3，R4和R5中的碳原子总数大于3但不大于11。

9. 发明授权

US4420557A Color photographic recording material containing a non-diffusible electron donor precursor compound 失效
标题翻译：含有不扩散电子给体前体化合物的彩色照相记录材料
公开(公告)号：US4420557A
公开(公告)日：1983-12-13
申请号：US436581
申请日：1982-10-25
申请人： Heinrich Odenwalder , Paul Marx
发明人： Heinrich Odenwalder , Paul Marx
IPC分类号： G03C7/26 , G03C8/08 , G03C8/36 , G03C1/40 , G03C1/06 , G03C1/48 , G03C5/30
CPC分类号： G03C8/08 , Y10S430/16
摘要： Compounds corresponding to the formula: ##STR1## wherein R.sup.1 represents an aromatic group, andR.sup.2 represents H, alkyl, alkenyl, aryl or acyl, are suitable ED precursor compounds for use in color photographic recording materials. They are preferably used in combination with reducible dye releasers. They are also suitable as so-called scavengers.
摘要翻译：对应于下式的化合物：其中R 1表示芳族基团，R 2表示H，烷基，烯基，芳基或酰基，是用于彩色照相记录材料的合适的ED前体化合物。它们优选与可还原的染料释放剂组合使用。它们也适合作为所谓的清道夫。

10. 发明授权

US4174969A Light sensitive photographic material 失效
标题翻译：感光感光材料
公开(公告)号：US4174969A
公开(公告)日：1979-11-20
申请号：US787970
申请日：1977-04-15
申请人： Heinrich Odenwalder , Erwin Ranz
发明人： Heinrich Odenwalder , Erwin Ranz
IPC分类号： G03C7/26 , C07D249/12 , C07D265/36 , C07D285/16 , C07D513/04 , G03C7/30 , G03C7/305 , G03C7/00 , G03C1/40
CPC分类号： C07D513/04 , C07D249/12 , G03C7/30511 , Y10S430/158
摘要： For controlling in a color photographic material the gradation, graininess, sharpness, edge and interimage effect and thus improving the overall color reproduction thioether DIR compounds of the following formula are particularly useful: ##STR1## in which X is a group that if split off together with the sulfur atom forms a diffusing development inhibiting mercaptan, Y represents --O--, ##STR2## or --S--, Z represents the ring members completing a 6-membered heterocyclic ring, R.sup.1 is an aliphatic, araliphatic or aromatic hydrocarbon group, a heterocyclic group or acyl, and R.sup.2 is the same as R.sup.1 or hydrogen.
摘要翻译：为了控制彩色照相材料，灰度，颗粒度，锐度，边缘和中间影响效应以及因此改善整体色彩还原的下列公式的硫醚DIR化合物特别有用：其中X是如果分开一起的组与硫原子形成抑制硫醇的扩散显影，Y表示-O-，-S-，Z表示完成6元杂环的环原子，R 1是脂族，芳脂族或芳族烃基，杂环基或酰基，R2与R1或氢相同。

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