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1. 发明授权

US4174969A Light sensitive photographic material 失效
标题翻译：感光感光材料
公开(公告)号：US4174969A
公开(公告)日：1979-11-20
申请号：US787970
申请日：1977-04-15
申请人： Heinrich Odenwalder , Erwin Ranz
发明人： Heinrich Odenwalder , Erwin Ranz
IPC分类号： G03C7/26 , C07D249/12 , C07D265/36 , C07D285/16 , C07D513/04 , G03C7/30 , G03C7/305 , G03C7/00 , G03C1/40
CPC分类号： C07D513/04 , C07D249/12 , G03C7/30511 , Y10S430/158
摘要： For controlling in a color photographic material the gradation, graininess, sharpness, edge and interimage effect and thus improving the overall color reproduction thioether DIR compounds of the following formula are particularly useful: ##STR1## in which X is a group that if split off together with the sulfur atom forms a diffusing development inhibiting mercaptan, Y represents --O--, ##STR2## or --S--, Z represents the ring members completing a 6-membered heterocyclic ring, R.sup.1 is an aliphatic, araliphatic or aromatic hydrocarbon group, a heterocyclic group or acyl, and R.sup.2 is the same as R.sup.1 or hydrogen.
摘要翻译：为了控制彩色照相材料，灰度，颗粒度，锐度，边缘和中间影响效应以及因此改善整体色彩还原的下列公式的硫醚DIR化合物特别有用：其中X是如果分开一起的组与硫原子形成抑制硫醇的扩散显影，Y表示-O-，-S-，Z表示完成6元杂环的环原子，R 1是脂族，芳脂族或芳族烃基，杂环基或酰基，R2与R1或氢相同。

2. 发明授权

US4046574A Color photographic material with homophthalimide thioether development inhibitor 失效
标题翻译：含有邻苯二甲酰亚胺衍生物抑制剂的彩色摄影材料
公开(公告)号：US4046574A
公开(公告)日：1977-09-06
申请号：US650676
申请日：1976-01-20
申请人： Heinrich Odenwalder , Erwin Ranz , Walter Puschel , Hans Vetter
发明人： Heinrich Odenwalder , Erwin Ranz , Walter Puschel , Hans Vetter
IPC分类号： G03C7/26 , G03C1/10 , G03C7/305 , G03C1/40 , G03C1/48 , G03C7/00
CPC分类号： G03C7/30511 , Y10S430/158
摘要： A color photographic material having a silver halide emulsion layer and containing a thioether compound which is reactable on chromogenic development thereby releasing a diffusible substance which inhibits the development of the silver halide.The thioether compound is a homophthalimide containing a removable mercapto group containing moiety in the 4-position and its nitrogen in the 2-position atom being a tertiary nitrogen.

3. 发明授权

US4301243A Photographic recording material 失效
标题翻译：摄影记录材料
公开(公告)号：US4301243A
公开(公告)日：1981-11-17
申请号：US103000
申请日：1979-12-12
申请人： Walter Puschel , Heinrich Odenwalder , Erwin Ranz
发明人： Walter Puschel , Heinrich Odenwalder , Erwin Ranz
IPC分类号： G03C7/00 , C07C45/00 , C07C46/06 , C07C50/02 , C07C67/00 , C07C69/734 , C07C233/09 , C07C233/31 , C07C235/48 , C07C235/60 , C07C253/00 , C07C255/41 , C07D207/44 , C07D207/448 , C07D207/452 , C07D311/22 , G03C1/06 , G03C7/392 , G03C1/40 , G03C1/10 , G03C1/48
CPC分类号： C07D207/448 , C07C46/06 , C07C50/02 , G03C7/39208 , Y10S430/158
摘要： Traces of free inhibitors for the development of silver halide which might be present as impurities of inhibitor releasing compounds or which might be prematurely released therefrom because of insufficient stability thereof during storage of the photographic material are scavenged by compounds which are capable of binding free inhibitors at pH values below 7 but to a much less extent at pH values higher than 9.
摘要翻译：用于开发可能作为抑制剂释放化合物的杂质存在或可能由于其在照相材料储存期间的稳定性不足而可能过早释放的卤化银的游离抑制剂痕迹由能够结合游离抑制剂的化合物清除 pH值低于7，但在pH值高于9的情况下，其程度要小得多。

4. 发明授权

US4250252A Light-sensitive color photographic material 失效
标题翻译：感光彩色照相材料
公开(公告)号：US4250252A
公开(公告)日：1981-02-10
申请号：US619301
申请日：1975-10-03
申请人： Heinrich Odenwalder , Hans Vetter , Walter Puschel , Erwin Ranz
发明人： Heinrich Odenwalder , Hans Vetter , Walter Puschel , Erwin Ranz
IPC分类号： G03C7/26 , C07D257/04 , G03C7/30 , G03C7/305 , G03C8/00 , G03C1/76
CPC分类号： C07D257/04 , C07C309/00 , G03C7/30511 , Y10S430/158
摘要： In a color photographic material wherein by color development there are produced either non-diffusing image dyes or diffusing image dyes (the latter being transferred to an image-receiving layer) the color development is controlled by means of non-diffusing thioether compounds which on color development release a diffusing mercapto compound but do not themselves form a dye. The mercapto compound inhibits the development of the silver halide and the thioether compound has the formula ##STR1## R.sub.1 =hydrogen or alkyl with 1-3 carbon atoms R.sub.2 =alkyl with up to 22 carbon atoms the group --S--Y is split off during color development and forms a mercaptane, e.g. 5-mercapto-1-phenyltetrazole, which inhibits the development.
摘要翻译：在通过彩色显影的彩色照相材料中，产生非漫射图像染料或漫射图像染料（后者转移到图像接收层），通过非扩散性硫醚化合物控制着色显色显影释放扩散巯基化合物，但本身不形成染料。巯基化合物抑制卤化银的发展，硫醚化合物具有下式R1 =氢或具有1-3个碳原子的烷基R2 =具有多达22个碳原子的烷基，-SY在显色期间分裂并形成硫醇，例如 5-巯基-1-苯基四唑，其抑制发育。

5. 发明授权

US4186012A Light sensitive color photographic material containing development inhibitor releasing coupler 失效
标题翻译：含有显影抑制剂释放成色剂的感光彩色照相材料
公开(公告)号：US4186012A
公开(公告)日：1980-01-29
申请号：US882631
申请日：1978-03-02
申请人： Heinrich Odenwalder , Walter Puschel , Robert J. Pollet , Erwin Ranz
发明人： Heinrich Odenwalder , Walter Puschel , Robert J. Pollet , Erwin Ranz
IPC分类号： G03C7/26 , C07D257/04 , G03C1/06 , G03C7/305 , G03C1/48 , G03C1/40 , G03C5/30
CPC分类号： C07D257/04 , G03C7/30511 , Y10S430/158
摘要： Non-diffusible thioether compounds capable of releasing, on reaction with color developer oxidation compounds, a diffusible silver halide development inhibitor without at the same time forming permanent dyes to any substantial extent are characterized by containing a group of the formula ##STR1## or its tautomeric form, wherein Z.sup.1 represents an electron attracting substituent and X represents an aliphatic, aromatic or heterocyclic group that if released together with the sulfur atom, forms a diffusible silver halide development inhibiting mercaptane.
摘要翻译：能够与着色显影剂氧化化合物反应释放扩散性卤化银显影抑制剂而不同时在任何实质上形成永久性染料的非扩散性硫醚化合物的特征在于含有下式的基团或其互变异构体形式，其中Z1表示吸电子取代基，X表示如果与硫原子一起释放的脂族，芳族或杂环基形成抑制硫化烷的扩散性卤化银显影剂。

6. 发明授权

US4171223A Light-sensitive color photographic material 失效
标题翻译：感光彩色照相材料
公开(公告)号：US4171223A
公开(公告)日：1979-10-16
申请号：US918390
申请日：1978-06-23
申请人： Heinrich Odenwalder , Walter Puschel , Erwin Ranz
发明人： Heinrich Odenwalder , Walter Puschel , Erwin Ranz
IPC分类号： G03C7/26 , C07D285/06 , C07D285/10 , C07D417/12 , G03C7/305 , G03C1/48 , G03C1/06 , G03C1/40 , G03C5/30
CPC分类号： C07D285/10 , G03C7/30511 , Y10S430/158
摘要： Non-diffusible silver halide development inhibitor releasing thioether compounds in which a color development does not give rise to a substantial formation of permanent dyes are 1,2,5'-.DELTA..sup.2 -thiadiazoline-1,1-dioxide derivatives of the following formula or its tautomeric (.DELTA..sup.3) form: ##STR1## in which X represents an aliphatic, aromatic or heterocyclic group such that when it is split off together with the sulphur atom of the thioether bridge, it forms a diffusible mercapto compound capable of inhibiting the development of the silver halide;R.sup.1 represents hydrogen, alkyl, aryl or a heterocyclic group andR.sup.2 represents hydrogen, alkyl, aryl, a heterocyclic group or preferably acyl.
摘要翻译：不扩散卤化银显影抑制剂释放的硫醚化合物，其中显色不会引起永久性染料的大量形成是下式的1,2,5'-三（2,3-二 - 噻二唑啉-1,1-二氧化物）衍生物或其互变异构体（DELTA 3）形式：其中X表示脂族，芳族或杂环基团，使得当其与硫醚桥的硫原子一起分离时，其形成可扩散的巯基化合物，其能够抑制开发卤化银; R 1表示氢，烷基，芳基或杂环基，R 2表示氢，烷基，芳基，杂环基或优选酰基。

7. 发明授权

US4088491A Light sensitive photographic material 失效
标题翻译：感光感光材料
公开(公告)号：US4088491A
公开(公告)日：1978-05-09
申请号：US742139
申请日：1976-11-16
申请人： Heinrich Odenwalder , Walter Puschel , Erwin Ranz
发明人： Heinrich Odenwalder , Walter Puschel , Erwin Ranz
IPC分类号： G03C7/26 , C07D221/16 , C07D257/02 , C07D257/04 , C07D295/096 , C07D401/12 , C07D403/12 , C07D405/12 , G03C7/305 , G03C7/32 , G03C7/00 , G03C1/02 , G03C5/30
CPC分类号： C07D257/04 , C07C317/00 , C07D221/16 , C07D295/096 , G03C7/305
摘要： High edge effects and interimage effects are provided in a color-photographic material by the use of new DIR-compounds. These are of the formula ##STR1## wherein X represents together with the sulfur atom a development inhibiting group;Y represents --O--, ##STR2## methylene group which may be alkyl substituted or a methine group; Z represents a methylene or ethylene group which may be alkyl substituted, a methine group, a vinylene group, an o-phenylene group, a carbonyl group, an oxycarbonyl group or a carbonamide group;R.sup.1 and R.sup.2 represent aliphatic, araliphatic or aromatic groups, acyl, acyloxy, alkoxy, aryloxy, amino, halogen, cyano, thioether groups or arylsulfoxyl or alkylsulfoxyl or both R.sup.1 and R.sup.2 together complete an at least mono-unsaturated or aromatic ring.
摘要翻译：通过使用新的DIR化合物，在彩色照相材料中提供了高边缘效果和图像间效应。这些具有式“IMAGE”，其中X表示与硫原子一起显影抑制基团; Y表示可以被烷基取代的亚甲基或次甲基; Z表示可以被烷基取代的亚甲基或亚乙基，次甲基，亚乙烯基，邻亚苯基，羰基，氧羰基或碳酰胺基; R 1和R 2表示脂族，芳脂族或芳族基团，酰基，酰氧基，烷氧基，芳氧基，氨基，卤素，氰基，硫醚基或芳基亚砜基或烷基亚磺酰基，或者R 1和R 2两者一起完成至少单不饱和或芳环。

8. 发明授权

US4310621A Photosensitive photographic material, a process for the production of photographic images, development baths and new hydroquinones 失效
标题翻译：感光照相材料，生产摄影图像的过程，开发浴和新的氢醌
公开(公告)号：US4310621A
公开(公告)日：1982-01-12
申请号：US217193
申请日：1980-12-16
申请人： Heinrich Odenwalder , Karl Frank , Reinhard Muller
发明人： Heinrich Odenwalder , Karl Frank , Reinhard Muller
IPC分类号： C07D249/12 , G03C5/30 , G03C7/305 , G03C1/06
CPC分类号： C07D249/12 , G03C5/3021 , G03C7/305 , G03C7/30541 , Y10S430/158 , Y10S430/16
摘要： New DIR-compounds of the formula ##STR1## are useful in photographic materials and processes.
摘要翻译：式（IMAGE）的新型DIR化合物在照相材料和方法中是有用的。

9. 发明授权

US6013428A Color photographic recording material having a 2-equivalent magenta coupler and a white coupler 失效
标题翻译：具有2-当量品红色耦合器和白色耦合器的彩色照相记录材料
公开(公告)号：US6013428A
公开(公告)日：2000-01-11
申请号：US891391
申请日：1997-07-11
申请人： Hans Langen , Heinrich Odenwalder , Uwe Dahlhaus
发明人： Hans Langen , Heinrich Odenwalder , Uwe Dahlhaus
IPC分类号： C07C69/757 , G03C7/30 , G03C7/392 , G03C7/333
CPC分类号： C07C69/757 , G03C7/3012 , G03C7/39232 , G03C7/39236
摘要： A colour photographic recording material having at least one red-sensitive silver halide emulsion layer which is associated with a cyan coupler, at least one green-sensitive silver halide emulsion layer which is associated with a magenta coupler, at least one blue-sensitive silver halide emulsion layer which is associated with a yellow coupler contains in at least one green-sensitive silver halide emulsion layer a 2-equivalent pyrazolone coupler and in a photosensitive or non-photosensitive layer a white coupler of the formula (I) ##STR1## in which X.sup.1 means an acyl residue derived from an aliphatic, cycloaliphatic or aromatic carboxylic or sulphonic acid, a carbonic acid semi-ester or a carbamic acid,Z means the residue required to complete a saturated or partially unsaturated 5- or 6-membered carbocyclic ring which is optionally substituted and/or provided with a further fused ring or ring system.The colour images produced using the recording material exhibit elevated storage stability without a subsequent increase in fog or a subsequent increase in colour density or spotting occurring during storage.
摘要翻译：一种彩色照相记录材料，其具有与青色成色剂相关联的至少一种感红卤化银乳剂层，与品红色成色剂相关的至少一种感绿卤化银乳剂层，至少一种蓝敏感卤化银与黄色成色剂相关联的乳剂层在至少一种感绿卤化银乳剂层中含有2-当量吡唑啉酮偶联剂，在光敏或非感光层中含有式（I）的白色偶联剂，其中X1表示衍生自脂族，脂环族或芳族羧酸或磺酸，碳酸半酯或氨基甲酸的酰基残基Z表示完成饱和或部分不饱和的5-或6-元碳环所需的残基，其任选被取代和/或设置有另外的稠环或环系统。使用记录材料产生的彩色图像表现出提高的储存稳定性，而不会随后增加雾度，或随后的颜色密度增加或储存期间发生斑点。

10. 发明授权

US5407789A Photographic recording material 失效
标题翻译：摄影记录材料
公开(公告)号：US5407789A
公开(公告)日：1995-04-18
申请号：US190686
申请日：1994-02-01
申请人： Heinrich Odenwalder , Hans hlschlager , Thomas Stetzer
发明人： Heinrich Odenwalder , Hans hlschlager , Thomas Stetzer
IPC分类号： G03C7/305 , C07D249/12 , C07D271/10 , C07D271/113 , C07D405/04 , C07D413/04 , G03C7/392 , G03C1/46
CPC分类号： C07D271/113 , C07D249/12 , C07D405/04 , C07D413/04 , G03C7/39228 , G03C7/39256 , G03C7/39272
摘要： A photographic recording material on a transparent support having at least one light-sensitive silver halide emulsion layer and optionally conventional interlayers and protective layers, characterized in that the photographic recording material contains, in at least one of the above-mentioned layers, a compound corresponding to formula I, II or III ##STR1## wherein R.sub.1 denotes an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryl group or an unsubstituted or substituted heterocyclic group,R2 denotes hydrogen, an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryl group or an unsubstituted or substituted alkylthio group,R.sub.3 denotes hydrogen or an unsubstituted or substituted alkyl group,R4 denotes an unsubstituted or substituted alkyl group, an unsubstituted or a substituted aryl group or an unsubstituted or substituted heterocyclic group,X denotes an alkylene group having 1 to 8 carbon atoms in which the carbon chain may be interrupted by oxygen or sulphur atoms, or it denotes an arylene group, andZ denotes hydrogen, a cation or a precursor compound thereof which is capable of releasing the mercapto compound non-imagewise in the course of development,is distinguished by excellent interimage and edge effects and by improved sharpness and graininess compared with conventional materials.
摘要翻译：在透明支撑体上的具有至少一个感光卤化银乳剂层和任选的常规中间层和保护层的照相记录材料，其特征在于，照相记录材料在至少一个上述层中含有相应的化合物其中R 1表示未取代或取代的烷基，未取代或取代的芳基或未取代或取代的杂环基，R 2表示氢，未取代或取代的烷基，未取代或取代的芳基或未取代或取代的烷硫基，R 3表示氢或未取代或取代的烷基，R 4表示未取代或取代的烷基，未取代或取代的芳基或未取代或取代的杂环基，X表示具有1至8个碳链可被中断的碳原子或者表示亚芳基，Z表示氢，可以在显影过程中非成像地释放巯基化合物的阳离子或其前体化合物，其特征在于优异的图像和边缘效果，通过与常规材料相比提高清晰度和颗粒度。

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