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1. 发明授权

US4210499A Method of forming colored patterns on aluminum or its alloys 失效
标题翻译：在铝或其合金上形成有色图案的方法
公开(公告)号：US4210499A
公开(公告)日：1980-07-01
申请号：US964464
申请日：1978-11-29
申请人： Hatsuo Hirono , Katsuyuki Nagata , Nobushige Doguchi
发明人： Hatsuo Hirono , Katsuyuki Nagata , Nobushige Doguchi
IPC分类号： B05D1/20 , B05D5/06 , B05D7/14 , B44F9/02 , C23C22/00 , C23C22/82 , C25D11/04 , C25D11/14 , C25D11/18 , C25D11/22 , C25D13/00 , C25D11/20
CPC分类号： B05D1/20 , B44F9/02 , C25D11/14 , C25D11/18 , C25D11/22 , B05D2202/25 , B05D5/061
摘要： A colored pattern imitating the grain of wood is formed on the surface of an article formed of an aluminum or its alloys by dipping the article, after oxidation process, in a coating bath floating a coating material in a multilinear or multiannular pattern to deposit the coating material in a wood grain pattern on the surfaces of the article and applying thereto a finish coating.
摘要翻译：在由铝或其合金形成的制品的表面上形成模仿木纹的彩色图案，其在氧化处理后浸渍在以多线或多层形式漂浮涂层材料的涂布浴中以沉积涂层在制品的表面上以木纹图案的材料并向其施加精加工涂层。

2. 发明授权

US4210695A Method of forming colored patterns on aluminum or its alloys 失效
标题翻译：在铝或其合金上形成有色图案的方法
公开(公告)号：US4210695A
公开(公告)日：1980-07-01
申请号：US964465
申请日：1978-11-29
申请人： Hatsuo Hirono , Katsuyuki Nagata , Nobushige Doguchi
发明人： Hatsuo Hirono , Katsuyuki Nagata , Nobushige Doguchi
IPC分类号： B05D1/20 , B05D1/32 , B05D5/06 , B44F9/02 , C25D11/04 , C25D11/14 , C25D11/22 , C25D13/00 , C23B9/02
CPC分类号： B05D1/322 , B05D1/20 , B44F9/02 , C25D11/022 , C25D11/04 , C25D11/14 , C25D11/22 , B05D2202/25 , B05D5/061 , Y10S205/917 , Y10T428/24438 , Y10T428/24917
摘要： A colored pattern imitating the grain of wood is formed on the surface of an article formed of an aluminum or its alloy by dipping the article in a coating bath floating a coating material in a multilinear pattern or multiannular pattern to form on the surface of the article a masking film in a pattern of the wood grain, subjecting the article to an oxide film application or etching and, after removal of the masking film, subjecting the article to an electrolytic coloring process.
摘要翻译：在由铝或其合金形成的制品的表面上形成模仿木纹的彩色图案，其通过将物品浸渍在以多线形图案或多圆形图案漂浮的涂层材料的涂层中，以形成在制品的表面上以木纹图案的掩模膜，对物品进行氧化膜施加或蚀刻，并且在去除掩模膜之后，使物品经受电解着色过程。

3. 发明授权

US4225398A Method of improving the corrosion resistance of an anodically oxidized surface film on aluminum articles 失效
标题翻译：提高铝制品上的阳极氧化表面膜的耐腐蚀性的方法
公开(公告)号：US4225398A
公开(公告)日：1980-09-30
申请号：US889443
申请日：1978-03-23
申请人： Mutsuo Hasegawa , Hatsuo Hirono , Katsuyuki Nagata , Shinji Hayashi , Hiroshi Yamagata
发明人： Mutsuo Hasegawa , Hatsuo Hirono , Katsuyuki Nagata , Shinji Hayashi , Hiroshi Yamagata
IPC分类号： B05D7/14 , C25D11/18 , C25D11/24 , C25D11/20 , C25D11/22
CPC分类号： B05D7/14 , C25D11/18 , C25D11/246
摘要： The corrosion resistance of an anodically oxidized surface film on aluminum articles is improved by sealing micropores and the like in such surface film with an aqueous sealing solution or dispersion containing siliceous material, such as silicic acid or a silicate, therein and thereafter overcoating the so-sealed surface with a select coating composition. The aqueous sealing solution is brought into contact with the aluminum article, such as by dipping the article into the solution and drying the so-coated article. Optionally, an electrical voltage may be applied through the sealing liquid and through the aluminum article during the sealing process. Further, in certain embodiments an electrical voltage may be applied through the sealing liquid before the liquid contacts the aluminum article. If desired, the surface of the aluminum article may be colored prior to sealing.
摘要翻译：在铝制品上的阳极氧化的表面膜的耐腐蚀性通过用含有硅质或硅酸盐等硅质材料的水性密封溶液或分散体密封这种表面膜中的微孔等来改善，密封表面与选择涂料组合物。使水性密封溶液与铝制品接触，例如通过将制品浸入溶液中并干燥如此涂覆的制品。可选地，可以在密封过程期间通过密封液体并通过铝制品施加电压。此外，在某些实施例中，在液体接触铝制品之前，可以通过密封液体施加电压。如果需要，铝制品的表面可以在密封之前着色。

4. 发明授权

US5120405A Method of coloring aluminum or aluminum alloy material 失效
标题翻译：铝或铝合金材料的着色方法
公开(公告)号：US5120405A
公开(公告)日：1992-06-09
申请号：US663009
申请日：1991-03-01
申请人： Seishiro Ito , Hideo Fukui , Norio Nakada , Hatsuo Hirono
发明人： Seishiro Ito , Hideo Fukui , Norio Nakada , Hatsuo Hirono
IPC分类号： C25D11/18 , C25D11/20 , C25D11/22 , C25D11/24
CPC分类号： C25D11/22 , C25D11/24
摘要： An aluminum or aluminum alloy material is subjected to anodic oxidation, then to a treatment of electrophoresis in a bath containing a hexacyanoferrate (II) or hexacyanoferrate (III), and subsequently to a treatment of immersion in a bath containing at least one metal salt selected from the group consisting of salts of Fe, Ni, Co, Cu, Zn, Cd, Ba, Tl, and Mg and at least one electrolyte selected from the group consisting of sodium sulfate, potassium sulfate, sodium chloride, and potassium chloride. Consequently, a coloring compound formed by the reaction of the aforementioned hexacyanoferrate (II) or hexacyanoferrate (III) with the aforementioned metal salt is deposited in the receding parts of micropores of an anodic oxide coating, with the result that the aluminum or aluminum alloy material is endowed with a durable color.
摘要翻译：对铝或铝合金材料进行阳极氧化，然后在含有六氰基铁酸盐（II）或六氰基铁酸盐（III）的浴中进行电泳处理，随后在包含至少一种选择的金属盐的浴中浸渍处理从由Fe，Ni，Co，Cu，Zn，Cd，Ba，Tl和Mg的盐组成的组中选出的至少一种电解质和选自硫酸钠，硫酸钾，氯化钠和氯化钾的至少一种电解质。因此，通过上述六氰基铁酸盐（II）或六氰基铁酸盐（III）与上述金属盐的反应形成的着色化合物沉积在阳极氧化物涂层的微孔的后退部分中，结果是铝或铝合金材料具有耐用的颜色。

5. 发明授权

US5217601A Method for impartation of blue color to aluminum or aluminum alloy 失效
标题翻译：用于将蓝色颜色转移到铝或铝合金的方法
公开(公告)号：US5217601A
公开(公告)日：1993-06-08
申请号：US894586
申请日：1992-06-05
申请人： Norio Nakada , Hideo Fukui , Hatsuo Hirono , Seishiro Ito
发明人： Norio Nakada , Hideo Fukui , Hatsuo Hirono , Seishiro Ito
IPC分类号： C25D11/22
CPC分类号： C25D11/22
摘要： Durable and clear blue color of freely controlled density can be expeditiously and efficiently impated to an anodic oxide film of aluminum by a method which comprises forming the anodic oxide film on the aluminum or aluminum alloy, then subjecting the aluminum or aluminum alloy to AC electrolysis in a bath containing an inorganic ferrous salt as a main component thereof thereby inducing deposition of iron in the pores of the oxide film, and subsequently placing the aluminum or aluminum alloy as an anode in a bath containing hexacyano iron (II) acid salt as a main component thereof and subjecting the same to DC electrolysis therein. In the alternative method, the pore-widening treatment is added next to said step of anodic oxidation. The pore-widening treatment is effected by immersing the aluminum or aluminum alloy in sulfuric acid or phosphoric acid or electrolyzing the same in phosphoric acid or a mixed solution of phosphoric acid and sulfuric acid.
摘要翻译：通过包括在铝或铝合金上形成阳极氧化膜，然后对铝或铝合金进行交流电解的方法，可以快速且有效地将耐用且清晰的蓝色的自由控制密度照射到铝的阳极氧化膜上含有无机亚铁盐作为主要成分的浴，由此在氧化膜的孔中引起铁的沉积，随后将铝或铝合金作为阳极置于含有六氰基铁（II）酸盐作为主体的浴中其组分并在其中进行DC电解。在替代方法中，在所述阳极氧化步骤旁边加入扩孔处理。通过将铝或铝合金浸渍在硫酸或磷酸中或在磷酸或磷酸和硫酸的混合溶液中电解，进行扩孔处理。

6. 发明授权

US5110782A Process for producing perovskite-type oxide catalyst 失效
标题翻译：生产氧化钇型氧化物催化剂的方法
公开(公告)号：US5110782A
公开(公告)日：1992-05-05
申请号：US507601
申请日：1990-04-10
申请人： Hatsuo Hirono , Koichi Moriyama , Hideo Fukui , Ikuya Matsuura
发明人： Hatsuo Hirono , Koichi Moriyama , Hideo Fukui , Ikuya Matsuura
IPC分类号： B01D53/94 , B01J23/00 , B01J23/89 , B01J37/00 , F23D14/18
CPC分类号： B01J37/0018 , B01J23/00 , Y10S502/525
摘要： The present invention provides a process for producing a perovskite-type oxide catalyst. The process comprises the steps of reacting an aqueous solution containing plural metal salts, such as chloride, sulfate, nitrate, etc., and an aqueous solution of a neutralizer such as alkali carbonate, alkali hydroxide, ammonia, etc., so as to cause coprecipitation of neutral salts and firing the coprecipitated salts to provide a perovskite-type oxide. At least one organic substance selected from the group consisting of cellulose, polyvinyl acetate, polyethylene, polystyrene, polypropylene, polyvinyl alcohol, starch, gelatin and saccharide is added prior to the firing step. The addition of the organic substance makes possible the attainment of a highly active perovskite-type oxide catalyst composed of very fine particles (primary particles).

7. 发明授权

US4973369A Alloy catalyst for oxidation of hydrogen 失效
标题翻译：氢氧化合金催化剂
公开(公告)号：US4973369A
公开(公告)日：1990-11-27
申请号：US518815
申请日：1990-05-04
申请人： Tsuyoshi Masumoto , Akihisa Inoue , Hisamichi Kimura , Hatsuo Hirono , Koichi Moriyama , Hideo Fukui
发明人： Tsuyoshi Masumoto , Akihisa Inoue , Hisamichi Kimura , Hatsuo Hirono , Koichi Moriyama , Hideo Fukui
IPC分类号： B22D11/06 , B01J21/06 , B01J23/75 , C22C16/00 , C22C19/00 , C22C19/07 , C22C45/04 , C22C45/10 , C22F1/00 , C22F1/10 , C22F1/18 , H01M4/90
CPC分类号： B01J23/75 , H01M4/90
摘要： The specification discloses an alloy catalyst for oxidation of hydrogen which is prepared by heat treating a material comprising an amorphous alloy represented by the formula: Zr.sub.x Co.sub.(100-x) (wherein 10 atomic %.ltoreq..times..ltoreq.80 atomic %), according to the following three-steps in an oxidizing atomsphere: first heat-treatment step at a temperature at which the foregoing alloy stably exists as an amorphous single phase; second heat-treatment step at a temperature at which the alloy exists as a mixed phase of a metastable phase and an amorphous phase; and third-heat treatment step at a temperature at which the alloy is entirely transformed into a crystalline phase. The alloy catalyst of the present invention is a highly active catalyst for oxidation of hydrogen and exhibits a superior catalytic efficiency especially in catalytic combustion of hydrogen and in deoxidation and dehydrogenation of a gas mixture of hydrogen and oxygen.

8. 发明授权

US5334297A Method for production of colored article of aluminum or aluminum alloy 失效
标题翻译：铝或铝合金彩色制品生产方法
公开(公告)号：US5334297A
公开(公告)日：1994-08-02
申请号：US119559
申请日：1993-09-13
申请人： Norio Nakada , Hideo Fukui , Hatsuo Hirono , Seishiro Ito
发明人： Norio Nakada , Hideo Fukui , Hatsuo Hirono , Seishiro Ito
IPC分类号： C25D11/04 , C25D11/20 , C25D11/22 , C25D13/04
CPC分类号： C25D11/22 , B60N2/4817 , B60N2/4847
摘要： A fast and brightly colored oxide film of aluminum which excels in durability and allows no separation of pigment is produced by using an aqueous dispersion of an organic pigment or carbon black finely divided to a size in the range between 3 and 150 nm, forming on a surface of an aluminum member an anodic oxide film containing pores larger in diameter than the ordinary pores, and causing the organic pigment or carbon black to migrate and deposit in the pores of the oxide film by means of electrophoresis. The formation of the anodic oxide film containing the pores larger in diameter than the ordinary pores is accomplished in the first method by subjecting the aluminum member to anodic oxidation at a high voltage in an aqueous solution of acid. In the second method, the anodic oxide film is subjected either to a treatment of immersion in an aqueous solution of at least one acid selected from among phosphoric acid, sulfuric acid, oxalic acid, and sulfamic acid or to a combination treatment of immersion and AC electrolysis repeated in a prescribed number of cycles in the solution, to enlarge the pores in the anodic oxide film.
摘要翻译：通过使用细分为3〜150nm范围内的有机颜料或炭黑的水性分散体，制造耐久性优异且不会分离颜料的快速且明亮的铝氧化膜，形成在铝构件的表面是含有直径大于普通孔的孔的阳极氧化膜，并且通过电泳使有机颜料或炭黑迁移并沉积在氧化膜的孔中。在第一种方法中，通过使铝构件在酸性水溶液中以高电压进行阳极氧化，实现了直径大于普通孔的阳极氧化膜的形成。在第二种方法中，将阳极氧化膜进行浸渍在选自磷酸，硫酸，草酸，氨基磺酸中的至少一种酸的水溶液中，或浸渍和AC的组合处理在溶液中以规定数量的循环重复电解，以扩大阳极氧化膜中的孔。

9. 发明授权

US4420378A Method for forming decorative colored streak patterns on the surface of an aluminum shaped article 失效
标题翻译：在铝制品的表面上形成装饰性有色条纹图案的方法
公开(公告)号：US4420378A
公开(公告)日：1983-12-13
申请号：US304671
申请日：1981-09-22
申请人： Masatake Tsuboi , Hatsuo Hirono , Kazuo Aikawa
发明人： Masatake Tsuboi , Hatsuo Hirono , Kazuo Aikawa
IPC分类号： C25D11/04 , C25D11/12 , C25D11/20 , C25D11/22
CPC分类号： C25D11/20 , C25D11/12 , C25D11/22
摘要： The invention provides a novel and improved method according to which the surface of a shaped article of aluminum or an aluminum-based alloy is provided with decorative streak patterns electrolytically engraved in the surface which can be subsequently colored to increase the decorative effect with uniform distribution over whole surface of the aluminum article. The method comprises first subjecting the anodically oxidized aluminum article to an anodic direct current electrolysis in an electrolytic solution containing a specified electrolyte and then carrying out a cathodic direct current electrolysis with the aluminum article and the counterelectrode kept as before in the same electrolytic solution as used in the first anodic direct current electrolysis with reversed polarity to give uniformly distributed streak patterns on the surface of the aluminum article. The surface of the aluminum article thus provided with the streak patterns is subsequently anodized to enhance the corrosion resistance and then subjected to a coloring treatment.
摘要翻译：本发明提供了一种新颖且改进的方法，其中铝或铝基合金成形制品的表面设置有电解雕刻在表面中的装饰条纹图案，其随后可以着色以增加均匀分布的装饰效果整个表面的铝制品。该方法包括首先使阳极氧化的铝制品在含有特定电解质的电解液中进行阳极直流电解，然后在与所用的相同的电解溶液中将铝制品和反电极保持如前所述进行阴极直流电解在第一次阳极直流电解中具有相反的极性，以在铝制品的表面上产生均匀分布的条纹图案。随后对由此提供条纹图案的铝制品的表面进行阳极氧化以增强耐腐蚀性，然后进行着色处理。

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