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1. 发明授权

US6111100A Preparation of bis(2-morpholinoethyl) ether 有权
标题翻译：双（2-吗啉代乙基）醚的制备
公开(公告)号：US6111100A
公开(公告)日：2000-08-29
申请号：US474906
申请日：1999-12-30
申请人： Hartmut Riechers , Joachim Simon , Andreas Henne , Arthur Hohn
发明人： Hartmut Riechers , Joachim Simon , Andreas Henne , Arthur Hohn
IPC分类号： C07D295/08 , B01J23/72 , C07D295/088 , C07D413/12
CPC分类号： C07D295/088
摘要： In a process for preparing bis(2-morpholinoethyl) ether by reacting diethylene glycol with ammonia under superatmospheric pressure and at elevated temperature in the presence of hydrogen and a hydrogenation catalyst, the catalytically active composition of the catalyst prior to reduction with hydrogen comprisesfrom 20 to 85% by weight of aluminum oxide (Al.sub.2 O.sub.3), zirconium dioxide (ZrO.sub.2), titanium dioxide (TiO.sub.2) and/or silicon dioxide (SiO.sub.2),from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO,from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr.sub.2 O.sub.3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, andless than 20% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO.
摘要翻译：在氢气和氢化催化剂的存在下，在二氧化乙烯与氨在超大气压和升高的温度下反应制备双（2-吗啉代乙基）醚的方法中，用氢还原之前的催化剂催化活性组合物包括20 至85重量％的氧化铝（Al 2 O 3），二氧化锆（ZrO 2），二氧化钛（TiO 2）和/或二氧化硅（SiO 2），1至70重量％的含氧化合物的铜，以CuO ，0〜50重量％的以氧化镁计的含氧化合物的镁，以Cr 2 O 3计算的含氧化合物的铬，以ZnO计的氧的含氧化合物，钡的含氧化合物，计算值作为BaO，和/或以CaO计的钙的含氧化合物，以NiO计，基于含氧化合物的铜，小于20重量％的含氧化合物的镍，以CuO计算。

2. 发明授权

US6160178A Racemization of optically active amines 有权
标题翻译：光学活性胺的外消旋化
公开(公告)号：US6160178A
公开(公告)日：2000-12-12
申请号：US303599
申请日：1999-05-03
申请人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
发明人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
IPC分类号： B01J23/72 , B01J23/755 , B01J37/18 , C07B55/00 , C07B61/00 , C07C209/00 , C07C209/68 , C07C211/07 , C07C213/08 , C07C217/08
CPC分类号： C07C213/08 , C07B2200/07 , C07C209/68 , C07C217/08 , C07C211/07
摘要： Optically active amines are racemized by reaction of the optically active amine in the gas phase at elevated temperature in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst.
摘要翻译：光学活性胺通过在氢气和氢化或脱氢催化剂存在下在高温下在气相中的光学活性胺的反应进行外消旋化。

3. 发明授权

US6153797A Racemizing of optically active amines 有权
标题翻译：光学活性胺的外消旋化
公开(公告)号：US6153797A
公开(公告)日：2000-11-28
申请号：US259043
申请日：1999-03-01
申请人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
发明人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
IPC分类号： B01J23/755 , C07B55/00 , C07B57/00 , C07B61/00 , C07C209/68 , C07C211/03 , C07C213/02 , C07C213/08 , C07C217/08 , C07C204/00
CPC分类号： C07C213/08 , C07C209/68
摘要： In a process for racemizing optically active amines by reacting the optically active amine in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperature, the reaction is carried out in liquid phase and the catalyst comprises the catalytically active constituents copper, silver, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium and/or platinum and a support material selected from the group consisting of aluminum oxide, zirconium dioxide, titanium dioxide, carbon and/or oxygen compounds of silicon.
摘要翻译：在通过使光学活性胺在氢气和氢化或脱氢催化剂的存在下在升高的温度下使光学活性胺反应的方法中，反应在液相中进行，催化剂包含催化活性成分铜，银，铁钴，镍，钌，铑，钯，锇，铱和/或铂，以及选自氧化铝，二氧化锆，二氧化钛，碳和/或氧化合物的硅的载体材料。

4. 发明授权

US6049007A Racemization of optically active amines 有权
标题翻译：光学活性胺的外消旋化
公开(公告)号：US6049007A
公开(公告)日：2000-04-11
申请号：US259042
申请日：1999-03-01
申请人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
发明人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
IPC分类号： B01J23/755 , C07B55/00 , C07B57/00 , C07B61/00 , C07C209/68 , C07C211/03 , C07C213/02 , C07C213/08 , C07C217/08 , C07C209/00
CPC分类号： C07C213/08 , C07C209/68
摘要： A process for the preparation of racemic amines of the formula I ##STR1## where R.sup.1 and R.sup.2 are different and R.sup.1, R.sup.2, R.sup.3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R.sup.3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III ##STR2## and the amine of the formula R.sup.3 NH.sub.2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.
摘要翻译：制备式I的外消旋胺的方法，其中R 1和R 2不同，R 1，R 2，R 3是烷基，环烷基，芳烷基，芳基，杂芳基和杂环基，R 3也可以是氢，其中基团可以带有取代基选自烷基，环烷基，烷氧基，芳氧基，氨基，烷基氨基和二烷基氨基，其包括同时使相应的光学活性胺I和式II的仲醇和/或式III的不对称酮和式R 3 NH 2的胺在氢气和氢化催化剂或脱氢催化剂的存在下在升高的温度下进行。

5. 发明授权

US06627756B1 Preparation of pure triethylenediamine 有权
标题翻译：纯三亚乙基二胺的制备
公开(公告)号：US06627756B1
公开(公告)日：2003-09-30
申请号：US09613718
申请日：2000-07-11
申请人： Hartmut Riechers , Arthur Höhn , Joachim Simon , Ortmund Lang , Hartmut Schoenmakers , Matthias Rauls , Koen Claerbout
发明人： Hartmut Riechers , Arthur Höhn , Joachim Simon , Ortmund Lang , Hartmut Schoenmakers , Matthias Rauls , Koen Claerbout
IPC分类号： C07D48708
CPC分类号： C07D487/08
摘要： Pure triethylenediamine (TEDA) is prepared by vaporizing TEDA, introducing the gaseous TEDA into a liquid solvent and subsequently crystallizing the TEDA from the solution obtained in this way.
摘要翻译：通过蒸发TEDA，将气态TEDA引入液体溶剂中并随后从以这种方式获得的溶液中使TEDA结晶来制备纯三亚乙基二胺（TEDA）。

6. 发明授权

US08349843B2 Carboxylic acid derivatives, their preparation and use 有权
标题翻译：羧酸衍生物，其制备和用途
公开(公告)号：US08349843B2
公开(公告)日：2013-01-08
申请号：US13267178
申请日：2011-10-06
申请人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Vogelbacher , Wolfgang Wernet , Andrea Hager-Wernet, legal representative , Liliane Unger , Manfred Raschack
发明人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
IPC分类号： A61K31/505 , A61K31/517 , A61K31/519
CPC分类号： C07D495/04 , C07D239/34 , C07D239/48 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/96 , C07D251/20 , C07D251/26 , C07D251/52 , C07D403/06 , C07D403/12 , C07D405/12 , C07D405/14 , C07D413/12 , C07D417/12 , C07D487/04 , C07D491/04 , C07D491/048
摘要： Carboxylic acid derivatives where R—R6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.
摘要翻译：其中R-R6，X，Y和Z具有说明书中所述含义的羧酸衍生物及其制备。新型化合物适用于控制疾病。

7. 发明授权

US07109205B2 Carboxylic acid derivatives, their preparation and use 有权
标题翻译：羧酸衍生物，其制备和用途
公开(公告)号：US07109205B2
公开(公告)日：2006-09-19
申请号：US10602275
申请日：2003-06-24
申请人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Müller , Ernst Baumann , Joachim Rheinheimer , Uwe Josef Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
发明人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Müller , Ernst Baumann , Joachim Rheinheimer , Uwe Josef Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
IPC分类号： C07D239/02 , A61K31/505
CPC分类号： C07D495/04 , C07D239/34 , C07D239/48 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/96 , C07D251/20 , C07D251/26 , C07D251/52 , C07D403/06 , C07D403/12 , C07D405/12 , C07D405/14 , C07D413/12 , C07D417/12 , C07D487/04 , C07D491/04 , C07D491/048
摘要： Carboxylic acid derivatives where R–R6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.
摘要翻译：其中R-R 6，X，Y和Z具有说明书中所述含义及其制备的羧酸衍生物。新型化合物适用于控制疾病。

8. 发明授权

US06197958B1 Carboxylic acid derivatives, their preparation and use 有权
标题翻译：羧酸衍生物，其制备和用途
公开(公告)号：US06197958B1
公开(公告)日：2001-03-06
申请号：US09309770
申请日：1999-05-11
申请人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Müller , Ernst Baumann , Joachim Rheinheimer , Uwe Josef Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
发明人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Müller , Ernst Baumann , Joachim Rheinheimer , Uwe Josef Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
IPC分类号： C07D23726
CPC分类号： C07D495/04 , C07D239/34 , C07D239/48 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/96 , C07D251/20 , C07D251/26 , C07D251/52 , C07D403/06 , C07D403/12 , C07D405/12 , C07D405/14 , C07D413/12 , C07D417/12 , C07D487/04 , C07D491/04 , C07D491/048
摘要： Carboxylic acid derivatives where R—R6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.
摘要翻译：其中R-R6，X，Y和Z的羧酸衍生物具有说明书中所述的含义及其制备。新型化合物适用于控制疾病。

9. 发明授权

US07601730B2 Carboxylic acid derivatives, their preparation and use 失效
公开(公告)号：US07601730B2
公开(公告)日：2009-10-13
申请号：US11502293
申请日：2006-08-10
申请人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Josef Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
发明人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Josef Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
IPC分类号： A61P7/02
CPC分类号： C07D495/04 , C07D239/34 , C07D239/48 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/96 , C07D251/20 , C07D251/26 , C07D251/52 , C07D403/06 , C07D403/12 , C07D405/12 , C07D405/14 , C07D413/12 , C07D417/12 , C07D487/04 , C07D491/04 , C07D491/048
摘要： Carboxylic acid derivatives where R—R6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.

10. 发明申请

US20070203338A1 Novel carboxylic acid derivatives, their preparation and use 失效
标题翻译：新型羧酸衍生物，其制备和用途
公开(公告)号：US20070203338A1
公开(公告)日：2007-08-30
申请号：US11789630
申请日：2007-04-25
申请人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
发明人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
IPC分类号： C07D251/22 , C07D207/00 , C07D233/22 , C07D303/48 , C07D257/06 , C07D239/24
CPC分类号： C07D495/04 , C07D239/34 , C07D239/48 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/96 , C07D251/20 , C07D251/26 , C07D251/52 , C07D403/06 , C07D403/12 , C07D405/12 , C07D405/14 , C07D413/12 , C07D417/12 , C07D487/04 , C07D491/04 , C07D491/048
摘要： Carboxylic acid derivatives where R—R6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.
摘要翻译：其中R-R 6，X，Y和Z具有说明书中所述含义及其制备的羧酸衍生物。新型化合物适用于控制疾病。

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