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1. 发明授权

US5004779A Process for the preparation of aqueous, oxidatively drying alkyd resins and their use in or as aqueous lacquers and coating compounds 失效
标题翻译：水性氧化干燥醇酸树脂的制备方法及其在水性漆和涂料化合物中的用途
公开(公告)号：US5004779A
公开(公告)日：1991-04-02
申请号：US462785
申请日：1990-01-10
申请人： Harald Blum , Jurgen Meixner , Manfred Schreckenberg , Lothar Fleiter , Wolfgang Wellner
发明人： Harald Blum , Jurgen Meixner , Manfred Schreckenberg , Lothar Fleiter , Wolfgang Wellner
IPC分类号： C09D175/04 , C08G18/00 , C08G18/08 , C08G18/42 , C08G18/66 , C08G63/49 , C09D5/00 , C09D175/06
CPC分类号： C08G18/0823 , C08G18/4288 , C08G18/6659
摘要： A process is disclosed for preparing aqueous, oxidatively-drying alkyd resins. The resins are useful as binders in aqueous lacquers and coating compositions.
摘要翻译：公开了制备水性，氧化干燥的醇酸树脂的方法。这些树脂可用作水性漆和涂料组合物中的粘合剂。

2. 发明授权

US5223582A Polymers capable of oxidative crosslinking 失效
标题翻译：能够进行氧化交联的聚合物
公开(公告)号：US5223582A
公开(公告)日：1993-06-29
申请号：US775647
申请日：1991-10-10
申请人： Harald Blum , Lothar Fleiter
发明人： Harald Blum , Lothar Fleiter
IPC分类号： C08F222/40 , C08F8/30 , C08F20/52 , C09D133/02 , C09D135/00 , C09K3/10
CPC分类号： C08F8/30 , C08F2800/20
摘要： The present invention relates to polymers capable of oxidative crosslinking, characterized in that they contain 10 to 80% by weight of structural units corresponding to formula (I) and/or (Ia) ##STR1## wherein R.sub.1 is an aliphatic saturated hydrocarbon radical containing 2 to 6 carbon atoms, provided that at least 2 carbon atoms are arranged between the nitrogen atom and the oxygen atom, andR.sub.2 at least 30% of the substituents R are monoolefinically or polyolefinically unsaturated hydrocarbon radicals and the remainder, i.e. up to 70% of the substituents R.sub.2, are saturated aliphatic and/or aromatic hydrocarbon radicals which may optionally contain oxygen and/or nitrogen as hetero atoms in the form of ether, ester, keto, urethane, urea and/or amide groups, provided that substituent R.sub.2 contains at least 2.0% by weight, based on the weight of the polymer, of aliphatically unsaturated double bonds, expressed as C.dbd.C (molecular weight=24).The present invention also relates to a process for the production of these polymers and to the use of these polymers as binders or binder component for coating or sealing compositions.
摘要翻译：本发明涉及能够进行氧化交联的聚合物，其特征在于它们含有10至80重量％的对应于式（I）和/或（Ia）的结构单元，其中 R1是含有2至6个碳原子的脂族饱和烃基，条件是至少2个碳原子排列在氮原子和氧原子之间，R2至少30％的取代基R是单烯属或聚烯烃不饱和烃基，剩余部分，即高达70％的取代基R2，是饱和的脂族和/或芳族烃基，其可以任选地含有氧和/或氮作为醚，酯，酮，氨基甲酸酯，脲和/或酰胺基团，条件是取代基R2基于聚合物的重量计含有至少2.0重量％的脂族不饱和双键，表示为C = C（分子量= 24）。本发明还涉及这些聚合物的制备方法以及这些聚合物作为粘合剂或粘合剂组分用于涂覆或密封组合物的用途。

3. 发明授权

US4400489A Aerially-crosslinking polyacrylate coating agents 失效
标题翻译：空气交联聚丙烯酸酯涂层剂
公开(公告)号：US4400489A
公开(公告)日：1983-08-23
申请号：US323763
申请日：1981-11-23
申请人： Rolf Dhein , Lothar Fleiter
发明人： Rolf Dhein , Lothar Fleiter
IPC分类号： C09D133/04 , C09D125/14 , C09D133/06 , C09D155/04 , C09D3/727 , C09D3/80
CPC分类号： C09D155/04 , C09D125/14 , C09D133/062
摘要： The invention relates to an aerially-crosslinking, pigmented or non-pigmented coating agent consisting of conventional lacquer auxiliaries and an aerially-crosslinking binder which has been reacted to form a dicarboxylic acid semi-ester by the reaction of a copolymer consisting of copolymerized units of at least one ester carrying at least one 1,2-epoxide group or hydroxyl group of an .alpha.,.beta.-monoolefinically unsaturated C.sub.3 -C.sub.5 -carboxylic acid and at least one vinyl or vinylidene monomer which is different therefrom with at least one drying fatty acid and optionally with at least one cyclic dicarboxylic acid anhydride, characterized in that the coating agent contains as an additional lacquer auxiliary from 0.2 to 2% by weight of at least one .alpha.-dicarbonyl compound, based on the aerially-crosslinking binder.
摘要翻译：本发明涉及由通常的漆助剂和空气交联粘合剂组成的空气交联，着色或非着色涂料，其通过共聚合反应形成二羧酸半酯反应，所述共聚物由共聚单元至少一个携带α，β-单烯属不饱和C3-C5-羧酸的至少一个1,2-环氧基或羟基的至少一个酯和至少一种与至少一种干燥脂肪酸不同的乙烯基或亚乙烯基单体和任选地与至少一种环状二羧酸酐，其特征在于，所述涂层剂基于所述空气交联粘合剂，含有0.2至2重量％的至少一种α-二羰基化合物作为附加漆。

4. 发明授权

US4129537A Air-drying acrylate lacquer binders 失效
标题翻译：空气干燥丙烯酸酯漆粘合剂
公开(公告)号：US4129537A
公开(公告)日：1978-12-12
申请号：US842042
申请日：1977-10-14
申请人： Rolf Dhein , Lothar Fleiter
发明人： Rolf Dhein , Lothar Fleiter
IPC分类号： C09D163/00 , C09D125/14 , C09D3/58 , C09D3/74
CPC分类号： C09D125/14 , C08K5/10
摘要： An air-drying lacquer binder comprising a copolymer of copolymerized units of20 to 55% by weight of styrene,5 to 30% by weight of glycidyl(meth)acrylate, and0 to 50% by weight of at least one (meth)acrylic acid ester with 1 to 10 carbon atoms in the alcohol component,Which has been esterified with0 to 15% by weight of at least one natural, drying fatty acid, and10 to 50% by weight of isomerized drying fatty acids(the sum of the percentage contents amounting to 22 - 50 percent by weight) based on the copolymer and drying fatty acids and dicarboxylic acid anhydride subsequently used, up to an acid number of
摘要翻译：一种空气干燥漆粘合剂，其包含共聚单元的共聚单位为20至55％，苯乙烯重量百分比为5至30％，丙烯酸（甲基）酯为重量百分比，和至少一个（甲基）丙烯酸重量的0至50％在酒精组分中含有1至10个碳原子的酸性酯，其已经以至少一种天然的重量为基准，0至15％的脂肪酸，以及等于脂肪酸的脂肪酸的重量为10至50％（“ 基于共聚物和干燥脂肪酸和二羧酸类抗坏血酸的百分比含量（以重量计）为22-50重量％，最多为<10，30至75％。含有相同双重债券的异构干燥脂肪酸，以及所形成的羟基组合，其后按照重量的0.5％至3％反应，基于BINDER，四氢醋酸酐和/或至少的总成分其中一个异星系漆粘合剂具有非常好的颜料吸收和润湿性能，非常好的漆级可加工性，甚至在恒定干燥条件下加入防结皮剂恒定干燥时间后，

5. 发明授权

US4186116A Air-drying and oven-drying acrylate lacquer binders 失效
标题翻译：空气干燥和烘干丙烯酸酯漆结合剂
公开(公告)号：US4186116A
公开(公告)日：1980-01-29
申请号：US917378
申请日：1978-06-20
申请人： Rolf Dhein , Lothar Fleiter , Wolfgang Beer
发明人： Rolf Dhein , Lothar Fleiter , Wolfgang Beer
IPC分类号： C08F242/00 , C08F246/00 , C09D125/14 , C09D133/04 , C09D133/14 , C09D3/52 , C09D3/80 , C09D3/81
CPC分类号： C09D133/14 , C08F242/00 , C08F246/00 , C09D125/14 , C09D133/04
摘要： An air-drying and oven-drying lacquer binder based on a copolymer having copolymerized units of5 to 40% by weight of styrene,10 to 50% by weight of at least one hydroxyalkyl(meth)acrylate with 2 to 4 carbon atoms in the alkyl group, and10 to 40% by weight of at least one (meth)acrylic acid ester with 1 to 10 carbon atoms in the alcohol component, esterified with10 to 50% by weight, based on the copolymer and drying fatty acid and dicarboxylic acid anhydride, of a drying fatty acid,from 10 to 70 mole % of the hydroxyl groups of the incorporated hydroxyalkyl(meth)acrylate units having been esterified with the drying fatty acid and thereafter from 0.5 to 20 mole % of the hydroxyl groups of the incorporated hydroxyalkyl(meth)acrylate units having been reacted with from 0.5 to 10% by weight, based on the lacquer binder, of at least one dicarboxylic acid cyclic anhydride to form the semiester of the corresponding dicarboxylic acid having an overall acid number of from 5 to 30, the overall acid number being composed of an acid number of from 1 to 10, as determined after esterification with the drying fatty acid and emanating from the free fatty acid, and of acid number of from 1 to 29, as determined on the solvent-free lacquer binder (end product) and emanating from formation of the semiester.
摘要翻译：基于共聚物的空气干燥和烘干漆粘合剂，其具有5至40重量％的苯乙烯，10至50重量％的至少一种具有2至4个碳原子的（甲基）丙烯酸羟烷基酯的共聚单元和10〜40重量％的至少一种在醇组分中具有1-10个碳原子的（甲基）丙烯酸酯，基于共聚物酯化10至50重量％，并干燥脂肪酸和二羧酸酸酐，干燥脂肪酸，10〜70摩尔％的已被干燥脂肪酸酯化的（甲基）丙烯酸羟烷基酯单元的羟基，然后将0.5〜20摩尔％的羟基引入了基于漆粘合剂0.5至10重量％的至少一种二羧酸环状酸酐反应的羟基烷基（甲基）丙烯酸酯单元，以形成总酸值为5的相应的二羧酸的半酯到30岁，超市酸值由1至10的酸值组成，如通过干燥脂肪酸酯化并从游离脂肪酸发出后测定的，酸值为1至29，如无溶剂漆粘合剂（最终产品），并由半成品的形成产生。

6. 发明授权

US4146519A Air-drying acrylate lacquer binders 失效
标题翻译：空气干燥丙烯酸酯漆粘合剂
公开(公告)号：US4146519A
公开(公告)日：1979-03-27
申请号：US876539
申请日：1978-02-09
申请人： Rolf Dhein , Lothar Fleiter
发明人： Rolf Dhein , Lothar Fleiter
IPC分类号： C09D133/04 , C08F8/14 , C09D3/74 , C09D3/80
CPC分类号： C08F8/14 , C08F2810/30
摘要： Air-drying lacquer binders comprising copolymers of copolymerised units of20 to 55% by weight of styrene,5 to 30% by weight of glycidyl (meth)acrylate, and0 to 50% by weight of at least one (meth)acrylic acid ester having from 1 to 10 C-atoms in the alcohol component,Which copolymers have been esterified to acid numbers of from 0 to 10 with from 22 to 50% by weight of air-drying fatty acids, based on the quantity of copolymer and drying fatty acids and dicarboxylic acid anhydride, and the hydroxyl groups thereby formed have subsequently been reacted with from 0.5 to 3% by weight of dicarboxylic acid anhydride, based on the quantity of copolymer and drying fatty acids and dicarboxylic acid anhydride, characterized in that the binders have acid numbers of from 5 to 15, these final acid numbers being made up of the acid numbers of from 0 to 10 obtained by the esterification with drying fatty acids and the acid numbers of from 1 to 15 obtained from the reaction with the dicarboxylic acid anhydride.
摘要翻译：空气干燥漆粘合剂，其包含20至55％共聚单元的共聚物，其中苯乙烯重量为5至30％，丙烯酸（甲基）酯为重量的5至30％，和至少一种（甲基）丙烯酸酯的重量的0至50％在醇组分中具有1至10个C原子，根据共聚物和干燥脂肪的数量，共聚物已被确定为0至10的数量，具有22至50％的空气干燥脂肪酸的重量酸和二羧酸酐，根据共聚物和干燥脂肪酸和二羧酸酸酐的数量，其形成的羟基根据重量的比例从0.5％至3％按重量计反应，其特征在于粘结剂从5到15的酸值，这些最终酸值是由干酪脂肪酸所得的0至10的酸值和与二羧酸反应获得的1至15的酸值的酸值 ID ANHYDRIDE。

7. 发明授权

US4684691A Process for the production of siccativated aqueous lacquers with polybutadiene/maleic acid anhydride adducts as bonding agent 失效
标题翻译：用聚丁二烯/马来酸酐加合物作为粘合剂生产酸洗水性漆的方法
公开(公告)号：US4684691A
公开(公告)日：1987-08-04
申请号：US757800
申请日：1985-07-22
申请人： Hans G. Stahl , Peter Hohlein , Hans-Joachim Traenckner , Lothar Fleiter , Jurgen Schwindt
发明人： Hans G. Stahl , Peter Hohlein , Hans-Joachim Traenckner , Lothar Fleiter , Jurgen Schwindt
IPC分类号： C08F279/00 , C08C19/28 , C08F279/02 , C09D7/80 , C09D151/00 , C09D151/04 , C09F9/00 , C08L51/00
CPC分类号： C08F279/02 , C08C19/28 , C09D151/04
摘要： Aqueous lacquers, which contain grafted polybutadiene/maleic acid semi-esters or semi-amides as bonding agent, can be siccativated while the siccative is firstly dispersed in the aqueous phase and the bonding agent is dispersed in this dispersion.
摘要翻译：含有接枝聚丁二烯/马来酸半酯或半酰胺作为粘合剂的水性漆可以在首先分散在水相中并将粘合剂分散在该分散体中的同时被干燥。

8. 发明授权

US4413116A Process for the preparation of polyesters or alkyd resins, resins which may be obtained according to this process and the use thereof as lacquer binders 失效
标题翻译：用于制备聚酯或醇酸树脂的方法，可以根据该方法获得的树脂及其作为漆粘合剂的用途
公开(公告)号：US4413116A
公开(公告)日：1983-11-01
申请号：US366584
申请日：1982-04-08
申请人： Knud Reuter , Rolf Dhein , Lothar Fleiter
发明人： Knud Reuter , Rolf Dhein , Lothar Fleiter
IPC分类号： C08G63/00 , C08G63/46 , C08G63/48 , C08G63/78 , C09D167/00 , C09D167/08 , C08G63/12 , C09D3/64
CPC分类号： C08G63/48 , C09D167/08
摘要： Penta- or hexahydric sugar alcohols are outstandingly suitable as a polyol component for the preparation of polyesters or alkyd resins. Secondary reactions resulting in darkening are substantially avoided if as small a quantity as possible of aromatic polycarboxylic acid components is used.
摘要翻译：五元醇或六元糖醇非常适合用作制备聚酯或醇酸树脂的多元醇组分。如果使用尽可能少的芳族多元羧酸组分的量，则基本上避免了导致变暗的二次反应。

9. 发明授权

US4304695A Air-drying, fatty acid-modified lacquer binders, based on fumaric or maleic acid bis-glycidyl ester copolymers 失效
标题翻译：基于富马酸或马来酸双缩水甘油酯共聚物的空气干燥脂肪酸改性漆粘合剂
公开(公告)号：US4304695A
公开(公告)日：1981-12-08
申请号：US181043
申请日：1980-08-25
申请人： Peter Hohlein , Hans-Joachim Traenckner , Lothar Fleiter , Ludwig Bottenbruch
发明人： Peter Hohlein , Hans-Joachim Traenckner , Lothar Fleiter , Ludwig Bottenbruch
IPC分类号： C08F8/00 , C08F8/14 , C09D155/04 , C09D163/00 , C08F220/32
CPC分类号： C09D155/04 , C08F8/14 , C08F2810/30
摘要： A binder composition which has a number average molecular weight of from 1000 to 20,000 and which comprises, in copolymerized form, from 5 to 55% by weight of fumaric acid and/or maleic acid bis-glycidyl ester and from 95 to 45% by weight of one or more vinyl and/or vinylidene monomers, esterified to an acid number of from 3 to 30 mg KOH/g with from 18 to 72% by weight, based on copolymer plus fatty acid, of a fatty acid and subsequently reacted with 0 to 3% by weight, based on copolymer plus fatty acid plus dicarboxylic acid anhydride, of a dicarboxylic acid anhydride.
摘要翻译：数均分子量为1000〜20,000的粘合剂组合物，其共聚形式为5〜55重量％的富马酸和/或马来酸双缩水甘油酯，95〜45重量％的一种或多种乙烯基和/或亚乙烯基单体，酯化为酸值为3至30mg KOH / g，基于共聚物加脂肪酸的18至72重量％的脂肪酸，随后与0 至3重量％，基于共聚物加脂肪酸加二羧酸酐的二羧酸酐。

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