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1. 发明授权

US06596796B1 Stabilizers for emulsion crude rubbers, synthetic latex and natural rubber latex 失效
标题翻译：乳化乳胶，合成胶乳和天然橡胶胶乳的稳定剂
公开(公告)号：US06596796B1
公开(公告)日：2003-07-22
申请号：US09688417
申请日：2000-10-16
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Paul Dubs , Samuel Evans
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Paul Dubs , Samuel Evans
IPC分类号： C08K5134
CPC分类号： C08K5/134 , C08L21/02
摘要： There are described compositions comprising a) an emulsion crude rubber, synthetic latex or natural rubber latex subject to oxidative, thermal, dynamic and/or light-induced degradation, and b) as stabilizer at least one compound of formula I wherein R1 is C8-C20alkyl; and optionally c) as further stabilizer at least one compound of formula II wherein R2 is C8-C12alkyl, R3 is hydrogen, C1-C12alkyl, cyclohexyl, 1-methylcyclohexyl, benzyl, &agr;-methylbenzyl, &agr;,&agr;-dimethylbenzyl or —CH2—S—R2, R4 is C1-C12alkyl, benzyl, &agr;-methylbenzyl, 60 ,&agr;-dimethylbenzyl or —CH2—S—R2, and R5 is hydrogen or methyl.
摘要翻译：描述的组合物包括：a）经受氧化，热，动态和/或光诱导降解的乳液粗橡胶，合成胶乳或天然橡胶胶乳，和b）作为稳定剂的至少一种式I化合物，其中R1是C8-C20烷基;和任选地，c）作为其它稳定剂的至少一种式II化合物，其中R2是C8-C12烷基，R3是氢，C1-C12烷基，环己基，1-甲基环己基，苄基，α-甲基苄基，α，α-二甲基苄基或-CH2-S-R2 R 4是C 1 -C 12烷基，苄基，α-甲基苄基，60，α-二甲基苄基或-CH 2 -S-R 2，R 5是氢或甲基。

2. 发明授权

US07947831B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07947831B2
公开(公告)日：2011-05-24
申请号：US11523441
申请日：2006-09-19
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C07C317/00 , C07C317/04 , C07C317/06 , C07C317/10 , C07C317/18 , C07C317/44
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, wherein the general symbols are as defined within, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I化合物接枝的聚合物，其中通式如上所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性。

3. 发明申请

US20070015870A1 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US20070015870A1
公开(公告)日：2007-01-18
申请号：US11523441
申请日：2006-09-19
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michele Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michele Gerster
IPC分类号： C08L63/00
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I化合物接枝的聚合物，其中通式符号如权利要求1所定义，对氧化，热，动态，光诱导和/或臭氧诱导的降解具有突出的稳定性。

4. 发明授权

US07160955B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07160955B2
公开(公告)日：2007-01-09
申请号：US10473848
申请日：2002-03-26
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C08F8/34
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, formula (I) wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation [R1—SOmnR—SOp—R2. (I)
摘要翻译：用式I化合物（I）接枝的聚合物，其中通式如权利要求1所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性，公式描述=“在线公式”end =“lead”？> [R＆lt; 1＆lt;＆lt;＆lt;＆lt;＆gt;＆lt; img id =“PRIVATE-USE-CHARACTER-00001” =“6.77mm”wi =“8.47mm”file =“US07160955-20070109-Brketclosest.TIF”alt =“私人使用字符Brketclosest”img-content =“character”img-format =“tif”/> R 2 SO 2 -R 2。（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>

5. 发明授权

US5258433A Sulfoxides of alkylthiomethylphenols 失效
标题翻译：烷硫基甲基苯酚的亚砜
公开(公告)号：US5258433A
公开(公告)日：1993-11-02
申请号：US747569
申请日：1991-08-20
申请人： Hans-Rudolf Meier , Paul Dubs
发明人： Hans-Rudolf Meier , Paul Dubs
IPC分类号： C07C317/18 , C07C317/44 , C08K5/41 , C09K15/14 , C10M135/08 , C10N30/00 , C10N30/08 , C10N30/12 , C10N40/08
CPC分类号： C08K5/41 , C07C317/18 , C09K15/14
摘要： Sulfoxides of alkylthiomethylphenols of the formula I ##STR1## in which R.sub.1 is hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.5 -C.sub.7 cycloalkyl, C.sub.5 -C.sub.7 cycloalkenyl, phenyl or C.sub.7 -C.sub.9 phenylalkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.5 -C.sub.7 cycloalkyl, C.sub.5 -C.sub.7 cycloalkenyl, phenyl, C.sub.7 -C.sub.9 phenylalkyl or a radical --CH.sub.2 --SO--R.sub.5, in which R.sub.5 is C.sub.8 -C.sub.20 alkyl which may be interrupted by --O--, --S-- or --SO-- groups, mono- or dihydroxy-substituted C.sub.2 -C.sub.12 alkyl, phenyl, benzyl, --(CH.sub.2).sub.n COOR.sub.6 or --CH(CH.sub.3)COOR.sub.6, in which R.sub.6 is C.sub.1 -C.sub.20 alkyl and n is 1 or 2, R.sub.3 is hydrogen or a group --CH.sub.2 --SO--R.sub.5, in which R.sub.5 is as defined above, and R.sub.4 has the same meanings as R.sub.2 , with the proviso that only one of the radicals R.sub.2, R.sub.3 or R.sub.4 is the group --CH.sub.2 --SO--R.sub.5 and that, if R.sub.4 is --CH.sub.2 --SO--R.sub.5 and R.sub.1 and R.sub.2 are simultaneously tert-butyl or tert-amyl, R.sub.5 is not C.sub.8 -C.sub.14 alkyl, or mixtures of these compounds with the corresponding non-oxidised compounds are suitable for stabilising organic materials which are sensitive to oxidative, thermal and/or light-induced degradation.
摘要翻译：其中R 1是氢，C 1 -C 20烷基，C 2 -C 18烯基，C 5 -C 7环烷基，C 5 -C 7环烯基，苯基或C 7 -C 9苯基烷基，R 2是氢，C 1 -C 20烷基，C 2（C 1 -C 20）烷基硫代甲基苯酚 -C 18烯基，C 5 -C 7环烷基，C 5 -C 7环烯基，苯基，C 7 -C 9苯基烷基或基团-CH 2 -SO 3 -R 5，其中R 5为可被-O - ， - S-或-SO-基团间隔的C 8 -C 20烷基，单或二羟基取代的C 2 -C 12烷基，苯基，苄基， - （CH 2）n COOR 6或-CH（CH 3）COOR 6，其中R 6是C 1 -C 20烷基，n是1或2，R 3是氢或基团-CH 2 -SO-R 5，其中R 5如上定义，并且R 4具有与R 2相同的含义，条件是基团R 2，R 3或R 4中只有一个是基团-CH 2 -SO-R 5，并且如果R 4 是-CH2-SO-R5，R1和R2同时是叔丁基或叔戊基，R5不是C8-C14烷基，或这些化合物与相应的非氧化化合物的混合物适用于稳定对氧化，热和 /或光诱导的降解。

6. 发明授权

US4863982A Isocyanuric acid derivatives 失效
标题翻译：异氰脲酸衍生物
公开(公告)号：US4863982A
公开(公告)日：1989-09-05
申请号：US217100
申请日：1988-07-06
申请人： Werner Stegmann , Eduard Troxler , Peter Hofmann , Hans-Rudolf Meier , Paul Dubs
发明人： Werner Stegmann , Eduard Troxler , Peter Hofmann , Hans-Rudolf Meier , Paul Dubs
IPC分类号： C07D251/72 , C07D251/14 , C07D251/34 , C08K5/34 , C08K5/3477
CPC分类号： C07D251/34 , C08K5/3477
摘要： Compounds of the formula I ##STR1## R.sup.4 is C.sub.5 -C.sub.7 -cycloalkyl which can be substituted by C.sub.1 -C.sub.4 -alkyl, and R.sup.5 to R.sup.9 are independently of one another C.sub.1 -C.sub.18 alkyl, unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.5 -C.sub.7 -cycloalkyl, phenyl, benzyl or allyl, are suitable for stabilizing organic material against thermal, oxidative and/or actinic degradation.
摘要翻译： R 1是C 1 -C 4 - 烷基取代的C 5 -C 7 - 环烷基，R 5至R 9彼此独立地为C 1 -C 18 烷基，未取代的或C 1 -C 4 - 烷基取代的C 5 -C 7 - 环烷基，苯基，苄基或烯丙基适于稳定有机材料以防止热，氧化和/或光化降解。

7. 发明授权

US4699939A Ortho cyclohexyl, para hydroxy aralkanoic acid esters and amide antioxidants 失效
标题翻译：邻苯环，对羟基芳烷酸酯和酰胺类抗氧化剂
公开(公告)号：US4699939A
公开(公告)日：1987-10-13
申请号：US916575
申请日：1986-10-08
申请人： Ivan Orban , Hans-Rudolf Meier , Paul Dubs , Samuel Evans , Peter Hofmann
发明人： Ivan Orban , Hans-Rudolf Meier , Paul Dubs , Samuel Evans , Peter Hofmann
IPC分类号： C07B63/04 , C07B31/00 , C07C67/00 , C07C69/732 , C07C69/734 , C07C69/90 , C07C233/18 , C07C235/34 , C07C235/46 , C07C235/48 , C07C235/50 , C07C313/00 , C07C323/12 , C07C323/14 , C07C323/41 , C07C323/42 , C08K5/06 , C08K5/103 , C08K5/13 , C08K5/16 , C08K5/20 , C08K5/37 , C08L101/00 , C09K15/08 , C09K15/14 , C09K15/24 , C09K15/28 , C09K15/30 , C07C69/94 , C07C69/616
CPC分类号： C09K15/24 , C08K5/103 , C08K5/20
摘要： Compounds of formula I ##STR1## wherein R.sub.1, R.sub.2 and A are essentially hydrocarbyl or substituted hydrocarbyl groups with at least one of R.sub.1 and R.sub.2 being cyclohexyl, n is 0, 1 or 2, m is an integer of 1 to 4 and X is oxygen or --N(R.sub.3)-- wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl.
摘要翻译：式I的化合物其中R 1，R 2和A基本上为具有至少一个R 1和R 2的烃基或取代的烃基，其中R 1和R 2为环己基，n为0,1或2，m为1至4的整数并且X是氧或-N（R3） - ，其中R3是氢，C1-C4烷基或苯基。

8. 发明授权

US09045430B2 Sterically hindered amines 有权
标题翻译：受阻胺
公开(公告)号：US09045430B2
公开(公告)日：2015-06-02
申请号：US13580991
申请日：2011-03-02
申请人： Hans-Rudolf Meier , Kai-Uwe Schoening , Shrirang Bhikaji Hindalekar
发明人： Hans-Rudolf Meier , Kai-Uwe Schoening , Shrirang Bhikaji Hindalekar
IPC分类号： C07D211/94 , C08K5/3435 , C08K5/378 , C08L21/02
CPC分类号： C08K5/3435 , C07D211/94 , C08K5/378 , C08L21/02
摘要： A compound of the formula (A) wherein the radicals R1 are independently of one another methyl, ethyl or n-propyl, and X is C2-C8alkylene or C2-C8alkylene interrupted by sulfur, is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.
摘要翻译：式（A）的化合物，其中基团R 1彼此独立地为甲基，乙基或正丙基，X为C 2 -C 8亚烷基或被中断的C 2 -C 8亚烷基，可用于稳定有机材料以防止由光，热或氧化。

9. 发明申请

US20060173107A1 Graftable hindered amine light stabilizers 有权
标题翻译：可接枝的受阻胺光稳定剂
公开(公告)号：US20060173107A1
公开(公告)日：2006-08-03
申请号：US10543428
申请日：2004-02-02
申请人： Hans-Rudolf Meier , Gerrit Knobloch
发明人： Hans-Rudolf Meier , Gerrit Knobloch
IPC分类号： C08K5/34 , C07D401/02
CPC分类号： C07D211/58 , C08F8/30 , C08F8/34 , C08K5/3435 , C08K5/378
摘要： The invention describes novel compound of the formula (I), wherein the general symbols are as defined in claim 1, as stabilizers for protecting organic materials, in particular synthetic polymers, against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：本发明描述了式（I）的新型化合物，其中通式为如权利要求1所定义，作为用于保护有机材料，特别是合成聚合物的稳定剂，用于氧化，热，动态，光诱导和/或臭氧 - 诱导退化。

10. 发明授权

US06797755B1 Stabilizers and antiozonants for elastomers 失效
标题翻译：用于弹性体的稳定剂和抗臭氧剂
公开(公告)号：US06797755B1
公开(公告)日：2004-09-28
申请号：US10110620
申请日：2002-04-15
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Samuel Evans
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Samuel Evans
IPC分类号： C08L541
CPC分类号： C07C323/25 , C07C317/28 , C07C317/44 , C07C323/52 , C07C2601/14 , C08K5/3725 , C08K5/41 , C08L21/00
摘要： Elastomers which have excellent stability to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation comprise, as stabilizers, at least one compound of the formula (I): [R—S(═O)m—CH2—CH(OH)—CH2]n—N(R1)2−n—R2, in which R is C4-C20alkyl, hydroxyl-substituted C4-C20alkyl; phenyl, benzyl, &agr;-methylbenzyl, &agr;,&agr;-dimethylbenzyl, cyclohexyl or —(CH2)qCOOR3, and, if m is 0, R may additionally be (a); and, if n is 1 and R4 is hydrogen, R may additionally be R2—R1N—CH2—CH(OH)—CH2—S(═O)m—(CH2)x— or R2—R1N—CH2—CH(OH)—CH2—S(═O)m—CH2—CH2—(OCH2—CH2)y—, R1 is hydrogen, cyclohexyl or C3-C12alkyl, R2 is (b), R3 is C1-C18alkyl, R4 is hydrogen or —CH2—CH(OH)—CH2—S(═O)m—R, X is C1-C8alkyl, Y is C1-C8alkyl, m is 0 or 1, n is 1 or 2, q is 1 or 2, x is from 2 to 6, and y is 1 or 2. The compounds of the formula (I) are also suitable as stabilizes for elastomers to prevent contact discoloration of substrates coming into contact with elastomers.
摘要翻译：具有优异稳定性以防止氧化，热，动态，光诱导和/或臭氧诱导的降解的弹性体包含作为稳定剂的至少一种式（I）化合物：[RS（= O）m -CH 2 -CH （OH）-CH 2] n N（R 1）2-n R 2，其中R是C 4 -C 20烷基，羟基取代的C 4 -C 20烷基; 苯基，苄基，α-甲基苄基，α，α-二甲基苄基，环己基或 - （CH 2）q COOR 3，如果m为0，则R可另外为（a）。并且如果n为1且R 4为氢，则R可以另外为R 2 -R 1 N-CH 2 -CH（OH）-CH 2 -S（= O）m - （CH 2）x - 或R 2 -R 1 N-CH 2 -CH（OH）-CH 2 -S（= O）m -CH 2 -CH 2 - （OCH 2 -CH 2）y - ，R 1是氢，环己基或C 3 C 12烷基，R 2是（b），R 3是C 1 -C 18烷基，R 4是氢或-CH 2 -CH（OH）-CH 2 -S（= O）m R，X是C 1 -C 8烷基，Y为C1-C8烷基，m为0或1，n为1或2，q为1或2，x为2至6，y为1或2.式（I）化合物也适用稳定弹性体以防止与弹性体接触的基底的接触变色。

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