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    • 1. 发明申请
    • CURABLE SILICONE COATING
    • 可固化硅胶涂层
    • US20070178321A1
    • 2007-08-02
    • US11669979
    • 2007-02-01
    • Hans E. Haas
    • Hans E. Haas
    • B32B27/00C08L83/04B01F3/04
    • C08L83/04C08G77/16C09D183/04Y10T428/31663
    • A curable silicone composition is provided that includes a silanol functional silicone fluid. A crosslinker reactive with the silanol functional silicone fluid is combined with the silanol fluid to yield a capped reactive silanol fluid. The composition is provided with a propellant in an aerosol container under pressure so as to expel the capped reactive silanol fluid along with a diluent such as a nonvolatile unreactive silicone, an organic plasticizer, a volatile organic solvent, or a combination thereof. A film produced from this composition provides a plastic or rubber substrate with a high gloss finish with desirable wear properties. The inclusion of the optional diluent and the optional propellant facilitates aerosol application of the curable silicone composition as a thin film coating. An additional attribute of a curable silicone composition as described herein is that a silicone coating cures from the capped reactive silanol fluid in ambient air at 20° Celsius in 60 minutes or less and is independent of cure catalysts that contain tin, titanate, zirconate or amine. A resultant coating is applied to the sidewall of a vehicle tire as an aesthetic and protectorant.
    • 提供了一种可固化的硅氧烷组合物,其包括硅烷醇官能的硅氧烷流体。 与硅烷醇官能的硅氧烷流体反应的交联剂与硅烷醇流体组合以产生封端的反应性硅烷醇流体。 组合物在压力下在气溶胶容器中设置有推进剂,以便与封闭的反应性硅烷醇流体一起排出稀释剂,例如非挥发性非反应性硅氧烷,有机增塑剂,挥发性有机溶剂或其组合。 由该组合物制成的薄膜提供具有所需磨损性能的具有高光泽度的塑料或橡胶基材。 包含任选的稀释剂和任选的推进剂有助于气溶胶涂覆可固化的硅氧烷组合物作为薄膜涂层。 如本文所述的可固化硅氧烷组合物的另外的特征是硅氧烷涂层在20分钟或更少的温度下在环境空气中在封闭的反应性硅烷醇流体中固化,并且不依赖于含有锡,钛酸盐,锆酸盐或胺的固化催化剂 。 将所得到的涂层作为美学和保护剂施加到车辆轮胎的侧壁上。
    • 2. 发明申请
    • Reduced Odor RTV Silicone
    • 降低气味RTV硅胶
    • US20080027164A1
    • 2008-01-31
    • US11782948
    • 2007-07-25
    • Hans E. Haas
    • Hans E. Haas
    • C08F283/12C08K3/04C08K3/10C08K3/34
    • C08K5/29C08K5/3412C08L83/04
    • A curable silicone composition is provided that includes a carboxylic acid scavenging reactant with an amount sufficient to reduce an odor associated with silicone curing. The carboxylic acid scavenging reactant illustratively includes a carbodiimide in the form of a monocarbodiimide or a polycarbodiimide; an aziridine; and a combination thereof. The composition optionally includes adjuvant provided to modify the physical or cure properties of the cured silicone. In particular, the composition is readily compatible with the inclusion of calcium carbonate, the use of which would otherwise cause gassing and/or curing upon storage. The composition optionally includes a condensation catalyst in the form of an organometallic compound with the metal ions of titanium, aluminum, tin, calcium, and zinc being particularly well suited for the function of catalyzing condensation reactions. A process for reducing acid emission from a RTV cured silicone is provided by adding a carbodiimide, an aziridine, or a combination thereof to a premanufactured RTV silicone composition containing acetoxy-terminated polysiloxane. The process is optionally provided with contacting a substrate to which the RTV silicone composition will be applied in intermediate layer of a carbodiimide, an aziridine, or a combination thereof.
    • 提供了一种可固化的有机硅组合物,其包括具有足以降低与硅酮固化相关的气味的量的羧酸清除反应物。 羧酸清除反应物示例性地包括单碳二亚胺或聚碳二亚胺形式的碳二亚胺; 氮丙啶 及其组合。 所述组合物任选地包括用于改变固化的硅氧烷的物理或固化性质的佐剂。 特别地,组合物容易与碳酸钙的包含相容,碳酸钙在储存时否则会导致气体和/或固化。 组合物任选地包括具有钛,铝,锡,钙和锌的金属离子的有机金属化合物形式的缩合催化剂,特别适合于催化缩合反应的功能。 通过将碳二亚胺,氮丙啶或其组合添加到含有乙酰氧基封端的聚硅氧烷的预制RTV有机硅组合物中来提供用于降低RTV固化的硅氧烷的酸排放的方法。 任选地,该方法提供将RTV有机硅组合物施用于碳二亚胺,氮丙啶或其组合的中间层中的基底的接触。
    • 9. 发明授权
    • Gelled composition applicator
    • 凝胶组合物涂布器
    • US07744298B2
    • 2010-06-29
    • US10966260
    • 2004-10-15
    • Hans E. HaasMarcia SnyderThomas M. PolatasRobert J. Harmacek
    • Hans E. HaasMarcia SnyderThomas M. PolatasRobert J. Harmacek
    • A46B11/00A46B17/02
    • B05C17/00503B43M11/08
    • An adhesive composition applicator includes a housing having sidewalls and a neck that tapers to an opening. The housing encloses a gelled adhesive composition. The housing has a cross-sectional area and the opening has a cross-sectional area less than that of the housing cross-sectional area. A cap is provided that engages the housing. A mechanism is provided for urging the gelled composition material from the housing through the opening. The neck optionally also includes a shield to prevent gelled adhesive composition from running down the neck and provides a barrier against gelled adhesive smear reaching the point of intersection between the cap and the housing. To facilitate application of gelled composition to a point of application, a spatula is provided adjacent to the opening.
    • 粘合剂组合物施用器包括具有侧壁和颈部的壳体,该颈部朝向开口逐渐变细。 外壳包封凝胶粘合剂组合物。 壳体具有横截面积,并且开口的横截面面积小于壳体横截面积的横截面面积。 提供与壳体接合的盖。 提供了一种机构,用于通过开口将凝胶化的组合物材料从壳体推动。 颈部任选地还包括屏蔽件,以防止凝胶化的粘合剂组合物沿着颈部向下运动,并提供阻挡胶粘剂涂抹物的屏障,到达帽和壳体之间的交点。 为了便于将凝胶化的组合物施用于施用点,在开口附近提供刮刀。