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1. 发明授权

US5461123A Gas phase fluidized bed polyolefin polymerization process using sound waves 失效
标题翻译：气相流化床聚烯烃聚合工艺使用声波
公开(公告)号：US5461123A
公开(公告)日：1995-10-24
申请号：US274840
申请日：1994-07-14
申请人： Gyung-Ho Song , Kiu H. Lee , Roger B. Painter
发明人： Gyung-Ho Song , Kiu H. Lee , Roger B. Painter
IPC分类号： C08F10/00 , B01J8/24 , B01J8/40 , C08F2/00 , C08F2/34 , C08F210/18
CPC分类号： B01J8/1809 , B01J8/40 , C08F210/18 , B01J2219/00247 , B01J2219/00254 , Y10S526/901
摘要： An improved method for polymerizing one or more polyolefins in the presence of a transition metal catalyst in at least one gas phase fluidized bed reactor, the improvement comprises generating at least one low frequency, high pressure sound wave inside a reactor system, which wave has sufficient frequency and pressure to dislodge and/or prevent particle build-up on interior surfaces of the reactor system.
摘要翻译：在过渡金属催化剂存在下在至少一个气相流化床反应器中聚合一种或多种聚烯烃的改进方法，其改进包括在反应器系统内产生至少一个低频，高压声波，该波具有足够的频率和压力以移除和/或防止在反应器系统的内表面上积聚。

2. 发明授权

US5416175A Method for reducing sheeting during polymerization of .alpha.-olefins 失效
标题翻译：在α-烯烃聚合过程中降低片材的方法
公开(公告)号：US5416175A
公开(公告)日：1995-05-16
申请号：US170003
申请日：1993-12-17
申请人： Gyung-Ho Song , Fathi D. Hussein , Kiu H. Lee , Henry B. Hinckley
发明人： Gyung-Ho Song , Fathi D. Hussein , Kiu H. Lee , Henry B. Hinckley
IPC分类号： C08F2/34 , C08F10/00
CPC分类号： C08F10/00
摘要： A method for reducing sheeting during polymerization of alpha-olefins in a fluidized bed employing catalysts prone to cause sheeting which comprises feeding a material carrying a static electric charge opposite to the static charge in said bed, said opposite charge of said material being generated by passing said material in contact with a surface adapted to impart said static electric charge to said material opposite the charge existing in said bed.
摘要翻译：一种用于在流化床中在α-烯烃聚合过程中减少片材的方法，该方法使用容易引起片材的催化剂，其包括将携带静电荷的物质与静电荷相反的方式进料，所述材料的相反电荷通过通过所述材料与适于将所述静电荷赋予与所述床中存在的电荷相对的所述材料的表面接触。

3. 发明授权

US5376743A Process for the production of sticky polymers 失效
标题翻译：生产粘性聚合物的方法
公开(公告)号：US5376743A
公开(公告)日：1994-12-27
申请号：US29821
申请日：1993-03-11
申请人： Edgar C. Baker , Jose F. Cevallos-Candau , Fathi D. Hussein , Kiu H. Lee , Allen Noshay
发明人： Edgar C. Baker , Jose F. Cevallos-Candau , Fathi D. Hussein , Kiu H. Lee , Allen Noshay
IPC分类号： C08F4/64 , C08F2/34 , C08F4/60 , C08F4/659 , C08F210/16 , C08F210/18 , C08F210/06
CPC分类号： C08F210/16 , C08F210/18 , Y10S526/901 , Y10S526/904
摘要： A process for the production of EPM or EPDM comprising contacting ethylene, propylene, and, optionally, one or more dienes, in a fluidized bed, at a temperature at or above the sticking temperature of the product resin, under polymerization conditions, with(i) a prepolymer containing a transition metal catalyst precursor with the proviso that the prepolymer is not sticky at the process temperature;(ii) a hydrocarbyl aluminum and/or a hydrocarbyl aluminum halide cocatalyst,; and, optionally,(iii) a halocarbon promoter; and, optionally,(iv) an inert particulate material having a mean particle size in the range of about 0.01 to about 150 microns wherein the particulate material is either contained in the prepolymer or is independent of the prepolymer,wherein the amount of prepolymer or the combined amount of prepolymer and inert particulate material is sufficient to essentially prevent agglomeration of the fluidized bed and the product resin.
摘要翻译：一种生产EPM或EPDM的方法，包括在聚合条件下，在聚合条件下，在等温或高于产物树脂的粘着温度的温度下，在流化床中使乙烯，丙烯和任选的一种或多种二烯与（i ）含有过渡金属催化剂前体的预聚物，条件是预聚物在工艺温度下不粘; （ii）烃基铝和/或烃基卤化铝助催化剂; 和（iii）卤代烃促进剂; 和（iv）平均粒度在约0.01至约150微米范围内的惰性颗粒材料，其中颗粒材料包含在预聚物中或独立于预聚物，其中预聚物或预聚物和惰性颗粒材料的组合量足以基本上防止流化床和产物树脂的团聚。

4. 发明授权

US5627242A Process for controlling gas phase fluidized bed polymerization reactor 失效
标题翻译：控制气相流化床聚合反应器的方法
公开(公告)号：US5627242A
公开(公告)日：1997-05-06
申请号：US623016
申请日：1996-03-28
申请人： Lance L. Jacobsen , Kiu H. Lee , John R. Parrish
发明人： Lance L. Jacobsen , Kiu H. Lee , John R. Parrish
IPC分类号： B01J8/24 , C08F2/34 , C08F10/00
CPC分类号： B01J8/1809 , C08F10/00 , B01J2208/00017 , B01J2208/00539 , B01J2208/0061 , C08F2400/02 , Y10S526/901
摘要： Control of a gas phase polymerization reactor is performed with the product melt index, the reaction temperature, and the partial pressure of the controlling reactant.
摘要翻译：用产物熔体指数，反应温度和控制反应物的分压进行气相聚合反应器的控制。

5. 发明授权

US5106926A Preparation of ethylene/1-octene copolymers of very low density in a fluidized bed reactor 失效
标题翻译：在流化床反应器中制备非常低密度的乙烯/ 1-辛烯共聚物
公开(公告)号：US5106926A
公开(公告)日：1992-04-21
申请号：US625769
申请日：1990-12-11
申请人： Ronald S. Eisinger , Kiu H. Lee
发明人： Ronald S. Eisinger , Kiu H. Lee
IPC分类号： C08F2/34 , C08F210/16
CPC分类号： C08F210/16 , Y10S526/901
摘要： A process for preparing ethylene/1-octene copolymers using a titanium based catalyst system under defined polymerization conditions.
摘要翻译：在规定的聚合条件下使用钛基催化剂体系制备乙烯/ 1-辛烯共聚物的方法。

6. 发明授权

US5548040A Process for passivation of a reactor after shutdown of alpha olefin polymerization processes 失效
标题翻译：在关闭α-烯烃聚合方法后钝化反应器的方法
公开(公告)号：US5548040A
公开(公告)日：1996-08-20
申请号：US359513
申请日：1994-12-20
申请人： Kevin J. Cann , Fathi D. Hussein , Daniel P. Zilker, Jr. , Kiu H. Lee
发明人： Kevin J. Cann , Fathi D. Hussein , Daniel P. Zilker, Jr. , Kiu H. Lee
IPC分类号： C08F2/00 , C08F2/34 , C08F4/60 , C08F4/68 , C08F10/00 , C08F210/16
CPC分类号： C08F210/16
摘要： A method for passivating internal surfaces of a reactor system during start-up and shutdown of an alpha olefin polymerization or copolymerization reaction by adding a passivation agent such as a dialkyl zinc compound, an alcohol, or an epoxide, to the reactor prior to exposing the internal reactor surfaces to air or moisture before reaction initiation and/or after reaction ceases.
摘要翻译：一种在将α-烯烃聚合或共聚反应的启动和停止期间钝化反应器系统的内表面的方法，在暴露所述反应器之前，向所述反应器中加入钝化剂，例如二烷基锌化合物，醇或环氧化物在反应开始和/或反应停止之后内部反应器表面与空气或水分。

7. 发明授权

US5510433A Process for the production of sticky polymers 失效
标题翻译：生产粘性聚合物的方法
公开(公告)号：US5510433A
公开(公告)日：1996-04-23
申请号：US311138
申请日：1994-09-23
申请人： Edgar C. Baker , Jose F. Cevallos-Candau , Fathi D. Hussein , Kiu H. Lee , Allen Noshay
发明人： Edgar C. Baker , Jose F. Cevallos-Candau , Fathi D. Hussein , Kiu H. Lee , Allen Noshay
IPC分类号： C08F4/64 , C08F2/34 , C08F4/60 , C08F4/659 , C08F210/16 , C08F210/18
CPC分类号： C08F210/16 , C08F210/18 , Y10S526/901 , Y10S526/904
摘要： A process for the production of EPM or EPDM comprising contacting ethylene, propylene, and, optionally, one or more dienes, in a fluidized bed, at a temperature at or above the sticking temperature of the product resin, under polymerization conditions, with(i) a prepolymer containing a transition metal catalyst precursor with the proviso that the prepolymer is not sticky at the process temperature;(ii) a hydrocarbyl aluminum and/or a hydrocarbyl aluminum halide cocatalyst,; and, optionally,(iii) a halocarbon promoter; and, optionally,(iv) an inert particulate material having a mean particle size in the range of about 0.01 to about 150 microns wherein the particulate material is either contained in the prepolymer or is independent of the prepolymer,wherein the amount of prepolymer or the combined amount of prepolymer and inert particulate material is sufficient to essentially prevent agglomeration of the fluidized bed and the product resin.
摘要翻译：一种生产EPM或EPDM的方法，包括在聚合条件下，在聚合条件下，在等温或高于产物树脂的粘着温度的温度下，在流化床中使乙烯，丙烯和任选的一种或多种二烯与（i ）含有过渡金属催化剂前体的预聚物，条件是预聚物在工艺温度下不粘; （ii）烃基铝和/或烃基卤化铝助催化剂; 和（iii）卤代烃促进剂; 和（iv）平均粒度在约0.01至约150微米范围内的惰性颗粒材料，其中颗粒材料包含在预聚物中或独立于预聚物，其中预聚物或预聚物和惰性颗粒材料的组合量足以基本上防止流化床和产物树脂的团聚。

8. 发明授权

US5126398A Process for the in situ blending of polymers 失效
标题翻译：聚合物原位共混方法
公开(公告)号：US5126398A
公开(公告)日：1992-06-30
申请号：US724804
申请日：1991-07-02
申请人： Kiu H. Lee , Frederick J. Karol , Sari B. Samuels
发明人： Kiu H. Lee , Frederick J. Karol , Sari B. Samuels
IPC分类号： C08F210/16 , C08F297/08
CPC分类号： C08F297/08 , C08F210/16
摘要： A process for the in situ blending of polymers comprising continuously contacting, under polymerization conditions, a mixture of ethylene and at least one alpha-olefin having at least 3 carbon atoms with a catalyst in at least two fluidized bed reactors connected in series, said catalyst comprising:(i) a complex consisting essentially of magnesium titanium, a halogen, and an electron donor;(ii) at least one activator compound; and(iii) a hydrocarbyl aluminum cocatalyst, the polymerization conditions being such that ethylene copolymer having a high melt index in the range of about 0.1 to about 1000 grams per 10 minutes is formed in at least one reactor and ethylene copolymer having a low melt index in the range of about 0.001 to about 1.0 gram per 10 minutes is formed in at least one other reactor, each copolymer having a density of about 0.860 to about 0.965 gram per cubic centimeter and a melt flow ratio in the range of about 22 to about 70, and being admixed with active catalyst.
摘要翻译：一种用于原位共混聚合物的方法，包括在聚合条件下将至少一种具有至少3个碳原子的至少一种α-烯烃的混合物与至少两个串联连接的流化床反应器中的催化剂连续接触，所述催化剂包括：（i）基本上由镁钛，卤素和电子给体组成的络合物; （ii）至少一种活化剂化合物; 和（iii）烃基铝助催化剂，聚合条件使得在至少一个反应器中形成熔体指数在约0.1至约1000克/ 10分钟范围内的乙烯共聚物，其熔体指数低在至少一个其它反应器中形成约0.001至约1.0克/ 10分钟的范围，每个共聚物的密度为约0.860至约0.965克/立方厘米，熔体流动比在约22至约 70，并与活性催化剂混合。

9. 发明授权

US4892853A Ethylene polymerization catalyst 失效
标题翻译：乙烯聚合催化剂
公开(公告)号：US4892853A
公开(公告)日：1990-01-09
申请号：US251360
申请日：1988-09-30
申请人： Kevin J. Cann , Frederick J. Karol , Kiu H. Lee , Arthur E. Marcinkowsky
发明人： Kevin J. Cann , Frederick J. Karol , Kiu H. Lee , Arthur E. Marcinkowsky
IPC分类号： C08F4/60 , C08F4/68 , C08F10/02
CPC分类号： C08F10/02
摘要： A vanadium catalyst composition comprising:(i) the reaction product of a vanadium compound and an electron donor, which is a liquid, organic Lewis base in which the vanadium compound is soluble;(ii) a hydrocarbyl aluminum cocatalyst; and(iii) a promoter having the following formula:C.sub.3 (X).sub.a (F).sub.b (H).sub.cwherein X is chlorine, bromine, or iodine, and each X can be alike or differenta=an integer from 6 to 8b=an integer from 0 to 2c=an integer from 0 to 2a+b+c=8

10. 发明授权

US5149738A Process for the in situ blending of polymers 失效
标题翻译：聚合物原位共混方法
公开(公告)号：US5149738A
公开(公告)日：1992-09-22
申请号：US724805
申请日：1991-07-02
申请人： Kiu H. Lee , Frederick J. Karol , Sari B. Samuels
发明人： Kiu H. Lee , Frederick J. Karol , Sari B. Samuels
IPC分类号： C08F210/16 , C08F297/08
CPC分类号： C08F297/08 , C08F210/16
摘要： A process for the in situ blending of polymers comprising continuously contacting, under polymerization conditions, a mixture of ethylene and at least one alpha-olefin having at least 3 carbon atoms with a catalyst in at least two fluidized bed reactors connected in series, said catalyst comprising:(i) a complex consisting essentially of magnesium titanium, a halogen, and an electron donor;(ii) at least one activator compound for the complex having the formula AlR".sub.e X'.sub.f H.sub.g wherein X' is Cl or OR'"; R" and R'" are saturated aliphatic hydrocarbon radicals having 1 to 14 carbon atoms and are alike or different; f is 0 to 1.5; g is 0 or 1; and e+f+g=3; and(iii) a hydrocarbyl aluminum cocatalyst, the polmerization conditions being such that ethylene copolymer having a high melt index in the range of about 0.1 to about 1000 grams per 10 minutes is formed in at least one reactor and ethylene copolymer having a low melt index in the range of about 0.001 to about 1.0 gram per 10 minutes is formed in at least one other reactor, each copolymer having a density of about 0.860 to about 0.965 gram per cubic centimeter and a melt flow ratio in the range of about 22 to about 70, and being admixed with active catalyst.
摘要翻译：一种用于原位共混聚合物的方法，包括在聚合条件下将至少一种具有至少3个碳原子的至少一种α-烯烃的混合物与至少两个串联连接的流化床反应器中的催化剂连续接触，所述催化剂包括：（i）基本上由镁钛，卤素和电子给体组成的络合物; （ii）具有式AlR''EX'fHg的络合物的至少一种活化剂化合物，其中X'为Cl或OR“'; R“和R”'是具有1至14个碳原子的饱和脂族烃基，并且是相同或不同的; f为0〜1.5; g为0或1; 和e + f + g = 3; 和（iii）烃基铝助催化剂，所述聚合条件使得在至少一个反应器和具有低熔体指数的乙烯共聚物中形成具有约0.1-约1000克/ 10分钟范围内的高熔体指数的乙烯共聚物在至少一个其它反应器中形成约0.001至约1.0克/ 10分钟的范围，每个共聚物的密度为约0.860至约0.965克/立方厘米，熔体流动比在约22至约 70，并与活性催化剂混合。

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