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1. 发明申请

US20110034628A1 BRANCHED POLYOLS CONTAINING ON AVERAGE TWO OR MORE HYDROXYL GROUPS PER MOLECULE,THEIR PREPARATION AND USE 审中-公开
标题翻译：包含平均每分子两个或多个羟基的分支的多元醇，其制备和使用
公开(公告)号：US20110034628A1
公开(公告)日：2011-02-10
申请号：US12300535
申请日：2007-05-09
申请人： Gunther Ott , Bjorn Feldmann , Sabine Holtschulte , Andreas Janssen , Christin Sobbe , Karl-Heinz Joost
发明人： Gunther Ott , Bjorn Feldmann , Sabine Holtschulte , Andreas Janssen , Christin Sobbe , Karl-Heinz Joost
IPC分类号： C08G18/72 , C08L75/04
CPC分类号： C08G18/792 , C08G18/0823 , C08G18/2825 , C08G18/3212 , C08G18/4063 , C08G18/4283 , C09D175/04
摘要： Disclosed are branched polyols (A) having two or more hydroxyl groups per molecule prepared by providing a polyisocyanate (A1) containing per molecule two or more isocyanate groups and either two or more hard segments (a11) which as part of a thermoset three-dimensional network raise its glass transition temperature, or two or more soft segments which as part of a thermoset three-dimensional network lower its glass transition temperature; and reacting the polyisocyanate (A1) with a polyol (A2) in a molar ratio (A2):(A1) of ≧2 and an equivalent ratio of [X+OH]:NCO≧2; wherein polyol (A2) has the general formula I: X [—R(—OH)n]m, and the variables have the following definitions: n is a number from 1 to 5, m is 1 or 2, X is an isocyanate-reactive functional group, and R is a divalent to pentavalent organic radical, with the proviso that R comprises at least one hard segment (a11) if (A1) comprises soft segments.
摘要翻译：公开了每分子具有两个或多个羟基的支化多元醇（A），其通过提供每分子含有两个或更多个异氰酸酯基团和两个或更多个硬链段（a11）制备的多异氰酸酯（A1），所述硬链段作为热固性三维网络提高其玻璃化转变温度，或两个或更多软段，作为热固性三维网络的一部分降低其玻璃化转变温度; 并使多异氰酸酯（A1）与摩尔比（A2）：（A1）= 2的多元醇（A2）和当量的[X + OH]:NCO≥2的比例反应; 其中多元醇（A2）具有通式I：X [-R（-OH）n] m，并且变量具有以下定义：n为1至5的数，m为1或2，X为异氰酸酯 - 反应性官能团，R是二价至五价有机基团，条件是如果（A1）包含软链段，R包含至少一个硬链段（a11）。

2. 发明申请

US20100273975A1 POLYOLS BASED ON MODIFIED AMINO RESINS, THEIR PREPARATION AND 失效
标题翻译：基于改性氨基树脂的多元醇及其制备方法
公开(公告)号：US20100273975A1
公开(公告)日：2010-10-28
申请号：US12160348
申请日：2007-02-09
申请人： Gunther Ott , Ulrike Rockrath , Bjorn Feldmann , Ulrike Clausen-Meiring , Karl-Heinz Joost
发明人： Gunther Ott , Ulrike Rockrath , Bjorn Feldmann , Ulrike Clausen-Meiring , Karl-Heinz Joost
IPC分类号： C08G12/40
CPC分类号： C08G12/44 , C08G6/02 , C09D161/32
摘要： Disclosed herein is a polyol (A) based on modified amino resins, prepared by reacting: an amino resin (B) comprising three acetalized or etherified N-methylol groups of the general formula (I)>N—CHR—OR1, wherein R is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or an aryl group of 6 to 10 carbon atoms and R1 is an alkyl group of 1 to 6 carbon atoms; with a polyol (C) of the general formula (II) R2(—OH)n, wherein n is a number from 2 to 6 and R2 is a divalent to hexavalent organic radical; wherein an equivalent ratio of the acetalized or etherified N-methylol groups to the polyol (C) is 0.5:1 to 1.2:1; with elimination of at least 50 mol % of a monoalcohol (D) of the general formula R1—OH, wherein R1 is as defined above, from the amino resin (B).
摘要翻译：本文公开了一种基于改性氨基树脂的多元醇（A），其通过使包含通式（I）的三个缩醛化或醚化的N-羟甲基的氨基树脂（B）与N-CHR-OR1反应制备，其中R为氢原子，1〜6个碳原子的烷基或6〜10个碳原子的芳基，R 1为1〜6个碳原子的烷基; 与通式（II）的多元醇（C）R 2（-OH）n，其中n是2至6的数，R 2是二价至六价的有机基团; 其中缩醛化或醚化的N-羟甲基与多元醇（C）的当量比为0.5:1至1.2:1; 从氨基树脂（B）中除去至少50mol％的通式R 1 -OH的一元醇（D），其中R 1如上定义。

3. 发明授权

US08153752B2 Polyols based on modified amino resins, process for their preparation and their use 失效
标题翻译：基于改性氨基树脂的多元醇，其制备方法及其用途
公开(公告)号：US08153752B2
公开(公告)日：2012-04-10
申请号：US12160348
申请日：2007-02-09
申请人： Gunther Ott , Ulrike Rockrath , Bjorn Feldmann , Ulrike Clausen-Meiring , Karl-Heinz Joost
发明人： Gunther Ott , Ulrike Rockrath , Bjorn Feldmann , Ulrike Clausen-Meiring , Karl-Heinz Joost
IPC分类号： C08G12/30 , C08G12/32 , C08G12/00
CPC分类号： C08G12/44 , C08G6/02 , C09D161/32
摘要： Disclosed herein is a polyol (A) based on modified amino resins, prepared by reacting: an amino resin (B) comprising three acetalized or etherified N-methylol groups of the general formula (I) >N—CHR—OR1, wherein R is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or an aryl group of 6 to 10 carbon atoms and R1 is an alkyl group of 1 to 6 carbon atoms; with a polyol (C) of the general formula (II) R2(—OH)n, wherein n is a number from 2 to 6 and R2 is a divalent to hexavalent organic radical; wherein an equivalent ratio of the acetalized or etherified N-methylol groups to the polyol (C) is 0.5:1 to 1.2:1; with elimination of at least 50 mol % of a monoalcohol (D) of the general formula R1—OH, wherein R1 is as defined above, from the amino resin (B).
摘要翻译：本文公开了一种基于改性氨基树脂的多元醇（A），其通过使包含通式（I）的三个缩醛化或醚化的N-羟甲基的氨基树脂（B）与N-CHR-OR1反应制备，其中R为氢原子，1〜6个碳原子的烷基或6〜10个碳原子的芳基，R 1为1〜6个碳原子的烷基; 与通式（II）的多元醇（C）R 2（-OH）n，其中n是2至6的数，R 2是二价至六价的有机基团; 其中缩醛化或醚化的N-羟甲基与多元醇（C）的当量比为0.5:1至1.2:1; 从氨基树脂（B）中除去至少50mol％的通式R 1 -OH的一元醇（D），其中R 1如上定义。

4. 发明申请

US20110152440A1 PAINT COMPOSITIONS, A METHOD OF FINISH-PAINTING AND PAINTED OBJECTS 有权
标题翻译：涂料组合物，涂漆和涂漆物品的方法
公开(公告)号：US20110152440A1
公开(公告)日：2011-06-23
申请号：US12674534
申请日：2008-08-22
申请人： Hitoshi Taniguchi , Hiroyuki Takagi , Eishi Tsukamoto , Andreas Poppe , Björn Feldmann , Julia Melzer , Sabine Holtschulte , Karl-Heinz Joost
发明人： Hitoshi Taniguchi , Hiroyuki Takagi , Eishi Tsukamoto , Andreas Poppe , Björn Feldmann , Julia Melzer , Sabine Holtschulte , Karl-Heinz Joost
IPC分类号： C09D133/08
CPC分类号： C09D133/066 , C08K5/29 , C08L33/066 , C08L101/02 , C08L2666/04
摘要： [Problem] To provide a paint composition which forms paint films which are excellent in terms of car-wash scratching resistance, acid resistance and weather resistance, a method of finish painting and painted objects.[Means of Resolution] A paint composition which has as essential components hydroxyl group containing resin (A) which has a hydroxyl group value of from 80 to 220 mgKOH/g, a glass transition temperature of −50° C. or above but below 0° C. and which contains from 25 to 55 mass % of units of 4-hydroxybutyl (meth)acrylate origin, hydroxyl group containing resin (B) which has a hydroxyl group value of from 80 to 220 mgKOH/g and a glass transition temperature of from 0 to 50° C. and crosslinking agent (C) comprising polyisocyanate compound, characterized in that the proportions of hydroxyl group containing resin (A) and hydroxyl group containing resin (B) included are, as a ratio of the solid fraction masses, from 95/5 to 50/50, and the proportion of isocyanate groups which are the functional groups of the crosslinking agent (C) included with respect to the hydroxyl groups in total of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B), as the NCO/OH mol ratio, is from 0.5 to 1.5.
摘要翻译： [问题]提供一种油漆组合物，其形成在洗车耐刮擦性，耐酸性和耐候性方面优异的漆膜，涂漆和涂漆物品的方法。 [解决方法]将羟基含量为80〜220mgKOH / g，玻璃化转变温度为-50℃以上但低于0的含羟基树脂（A）作为必要成分的涂料组合物 ℃，含有25〜55质量％的（甲基）丙烯酸4-羟基丁酯单元，羟值为80〜220mgKOH / g的羟基树脂（B），玻璃化转变温度为0〜50℃，含有多异氰酸酯化合物的交联剂（C）的特征在于，含有羟基的树脂（A）和含有羟基的树脂（B）的比例为固体成分质量比，95/5〜50/50，作为交联剂（C）的官能团的异氰酸酯基的含量相对于含羟基的树脂（A）和羟基的羟基的比例含有树脂（B），作为NCO / OH摩尔比例为0.5〜1.5。

5. 发明授权

US09266995B2 Binding agent mixture, coating agents containing said binding agent mixture, and coatings produced from said coating agents, said coatings having a high scratch resistance, high weathering stability, and good optical properties 有权
标题翻译：结合剂混合物，包含所述粘合剂混合物的涂层剂和由所述涂覆剂制备的涂层，所述涂层具有高耐刮擦性，高风化稳定性和良好的光学性能
公开(公告)号：US09266995B2
公开(公告)日：2016-02-23
申请号：US13395576
申请日：2010-08-03
申请人： Günter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
发明人： Günter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
IPC分类号： C08L75/06 , C08G18/42 , C08G18/16 , C08G18/28 , C08G18/71 , C08G18/77 , C08G18/80 , C09D175/04 , C08G18/18
CPC分类号： C08G18/4288 , C08G18/168 , C08G18/18 , C08G18/1883 , C08G18/289 , C08G18/42 , C08G18/718 , C08G18/778 , C08G18/809 , C09D175/04 , Y10T428/31663
摘要： Binder mixture comprising a hydroxyl-containing compound (A), and at least 1.0% by weight, based on the nonvolatile constituents of the binder mixture, of a phosphorus- and nitrogen-containing catalyst (D) for the crosslinking of silane groups, wherein the hydroxyl-containing compound (A) comprises a hydroxyl-functional polyester having on average at least one hydroxyl function of the polyester esterified with a C8 to C9 monocarboxylic acid, and the catalyst (D) is blocked with at least one tertiary amine of the formula (I) where R1 is an acyclic aliphatic or araliphatic hydrocarbon radical having at least 3 C atoms, R2 is an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R3, and R3 is hydrogen or an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R2.
摘要翻译：包含含羟基化合物（A）的粘合剂混合物和至少1.0重量％，基于粘合剂混合物的不挥发成分，用于交联硅烷基团的含磷和氮的催化剂（D），其中含羟基化合物（A）包含平均具有C8-C9单羧酸酯化的聚酯的至少一个羟基官能团的羟基官能聚酯，催化剂（D）被至少一种叔胺式（I）其中R 1是具有至少3个C原子的无环脂族或芳脂族烃基，R 2是与R 1和/或R 3相同或不同的无环脂族或芳脂族烃基，R 3是氢或无环与R 1和/或R 2相同或不同的脂族或芳脂族烃基。

6. 发明申请

US20130052469A1 BINDING AGENT MIXTURE, COATING AGENTS CONTAINING SAID BINDING AGENT MIXTURE, AND COATINGS PRODUCED FROM SAID COATING AGENTS, SAID COATINGS HAVING A HIGH SCRATCH RESISTANCE, HIGH WEATHERING STABILITY, AND GOOD OPTICAL PROPERTIES 有权
标题翻译：粘合剂混合物，含有粘合剂混合物的涂料代理，以及由上述涂料代理生产的涂料，具有高耐刮擦性，高耐候性和良好光学性能的涂料
公开(公告)号：US20130052469A1
公开(公告)日：2013-02-28
申请号：US13395576
申请日：2010-08-03
申请人： Gunter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
发明人： Gunter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
IPC分类号： C08L67/08 , B05D1/36 , B32B9/00 , C09D183/08
CPC分类号： C08G18/4288 , C08G18/168 , C08G18/18 , C08G18/1883 , C08G18/289 , C08G18/42 , C08G18/718 , C08G18/778 , C08G18/809 , C09D175/04 , Y10T428/31663
摘要： Binder mixture comprising a hydroxyl-containing compound (A), and at least 1.0% by weight, based on the nonvolatile constituents of the binder mixture, of a phosphorus- and nitrogen-containing catalyst (D) for the crosslinking of silane groups, wherein the hydroxyl-containing compound (A) comprises a hydroxyl-functional polyester having on average at least one hydroxyl function of the polyester esterified with a C8 to C9 monocarboxylic acid, and the catalyst (D) is blocked with at least one tertiary amine of the formula (I) where R1 is an acyclic aliphatic or araliphatic hydrocarbon radical having at least 3 C atoms, R2 is an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R3, and R3 is hydrogen or an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R2.
摘要翻译：包含含羟基化合物（A）的粘合剂混合物和至少1.0重量％，基于粘合剂混合物的不挥发成分，用于交联硅烷基团的含磷和氮的催化剂（D），其中含羟基化合物（A）包含平均具有C8-C9单羧酸酯化的聚酯的至少一个羟基官能团的羟基官能聚酯，催化剂（D）被至少一种叔胺式（I）其中R 1是具有至少3个C原子的无环脂族或芳脂族烃基，R 2是与R 1和/或R 3相同或不同的无环脂族或芳脂族烃基，R 3是氢或无环与R 1和/或R 2相同或不同的脂族或芳脂族烃基。

7. 发明授权

US08236895B2 Paint compositions, a method of finish-painting and painted objects 有权
标题翻译：油漆成分，涂漆方法和涂漆物品
公开(公告)号：US08236895B2
公开(公告)日：2012-08-07
申请号：US12674534
申请日：2008-08-22
申请人： Hitoshi Taniguchi , Hiroyuki Takagi , Eishi Tsukamoto , Andreas Poppe , Björn Feldmann , Julia Melzer , Sabine Holtschulte , Karl-Heinz Joost
发明人： Hitoshi Taniguchi , Hiroyuki Takagi , Eishi Tsukamoto , Andreas Poppe , Björn Feldmann , Julia Melzer , Sabine Holtschulte , Karl-Heinz Joost
IPC分类号： C08L75/02
CPC分类号： C09D133/066 , C08K5/29 , C08L33/066 , C08L101/02 , C08L2666/04
摘要： Disclosed is a finish paint composition having a hydroxyl group containing resin (A) comprising a hydroxyl group value of 80 to 220 mgKOH/g, a glass transition temperature of −50° or above but below 0° C., and 25 to 55 mass% of units of 4-hydroxybutyl (meth)acrylate origin, a hydroxyl group containing resin (B) with a hydroxyl group value of 80 to 220 mgKOH/g, and a glass transition temperature of 0 to 50° C., and a crosslinking agent (C) comprising polyisocyanate compound having isocyanate groups, wherein the proportions of hydroxyl group containing resin (A) and hydroxyl group containing resin (B) are, as a ratio of solid fraction masses, from 95/5 to 50/50, and the proportion of isocyanate groups of the crosslinking agent (C) with respect to the hydroxyl groups in total of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B), as the NCO/OH mol ratio, is 0.5 to 1.5.
摘要翻译：公开了具有羟基值为80〜220mgKOH / g，玻璃化转变温度为-50℃以上且低于0℃的含羟基的树脂（A）和25〜55质量％的表面漆组合物（甲基）丙烯酸4-羟基丁酯单元的％，羟基值为80〜220mgKOH / g，玻璃化转变温度为0〜50℃的含羟基的树脂（B），交联包含具有异氰酸酯基的多异氰酸酯化合物的试剂（C），其中含羟基的树脂（A）和含羟基的树脂（B）的比例为固体成分质量比为95/5至50/50，和作为NCO / OH摩尔比，交联剂（C）的异氰酸酯基相对于含羟基树脂（A）和含羟基树脂（B）的总数相对于羟基的比例为0.5〜 1.5。

8. 发明授权

US07915321B2 Aqueous dispersion and the use thereof in the production of coating agents, adhesives and sealing agents that can be cured by heat or by actinic radiation 失效
标题翻译：水性分散体及其在生产可通过热或通过光化辐射固化的涂层剂，粘合剂和密封剂的用途
公开(公告)号：US07915321B2
公开(公告)日：2011-03-29
申请号：US10344057
申请日：2001-08-22
申请人： Hubert Baumgart , Uwe Meisenburg , Petra Toboll , Karl-Heinz Joost , Reinhold Schwalm
发明人： Hubert Baumgart , Uwe Meisenburg , Petra Toboll , Karl-Heinz Joost , Reinhold Schwalm
IPC分类号： C08G18/06 , B05D7/00
CPC分类号： C08G18/3212 , C08G18/0823 , C08G18/284 , C08G18/285 , C08G18/7837 , C08G18/8175 , C08G2170/80 , C09D175/14
摘要： Novel aqueous dispersion comprising at least one polymer containing on average (i) at least one primary and/or secondary carbamate group, (ii) at least one functional group having at least one bond which may be activated with actinic radiation, and (iii) at least one dispersive ionic functional group; process for preparing it and its use for preparing coating materials, adhesives and sealing compounds which are curable thermally and with actinic radiation, and also novel coating materials, adhesives and sealing compounds consisting of or comprising the novel aqueous dispersion.
摘要翻译：（i）至少一种伯和/或次级氨基甲酸酯基团的至少一种聚合物，（ii）至少一种具有至少一个能被光化辐射活化的键的官能团，和（iii）至少一个分散离子官能团; 制备方法及其用于制备可热固化和光化辐射固化的涂料，粘合剂和密封化合物的用途，以及由新型水性分散体组成或包含新颖的涂料，粘合剂和密封剂。

9. 发明授权

US06716891B1 Coating material that can be cured thermally or by actinic radiation, and its use 失效
标题翻译：可以热固化或通过光化辐射固化的涂层材料及其用途
公开(公告)号：US06716891B1
公开(公告)日：2004-04-06
申请号：US09926532
申请日：2001-11-16
申请人： Uwe Meisenburg , Heinz-Peter Rink , Karl-Heinz Joost , Hubert Baumgart
发明人： Uwe Meisenburg , Heinz-Peter Rink , Karl-Heinz Joost , Hubert Baumgart
IPC分类号： C08F246
CPC分类号： C09D175/16 , C09D4/06 , Y10T428/31511 , Y10T428/31533 , Y10T428/31551 , Y10T428/31794 , Y10T428/31855 , C08F290/067 , C08F290/061
摘要： The invention relates to a coating material that can be cured thermally or by actinic radiation and that contains at least one component (a1) with at least two functional groups (a11) which serve for cross-linking, by actinic radiation, and at least one functional group (a12) that can enter into thermal cross-linking reactions with the hydroxyl and/or thiol groups (a21) in component (a2), at least one branched cyclic and/or acyclic C9-C16 alkane (a2)) that is functionalized with at least two hydroxyl or thiol groups (a21) or with at least one hydroxyl and at least one thiol group, and optionally at least one photo initiator (a3), at least one initiator of the thermal cross-linking reaction (a4), at least one reactive diluent that is cured by actinic radiation and/or thermafly, at least one lacquer additive (a6), at least one thermally curable component (a7) and/or at least one organic solvent (a8). The inventive coating material is used to produce transparent lacquers and multi-layer chromophor and/or effect lacquers.
摘要翻译：本发明涉及一种可以热或通过光化辐射固化并且含有至少一种具有至少两个用于通过光化辐射交联的官能团（a11）的组分（a1）的涂料，以及至少一种可以与组分（a2）中的羟基和/或硫醇基团（a21），至少一种支链环状和/或非环状C 9 -C 16烷烃（a2）进行热交换反应的官能团（a12）用至少两个羟基或硫醇基团（a21）或至少一个羟基和至少一个硫醇基官能化，和任选地至少一个光引发剂（a3），至少一个热交联反应引发剂（a4），至少一种通过光化辐射和/或热解固化的反应性稀释剂，至少一种漆添加剂（a6），至少一种可热固化组分（a7）和/或至少一种有机溶剂（a8）。本发明的涂料用于生产透明漆和多层发色体和/或效果漆。

10. 发明授权

US07122289B2 Mixture which can be thermally hardened and hardened by actinic radiation and use thereof 有权
标题翻译：可通过光化辐射热硬化和硬化的混合物及其用途
公开(公告)号：US07122289B2
公开(公告)日：2006-10-17
申请号：US10468884
申请日：2002-03-14
申请人： Guido Wilke , Ulrike Röckrath , Karl-Heinz Joost , Egon Wegner , Hubert Baumgart , Uwe Meisenburg
发明人： Guido Wilke , Ulrike Röckrath , Karl-Heinz Joost , Egon Wegner , Hubert Baumgart , Uwe Meisenburg
IPC分类号： G03F7/004
CPC分类号： C08J3/243 , C08G18/6254 , C08G18/8175 , C08J2375/16 , C09D175/16 , C08G18/62 , C08L2666/14
摘要： A mixture and method for preparing a composition curable thermally and with actinic radiation comprising a binder free from carbon-carbon double bonds activatable with actinic radiation, at least one blocked or unblocked polyisocyanate having at least one soft, flexibilizing segment, and at least one unsaturated polyfunctional urethane that is free from isocyanate-reactive functional groups and contains on average per molecule more than four carbon-carbon double bonds activatable with actinic radiation and at least one hardening segment.
摘要翻译：一种用于制备可热固化和光化辐射固化的组合物的混合物和方法，其包含不含可活化光化辐射的碳 - 碳双键的粘合剂，至少一种封闭或未封端的多异氰酸酯，其具有至少一个柔软的柔性链段和至少一个不饱和的多官能氨基甲酸酯，其不含异氰酸酯反应性官能团，并且平均每分子含有多于四个可用光化辐射和至少一个硬化段活化的碳 - 碳双键。

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