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1. 发明授权

US4153501A Process and apparatus for removing vaporizable constituents from viscous solutions or melts of thermoplastics 失效
标题翻译：从热塑性塑料的粘稠溶液或熔体中除去可挥发成分的方法和设备
公开(公告)号：US4153501A
公开(公告)日：1979-05-08
申请号：US768636
申请日：1977-02-14
申请人： Peter Fink , Hans Wild , Johann Zizlsperger , Rudi W. Reffert , Gunter Thielen
发明人： Peter Fink , Hans Wild , Johann Zizlsperger , Rudi W. Reffert , Gunter Thielen
IPC分类号： B01D1/22 , B01D19/00 , B29B13/02 , C08F6/10 , F28F7/02
CPC分类号： C08F6/10 , B01D1/22 , B01D19/0021 , B29B13/02 , F28F7/02 , Y10S159/10
摘要： A process for removing vaporizable constituents from high-viscosity solutions or melts of thermoplastics by continuous evaporation along a heated devolatilization zone and separation of the vapor phase from the liquid phase in a downstream separating vessel. The plastic solution or melt is first heated stepwise in increments, in the devolatilization zone, while the product is in the form of thin layers from about 0.5 to 4 mm, so as to maintain a temperature difference of less than 50.degree. C. between the heat transfer medium and the plastic solution or melt until the devolatilization temperature is reached, the distribution of the solution or melt to form thin layers of product taking place while the temperature conditions still correspond to those of the feed of solution or melt, after which the vaporizable constituents are evaporated so as to form a two-phase system of vapor and melt, and the heat of evaporation absorbed is substantially returned to the product during the evaporation along the devolatilization zone. The process permits the removal of vaporizable constituents under mild conditions.
摘要翻译：通过沿着加热的脱挥发分区连续蒸发并在下游分离容器中将液相从液相中分离出来，从热塑性塑料的高粘度溶液或熔体中除去可挥发成分的方法。首先在脱挥发区中逐步逐渐加热塑料溶液或熔体，同时产物为0.5〜4mm的薄层形式，以保持温度差在50℃以下传热介质和塑料溶液或熔体，直到达到脱挥发分温度，溶液或熔体的分布形成薄层产品，同时温度条件仍然对应于溶液或熔体进料的温度条件，之后可蒸发的成分被蒸发以形成蒸气和熔体的两相体系，并且在沿着脱挥发分区的蒸发期间吸收的蒸发热量基本上返回到产物中。该方法允许在温和条件下除去可汽化组分。

2. 发明授权

US4150719A Process and apparatus for controlled and gentle heating or cooling of viscous solutions or melts of thermoplastics 失效
标题翻译：用于控制和温和加热或冷却热塑性塑料的粘稠溶液或熔体的方法和设备
公开(公告)号：US4150719A
公开(公告)日：1979-04-24
申请号：US746885
申请日：1976-12-02
申请人： Gunter Thielen , Johann Zizlsperger , Rudi W. Reffert , Hans Wild , Peter Fink
发明人： Gunter Thielen , Johann Zizlsperger , Rudi W. Reffert , Hans Wild , Peter Fink
IPC分类号： B29B13/02 , F28F7/02 , F28F3/08
CPC分类号： F28F7/02 , B29B13/02
摘要： A process and an apparatus for heating or cooling very viscous solutions or melts of thermoplastics in the form of thin layers. The plastic solution or melt is spread under the temperature conditions of the feed solution or melt, and the thin layers are heated stepwise so that the temperature difference between the heat transfer medium and the solution or melt is at all times less than 50.degree. C. and preferably less than 20.degree. C. Viscous solutions or melts of thermoplastics can be heated or cooled rapidly and uniformly under gentle and controlled conditions, to prepare the solutions or melts for further treatment in conventional equipment.
摘要翻译：用于加热或冷却薄层形式的热塑性塑料的非常粘稠的溶液或熔体的方法和装置。塑料溶液或熔体在进料溶液或熔体的温度条件下分散，薄层逐步加热，使传热介质与溶液或熔体之间的温差始终低于50℃。优选小于20℃。在温和和受控的条件下，热塑性塑料的粘性溶液或熔体可以快速均匀地加热或冷却，以制备用于常规设备中进一步处理的溶液或熔体。

3. 发明授权

US4503219A Treatment of (Co)polymers to remove residual monomers 失效
标题翻译：（Co）聚合物的处理以除去残留的单体
公开(公告)号：US4503219A
公开(公告)日：1985-03-05
申请号：US489558
申请日：1983-04-28
申请人： Rudi W. Reffert , Juergen Hambrecht , Rudolf H. Jung , Adolf Echte
发明人： Rudi W. Reffert , Juergen Hambrecht , Rudolf H. Jung , Adolf Echte
IPC分类号： C08F6/00 , C08G6/00 , C08J3/00
CPC分类号： C08F6/006
摘要： (Co)polymers which are composed of one or more monomers from the group comprising(a) the vinyl-aromatic monomers and(b) the ethylenically unsaturated monomersand furthermore contain one or more monomer components (a) or (b), or (a) and (b), as unreacted residual monomers are treated at above the glass temperature of the (co)polymer and in the presence of one or more assistants, which have been added to the (co)polymer. The assistant used is a bicyclic compound of the general formula I ##STR1## where X is a methylene, ethylene, 1,1-ethenyl, 1,2-ethenyl, carbonyl, azo, amino, ether or thioether group which is unsubstituted or substituted by halogen, alkyl, alkenyl, cycloalkyl, aryl, carboxyl, carboxyalkyl, an ether group or a thioether group, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each hydrogen, halogen, alkyl, alkenyl, cycloalkyl, aryl, carboxyalkyl or nitrile, R.sup.5 and R.sup.6 are each hydrogen, halogen, alkyl or carboxyalkyl, and R.sup.7 and R.sup.8 are each hydrogen, halogen, alkyl, alkenyl, aryl, carboxyalkyl, carboxyl or nitrile.
摘要翻译：（a）乙烯基芳族单体和（b）烯键式不饱和单体并且还含有一种或多种单体组分（a）或（b）或（a）的单体组分 a）和（b）中，作为未反应的残余单体在（共）聚合物的玻璃化温度以上和在已加入到（共））聚合物中的一种或多种助剂的存在下进行处理。使用的助剂是通式I的双环化合物，其中X是未取代或取代的亚甲基，亚乙基，1,1-乙烯基，1,2-乙烯基，羰基，偶氮，氨基，醚或硫醚基卤素，烷基，烯基，环烷基，芳基，羧基，羧基烷基，醚基或硫醚基，R1，R2，R3和R4各自为氢，卤素，烷基，烯基，环烷基，芳基，羧烷基或腈，R5和 R 6各自为氢，卤素，烷基或羧基烷基，R 7和R 8各自为氢，卤素，烷基，烯基，芳基，羧基烷基，羧基或腈。

4. 发明授权

US4654418A Continuous removal of the catalyst from polyphenylene ethers 失效
标题翻译：从聚苯醚连续除去催化剂
公开(公告)号：US4654418A
公开(公告)日：1987-03-31
申请号：US627984
申请日：1984-07-05
申请人： Rosemarie Berger , Hermann Dreher , Juergen Hambrecht , Eduard Heil , Rudi W. Reffert , Johann Swoboda , Adolf Echte , Peter Siebel
发明人： Rosemarie Berger , Hermann Dreher , Juergen Hambrecht , Eduard Heil , Rudi W. Reffert , Johann Swoboda , Adolf Echte , Peter Siebel
IPC分类号： C08G65/46 , C08G65/42
CPC分类号： C08G65/46
摘要： The catalyst is removed in the preparation of high molecular weight polyphenylene ethers from monohydric phenols, which are alkyl-substituted at the two ortho-positions but not at the para-position and may or may not be alkyl-substituted at the meta-position, by an oxidative coupling reaction with oxygen at from 15.degree. to 50.degree. C. in the presence of a catalyst complex obtained from a copper salt and an organic amine, in the presence of from 1 to 20 parts by weight of a solvent per part by weight of the monomeric phenol, and in the presence or absence of an activator, and removal of the metal component of the catalyst from the polyphenylene ether solution with a complex-forming or chelate-forming compound in aqueous solution, in the presence or absence of reducing and stabilizing substances and assistants for accelerating the interphase reactions and for phase separation, by a method in which the continuous removal of the copper catalyst is carried out in one or more mixer-settler stages at a phase volume ratio of the organic phase to the aqueous phase of from 1:0.1 to 1:1.0, preferably from 1:0.4 to 1:0.6.
摘要翻译：在从一元酚制备高分子量聚苯醚时除去催化剂，该二元酚在两个邻位进行烷基取代，而不是在对位，在间位可以是或不是烷基取代的，在由铜盐和有机胺获得的催化剂配合物的存在下，在15〜50℃下，与氧气进行氧化偶合反应，每份由1〜20份重量的溶剂单体苯酚的重量，并且在存在或不存在活化剂的情况下，在存在或不存在复合物形成或螯合形成化合物的情况下，在聚苯醚溶液中除去催化剂的金属组分减少和稳定物质和辅助剂，用于加速相间反应和相分离，方法是连续除去铜催化剂的方法是在一个或多个混合沉淀器以有机相与水相的相体积比为1:0.1至1:1.0，优选1:0.4至1:0.6。

5. 发明授权

US4536567A Removal of the catalyst from polyphenylene ethers 失效
标题翻译：从聚苯醚中除去催化剂
公开(公告)号：US4536567A
公开(公告)日：1985-08-20
申请号：US631948
申请日：1984-07-18
申请人： Juergen Hambrecht , Rudi W. Reffert , Peter Minges , Johann Swoboda
发明人： Juergen Hambrecht , Rudi W. Reffert , Peter Minges , Johann Swoboda
IPC分类号： C08G65/46 , C08G65/44
CPC分类号： C08G65/46
摘要： High molecular weight polyphenylene ethers are prepared from a monohydric phenol by an oxidative coupling reaction with oxygen in the presence of a catalyst complex obtained from a copper salt and an organic amine, and in the presence of a solvent, by a process in which the metal component of the catalyst is removed after the polymerization by adding one or more organic ammonium salts of the general formula ##STR1## where A.sup..crclbar. is an anion or polyanion of an organic carboxylic, sulfonic or phosphonic acid, R.sup.1 is hydrogen, R.sup.2 and R.sup.3 are each hydrogen, alkyl of 1 to 18 carbon atoms or aryl and R.sup.4 is alkyl of 1 to 18 carbon atoms or aryl.
摘要翻译：在由铜盐和有机胺得到的催化剂配合物存在下，通过与氧的氧化偶联反应，在溶剂存在下，通过一种方法制备高分子量聚苯醚，其中金属通过加入一种或多种通式为“IMAGE”的有机铵盐，其中A（ - ）是有机羧酸，磺酸或膦酸的阴离子或聚阴离子，R1是氢，R2和R2，并且 R3各自为氢，1至18个碳原子的烷基或芳基，R4为1至18个碳原子的烷基或芳基。

6. 发明授权

US4436870A Production of molding materials containing polyphenylene ethers 失效
标题翻译：生产含聚苯醚的成型材料
公开(公告)号：US4436870A
公开(公告)日：1984-03-13
申请号：US400689
申请日：1982-07-22
申请人： Klaus Hinselmann , Herbert Naarmann , Adolf Echte , Eduard Heil , Albert Nikles , Rudi W. Reffert , Juergen Hambrecht
发明人： Klaus Hinselmann , Herbert Naarmann , Adolf Echte , Eduard Heil , Albert Nikles , Rudi W. Reffert , Juergen Hambrecht
IPC分类号： C08L7/00 , B29C35/00 , B29C45/00 , C08G65/46 , C08J3/00 , C08J3/20 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L71/00 , C08L71/12 , C08L101/00 , C08L71/04
CPC分类号： C08J3/005 , C08G65/46 , C08L71/12 , Y10S525/905
摘要： Molding materials containing high molecular weight polyphenylene ethers are produced by a process in which a solution of a polyphenylene ether in an organic solvent, together with another polymer, is freed of solvent by multi-stage evaporation.The solvent is preferably an aromatic compound from the class comprising the hydrocarbons, halohydrocarbons, ethers or esters, the ratio of the other polymer to the polyphenylene ether is advantageously from 99:1 to 20:80 parts by weight, the other polymer is, in particular, a homopolymer or copolymer of styrene or of a homolog thereof, which may be modified with rubber, and the multi-stage evaporation process preferably comprises not less than two and not more than four working up stages.The evaporation is carried out in general at from 120.degree. to 280.degree. C. and under a pressure of from 1 to 3,000 mbar, advantageously in the presence of assistants which reduce the partial pressure, eg. water and/or methanol.
摘要翻译：含有高分子量聚苯醚的成型材料是通过多层蒸发而将有机溶剂中的聚苯醚与其它聚合物一起溶解的方法而制得的。溶剂优选为包含烃类，卤代烃类，醚类或酯类的芳族化合物，另一种聚合物与聚苯醚的比率有利地为99:1至20:80重量份，另一个聚合物为特别是可以用橡胶改性的苯乙烯或其同系物的均聚物或共聚物，多级蒸发方法优选包括不少于2个且不超过4个加工阶段。蒸发通常在120℃至280℃和1至3,000毫巴的压力下进行，有利的是在有助于降低分压的助剂的存在下进行。水和/或甲醇。

7. 发明授权

US4496679A Stabilization of polyphenylene ether solutions 失效
标题翻译：聚苯醚溶液的稳定化
公开(公告)号：US4496679A
公开(公告)日：1985-01-29
申请号：US531656
申请日：1983-09-13
申请人： Juergen Hambrecht , Rudi W. Reffert , Adolf Echte , Johann Swoboda
发明人： Juergen Hambrecht , Rudi W. Reffert , Adolf Echte , Johann Swoboda
IPC分类号： C08G65/46 , C08L71/04
CPC分类号： C08G65/46
摘要： A process for the preparation of high molecular weight polyphenylene ethers from alkyl-substituted monohydric phenols by an oxidative coupling reaction with oxygen in the presence of a catalyst complex of a copper salt and an organic amine, subsequent stopping of the reaction and removal of the metal component of the catalyst by addition of chelating and/or salt-forming agents, wherein the polymer solution is treated with a compound having the general structure: ##STR1## where R.sup.2 and R.sup.3 can be identical or different and each is OH, NH.sub.2, NHR.sup.5, where R.sup.5 is alkyl or cycloalkyl, or SH, and where R.sup.1 and R.sup.4 are identical or different, being hydrogen, alkyl, cycloalkyl, aryl, carbonyl, carboxyl, carboxyalkyl or nitrile, and can be linked to form a ring, advantageously in an amount of from 0.1 to 100 mmoles and advantageously in from 1 to 20% strength aqueous solutions.
摘要翻译：在铜盐和有机胺的催化剂络合物存在下，通过与氧的氧化偶联反应从烷基取代的一元酚制备高分子量聚苯醚的方法，随后停止反应和除去金属通过加入螯合和/或成盐剂的催化剂组分，其中聚合物溶液用具有以下通式结构的化合物处理：其中R 2和R 3可以相同或不同，并且各自为OH，NH 2，NHR 5 ，其中R 5是烷基或环烷基或SH，并且其中R 1和R 4相同或不同，是氢，烷基，环烷基，芳基，羰基，羧基，羧基烷基或腈，并且可以连接形成环，有利地在量为0.1至100毫摩尔，有利地为1至20％强度的水溶液。

8. 发明授权

US4482705A Removal of the catalyst from polyphenylene ethers 失效
标题翻译：从聚苯醚中除去催化剂
公开(公告)号：US4482705A
公开(公告)日：1984-11-13
申请号：US518612
申请日：1983-07-29
申请人： Juergen Hambrecht , Rudi W. Reffert , Volker Muench , Adolf Echte , Johann Swoboda
发明人： Juergen Hambrecht , Rudi W. Reffert , Volker Muench , Adolf Echte , Johann Swoboda
IPC分类号： C08G65/46
CPC分类号： C08G65/46
摘要： High molecular weight polyphenylene ethers are prepared from monohydric phenols by an oxidative coupling reaction with oxygen in the presence of a catalyst complex obtained from a copper salt and an organic amine by a method wherein the metal component of the catalyst is separated off, after the polymerization, by the addition of a polymeric polycarboxylic acid which is essentially composed of unsaturated monofunctional or difunctional carboxylic acids and/or their anhydrides.Advantageously, the polymeric polycarboxylic acids used are homopolymers or copolymers of (a) from 50 to 100% by weight of one or more unsaturated monofunctional acids of 3 to 10 carbon atoms and/or one or more difunctional acids or their anhydrides of 4 to 6 carbon atoms and from 0 to 50% by weight of one or more monomers which do not possess an acid function and can be copolymerized with (a).
摘要翻译：在由铜盐和有机胺得到的催化剂配合物的存在下，通过与氧的氧化偶合反应，通过催化剂的金属组分在聚合后分离的方法，由一元酚制备高分子量聚苯醚通过加入基本上由不饱和单官能或双官能羧酸和/或它们的酸酐组成的聚合多元羧酸。有利地，所使用的聚合多元羧酸是（a）50至100重量％的一种或多种3至10个碳原子的不饱和单官能酸和/或一种或多种双官能酸或其酸酐4至6的均聚物或共聚物碳原子和0至50重量％的一种或多种不具有酸官能并可与（a）共聚的单体。

9. 发明授权

US4460764A Removal of the catalyst from polyphenylene ethers 失效
标题翻译：从聚苯醚中除去催化剂
公开(公告)号：US4460764A
公开(公告)日：1984-07-17
申请号：US516383
申请日：1983-07-21
申请人： Rudi W. Reffert , Juergen Hambrecht , Adolf Echte , Hans H. Schuster , Hermann Dreher
发明人： Rudi W. Reffert , Juergen Hambrecht , Adolf Echte , Hans H. Schuster , Hermann Dreher
IPC分类号： C08G65/46 , C08G65/44
CPC分类号： C08G65/46
摘要： In the preparation of a high molecular weight polyphenylene ether from a monohydric phenol by an oxidative coupling reaction with oxygen in the presence of a catalyst complex obtained from a metal salt and an organic amine and in the presence of a solvent, and isolation of the metal ion component of the catalyst from the polyphenylene ether solution by means of a complex-forming or chelate-forming compound, the catalyst is removed by a method wherein complex formation and isolation of the metal ion component of the catalyst are carried out in an aqueous medium in the presence of from 0.1 to 5,000 mg of an anionic or non-ionic surfactant.
摘要翻译：在由金属盐和有机胺获得的催化剂配合物的存在下和在溶剂的存在下，通过与氧的氧化偶联反应从一元酚制备高分子量聚苯醚，并分离金属通过复合物形成或螯合形成化合物从聚苯醚溶液中除去催化剂的离子组分，通过催化剂的金属离子组分的复合形成和分离在水性介质中进行的方法除去催化剂在0.1至5,000mg阴离子或非离子表面活性剂的存在下。

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