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    • 1. 发明授权
    • Photographic recording material
    • 摄影记录材料
    • US4656125A
    • 1987-04-07
    • US776677
    • 1985-09-16
    • Gunter RennerWerner Liebe
    • Gunter RennerWerner Liebe
    • G03C7/26G03C7/36G03C7/392G03C1/40
    • G03C7/39216
    • Compounds having a structure corresponding to the following formula. ##STR1## wherein G represents OH or a precursor group which is unstable to alkali,X represents a substituent which cannot be split off,Y represents --O--alkyl, --SO.sub.2 --NR.sup.1 --R.sup.2, --CO--NR.sup.1 --R.sup.2, --NR.sup.1 --CO--R.sup.3, or --NR.sup.1 --SO.sub.2 --R.sup.3,R.sup.1 represents H or alkyl,R.sup.2 represents alkyl, aralkyl or aryl,R.sup.3 represents alkoxy, aroxy, alkylamino, arylamino or R.sup.2,Z represents H, alkyl, alkoxy, halogen or acylamino andn represents 1 or 2are suitable for improving the stability to light of image dyes produced from photographic couplers, in particular yellow couplers.
    • 具有对应于下式的结构的化合物。 其中G表示OH或对碱不稳定的前体基团,X表示不能分解的取代基,Y表示-O-烷基,-SO 2 -NR 1 -R 2,-CO-NR 1 -R 2,-NR 1 -CO-R3或-NR1-SO2-R3,R1表示H或烷基,R2表示烷基,芳烷基或芳基,R3表示烷氧基,芳氧基,烷基氨基,芳基氨基或R2,Z表示H,烷基,烷氧基,卤素或酰基氨基 并且n表示1或2适于改善由照相成色剂,特别是黄色成色剂产生的图像染料的光稳定性。
    • 2. 发明授权
    • Color photographic recording material
    • 彩色摄影材料
    • US4855222A
    • 1989-08-08
    • US273955
    • 1988-11-18
    • Gunter RennerErich WolffHeinz WiesenWerner Liebe
    • Gunter RennerErich WolffHeinz WiesenWerner Liebe
    • G03C7/36G03C7/305
    • G03C7/30535
    • Dye images of high color yield and high gradation are obtained with a color photographic recording material containing 2-equivalent yellow couplers corresponding to formula I, particularly in modern rapid processing methods or in developers free from benzyl alcohol. ##STR1## R.sup.1, R.sup.2 (same or different) represent hydrogen, alkyl or halogen; R.sup.3 represents alkoxyalkyl or an alkyl radical substituted by a heterocyclic group containing at least one oxygen atom;R.sup.4 represents alkyl or aryl;R.sup.5 represents halogen or alkoxy;R.sup.6 represents hydrogen, alkoxy, amino, acylamino or carbamoyl;represents alkoxy, acylamino, carbalkoxy, carbamoyl or sulfamoyl.
    • 使用含有对应于式I的2-当量黄色成色剂的彩色照相记录材料,特别是现代快速加工方法或不含苄醇的显影剂,可获得高产率和高分级的染料图像。 R1,R2(相同或不同)表示氢,烷基或卤素; R3表示烷氧基烷基或被含有至少一个氧原子的杂环基取代的烷基; R4代表烷基或芳基; R5代表卤素或烷氧基; R6表示氢,烷氧基,氨基,酰氨基或氨基甲酰基; 表示烷氧基,酰氨基,烷氧羰基,氨基甲酰基或氨磺酰基。
    • 3. 发明授权
    • Color photographic recording material containing 2-equivalent magenta
couplers
    • 含有2当量品红色成色剂的彩色照相材料
    • US5002864A
    • 1991-03-26
    • US347396
    • 1989-05-04
    • Gunter RennerWerner Liebe
    • Gunter RennerWerner Liebe
    • G03C7/38C07D231/52C07D405/00C07D493/10G03C7/384
    • G03C7/384C07D231/52
    • Stable, color neutral images may be produced by a short time photographic process using a color photographic recording material containing at least one silver halide emulsion layer and at least one 2-equivalent magenta coupler corresponding to formula I on a (preferably reflective) layer support. ##STR1## In the above formula, B denotes a stabilizing group,Y denotes halogen, alkoxy, alkyl, alkylsulphonyl, acylamino, alkoxycarbonyl, carbamoyl, sulphamoyl, amino, trifluoromethyl or cyano,n and o stand for 0, 1 or 2 (but not both 0),p stands for 0 or an integer .ltoreq.3-o,q stands for 0 or an integer .ltoreq.5-n, andAlk stands for alkyl which may be straight chained or branched and preferably has 1 to 22 carbon atoms and is optionally substituted, e.g. with hydroxy, alkoxy, aroxy or alkoxycarbonyl.
    • 使用含有至少一种卤化银乳剂层的彩色照相记录材料和在(优选反射性)层载体上对应于式I的至少一种2-等价的品红色成色剂,可以通过短时间照相方法产生稳定的彩色中性图像。 (I)在上式中,B表示稳定基团,Y表示卤素,烷氧基,烷基,烷基磺酰基,酰氨基,烷氧基羰基,氨基甲酰基,氨磺酰基,氨基,三氟甲基或氰基,n和o表示0,1或 2(但不同时为0),p表示0或整数
    • 4. 发明授权
    • Color photographic recording material containing new colored cyan
couplers
    • 包含新彩色圆形联轴器的彩色摄影记录材料
    • US5075207A
    • 1991-12-24
    • US694822
    • 1991-05-02
    • Hans LangenGunter RennerJurgen Plamper
    • Hans LangenGunter RennerJurgen Plamper
    • G03C7/34G03C7/32G03C7/333
    • G03C7/3335G03C7/3225
    • Colored cyan couplers corresponding to formula II are eminently suitable for masking the yellow secondary density of cyan dyes. The reproduction of blues and yellows is thus improved. The colored cyan couplers of formula II are preferably used together with phenolic cyan couplers bearing a phenylureido group in the 2-position and an acylamino group with a ballast group in the 5-position ##STR1## In formula II: CC represents a cyan coupler group to the coupling position of which L is attached;L is a bifunctional connecting group;Q.sup.1, Q.sup.2 represent H or photographially inert substituents;R represents a coupling component such that the compound of formula II is a yellow dye. ##STR2## in which R.sup.3 is alkyl, aryl, carboxyl, carbamoyl, acylamino, anilino;R.sup.4 is H, alkyl, aryl, a heterocyclic group;R.sup.5, R.sup.6 (same or different) represent -CO-alkyl, -CO-aryl, -CO-alkoxy, carbamoyl, -CN;represents O, S, NH;Z is the group required to complete a 5- or 6-membered carbocyclic or heterocyclic ring.
    • 对应于式II的着色青色成色剂特别适用于掩蔽青色染料的黄色二次密度。 因此,蓝调和黄色的再现被改善。 式II的着色青色成色剂优选与在2-位上带有苯基脲基的酚蓝色成色剂一起使用,并且在5位上具有镇流剂基团的酰氨基。在式II中:CC表示青色成色剂 组合到其所连接的联接位置; L是双功能连接组; Q1,Q2表示H或照相惰性取代基; R表示偶联组分,使式II化合物为黄色染料。 其中R3是烷基,芳基,羧基,氨基甲酰基,酰基氨基,苯胺基; R4是H,烷基,芳基,杂环基; R5,R6(相同或不同)表示-CO-烷基,-CO-芳基,-CO-烷氧基,氨基甲酰基,-CN; 表示O,S,NH; Z是完成5-或6-元碳环或杂环所需的基团。
    • 5. 发明授权
    • No-rinse photographic processing method and the stabilizing bath used
for this method
    • 无冲洗照相处理方法和用于该方法的稳定浴
    • US4855216A
    • 1989-08-08
    • US253664
    • 1988-10-05
    • Heinz MecklErika SpriewaldGunter Renner
    • Heinz MecklErika SpriewaldGunter Renner
    • G03C11/00G03C7/30
    • G03C7/3046
    • A no-rinse processing method for the production of color photographic images comprising the steps of developing, bleaching, fixing and stabilizing, of which the bleaching and fixing steps may be combined into a bleach fixing step, gives dye images of satisfactory quality, even after prolonged use, if the stabilizing bath used in the stabilizing step contains an effective quantity of a pyrazole which, in one of the possible tautomeric forms, corresponds to the following general formula: ##STR1## in which X represents OH or NH.sub.2,R.sub.1 represents alkyl, substituted alkyl, aryl, substituted aryl or carboxyl,R.sub.2 represents hydrogen, alkyl or substituted alkyl,R.sub.3 represents hydrogen, alkyl, substituted alkyl, aryl or substituted aryl.
    • 用于生产彩色摄影图像的无漂洗处理方法包括显影,漂白,定影和稳定步骤,其中漂白和固定步骤可以组合到漂白定影步骤中,使染色图像具有令人满意的质量,即使在 如果在稳定化步骤中使用的稳定浴含有有效量的吡唑,其可以互变异构形式之一对应于以下通式:其中X表示OH或NH 2,R 1表示烷基 ,取代的烷基,芳基,取代的芳基或羧基,R 2表示氢,烷基或取代的烷基,R 3表示氢,烷基,取代的烷基,芳基或取代的芳基。
    • 10. 发明授权
    • Color photographic recording material for the production of color images
viewed by reflected light
    • 用于生产通过反射光观看的彩色图像的彩色摄影记录材料
    • US4581324A
    • 1986-04-08
    • US666265
    • 1984-10-29
    • Erich WolffGunter RennerFriedrich-Wilhelm Kunitz
    • Erich WolffGunter RennerFriedrich-Wilhelm Kunitz
    • C07D231/52G03C7/32G03C7/34G03C7/36G03C7/38G03C7/384G03C1/46
    • G03C7/3225
    • Colored, reflection-viewed images having improved stability to light, heat and moisture and improved storage stability while retaining the original color character thereof are produced using color photographic recording materials containing, on a light-reflecting layer support, a red-sensitive, a green-sensitive and a blue-sensitive silver halide emulsion layer, each with spectrally associated color coupler, the yellow coupler being a 2-equivalent yellow coupler derived from pivaloyl acetanilide, the magenta coupler a 3-anilinopyrazolone coupler and the cyan coupler a coupler corresponding to the following general formula (I): ##STR1## wherein R.sup.1 represents H or halogen;R.sup.2 represents alkyl having at least 2 carbon atoms;R.sup.3 represents H or alkyl having up to 5 carbon atoms;R.sup.4 represents acyl; andX.sup.1 represents H or a group releasable in the process of color coupling.
    • 使用在光反射层载体上含有红色敏感的绿色的彩色照相记录材料制造具有改善的光,热和湿气稳定性以及改善的储存稳定性的彩色反射观看图像,同时保持其原始颜色特征 敏感的和感蓝卤化银乳剂层,每个具有光谱相关的颜色成色剂,黄色成色剂是衍生自新戊酰基乙酰苯胺的2-当量黄色成色剂,品红色偶联剂3-苯胺基吡唑啉酮偶联剂和青色成色剂对应于 以下通式(I):其中R 1表示H或卤素; R2表示具有至少2个碳原子的烷基; R3表示H或具有至多5个碳原子的烷基; R4表示酰基; X1表示H或在彩色偶联过程中可释放的基团。