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1. 发明申请

US20080041274A1 Thermally Hardening, Transparent Coating Substance, Method for the Production Thereof and its Use 有权
标题翻译：耐热硬化，透明涂层物质，其生产方法及其用途
公开(公告)号：US20080041274A1
公开(公告)日：2008-02-21
申请号：US10595059
申请日：2004-07-10
申请人： Gunter Klein , Ulrike Rockrath , Jurgen Niemann , Ulrich Poth , Andre Brosseit , Karin Wermelt , Alexandra Huber
发明人： Gunter Klein , Ulrike Rockrath , Jurgen Niemann , Ulrich Poth , Andre Brosseit , Karin Wermelt , Alexandra Huber
IPC分类号： C08G18/72
CPC分类号： C08G18/4063 , C08G18/722 , C08G18/8077 , C09D175/04
摘要： A thermosetting transparent coating material, its preparation and use. The coating includes (meth)acrylate (co)polymer having a number-average molecular weight of from 1,000 to 6,000 daltons, a glass transition temperature of −15 to +70° C., and a hydroxyl number of from 80 to 200 mg KOH/g; polyester having a number-average molecular weight of from 800 to 6,000 daltons, a hydroxyl number of from 80 to 200 mg KOH/g and an acid number of from 1 to 50 mg KOH/g, comprising, based on the polyester, from 30 to 70% by weight of cycloaliphatic structural units; a blocked polyisocyanate in which the blocked polyisocyanate groups are attached to flexibilizing structural units which, as part of a three-dimensional network, lower its glass transition temperature; and blocked polyisocyanate in which the blocked polyisocyanate groups are attached to hardening structural units which, as part of a three-dimensional network, raise its glass transition temperature.
摘要翻译：一种热固性透明涂料，其制备和使用。涂层包括数均分子量为1,000至6,000道尔顿的玻璃化转变温度为-15至+ 70℃，羟基数为80至200mg KOH（共）的（甲基）丙烯酸酯 /G; 数均分子量为800至6,000道尔顿的聚酯，羟基数为80至200mg KOH / g，酸值为1至50mg KOH / g，基于聚酯，包含30 至70重量％的脂环族结构单元; 封闭的多异氰酸酯，其中封端的多异氰酸酯基团连接到柔性结构单元，其作为三维网络的一部分降低其玻璃化转变温度; 和封端的多异氰酸酯，其中封端的多异氰酸酯基团连接到作为三维网络的一部分的硬化结构单元，其升高其玻璃化转变温度。

2. 发明申请

US20080047469A1 Highly Scratch-Resistant and Highly Elastic Coating Agents Based on Alkoxysilane Functional Components 失效
标题翻译：基于烷氧基硅烷功能组分的高耐刮擦和高弹性涂料
公开(公告)号：US20080047469A1
公开(公告)日：2008-02-28
申请号：US11575979
申请日：2005-09-03
申请人： Andreas Poppe , Gunter Klein , Andre Brosseit , Karin Wermelt , Martina Mollers
发明人： Andreas Poppe , Gunter Klein , Andre Brosseit , Karin Wermelt , Martina Mollers
IPC分类号： C08G18/62
CPC分类号： C08G18/284 , C08G18/631 , C08G18/706 , C08L2666/02 , C09D175/06 , C09J133/04 , Y10T428/31663
摘要： A thermosetting coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material of (A1) from 0% to 50% by weight, based on the entirety of components (A1) and (A2), of a polymethacrylate copolymer containing more than 50% by weight, based on the entirety of comonomers in the copolymer (A1), of free-radically polymerizable, ethylenically unsaturated compounds (a1) containing at least one reactive group of the formula I —X—SiR″x(OR″)3-x (I) and (A2) from 50% to 100% by weight, based on the entirety of components (A1) and (A2), of an adduct of polyisocyanate and alkoxysilane, (A2) containing at least one reactive group of the formula II: —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II) (B) a catalyst for the crosslinking of the —Si(OR′)3-x units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要翻译：一种热固性涂料，其包含（A）至少50重量％，基于组合物（A1）和（A1）的总成分（A1）中（A1）的涂料中的非挥发性物质的量为0重量％至50重量％ A2），含有基于共聚物（A1）中共聚单体总共的50重量％以上的含有至少一个式I的反应性基团的可自由基聚合的烯属不饱和化合物（a1）的聚甲基丙烯酸酯共聚物 <？in-line-formula description =“In-line Formulas”end =“lead”？> X-SiR“x”（OR“）3-x C（O）-N-（X-SiR“x”（OR'）3-x N）（X'-SiR' '_{y m（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>（ B）用于交联-Si（OR'）3-x 单元的催化剂，和（C）非质子溶剂或非质子传递溶剂的混合物。}

3. 发明申请

US20100015344A1 COATING COMPOSITIONS WITH HIGH SCRATCH RESISTANCE AND WEATHERING STABILITY 审中-公开
标题翻译：具有高耐蚀性和耐候性的涂料组合物
公开(公告)号：US20100015344A1
公开(公告)日：2010-01-21
申请号：US12519466
申请日：2007-12-19
申请人： Matthijs Groenewolt , Andreas Poppe , Gunter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stubbe , Simone Hesener
发明人： Matthijs Groenewolt , Andreas Poppe , Gunter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stubbe , Simone Hesener
IPC分类号： B05D1/36 , C09D175/00
CPC分类号： C09D175/14 , C08G18/289 , C08G18/6254 , C08G18/778 , C08G18/809 , C09D175/04
摘要： Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, where (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (iii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network. The finally cured coating obtained from the coating composition has a post-crosslinking index (PCI) of less than 2, wherein (PCI) is defined as the ratio of the storage modulus E′(200) at 200° C. to the minimum of the storage modulus E′(min) at a temperature above the measured glass transition temperature Tg.
摘要翻译：公开了包含（a）至少一种含羟基的化合物（A），（b）至少一种具有游离和/或封闭的异氰酸酯基团的化合物（B）的涂料组合物，和（c）至少一种用于硅烷基团的交联，其中（i）涂料组合物中的一种或多种组分含有可水解的硅烷基团，和（iii）涂料组合物可最终固化成具有统计分布的Si-O-Si网络区域的涂层。从涂料组合物得到的最终固化涂层具有小于2的后交联指数（PCI），其中（PCI）定义为200℃下的储能模量E'（200）与最低在高于测量的玻璃化转变温度Tg的温度下的储能模量E'（min）。

4. 发明授权

US4515005A Hydropneumatic blind riveter with automatic mandrel catcher 失效
标题翻译：液压气动盲铆钉机具有自动心轴捕手
公开(公告)号：US4515005A
公开(公告)日：1985-05-07
申请号：US363288
申请日：1982-03-29
申请人： Gunter Klein
发明人： Gunter Klein
IPC分类号： B21J15/00 , B21J15/02 , B21J15/06 , B21J15/16 , B21J15/22 , B21J15/28 , B21J15/32 , B21J15/36 , B21D31/00
CPC分类号： B21J15/22 , B21J15/105 , B21J15/326 , Y10T29/53748
摘要： A riveter has a housing forming an air chamber and a liquid-filled hydraulic chamber adjacent thereto, a head on the housing having a tip and forming a liquid-filled working chamber communicating with the hydraulic chamber, and a working piston in the working chamber and carrying a chuck for grasping a mandrel of a blind rivet. The head and chuck form a passage having a front end opening at the tip and a rear end opening into a mandrel-catching compartment and the piston displaceable in the working chamber between a ready position in which a mandrel of a blind rivet can be fitted into the passage at the chuck with the rivet engaged backwardly against the tip and an actuated position spaced from the tip and wherein the chuck is retracted. An air piston is provided in the air chamber and carries a hydraulic piston displaceable in the hydraulic chamber between an advanced position pressurizing the hydraulic and working chambers and corresponding to a front position of the air piston and a retracted position corresponding to a rear position of the air piston.
摘要翻译：铆钉具有形成空气室和与其相邻的液体充填液压室的壳体，壳体上的头部具有尖端并形成与液压室连通的充满液体的工作室，以及工作室中的工作活塞，携带用于抓握盲铆钉的心轴的卡盘。头部和卡盘形成通道，该通道在尖端处具有前端开口，后端开口进入心轴捕获室，活塞可在工作室中移位，该就绪位置可以将盲铆钉的心轴嵌入其中在卡盘处的通道与铆钉相对于顶端接合，并且与尖端间隔开的致动位置，并且其中卡盘缩回。空气活塞设置在空气室中，并且承载液压活塞，该液压活塞可在液压室中位移，该前进位置对液压和工作室进行加压，并对应于空气活塞的前部位置，并且对应于后退位置的缩回位置空气活塞。

5. 发明授权

US09353287B2 Coating agents having high scratch resistance and weathering stability 有权
标题翻译：具有高耐刮擦性和耐候稳定性的涂层剂
公开(公告)号：US09353287B2
公开(公告)日：2016-05-31
申请号：US12519449
申请日：2007-12-19
申请人： Matthijs Groenewolt , Andreas Poppe , Gunter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stubbe , Simone Hesener
发明人： Matthijs Groenewolt , Andreas Poppe , Gunter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stubbe , Simone Hesener
IPC分类号： D06M15/643 , C09D175/14 , C08G18/28 , C08G18/62 , C08G18/77 , C08G18/80 , C09D175/04
CPC分类号： C09D175/14 , C08G18/289 , C08G18/6254 , C08G18/778 , C08G18/809 , C09D175/04
摘要： Disclosed are coating compositions comprising at least one hydroxyl-containing compound (A) and at least one isocyanato-containing compound (B), wherein one or more of the constituents of the coating composition comprise between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (I) —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (I) and between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (II) —Z—(X—SiR″x(OR′)3-x) (II).
摘要翻译：公开了包含至少一种含羟基的化合物（A）和至少一种含异氰酸酯基的化合物（B）的涂料组合物，其中涂料组合物的一种或多种组分包含2.5至97.5mol％结构单元（I）和（II）的至少一种结构单元的式（I）-N（X-SiR“x（OR'）3-x）n（X'-SiR”y（OR' ）（I）和（II）的至少一种结构单元，基于整个结构单元（I）和（II），2.5至97.5摩尔％ SiR“x（OR'）3-x）（II）。

6. 发明申请

US20130052469A1 BINDING AGENT MIXTURE, COATING AGENTS CONTAINING SAID BINDING AGENT MIXTURE, AND COATINGS PRODUCED FROM SAID COATING AGENTS, SAID COATINGS HAVING A HIGH SCRATCH RESISTANCE, HIGH WEATHERING STABILITY, AND GOOD OPTICAL PROPERTIES 有权
标题翻译：粘合剂混合物，含有粘合剂混合物的涂料代理，以及由上述涂料代理生产的涂料，具有高耐刮擦性，高耐候性和良好光学性能的涂料
公开(公告)号：US20130052469A1
公开(公告)日：2013-02-28
申请号：US13395576
申请日：2010-08-03
申请人： Gunter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
发明人： Gunter Klein , Andreas Poppe , Sabine Holtschulte , Björn Feldmann , Ulrike Wenking , Karl-Heinz Joost
IPC分类号： C08L67/08 , B05D1/36 , B32B9/00 , C09D183/08
CPC分类号： C08G18/4288 , C08G18/168 , C08G18/18 , C08G18/1883 , C08G18/289 , C08G18/42 , C08G18/718 , C08G18/778 , C08G18/809 , C09D175/04 , Y10T428/31663
摘要： Binder mixture comprising a hydroxyl-containing compound (A), and at least 1.0% by weight, based on the nonvolatile constituents of the binder mixture, of a phosphorus- and nitrogen-containing catalyst (D) for the crosslinking of silane groups, wherein the hydroxyl-containing compound (A) comprises a hydroxyl-functional polyester having on average at least one hydroxyl function of the polyester esterified with a C8 to C9 monocarboxylic acid, and the catalyst (D) is blocked with at least one tertiary amine of the formula (I) where R1 is an acyclic aliphatic or araliphatic hydrocarbon radical having at least 3 C atoms, R2 is an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R3, and R3 is hydrogen or an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R2.
摘要翻译：包含含羟基化合物（A）的粘合剂混合物和至少1.0重量％，基于粘合剂混合物的不挥发成分，用于交联硅烷基团的含磷和氮的催化剂（D），其中含羟基化合物（A）包含平均具有C8-C9单羧酸酯化的聚酯的至少一个羟基官能团的羟基官能聚酯，催化剂（D）被至少一种叔胺式（I）其中R 1是具有至少3个C原子的无环脂族或芳脂族烃基，R 2是与R 1和/或R 3相同或不同的无环脂族或芳脂族烃基，R 3是氢或无环与R 1和/或R 2相同或不同的脂族或芳脂族烃基。

7. 发明申请

US20100062168A1 COATING COMPOSITIONS COMPRISING ADDUCTS WITH SILANE FUNCTIONALITY, AND HIGH SCRATCH RESISTANCE COATINGS WITH IMPROVED CRACK RESISTANCE PRODUCED FROM THEM 有权
标题翻译：包含硅烷功能助剂的涂料组合物和具有改进的抗裂纹性的高耐蚀涂层
公开(公告)号：US20100062168A1
公开(公告)日：2010-03-11
申请号：US12531342
申请日：2008-01-22
申请人： Andreas Poppe , Egon Wegner , Gunter Klein
发明人： Andreas Poppe , Egon Wegner , Gunter Klein
IPC分类号： B05D3/02 , C08L83/06
CPC分类号： C09D5/29 , C08G18/289 , C08G18/61 , C08G18/6254 , C08G18/792 , C08G18/809 , C08L75/12 , C09D143/04 , C09D175/04 , C08L2666/20 , C08L2666/16
摘要： Disclosed are coating compositions comprising film-forming material with at least one reactive functional group G″′, catalyst for the crosslinking of the silane groups, aprotic solvents, and at least one adduct with silane functionality which is prepared by an addition reaction of (a) at least one silane (S1) which has at least one functional group G′ which is reactive with the complementary functional groups G″ of the compound (O), and (b) at least one compound (O) which has at least one complementary functional group G″ and at least one surface-active radical. Also disclosed are multicoat paint systems in which the transparent coating has been produced from these coating compositions, methods of making and use, as well as methods of improving the hardness and/or the scratch resistance of coatings.
摘要翻译：公开了包含具有至少一个反应性官能团G“'的成膜材料，用于硅烷基团交联的催化剂，非质子溶剂和至少一种与硅烷官能团的加合物的涂料组合物，其通过（a ）至少一种具有至少一个与化合物（O）的互补官能团G“反应的官能团G'的硅烷（S1），和（b）至少一种具有至少一个互补官能团G“和至少一个表面活性基团。还公开了多层涂料体系，其中由这些涂料组合物制备透明涂料，制备和使用方法，以及提高涂层硬度和/或耐划伤性的方法。

8. 发明申请

US20100028544A1 COATING COMPOSITIONS WITH HIGH SCRATCH RESISTANCE AND WEATHERING STABILITY 有权
标题翻译：具有高耐蚀性和耐候性的涂料组合物
公开(公告)号：US20100028544A1
公开(公告)日：2010-02-04
申请号：US12519449
申请日：2007-12-19
申请人： Matthijs Groenewolt , Andreas Poppe , Gunter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stubbe , Simone Hesener
发明人： Matthijs Groenewolt , Andreas Poppe , Gunter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stubbe , Simone Hesener
IPC分类号： B05D3/02 , C09D5/00 , B05D1/36
CPC分类号： C09D175/14 , C08G18/289 , C08G18/6254 , C08G18/778 , C08G18/809 , C09D175/04
摘要： Disclosed are coating compositions comprising at least one hydroxyl-containing compound (A) and at least one isocyanato-containing compound (B), wherein one or more of the constituents of the coating composition comprise between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (I) —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (I) and between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (II) —Z—(X—SiR″x(OR′)3-x) (II).
摘要翻译：公开了包含至少一种含羟基的化合物（A）和至少一种含异氰酸酯基的化合物（B）的涂料组合物，其中所述涂料组合物的一种或多种组分包含2.5至97.5mol％的结构单元（I）和（II）的至少一种结构单元的式（I）-N（X-SiR''x（OR'）3-x）n（X'-SiR''y OR'）3-y）m（I），并且基于整个结构单元（I）和（II），2.5至97.5mol％的至少一种式（II）-Z-（ X-SiR''x（OR'）3-x）（II）。

9. 发明授权

US4082580A Iron-nickel-molybdenum alloy having improved stability and high initial permeability 失效
标题翻译：具有改善稳定性和高初始渗透性的铁 - 镍 - 钼合金
公开(公告)号：US4082580A
公开(公告)日：1978-04-04
申请号：US519721
申请日：1974-10-31
申请人： Friedrich Pfeifer , Gunter Klein
发明人： Friedrich Pfeifer , Gunter Klein
IPC分类号： C21D6/00 , C22C38/08 , C04B35/00
CPC分类号： C21D6/001 , C22C38/08
摘要： An alloy is described which contains between about 33 and 35% nickel, about 1 and 4% molybdenum and the balance iron with incidental impurities. The alloy is characterized by having a completely secondarily recrystallized structure, improved stability preventing substantial transformation to martensite at temperatures as low as -320.degree. F, high resistance and high initial permeability.

10. 发明申请

US20140023789A1 COATING AGENTS HAVING HIGH SCRATCH RESISTANCE AND WEATHERING STABILITY 审中-公开
标题翻译：具有高耐蚀性和耐候性的涂料代理
公开(公告)号：US20140023789A1
公开(公告)日：2014-01-23
申请号：US14036367
申请日：2013-09-25
申请人： Matthijs Groenewolt , Andreas Poppe , Gunter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stubbe , Simone Hesener
发明人： Matthijs Groenewolt , Andreas Poppe , Gunter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stubbe , Simone Hesener
IPC分类号： C09D175/14
CPC分类号： C09D175/14 , C08G18/289 , C08G18/6254 , C08G18/778 , C08G18/809 , C09D175/04
摘要： Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, said catalyst (D) comprising phosphorus. It is an aspect of the disclosed coating compositions that (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (ii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network.
摘要翻译：公开了包含（a）至少一种含羟基化合物（A），（b）至少一种具有异氰酸酯基团的化合物（B）和（c）至少一种用于硅烷基团交联的催化剂（D），所述催化剂（D）包含磷。所公开的涂料组合物的一个方面是（i）涂料组合物中的一种或多种组分含有可水解的硅烷基团，和（ii）涂料组合物可以最终固化成具有统计分布的Si-O- Si网络。

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