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    • 2. 发明授权
    • Preparation of triethyl phosphate
    • 磷酸三乙酯的制备
    • US06673955B2
    • 2004-01-06
    • US10302543
    • 2002-11-22
    • Karl-Heinz MitschkeKaspar HallenbergerOttfried SchlakJohannes Kaulen
    • Karl-Heinz MitschkeKaspar HallenbergerOttfried SchlakJohannes Kaulen
    • C07F902
    • C07F9/11
    • The invention relates to a process for preparing triethyl phosphate by reacting phosphorus oxychloride with a greater than stoichiometric quantity of ethanol under reduced pressure at temperatures of from 0 to 50° C. in a reaction vessel, wherein a) the volatile components resulting from the reaction are predominantly condensed by means of a reflux condenser and the remaining volatile components are passed into a scrubber filled with water, b) after the end of the reaction, the reaction mixture is separated distillatively in an outgassing column into a top product and a bottom product which predominantly comprises triethyl phosphate, c) the top product of the outgassing column is combined with the contents of the scrubber and d) the contents of the scrubber are separated distillatively in an azeotropic distillation to obtain water and ethanol as top product and the ethanol, preferably after dewatering, is preferably returned to the reaction.
    • 本发明涉及通过在反应容器中在0至50℃的温度下在减压下使磷酰氯与大于化学计量的乙醇反应来制备磷酸三乙酯的方法,其中a)由反应产生的挥发性组分为 主要通过回流冷凝器冷凝,剩余的挥发性成分进入填充有水的洗涤器,b)在反应结束后,将反应混合物在脱气塔中蒸馏分离成顶部产物和底部产物, 主要包括磷酸三乙酯,c)除气塔的顶部产物与洗涤器的内容物组合,d)洗涤器的内容物在共沸蒸馏中蒸馏分离,得到水和乙醇作为顶级产物和乙醇,优选在 脱水,优选返回到反应中。