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1. 发明授权

US07498373B2 Hot sealing compound for aluminum foils applied to polypropylene and polystyrene 有权
标题翻译：适用于聚丙烯和聚苯乙烯的铝箔热密封胶
公开(公告)号：US07498373B2
公开(公告)日：2009-03-03
申请号：US10470276
申请日：2002-02-05
申请人： Guenter Schmitt , Michael Wicke , Juergen Hartmann , Klaus Schultes , Helmut Schwind , Thomas Arnold
发明人： Guenter Schmitt , Michael Wicke , Juergen Hartmann , Klaus Schultes , Helmut Schwind , Thomas Arnold
IPC分类号： C08K5/101
CPC分类号： C09J133/10 , B32B15/08 , B32B15/20 , C08L23/00 , C08L33/10 , C08L2666/02 , C08L2666/04 , C09D123/02 , C09J151/003
摘要： The invention relates to a hot sealing system comprised of an olefin polymer or of an olefin polymer A, of a methacrylate polymer B, of a graft polymer A-X consisting of the above-mentioned constituents and of a solvent or solvent mixture. The hot sealing system is characterized by having a high thermal stability and short sealing times.
摘要翻译：本发明涉及由烯烃聚合物或甲基丙烯酸酯聚合物B的烯烃聚合物A，由上述成分组成的接枝聚合物A-X和溶剂或溶剂混合物组成的热封系统。热封系统的特征在于具有高的热稳定性和短的密封时间。

2. 发明授权

US06809163B2 Process for preparing bead polymers with an average particle size in the range from 1 to 40 &mgr;M, moulding compositions comprising bead polymer, and mouldings and PAMA plastisols 有权
标题翻译：制备平均粒度为1至40μm的珠粒聚合物的方法，包含珠粒聚合物的模塑组合物和模塑料和PAMA增塑溶胶
公开(公告)号：US06809163B2
公开(公告)日：2004-10-26
申请号：US10029289
申请日：2001-12-28
申请人： Klaus Schultes , Thomas Suefke , Markus Parusel , Guenter Schmitt , Winfried Belzner
发明人： Klaus Schultes , Thomas Suefke , Markus Parusel , Guenter Schmitt , Winfried Belzner
IPC分类号： C08F224
CPC分类号： C08F2/24
摘要： The present invention provides a process for preparing bead polymers having an average particle size of 1 to 40 &mgr;m, which includes: contacting: at least one polymerizable mix which includes at least 50% by weight of at least one (meth)acrylate monomer, at least one aluminum compound, and an aqueous phase, to prepare a mixture; dispersing the mixture at a shear rate≧103 s−1 to form a dispersion, wherein the dispersion is stabilized by the aluminum compound; and polymerizing to produce bead polymers having an average particle size of 1 to 40 &mgr;m.
摘要翻译：本发明提供了一种制备平均粒径为1至40μm的珠粒聚合物的方法，其包括：将至少一种包含至少50重量％的至少一种（甲基）丙烯酸酯单体的可聚合混合物在至少一种铝化合物和水相，以制备混合物;将混合物以剪切速率> 10 3 s -1分散以形成分散体，其中分散体由铝化合物稳定; 并且聚合以制备平均粒径为1至40μm的珠粒聚合物。

3. 发明授权

US09410043B2 Reactive mixture for coating molded objects by means of reaction injection molding and coated molded object 有权
标题翻译：通过反应注射成型和涂覆成型物体涂覆成型物体的反应性混合物
公开(公告)号：US09410043B2
公开(公告)日：2016-08-09
申请号：US13546051
申请日：2012-07-11
申请人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Höβ , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
发明人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Höβ , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
IPC分类号： C09D4/00 , C08F4/32 , C08F2/46 , B29C45/16 , B29C45/00
CPC分类号： C09D4/00 , B29C45/0001 , B29C45/1679 , C08F2/46 , C08F4/32 , Y10T428/263 , Y10T428/264 , Y10T428/31721 , Y10T428/31913 , Y10T428/31924 , Y10T428/31928
摘要： A reactive mixture for coating mouldings by means of reaction injection moulding, containing at least 40% by weight of (meth)acrylates having at least two double bonds. The reactive mixture contains at least one photoinitiator and at least one thermal initiator. The present invention furthermore describes a coated moulding including a moulding which is obtainable by injection moulding processes and includes at least one polymer selected from polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer and polymethyl methacrylate copolymers, and a coating which is obtainable by polymerization of (meth)acrylates having at least two double bonds. The coating has an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.
摘要翻译：用于通过反应注射成型涂覆模制品的反应性混合物，其含有至少40重量％的具有至少两个双键的（甲基）丙烯酸酯。反应性混合物含有至少一种光引发剂和至少一种热引发剂。本发明还描述了一种涂覆的模制品，其包括可通过注射成型工艺获得的模制品，并且包括至少一种选自聚甲基丙烯酸甲酯，聚甲基丙烯酸甲酯，苯乙烯 - 丙烯腈共聚物，苯乙烯 - 马来酸共聚物和聚甲基丙烯酸甲酯共聚物的聚合物，可通过具有至少两个双键的（甲基）丙烯酸酯的聚合获得。根据交叉影线试验，涂层的粘合强度等级不超过1，并且根据ASTM 1044（12/05）进行耐擦伤性试验后20°下的光泽度降低（施加重量500g，循环次数= 100）不超过10％。

4. 发明授权

US09067389B2 Transparent plastic composite 有权
标题翻译：透明塑料复合材料
公开(公告)号：US09067389B2
公开(公告)日：2015-06-30
申请号：US12300408
申请日：2007-03-14
申请人： Werner Hoess , Michael Zietek , Michael Enders , Christian Eberle , Sven Schroebel , Klaus Albrecht , Rudolf Blass , Klaus Schultes , Arne Schmidt
发明人： Werner Hoess , Michael Zietek , Michael Enders , Christian Eberle , Sven Schroebel , Klaus Albrecht , Rudolf Blass , Klaus Schultes , Arne Schmidt
IPC分类号： B32B27/18 , B32B27/40 , B32B27/30
CPC分类号： B32B27/18 , B32B27/30 , B32B27/308 , B32B27/40 , Y10T428/31576
摘要： The invention describes a transparent plastics composite composed of PMMA and TPU with excellent mechanical properties.
摘要翻译：本发明描述了由具有优异机械性能的PMMA和TPU组成的透明塑料复合材料。

5. 发明申请

US20130203918A1 WEATHERING-RESISTANT, COLORED MOLDINGS WITH IMPROVED GLOSS AND WIPE RESISTANCE 有权
标题翻译：耐候耐用，具有改进的胶和耐擦性的彩色模具
公开(公告)号：US20130203918A1
公开(公告)日：2013-08-08
申请号：US13824624
申请日：2011-08-22
申请人： Victor Khrenov , Andreas Mischlich , Ursula Golchert , Stefan Nau , Anton Halblaender , Klaus Schultes , Marc Poth , Antonios Manis , Kathrin Lehmann , Zhen Zhu
发明人： Victor Khrenov , Andreas Mischlich , Ursula Golchert , Stefan Nau , Anton Halblaender , Klaus Schultes , Marc Poth , Antonios Manis , Kathrin Lehmann , Zhen Zhu
IPC分类号： C08K5/5419
CPC分类号： C08K5/5419 , C08L33/08 , C08L33/10 , C08L83/04 , C08L83/00
摘要： The present invention relates to weathering-resistant, colored moldings made of poly(alkyl) (meth)acrylate with improved gloss and resistance to mechanical influences acting on the surface of the molding, in particular with improved wipe resistance and improved scratch resistance, and also to molding compositions for producing the same.
摘要翻译：本发明涉及具有改善的光泽度和抗机械影响的聚（烷基）（甲基）丙烯酸酯制成的耐候性着色模制品，特别是具有改进的耐擦拭性和改善的耐刮擦性，以及成型用组合物。

6. 发明申请

US20130096237A1 COMPOSITE MATERIAL MADE OF A MATERIAL CONTAINING CELLULOSE WITH PMMA AS A PLASTIC MATRIX USING DIFFERENT COUPLING COMPONENTS 审中-公开
标题翻译：包含纤维素的材料与PMMA的复合材料作为使用不同的耦合组分的塑料基质
公开(公告)号：US20130096237A1
公开(公告)日：2013-04-18
申请号：US13703746
申请日：2011-06-01
申请人： Carlo Schuetz , Christian Roth , Ruediger Carloff , Klaus Schultes , Victor Khrenov , Eric Reinheimer
发明人： Carlo Schuetz , Christian Roth , Ruediger Carloff , Klaus Schultes , Victor Khrenov , Eric Reinheimer
IPC分类号： C08L33/12
CPC分类号： C08L33/12 , B29C48/92 , B29C2948/92704 , C08J5/045 , C08J5/10 , C08J2333/06 , C08J2400/22 , C08L97/02 , C08L2666/26 , C08L33/08
摘要： The invention relates to novel composite materials with improved mechanical properties and improved weathering resistance, said composite materials being made of at least one material containing cellulose, preferably wood, and at least one plastic, and to a method for producing said composite materials and for using same.
摘要翻译：本发明涉及具有改善的机械性能和改善的耐候性的新型复合材料，所述复合材料由至少一种含有纤维素，优选木材和至少一种塑料的材料制成，以及一种生产所述复合材料并用于相同。

7. 发明授权

US08399560B2 Use of polyalkyl(meth)acrylate bead polymers and moulding material for producing extruded moulded parts with a matt surface 有权
标题翻译：使用聚（甲基）丙烯酸烷基酯珠粒聚合物和用于生产具有无光泽表面的挤出成型部件的成型材料
公开(公告)号：US08399560B2
公开(公告)日：2013-03-19
申请号：US11661651
申请日：2005-08-30
申请人： Klaus Schultes , Peter Battenhausen , Ursula Golchert , Stefan Nau , Werner Hoess
发明人： Klaus Schultes , Peter Battenhausen , Ursula Golchert , Stefan Nau , Werner Hoess
IPC分类号： C08F2/38 , C08F20/10 , C08J5/10 , C08L33/12 , C08L51/06
CPC分类号： C08L33/12 , C08L2205/02 , C08L2205/18 , C08L2666/04
摘要： The invention relates to the use of polyalkyl(meth)acrylate bead polymers with an average particle size V50 that ranges between 30 and 70 μm for improving the stress cracking resistance of moulding materials containing polyalkyl(meth)acrylate. The invention also relates to moulding materials comprising: a) at least 50 wt. % of an impact resistance modifying agent, which contains at least one polyalkyl(meth)acrylate phase; b) at least 8 wt. % of a polyalkyl(meth)acrylate bead polymer with an average particle size V50 that ranges between 30 and 70 μm; and c) between 0 and 42 wt. % of a polyalkyl(meth)acrylate with a molecular weight ranging between 20,000 and 350,000 g/mol, whereby the wt. % of the components a) to c) amounts to 100 wt. %, and to moulded bodies that can be obtained from said materials.
摘要翻译：本发明涉及平均粒度V50为30〜70μm的聚（甲基）丙烯酸烷基酯聚合物（聚甲基丙烯酸烷基酯）聚合物用于提高含（甲基）丙烯酸聚烷基酯的成型材料的抗应力开裂性。本发明还涉及成型材料，其包含：a）至少50wt。％的耐冲击改性剂，其含有至少一种（甲基）丙烯酸烷基酯相; b）至少8wt。％的平均粒度V50为（30〜70μm）的（甲基）丙烯酸烷基酯聚合的（甲基）丙烯酸烷基酯聚合物; 和c）0至42wt。％的分子量在20,000和350,000g / mol之间的聚（甲基）丙烯酸烷基酯，其中wt。组分a）至c）的％相当于100wt。％，以及可以从所述材料获得的成型体。

8. 发明申请

US20130001825A1 REACTIVE MIXTURE FOR COATING MOLDED OBJECTS BY MEANS OF REACTION INJECTION MOLDING AND COATED MOLDED OBJECT 审中-公开
标题翻译：通过反应注射成型和涂覆成型对象涂覆模制对象的反应混合物
公开(公告)号：US20130001825A1
公开(公告)日：2013-01-03
申请号：US13546051
申请日：2012-07-11
申请人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Höss , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
发明人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Höss , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
IPC分类号： B29C45/16
CPC分类号： C09D4/00 , B29C45/0001 , B29C45/1679 , C08F2/46 , C08F4/32 , Y10T428/263 , Y10T428/264 , Y10T428/31721 , Y10T428/31913 , Y10T428/31924 , Y10T428/31928
摘要： A reactive mixture for coating mouldings by means of reaction injection moulding, containing at least 40% by weight of (meth)acrylates having at least two double bonds. The reactive mixture contains at least one photoinitiator and at least one thermal initiator. The present invention furthermore describes a coated moulding including a moulding which is obtainable by injection moulding processes and includes at least one polymer selected from polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer and polymethyl methacrylate copolymers, and a coating which is obtainable by polymerization of (meth)acrylates having at least two double bonds. The coating has an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.
摘要翻译：用于通过反应注射成型涂覆模制品的反应性混合物，其含有至少40重量％的具有至少两个双键的（甲基）丙烯酸酯。反应性混合物含有至少一种光引发剂和至少一种热引发剂。本发明还描述了一种涂覆的模制品，其包括可通过注射成型工艺获得的模制品，并且包括至少一种选自聚甲基丙烯酸甲酯，聚甲基丙烯酸甲酯，苯乙烯 - 丙烯腈共聚物，苯乙烯 - 马来酸共聚物和聚甲基丙烯酸甲酯共聚物的聚合物，可通过具有至少两个双键的（甲基）丙烯酸酯的聚合获得。根据交叉影线试验，涂层的粘合强度等级不超过1，并且根据ASTM 1044（12/05）进行耐擦伤性试验后20°下的光泽度降低（施加重量500g，循环次数= 100）不超过10％。

9. 发明授权

US08227549B2 Composition with increased stress cracking resistance 失效
标题翻译：具有增加的抗开裂性的组合物
公开(公告)号：US08227549B2
公开(公告)日：2012-07-24
申请号：US12600840
申请日：2008-04-09
申请人： Klaus Schultes , Werner Hoess , Nils Mehler
发明人： Klaus Schultes , Werner Hoess , Nils Mehler
IPC分类号： C08L25/02 , C08L33/02 , C08L33/04 , C08L33/14 , C08L33/18 , C08L33/20 , C08L35/02
CPC分类号： C08L33/08 , C08L25/12 , C08L33/10 , C08L2666/04
摘要： Composition containing, based in each case on its total weight, A) 50.0% by weight to 99.5% by weight of at least one (meth)acrylate (co)polymer and B) 0.5% by weight to 50.0% by weight of at least one copolymer obtainable by polymerization of a monomer mixture comprising i. 70% by weight to 92% by weight of a vinylaromatic monomer and ii. 8% by weight to 30% by weight of acrylonitrile or methacrylonitrile or mixtures thereof and iii. 0% by weight to 22% by weight of at least one further monomer, the composition having a haze according to ASTM D1003 of less than 2.0% at 23° C. and a haze according to ASTM D1003 of less than 4.0% at 40° C. and the composition containing at least one (meth)acrylate (co)polymer a) having a solution viscosity in chloroform at 25° C. (ISO 1628—part 6) of greater than 55 ml/g. The moldings obtainable from the composition are distinguished in particular by improved stress cracking resistance and are suitable in particular for coverings, finishes or films.
摘要翻译：包含基于每种情况的总重量的组合物A）50.0重量％至99.5重量％的至少一种（甲基）丙烯酸酯（共）聚合物，和B）至少0.5重量％至50.0重量％一种共聚物，其通过单体混合物的聚合获得，所述单体混合物包含i。 70重量％至92重量％的乙烯基芳族单体，和ii。 8重量％至30重量％的丙烯腈或甲基丙烯腈或其混合物，iii。 0重量％至22重量％的至少一种其它单体，该组合物在-23℃下具有根据ASTM D1003的雾度小于2.0％，并且根据ASTM D1003的雾度小于4.0％ 40℃，组合物含有至少一种在-25℃（ISO 1628-第6部分）中溶液粘度在55ml / g以上的（甲基）丙烯酸酯（共）聚合物）a）。可从组合物获得的模制品特别是通过改进的耐应力开裂性来区分，特别适用于覆盖物，表面处理剂或膜。

10. 发明申请

US20110230610A1 POLYMER BLEND FOR MATTE INJECTION MOULDED PARTS 审中-公开
标题翻译：聚合物混合注射成型件
公开(公告)号：US20110230610A1
公开(公告)日：2011-09-22
申请号：US13115446
申请日：2011-05-25
申请人： Klaus Schultes , Michael Wicker , Peter Kempf , Werner Hoß , Klaus Albrecht , Ursula Golchert , Stefan Nau
发明人： Klaus Schultes , Michael Wicker , Peter Kempf , Werner Hoß , Klaus Albrecht , Ursula Golchert , Stefan Nau
IPC分类号： C08L33/12 , C08L83/00 , C08K5/05
CPC分类号： C08L33/062 , C08L35/00 , C08L2205/03 , C08L2205/18 , C08L2666/04
摘要： The invention relates to a polymer mixture, comprising a) a polymer matrix which is composed of a (meth)acrylate (co)polymer or of a mixture of (meth)acrylate (co)polymers with a Vicat softening point VSP (ISO 306-B50) of at least 104° C. and/or of a (meth)acrylimide (co)polymer, b) an impact modifier which is based on crosslinked poly(meth)acrylates and which does not have covalent bonding to the polymer matrix a), c) from 1 to 15% by weight of plastics particles composed of crosslinked polymers based on polymethyl methacrylate, on polystyrene and/or on polysilicones. The polymer mixture can be used to obtain injection mouldings with matt surfaces and Vicat softening points VSPs (ISO 306-B50) of at least 90° C.
摘要翻译：本发明涉及聚合物混合物，其包含a）聚合物基质，其由（甲基）丙烯酸酯（共）聚合物或具有维卡软化点VSP的（甲基）丙烯酸酯（共）聚合物的混合物组成） B50）至少为104℃和/或（甲基）丙烯酰亚胺（共）聚合物，b）基于交联的聚（甲基）丙烯酸酯并且不与聚合物基质a共价结合的抗冲改性剂），c）1至15重量％的由基于聚甲基丙烯酸甲酯的交联聚合物，聚苯乙烯和/或多晶硅组成的塑料颗粒。聚合物混合物可用于获得具有亚光表面和维卡软化点VSP（ISO 306-B50）至少90℃的注射成型品。

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