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    • 3. 发明申请
    • MOLDED BODY HAVING MATT AND STRUCTURED SURFACE PROPERTIES
    • 具有匹配和结构表面性能的模制体
    • US20100272960A1
    • 2010-10-28
    • US12738033
    • 2008-08-29
    • Klaus SchultesSabine Schwarz-BaracKlaus AlbrechtUrsula GolchertStefan NauSabrina ThomasMichael Schnabel
    • Klaus SchultesSabine Schwarz-BaracKlaus AlbrechtUrsula GolchertStefan NauSabrina ThomasMichael Schnabel
    • B32B3/30C08L33/12
    • C08L33/08C08L33/10C08L2205/02C08L2555/40Y10T428/24479C08L2666/04
    • Composition for the production of mouldings having a matt and structured surface character, comprising a polymer matrix and crosslinked polymer particles, the polymer matrix comprising at least one acrylic polymer and the composition containing (i) first crosslinked polymer particles having a volume average of the particle size in the range from 30 μm to 1500 μm and (ii) second crosslinked polymer particles having a volume average of the particle size of less than 30 μm, the difference between the refractive index of the first polymer particles and the refractive index of the polymer matrix, measured in each case at 25° C., being less than 0.015 as an absolute value and the difference between the refractive index of the second polymer particles and the refractive index of the polymer matrix, measured at 25° C., being greater than or equal to 0.015 as an absolute value. The mouldings of the invention are suitable in particular for use as components for lighting, signs and symbols, points-of-sale, cosmetics display stands, containers, home and office decoration, furniture applications, shower cabinet doors and office doors.
    • 用于生产具有无光泽和结构化表面特征的模制品的组合物,其包含聚合物基质和交联的聚合物颗粒,所述聚合物基质包含至少一种丙烯酸类聚合物,所述组合物包含(i)具有所述颗粒的体积平均值的第一交联聚合物颗粒 尺寸在30μm至1500μm的范围内,和(ii)具有小于30μm的体积平均粒径的第二交联聚合物颗粒,第一聚合物颗粒的折射率与聚合物的折射率之间的差异 在25℃下每种情况下测定的基体作为绝对值小于0.015,并且在25℃下测量的第二聚合物颗粒的折射率与聚合物基质的折射率之间的差异更大 不大于或等于0.015作为绝对值。 本发明的模制品特别适用于照明,标志和符号,销售点,化妆品展示架,集装箱,家庭和办公室装饰,家具应用,淋浴柜门和办公室门的部件。
    • 4. 发明授权
    • Multilayered film made of (meth)acrylate copolymer and polycarbonate
    • 由(甲基)丙烯酸酯共聚物和聚碳酸酯制成的多层薄膜
    • US07682698B2
    • 2010-03-23
    • US12436809
    • 2009-05-07
    • Klaus SchultesMichael WickerKlaus AlbrechtMona RueppelGabriele DassingerEric ReinheimerJohann KappacherAndreas Hoellebauer
    • Klaus SchultesMichael WickerKlaus AlbrechtMona RueppelGabriele DassingerEric ReinheimerJohann KappacherAndreas Hoellebauer
    • B32B27/36C08G64/00
    • B32B27/08B32B27/18B32B27/20B32B27/308B32B27/36B32B27/365B32B2369/00C08L33/10C08L69/00Y10T428/249921Y10T428/31504Y10T428/31507Y10T428/31786C08L2666/04
    • The invention relates to a multilayer film encompassing at least one upper layer a) and one middle layer b) composed of (meth)acrylate copolymers, and also a backing layer c) composed of polycarbonate, where the upper layer a) comprises a light stabilizer and is composed of a (meth)acrylate copolymer which can form semicompatible mixtures with the polycarbonate of the backing layer c), where a test specimen produced from a mixture composed of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate has a tensile strain at break of at least 75% (ISO 527-2) at 23° C., the middle layer b) comprises a dye and, where appropriate, a light stabilizer, and is composed of an identical or different (meth)acrylate copolymer which can form semicompatible mixtures with the polycarbonate of the backing layer c), where a test specimen produced from a mixture composed of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate has a tensile strain at break of at least 75% (ISO 527-2) at 23° C., and the backing layer c) is composed of polycarbonate which can, where appropriate, comprise up to 30% by weight of the material of the layers a) and b). The invention also relates to the production and uses of the multilayer film, and also to semicompatible polymer mixtures composed of (meth)acrylate copolymers and polycarbonate.
    • 本发明涉及包含由(甲基)丙烯酸酯共聚物组成的至少一个上层a)和一个中间层b)以及由聚碳酸酯构成的背衬层c)的多层膜,其中上层a)包含光稳定剂 并且由与背衬层c)的聚碳酸酯形成半不溶性混合物的(甲基)丙烯酸酯共聚物组成,其中由20重量%的(甲基)丙烯酸酯共聚物和80重量%的混合物制成的试样 的聚碳酸酯在23℃下的拉伸断裂应变为至少75%(ISO 527-2),中间层b)包含染料,并且在适当的情况下包含光稳定剂,并且由相同或不同的 (甲基)丙烯酸酯共聚物,其可以与背衬层c)的聚碳酸酯形成半相容的混合物,其中由由20重量%的(甲基)丙烯酸酯共聚物和80重量%的聚碳酸酯组成的混合物制备的试样具有拉伸 a 在23℃下至少75%(ISO 527-2),背衬层c)由聚碳酸酯组成,其可以适当地包含至多30重量%的层a)和b)的材料, 。 本发明还涉及多层膜的制备和使用,以及由(甲基)丙烯酸酯共聚物和聚碳酸酯组成的半不饱和聚合物混合物。
    • 7. 发明授权
    • Multilayered film made of (meth)acrylate copolymer and polycarbonate
    • 由(甲基)丙烯酸酯共聚物和聚碳酸酯制成的多层薄膜
    • US07585565B2
    • 2009-09-08
    • US10577954
    • 2004-09-15
    • Klaus SchultesMichael WickerKlaus AlbrechtMona RueppelGabriele DassingerEric ReinheimerJohann KappacherAndreas Hollebauer
    • Klaus SchultesMichael WickerKlaus AlbrechtMona RueppelGabriele DassingerEric ReinheimerJohann KappacherAndreas Hollebauer
    • B32B27/36C08G64/00
    • B32B27/08B32B27/18B32B27/20B32B27/308B32B27/36B32B27/365B32B2369/00C08L33/10C08L69/00Y10T428/249921Y10T428/31504Y10T428/31507Y10T428/31786C08L2666/04
    • The invention relates to a multilayered film comprising at least one upper layer a), a middle layer b) made of (meth)acrylate copolymer, and a supporting layer c) made of polycarbonate. Upper layer a) contains a light-stability agent and is made of a (meth)acrylate copolymer that, together with the polycarbonate of supporting layer c), can form partially compatible mixtures. A test piece, which is made from a mixture consisting of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate, has a breaking elongation (ISO 527-2) of at least 75% at 23° C. The middle layer b) contains a colorant and, optionally, a light-stability agent and is made from an identical or different (meth)acrylate copolymer that, together with the polycarbonate of supporting layer c), can form partially compatible mixtures. A test piece, which is made from a mixture consisting of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate, has a breaking elongation (ISO 527-2) of at least 75% at 23° C., and the supporting layer c) is made of polycarbonate that, optionally up to 30% by weight of the material of the layers, can contain a) and b). The invention also relates to the production and uses of the multilayered film and to partially compatible polymer mixtures consisting of (meth)acrylate copolymer and polycarbonate.
    • 本发明涉及包含至少一个上层a),由(甲基)丙烯酸酯共聚物制成的中间层b)和由聚碳酸酯制成的支撑层c)的多层膜。 上层a)含有光稳定剂,并且由(甲基)丙烯酸酯共聚物制成,其与支撑层c)的聚碳酸酯一起可以形成部分相容的混合物。 由20重量%的(甲基)丙烯酸酯共聚物和80重量%的聚碳酸酯组成的混合物制成的试件在23℃具有至少75%的断裂伸长率(ISO 527-2) 中间层b)包含着色剂和任选的光稳定剂,并且由相同或不同的(甲基)丙烯酸酯共聚物制成,其与支撑层c)的聚碳酸酯一起可以形成部分相容的混合物。 由20重量%的(甲基)丙烯酸酯共聚物和80重量%的聚碳酸酯组成的混合物制成的试件在23℃具有至少75%的断裂伸长率(ISO 527-2) ,并且支撑层c)由聚碳酸酯制成,任选地,多至30重量%的层的材料可以含有a)和b)。 本发明还涉及多层膜和由(甲基)丙烯酸酯共聚物和聚碳酸酯组成的部分相容的聚合物混合物的制备和用途。
    • 10. 发明申请
    • MULTILAYERED FILM MADE OF (METH)ACRYLATE COPOLYMER AND POLYCARBONATE
    • (甲基)丙烯酸酯共聚物和聚碳酸酯的多层膜
    • US20090215962A1
    • 2009-08-27
    • US12436809
    • 2009-05-07
    • Klaus SCHULTESMichael WickerKlaus AlbrechtMona RueppelGabriele DassingerEric ReinheimerJohann KappacherAndreas Hoellebauer
    • Klaus SCHULTESMichael WickerKlaus AlbrechtMona RueppelGabriele DassingerEric ReinheimerJohann KappacherAndreas Hoellebauer
    • C08L69/00C08L33/12
    • B32B27/08B32B27/18B32B27/20B32B27/308B32B27/36B32B27/365B32B2369/00C08L33/10C08L69/00Y10T428/249921Y10T428/31504Y10T428/31507Y10T428/31786C08L2666/04
    • The invention relates to a multilayer film encompassing at least one upper layer a) and one middle layer b) composed of (meth)acrylate copolymers, and also a backing layer c) composed of polycarbonate, where the upper layer a) comprises a light stabilizer and is composed of a (meth)acrylate copolymer which can form semicompatible mixtures with the polycarbonate of the backing layer c), where a test specimen produced from a mixture composed of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate has a tensile strain at break of at least 75% (ISO 527-2) at 23° C., the middle layer b) comprises a dye and, where appropriate, a light stabilizer, and is composed of an identical or different (meth)acrylate copolymer which can form semicompatible mixtures with the polycarbonate of the backing layer c), where a test specimen produced from a mixture composed of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate has a tensile strain at break of at least 75% (ISO 527-2) at 23° C., and the backing layer c) is composed of polycarbonate which can, where appropriate, comprise up to 30% by weight of the material of the layers a) and b). The invention also relates to the production and uses of the multilayer film, and also to semicompatible polymer mixtures composed of (meth)acrylate copolymers and polycarbonate.
    • 本发明涉及包含由(甲基)丙烯酸酯共聚物组成的至少一个上层a)和一个中间层b)以及由聚碳酸酯构成的背衬层c)的多层膜,其中上层a)包含光稳定剂 并且由与背衬层c)的聚碳酸酯形成半不溶性混合物的(甲基)丙烯酸酯共聚物组成,其中由20重量%的(甲基)丙烯酸酯共聚物和80重量%的混合物制成的试样 的聚碳酸酯在23℃下的拉伸断裂应变为至少75%(ISO 527-2),中间层b)包含染料,并且在适当的情况下包含光稳定剂,并且由相同或不同的 (甲基)丙烯酸酯共聚物,其可以与背衬层c)的聚碳酸酯形成半相容的混合物,其中由由20重量%的(甲基)丙烯酸酯共聚物和80重量%的聚碳酸酯组成的混合物制备的试样具有拉伸 a 在23℃下至少75%(ISO 527-2),背衬层c)由聚碳酸酯组成,其可以适当地包含至多30重量%的层a)和b)的材料, 。 本发明还涉及多层膜的制备和使用,以及由(甲基)丙烯酸酯共聚物和聚碳酸酯组成的半不饱和聚合物混合物。