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    • 2. 发明授权
    • Low monomer polyurethane prepolymer and process therefore
    • 低单体聚氨酯预聚物和工艺因此
    • US06515164B1
    • 2003-02-04
    • US09341080
    • 1999-07-02
    • Gerd BolteGuenter HenkeMarkus KruedenscheidtAstrid Omoruyi
    • Gerd BolteGuenter HenkeMarkus KruedenscheidtAstrid Omoruyi
    • C07C26902
    • C09J175/04B32B7/12C08G18/10C08G18/721C08G18/7607C08G18/7621C08G18/7671
    • A low-monomer PU prepolymer containing free NCO groups which is obtained from polyhydric alcohols and diisocyanates differing in their reactivity and which is distinguished by the ratio of the NCO groups of the partly slower-reacting diisocyanate to the NCO groups of the faster-reacting diisocyanate. It is greater than 6:1. Nevertheless the prepolymer according to the invention cures more quickly than a known prepolymer predominantly containing fast-reacting NCO groups. In a preferred embodiment, TDI is used as the partly slower-reacting diisocyanate while MDI is used as the faster-reacting diisocyanate. The prepolymer is produced in two stages. The prepolymer according to the invention is suitable for bonding plastic articles, metals and paper, especially films. The accelerated absence of migration is particularly noticeable in this regard.
    • 含有游离NCO基团的低单体PU预聚物,其由多元醇和其反应性不同的二异氰酸酯获得,其特征在于部分较慢反应的二异氰酸酯的NCO基团与较快反应的二异氰酸酯的NCO基团的比例 。 大于6:1。 然而,根据本发明的预聚物比主要含有快速反应的NCO基团的已知预聚物更快地固化。 在优选的实施方案中,TDI用作部分较慢反应的二异氰酸酯,而MDI用作较快反应的二异氰酸酯。 预聚物分两个阶段生产。 根据本发明的预聚物适用于粘合塑料制品,金属和纸,特别是薄膜。 在这方面,加速不存在移民尤其明显。