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    • 2. 发明授权
    • Azo dyes with a diazo component of the 3-amino thiophene series and a
coupling component of the pyridine, pyridone or pyrazole series
    • 具有3-氨基噻吩系列的重氮组分的偶氮染料和吡啶,吡啶酮或吡唑系的偶联组分
    • US4994564A
    • 1991-02-19
    • US269646
    • 1988-11-10
    • Karl-Heinz EtzbachHelmut ReicheltGuenter HansenErnst SchefczikHelmut HagenGunther Lamm
    • Karl-Heinz EtzbachHelmut ReicheltGuenter HansenErnst SchefczikHelmut HagenGunther Lamm
    • C09B29/09C09B29/00C09B29/42C09B29/48
    • C09B29/0059C09B29/3621C09B29/3634C09B29/3656
    • Thien-3-ylazo dyes of the formula: ##STR1## where X is cyano, nitro, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are identical or different and each is independently of each other substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.4 -alkenyl, substituted or unsubstituted phenyl or together with the nitrogen atom linking them a 5- or 6-membered saturated heterocyclic radical, and R.sup.2 may additionally be hydrogen, Y is hydrogen, cyano, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, C.sub.1 -C.sub.4 -alkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are each as defined above, Z is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, substituted or unsubstituted phenyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylthio, substituted or unsubstituted phenylthio, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylsulfonyl or phenylsulfonyl or together with the radical Y a fused benzo ring which may be substituted, and K is the radical of a coupling component of the 2,6-diaminopyridine, 6-hydroxypyrid-2-one or 5-aminopyrazole series, are used for dyeing synthetic fiber materials, in particular synthetic polyesters, in yellow to red shades and are notable for good light fastness, fastness to dry heat setting and pleating and for good affinity.
    • 噻吩-3-基偶氮染料,其结构式如下:其中X为氰基,硝基,C 1 -C 6烷酰基,取代或未取代的苯甲酰基,取代或未取代的苯基或基团COOR1或CONR1R2,其中R 1和R 2相同或不同, 各自独立地为取代或未取代的C 1 -C 8 - 烷基,C 5 -C 7 - 环烷基,C 3 -C 4 - 烯基,取代或未取代的苯基或与连接它们的氮原子一起形成5-或6-元饱和杂环基, R 2可另外为氢,Y为氢,氰基,C 1 -C 6烷酰基,取代或未取代的苯甲酰基,C 1 -C 4 - 烷基磺酰基,取代或未取代的苯基磺酰基,取代或未取代的苯基或基团COOR1或CONR1R2,其中R1和R2为 Z是氢,取代或未取代的C 1 -C 8 - 烷基,取代或未取代的苯基,取代或未取代的C 1 -C 6 - 烷硫基,取代或未取代的苯硫基,取代或未取代的C 1 -C 6 - 烷基磺酰基 或与苯基磺酰基或与基团Y一起可以被取代的稠合苯并环,K是2,6-二氨基吡啶,6-羟基吡啶-2-酮或5-氨基吡唑系列的偶联组分的基团 用于将合成纤维材料,特别是合成聚酯染色为黄色至红色,并且具有良好的耐光性,耐干燥定型和打褶的牢度以及良好的亲和力。
    • 7. 发明授权
    • Thiopheneazo dye based on a coupling component of the thiazole series
    • 噻吩偶氮染料基于噻唑系的偶联成分
    • US5216139A
    • 1993-06-01
    • US620457
    • 1990-12-04
    • Karl-Heinz EtzbachGuenter HansenGunther LammHelmut Reichelt
    • Karl-Heinz EtzbachGuenter HansenGunther LammHelmut Reichelt
    • C09B29/00C09B29/36C09B31/14
    • C09B29/3691C09B29/0059C09B31/14Y10S534/01
    • Thiopheneazo dyes of the formula ##STR1## where R.sup.1 is cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, phenylazo, phenylsulfonyl, formyl or the radical ##STR2## where R.sup.7 and R.sup.8 are independently of the other cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, phenyl, halogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl, or R.sup.1 and R.sup.2 together are the radical (CH.sub.2).sub.3 --CO, which may be substituted by 1 or 2 methyl groups and whose carbonyl group is bonded to the thiophene ring in the ortho position relative to the sulfur atom,R.sup.3 is cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, cyclohexyl, phenoxy-C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, or substituted or unsubstituted thienyl,R.sup.5 is C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.7 -alkyl whose alkyl chain is interrupted by 1 or 2 oxygen atoms, or C.sub.1 -C.sub.4 -alkoxy andR.sup.6 is cyanoethyl, phenylethyl or C.sub.3 -C.sub.12 -alkyl whose alkyl chain is interrupted by from 1 to 4 oxygen atoms and which may be substituted by phenyl or phenoxy,with the proviso that, when R.sup.5 and R.sup.6 are each oxygen-interrupted alkyl, R.sup.6 has 2 or more carbon atoms more than R.sup.5, are used for dyeing textile fibers.
    • 其中R 1为氰基,C 1 -C 4 - 烷氧基羰基,苯偶氮,苯磺酰基,甲酰基或基团,其中R 7和R 8独立于其它氰基或C 1 -C 4 - 烷氧基羰基,R 2为C 1的噻吩偶氮染料 -C 1-4烷基,苯基,卤素,C 1 -C 4 - 烷氧基或C 1 -C 4烷氧基羰基,或者R 1和R 2一起是可被1或2个甲基取代的基团(CH 2)3 -CO,其羰基 R 3是氰基或C 1 -C 4烷氧基羰基,R 4是C 1 -C 8 - 烷基,环己基,苯氧基-C 1 -C 4烷基,取代或未取代的苯基,或 取代或未取代的噻吩基,R 5是C 1 -C 4 - 烷基,其烷基被1或2个氧原子间隔的C 3 -C 7 - 烷基或C 1 -C 4 - 烷氧基,R 6是氰基乙基,苯基乙基或C 3 -C 12 - 链被1至4个氧原子中断并且可以被苯基或苯氧基取代,条件是当R5和R6各自为氧中断的烷基时 l,R6具有比R5多2个或更多个碳原子,用于染色纺织纤维。
    • 10. 发明授权
    • Naphtholactam dyes
    • 萘酚内酰胺染料
    • US5929245A
    • 1999-07-27
    • US776596
    • 1997-02-18
    • Clemens GrundErnst SchefczikGunther LammRoland MergerRudiger Sens
    • Clemens GrundErnst SchefczikGunther LammRoland MergerRudiger Sens
    • C07D401/04C07D495/04C07D495/06C09B57/00C09B57/06
    • C07D401/04C07D495/06C09B57/06
    • The invention concerns naphtholactam derivatives of formula (I), in which: R.sup.1 represents hydrogen, optionally substituted C.sub.1 -C.sub.6 alkyl C.sub.5 -C.sub.6 cycloalkcyl or substituted phenyl; R.sup.2 and R.sup.3 represent hydrogen, C.sub.1 -C.sub.8 alkanoyl, optionally substituted benzoyl, optionally substituted C.sub.2 -C.sub.4 alkyl, optionally substituted C.sub.2 -C.sub.4 alkenyl, optionally substituted C.sub.2 -C.sub.4 alkinyl, a halogen, nitro, sulphamoyl, optionally substituted hydroxy, optionally substituted mercapto, C.sub.1 -C.sub.6 alkysulphonyl or optionally substituted phenylsulphonyl; R.sup.4 represents hydrogen or, with R.sup.3, a group of formula (II); R.sup.5 represents hydrogen or C.sub.1 -C.sub.6 alkyl; R.sup.6 represents cyano, carbamoyl, C.sub.1 -C.sub.4 mono- or dialkylcarbamoyl carboxyl or C.sub.1 -C.sub.4 alkoxycarbonyl; and R.sup.7 represents substituted C.sub.1 -C.sub.4 alkyl, optionally substituted C.sub.5 -C.sub.13 alkyl or benzoyl. Also disclosed is the use of these derivatives for dyeing or printing textiles.
    • PCT No.PCT / EP95 / 03112 Sec。 371日期1997年2月18日 102(e)日期1997年2月18日PCT提交1995年8月4日PCT公布。 公开号WO96 / 06137 日期:1996年2月29日本发明涉及式(I)的萘内酰胺衍生物,其中:R 1表示氢,任选取代的C 1 -C 6烷基C 5 -C 6环烷基或取代的苯基; R 2和R 3表示氢,C 1 -C 8烷酰基,任选取代的苯甲酰基,任选取代的C 2 -C 4烷基,任选取代的C 2 -C 4烯基,任选取代的C 2 -C 4炔基,卤素,硝基,氨磺酰基,任选取代的羟基,任选取代的巯基 ,C 1 -C 6烷磺酰基或任选取代的苯基磺酰基; R4表示氢,或与R3表示式(Ⅱ)的基团。 R5表示氢或C1-C6烷基; R6表示氰基,氨基甲酰基,C1-C4单或二烷基氨基甲酰基羧基或C1-C4烷氧基羰基; 并且R 7表示取代的C 1 -C 4烷基,任选取代的C 5 -C 13烷基或苯甲酰基。 还公开了这些衍生物用于染色或印花纺织品的用途。