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1. 发明申请

US20060074267A1 Aluminophosphate molecular sieve, its synthesis and use 有权
公开(公告)号：US20060074267A1
公开(公告)日：2006-04-06
申请号：US11231677
申请日：2005-09-21
申请人： Guang Cao , Matu Shah , John Brody , Douglas Dorset , Karl Strohmaier
发明人： Guang Cao , Matu Shah , John Brody , Douglas Dorset , Karl Strohmaier
IPC分类号： C07C1/00 , C01B37/04 , C01B37/06
CPC分类号： C07C1/20 , B01J29/83 , B01J29/85 , C01B37/04 , C01B37/08 , C01B39/54 , C10G3/00 , C10G3/49 , C10G2400/20 , C07C11/02
摘要： A large pore (metallo)aluminophosphate molecular sieve is disclosed The material has an X-ray diffraction pattern including the lines listed in Table 4 and is synthesized in the presence of 4-dimethylaminopyridine as structure directing agent.

2. 发明申请

US20050009691A1 Synthesis of silicoaluminophosphates 有权
公开(公告)号：US20050009691A1
公开(公告)日：2005-01-13
申请号：US10617852
申请日：2003-07-11
申请人： Guang Cao , Matu Shah , John Brody
发明人： Guang Cao , Matu Shah , John Brody
IPC分类号： B01J29/85 , B01J35/02 , B01J37/00 , C01B37/08 , C01B39/54 , B01J27/182
CPC分类号： B01J29/85 , B01J35/023 , B01J37/0045 , B01J2229/42 , C01B37/08 , C01B39/54 , Y10S423/30
摘要： The invention is directed to a method of synthesising silicoaluminophosphate molecular sieves and in particular those of framework type CHA and AEL. The method uses synthesis templates that comprise one or more tertiary dialkylbutylamines, wherein the alkyl groups are not butyl. The use of such templates. especially N,N-dimethylbutylamine, results in SAPO-11 of a desirable platelet morphology.

3. 发明申请

US20070100185A1 Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
标题翻译：含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途
公开(公告)号：US20070100185A1
公开(公告)日：2007-05-03
申请号：US11521155
申请日：2006-09-14
申请人： Guang Cao , Machteld Mertens , Matu Shah , Marc Anthonis , Hailian Li , Anil Guram , Robert Saxton , Mark Muraoka , Jeffrey Yoder , Anthony Volpe
发明人： Guang Cao , Machteld Mertens , Matu Shah , Marc Anthonis , Hailian Li , Anil Guram , Robert Saxton , Mark Muraoka , Jeffrey Yoder , Anthony Volpe
IPC分类号： C07C1/00 , C01B39/00 , C01B39/48
CPC分类号： C01B39/48 , B01J29/70 , B01J29/7015 , B01J29/80 , C01B37/02 , C01B39/023 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/1011 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R1R2R3N—R4]+Q− wherein R1 and R2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R1 and R2 may be joined to form a nitrogen-containing heterocyclic structure, R3 is an alkyl group having 2 to 4 carbon atoms and R4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R3 and R4 are hydrocarbyl groups having from 1 to 3 carbon atoms joined to form a nitrogen-containing heterocyclic structure; and Q− is a anion.
摘要翻译：包含菱沸石型框架分子筛的结晶材料，特别是高二氧化硅沸石的合成在有机导向剂的存在下进行，所述有机导向剂具有以下结构式：<？in-line-formula description =“In-line 公式“end =”lead“？> [R 1] 2 3 <？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1和R 2 > 2个独立地选自烃基和具有1至3个碳原子的羟基取代的烃基，条件是R 1和R 2可以连接形成含氮杂环结构，R 3是具有2至4个碳原子的烷基，R 4选自4-至8-元环烷基任选被1至3个具有1至3个碳原子的烷基取代; 和具有1至3个杂原子的4至8元杂环基，所述杂环基任选被1至3个具有1至3个碳原子的烷基取代，并且所述杂环基中的每个杂原子被选定由O，N和S组成的组，或R 3和R 4是具有1至3个碳原子的烃基，连接形成含氮杂环结构体; 而Q ^{是阴离子。}

4. 发明申请

US20070286799A1 Aluminophosphate Molecular Sieve, Its Synthesis and Use 失效
标题翻译：磷酸铝分子筛，其合成与应用
公开(公告)号：US20070286799A1
公开(公告)日：2007-12-13
申请号：US11663716
申请日：2005-09-12
申请人： Guang Cao , Matu Shah
发明人： Guang Cao , Matu Shah
IPC分类号： C01B39/00 , C01B33/36
CPC分类号： C01B39/54 , B01J29/83 , B01J29/85 , C01B37/04 , C01B37/08 , C07C1/20 , C10G3/49 , C10G3/56 , C10G3/62 , C10G2400/20 , C10G2400/22 , C07C11/02
摘要： A novel small pore (metallo)aluminophosphate molecular sieve is disclosed. The as-synthesized material has an X-ray diffraction pattern including the lines listed in Table 1 and is produced in the presence of fluoride ions and 4-dimethylaminopyridine as structure directing agent. The silicoaluminophosphate material has methanol conversion activity and n-hexane cracking activity.
摘要翻译：公开了一种新型的小孔（金属）磷酸铝分子筛。合成原料具有包括表1中列出的线的X射线衍射图，并且在氟离子和4-二甲基氨基吡啶作为结构导向剂存在下制备。硅铝磷酸盐材料具有甲醇转化活性和正己烷裂解活性。

5. 发明申请

US20070043249A1 Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins 有权
标题翻译：具有菱沸石骨架类型的分子筛的合成及其在将含氧化合物转化为烯烃的用途
公开(公告)号：US20070043249A1
公开(公告)日：2007-02-22
申请号：US11206444
申请日：2005-08-18
申请人： Guang Cao , Matu Shah
发明人： Guang Cao , Matu Shah
IPC分类号： C07C1/00 , C01B37/04 , C01B37/08
CPC分类号： C01B39/54 , B01J29/83 , B01J29/85 , C01B37/04 , C01B37/08 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2400/20 , Y02P30/42
摘要： The synthesis of a crystalline aluminophosphate or silicoaluminophosphate molecular sieve having a chabazite-type framework type is conducted in the presence of an organic directing agent having the formula (I) [R1R2R3N—R4]+X− (I) wherein R1, R2 and R3 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R4 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms; 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S; and aromatic groups optionally substituted by 1 to 3 alkyl groups, said alkyl groups having from 1 to 3 carbon atoms; and X− is an anion.
摘要翻译：在具有式（I）的有机导向剂的存在下进行具有菱沸石型骨架型的结晶铝磷酸盐或硅铝磷酸盐分子筛的合成<？in-line-formula description =“In-Line Formulas”end = “铅”？> [R 1] 2 3 3 4 （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1，R 2， 2和R 3独立地选自具有1至3个碳原子的烷基和具有1至3个碳原子的羟基烷基; R 4选自4-8元环烷基，任选被1至3个具有1至3个碳原子的烷基取代; 具有1至3个杂原子的4-至8-元杂环基，所述杂环基团任选被1至3个具有1至3个碳原子的烷基取代，所述杂环基中的杂原子选自O， N和S; 和任选被1至3个烷基取代的芳族基团，所述烷基具有1至3个碳原子; 而X - 是阴离子。

6. 发明申请

US20050197519A1 AEI-type zeolite, its synthesis and its use in the conversion of oxygenates to olefins 有权
标题翻译： AEI型沸石，其合成及其在含氧化合物转化为烯烃的应用
公开(公告)号：US20050197519A1
公开(公告)日：2005-09-08
申请号：US11017091
申请日：2004-12-20
申请人： Guang Cao , Karl Strohmaier , Hailian Li , Anil Guram , Robert Saxton , Mark Muraoka , Jeffrey Yoder , Karin Yaccato
发明人： Guang Cao , Karl Strohmaier , Hailian Li , Anil Guram , Robert Saxton , Mark Muraoka , Jeffrey Yoder , Karin Yaccato
IPC分类号： B01J29/035 , B01J29/70 , C01B37/02 , C01B39/04 , C01B39/48 , C07C1/00 , C07C1/20 , C10G3/00
CPC分类号： B01J29/70 , B01J29/035 , C01B37/02 , C01B39/48 , C07C1/20 , C10G3/45 , C10G3/49 , C10G3/62 , C10G2400/20 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： A crystalline material is described that has an AEI framework type, wherein the material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element, Y is a tetravalent element n is from 0 to less than 0.01. The material is normally synthesized in a halide, typically a fluoride, medium and exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译：描述了具有AEI骨架类型的结晶材料，其中以煅烧的无水形式的材料具有涉及摩尔关系的组成：<？in-line-formula description =“In-line Formulas”end =“lead “？”（n）X 2 O 3：YO 2，<βin-line-formula description =“In-Line Formulas” end =“tail”？>其中X为三价元素，Y为四价元素，n为0至小于0.01。该材料通常在卤化物（通常为氟化物）介质中合成，并且在甲醇转化为低级烯烃，特别是乙烯和丙烯中表现出活性和选择性。

7. 发明申请

US20050154244A1 Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins 有权
标题翻译：含有菱沸石的分子筛，其合成及其在含氧化合物转化为烯烃中的应用
公开(公告)号：US20050154244A1
公开(公告)日：2005-07-14
申请号：US11017286
申请日：2004-12-20
申请人： Guang Cao , Machteld Mertens , Karl Strohmaier , Richard Hall , Thomas Colle , Mobae Afeworki , Antonie Bons , Wilfried Mortier , Chris Kliewer , Hailian Li , Anil Guram , Robert Saxton , Mark Murakoa , Jeffrey Yoder
发明人： Guang Cao , Machteld Mertens , Karl Strohmaier , Richard Hall , Thomas Colle , Mobae Afeworki , Antonie Bons , Wilfried Mortier , Chris Kliewer , Hailian Li , Anil Guram , Robert Saxton , Mark Murakoa , Jeffrey Yoder
IPC分类号： C01B37/02 , C01B39/02 , C01B39/46 , C01B39/48 , C10G3/00 , C07C1/00
CPC分类号： C01B39/46 , C01B37/02 , C01B39/023 , C01B39/48 , C10G3/45 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2300/802 , C10G2400/20 , Y02P30/20 , Y02P30/42
摘要： A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译：基本上不含骨架磷的结晶物质，其包含具有堆垛层错的CHA骨架型分子筛或CHA骨架型分子筛和AEI骨架型分子筛的至少一个共生相，其中所述材料以其煅烧的无水形式具有涉及摩尔关系的组成：<？in-line-formula description =“In-line Formulas”end =“lead”？>（n）X＆lt; 2＆lt; 3＆lt; 3＆其中X是三价元素;其中X是三价元素;其中X是三价元素; Y是四价元素; 且n为0至约0.5。该材料在甲醇转化为低级烯烃，特别是乙烯和丙烯时具有活性和选择性。

8. 发明授权

US08293854B2 Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
公开(公告)号：US08293854B2
公开(公告)日：2012-10-23
申请号：US13449424
申请日：2012-04-18
申请人： Machteld M. Mertens , Stephen N. Vaughn , Guang Cao , Luc R. M. Martens , Mobae Afeworki
发明人： Machteld M. Mertens , Stephen N. Vaughn , Guang Cao , Luc R. M. Martens , Mobae Afeworki
IPC分类号： C08F2/00 , C01B37/08 , B01J27/182
CPC分类号： C07C1/20 , B01J29/85 , B01J29/90 , B01J2229/42 , C01B39/54 , C07C2529/85 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.

9. 发明授权

US07772335B1 Light olefin selective oxygenate conversion process using CHA framework type aluminosilicate 有权
标题翻译：使用CHA骨架型铝硅酸盐的轻烯烃选择性含氧化合物转化方法
公开(公告)号：US07772335B1
公开(公告)日：2010-08-10
申请号：US12412788
申请日：2009-03-27
申请人： Guang Cao , John F. Brody , Matu J. Shah
发明人： Guang Cao , John F. Brody , Matu J. Shah
IPC分类号： C08F2/00 , C07C1/20 , C08F10/02
CPC分类号： C01B39/48 , B01J29/7015 , B01J2229/42 , C07C1/20 , C08F10/02 , C08F210/16 , Y02P20/52 , Y02P30/42 , C07C11/04 , C08F2/00 , C08F210/06
摘要： The invention relates to a method for converting an oxygenated hydrocarbon feedstock into an olefin product comprising: (a) forming a CHA framework type aluminosilicate sieve catalyst made from a substantially fluoride-free synthesis mixture comprising silicon and aluminum sources, a slurry medium, and a template, wherein the sieve is substantially free from framework phosphorus and exhibits a Si/Al ratio from about 40-60; (b) optionally formulating the molecular sieve catalyst with an oxidized aluminum-containing precursor matrix material and a clay binder to form a molecular sieve catalyst composition; (c) activating the catalyst by removing/decomposing the template; and (d) contacting the activated catalyst with the feedstock under conditions sufficient to form an olefin product comprising ≧about 65% by weight, on a water-free basis, of ethylene and propylene and having an ethylene-to-propylene ratio ≧about 1.2. Ethylene- and propylene-containing polymers can be formed from the olefin product.
摘要翻译：本发明涉及一种将含氧烃原料转化成烯烃产物的方法，包括：（a）形成由基本上不含氟化物的合成混合物制成的CHA骨架型硅铝酸盐筛催化剂，其包含硅和铝源，浆料介质和模板，其中所述筛基本上不含框架磷并且表现出约40-60的Si / Al比; （b）任选地用氧化的含铝前体基质材料和粘土粘合剂配制分子筛催化剂以形成分子筛催化剂组合物; （c）通过去除/分解模板来活化催化剂; 和（d）使活化的催化剂与原料在足够的条件下接触，所述条件足以在无水基础上形成包含≥65重量％的乙烯和丙烯并且乙烯与丙烯之比≥约1.2的烯烃产物。含烯烃和含丙烯的聚合物可以由烯烃产物形成。

10. 发明申请

US20100179363A1 Oxygenate Conversion Catalyst System And Processes For Making And Using Same 有权
标题翻译：氧化转化催化剂体系和制备和使用相同的方法
公开(公告)号：US20100179363A1
公开(公告)日：2010-07-15
申请号：US12352433
申请日：2009-01-12
申请人： Stephen H. Brown , Guang Cao , Teng Xu
发明人： Stephen H. Brown , Guang Cao , Teng Xu
IPC分类号： C07C1/00 , B01J31/02
CPC分类号： B01J29/85 , B01J29/7015 , B01J37/0201 , B01J37/0203 , C07C1/20 , C07C2529/70 , C07C2529/85 , C07C11/02
摘要： The invention includes a method for impregnating a molecular sieve primary catalyst with an aromatic co-catalyst, the method comprising contacting the small pore molecular sieve primary catalyst having a porous framework structure with a combination of from at least 50 wt % to about 99.9 wt % of an aromatic co-catalyst and from about 0.1 wt % to less than 50 wt % of a polar impregnation agent containing one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, phosphorus, and boron, under conditions sufficient to impregnate the porous framework structure of the primary catalyst with the aromatic co-catalyst (and optionally also with the polar impregnation agent), thus forming an integrated catalyst system. Methods for converting oxygenates to olefins using said integrated catalyst system are also described herein.
摘要翻译：本发明包括用芳族助催化剂浸渍分子筛初级催化剂的方法，该方法包括将具有多孔骨架结构的小孔分子筛初级催化剂与至少50wt％至约99.9wt％的芳族助催化剂和约0.1重量％至小于50重量％的含有一个或多个选自氮，氧，硫，磷和硼的杂原子的极性浸渍剂，在足以浸渍的条件下主要催化剂与芳族助催化剂（以及任选地还与极性浸渍剂）的多孔骨架结构，从而形成一体的催化剂体系。本文还描述了使用所述一体化催化剂体系将含氧化合物转化为烯烃的方法。

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