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1. 发明授权

US4988656A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4988656A
公开(公告)日：1991-01-29
申请号：US351408
申请日：1989-05-12
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , Y10S526/904
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonte or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译：具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括通过（A）由镁碳酸镁或羧酸镁形成含镁物质的溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。

2. 发明授权

US4866022A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4866022A
公开(公告)日：1989-09-12
申请号：US186359
申请日：1988-04-25
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F10/00
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译：具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括由（A）形成镁酸盐或羧酸镁的含镁物质溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。

3. 发明授权

US5013702A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US5013702A
公开(公告)日：1991-05-07
申请号：US434915
申请日：1989-11-09
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
IPC分类号： C08F4/656 , C08F10/00
CPC分类号： C08F10/00
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译：具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括由（A）形成镁酸盐或羧酸镁的含镁物质溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。

4. 发明授权

US4946816A Morphology-controlled olefin polymerization catalyst 失效
标题翻译：形态控制烯烃聚合催化剂
公开(公告)号：US4946816A
公开(公告)日：1990-08-07
申请号：US395990
申请日：1989-08-21
申请人： Steven A. Cohen , Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee
发明人： Steven A. Cohen , Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee
IPC分类号： C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/903
摘要： In a solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprising the product formed by (A) forming a solution of a magnesium-containing species from a magnesium alkyl (or hydrocarbyl) carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing toluene-based solvent by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic either; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor, the morphology of such component is modified by incorporating a morphology-affecting amount of C.sub.8 -C.sub.10 aromatics within the toluene-based solvent in Step B, Step A, in Step C prior to addition of ether, or combinations thereof.
摘要翻译：在具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分中，包括通过（A）由碳酸烷基（或烃基）或镁的镁形成镁的物质溶液形成的产物羧酸酯; （B）用过渡金属卤化物和有机硅烷处理从这种含镁甲苯系溶剂中析出固体颗粒; （C）从含有环状的混合物中再沉淀此类固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒，通过在步骤B，步骤A中在甲苯系溶剂中引入形态影响量的C 8 -C 10芳族化合物来修饰这些组分的形态，在步骤C中加入醚之前，或其组合。

5. 发明授权

US4612299A Magnesium carboxylate supports 失效
标题翻译：羧酸镁载体
公开(公告)号：US4612299A
公开(公告)日：1986-09-16
申请号：US741858
申请日：1985-06-06
申请人： Gregory G. Arzoumanidis , Habet M. Khelghatian , Sam S. Lee
发明人： Gregory G. Arzoumanidis , Habet M. Khelghatian , Sam S. Lee
IPC分类号： C08F4/02 , C08F4/60 , C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , Y10S526/904
摘要： Composition comprising a transition metal component and magnesium carboxylate prepared by reacting a solution of hydrocarbyl magnesium compound with carbon dioxide to precipitate a magnesium carboxylate and reacting magnesium carboxylate with transition metal component.
摘要翻译：含有过渡金属组分和羧酸镁的组合物，其通过使烃基镁化合物的溶液与二氧化碳反应而沉淀羧酸镁并使羧酸镁与过渡金属组分反应制备。

6. 发明授权

US3962203A Dechlorination of high yield polyolefins using neutral phosphoryl esters 失效
标题翻译：使用中性磷酸酯脱除高效多聚烯烃
公开(公告)号：US3962203A
公开(公告)日：1976-06-08
申请号：US534189
申请日：1974-12-19
申请人： Nicholas M. Karayannis , Habet M. Khelghatian , John S. Skryantz
发明人： Nicholas M. Karayannis , Habet M. Khelghatian , John S. Skryantz
IPC分类号： C08F6/02 , C08F6/00 , C08F6/28
CPC分类号： C08F6/02
摘要： Lower alkyl, neutral phosphoryl esters are disclosed herein as effective materials to reduce deleterious chloro compound concentrations in polyolefins and compositions based thereon, which polyolefins and compositions are produced in bulk or vapor-phase processes using high yield catalysts in which catalyst residues and solubles need not be removed prior to processing.

7. 发明授权

US4184987A Stabilizing additives for polyolefins 失效
标题翻译：聚烯烃稳定添加剂
公开(公告)号：US4184987A
公开(公告)日：1980-01-22
申请号：US901587
申请日：1978-05-01
申请人： Nicholas M. Karayannis , Habet M. Khelghatian , John S. Skryantz
发明人： Nicholas M. Karayannis , Habet M. Khelghatian , John S. Skryantz
IPC分类号： C08K5/103 , C08L23/02 , C08K5/52
CPC分类号： C08K5/103 , C08K5/10
摘要： Partial esters of polyhydroxy compounds and combinations thereof with organophosphorus compounds have been found to be effective stabilizers for polyolefins made in processes wherein such polymers are not subjected to extensive removal of process produced impurities during or subsequent to the polymerization process. Combinations of polypropylene produced in a solventless polymerization process and such partial esters are particularly suitable and show substantially improved stability in the presence of additional stabilizing compounds.
摘要翻译：已经发现，多羟基化合物的部分酯及其与有机磷化合物的组合是在聚合过程中或之后不对其进行广泛去除的过程中制备的聚烯烃的有效稳定剂。在无溶剂聚合方法中生产的聚丙烯和这种偏酯的组合是特别合适的，并且在另外的稳定化合物的存在下显示出显着提高的稳定性。

8. 发明授权

US5081090A Dry olefin polymerization catalyst 失效
标题翻译：干烯烃聚合催化剂
公开(公告)号：US5081090A
公开(公告)日：1992-01-14
申请号：US557139
申请日：1990-07-23
申请人： Gregory G. Arzoumanidis , Habet M. Khelghatian , Linda Ornellas
发明人： Gregory G. Arzoumanidis , Habet M. Khelghatian , Linda Ornellas
IPC分类号： C08F4/658 , C08F4/60 , C08F4/643 , C08F4/654 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/903
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprising the product formed by A) forming a solution of a magnesium-containing species from a magnesium alkyl (or hydrocarbyl) carbonate or a magnesium carboxylate; B) precipitating solid particles from such solution by treatment with a transition metal halide; C) reprecipitating such solid particles from a mixture containing a cyclic ether; D) treating the reprecipitated particles with a transition metal compound and an electron donor; and E) drying the resulting solid particles such that the residual volatile hydrocarbon content is between 0.1 and 0.9 weight percent.
摘要翻译：一种具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分，其包含通过A）形成的产物，由碳酸烷基（或烃基）或羧酸镁形成镁的物质溶液; B）用过渡金属卤化物处理从这种溶液中沉淀出固体颗粒; C）从含有环醚的混合物中再沉淀出这种固体颗粒; D）用过渡金属化合物和电子给体处理再沉淀的颗粒; 和E）干燥所得固体颗粒，使得残留的挥发性烃含量为0.1-0.9重量％。

9. 发明授权

US4365045A Crystalline olefin block polymers 失效
公开(公告)号：US4365045A
公开(公告)日：1982-12-21
申请号：US424819
申请日：1965-01-11
申请人： Abraham Schneider , Habet M. Khelghatian , Louise D. Hague , James L. Jezl
发明人： Abraham Schneider , Habet M. Khelghatian , Louise D. Hague , James L. Jezl
IPC分类号： C08F210/00 , C08F297/08
CPC分类号： C08F297/083 , C08F210/00
摘要： 1. A process for producing a block polymer which comprises contacting, under polymerizing conditions, propylene with a catalyst comprising a dispersion of solid particles of a metal subhalide wherein said metal is selected from the group consisting of the metals of Groups IVa, Va and VIa of the Periodic Table according to Mendeleeff and an activator therefor selected from the group consisting of metal alkyls, metal hydrides, metal borohydrides, aryl metal halides, and alkyl metal halides wherein said metal is selected from the group consisting of aluminum, zinc, beryllium, chromium, magnesium, lithium, sodium, potassium, and lead, in an inert hydrocarbon liquid reaction medium, whereby said propylene is polymerized to form a polymeric block, then contacting a second monomeric composition selected from the group consisting of ethylene and mixtures thereof with propylene, with said catalyst system under polymerizing conditions whereby said second monomeric composition polymerizes in the presence of the previously formed polymeric block as a linear extension thereto, the polymerization of propylene being performed in the presence of sufficient hydrogen to give a melt index suitable for melt processing of the resulting block polymer and the polymerization of said second monomeric composition being performed in the substantial absence of added hydrogen, terminating the polymerization reaction and separating from the reaction mixture a solid, substantially crystalline block polymer which is predominantly insoluble in said reaction mixture at polymerization temperature and comprises molecules consisting essentially of a single homopolymer block linearly connected to a single polymer block selected from the group consisting of an interpolymer block and a homopolymer block derived from a monomer different from that of the first-mentioned homopolymer block, said block polymer consisting essentially of 99.8 to 40 weight percent of propylene and 0.2 to 60 weight percent of ethylene.

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