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1. 发明授权

US08809561B2 Hybrid, organic-inorganic, crystalline, porous silicates and metal-silicates 有权
标题翻译：混合有机 - 无机，结晶，多孔硅酸盐和金属硅酸盐
公开(公告)号：US08809561B2
公开(公告)日：2014-08-19
申请号：US13254999
申请日：2010-02-25
申请人： Giuseppe Bellussi , Angela Carati , Mariangela Cozzolino , Caterina Rizzo , Stefano Zanardi
发明人： Giuseppe Bellussi , Angela Carati , Mariangela Cozzolino , Caterina Rizzo , Stefano Zanardi
IPC分类号： C07F7/08 , B01J20/00
CPC分类号： C01B37/00 , C01P2002/72
摘要： The present invention relates to new hybrid, organic-inorganic hybrid silicates and metal-silicates characterized by a crystalline structure containing structural units having formula (a), wherein R is an organic group possibly containing one or more element T selected from Group IIIB, IVB, VB and from transition metals. A process starting from cyclic trisilanes for the preparation of said materials, is also described. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the area of nanotechnology.
摘要翻译：本发明涉及新型混合有机 - 无机杂化硅酸盐和金属硅酸盐，其特征在于含有具有式（a）的结构单元的晶体结构，其中R是可能含有一种或多种选自IIIB族，IVB族元素的有机基团，VB和过渡金属。还描述了从用于制备所述材料的环状三硅烷开始的方法。这些材料可用作催化领域的分子筛，吸附剂，电子领域，传感器领域，纳米技术领域。

2. 发明申请

US20120059181A1 HYBRID, ORGANIC-INORGANIC, CRYSTALLINE, POROUS SILICATES AND METAL-SILICATES 有权
标题翻译：混合有机无机，结晶，多孔硅酸盐和金属硅酸盐
公开(公告)号：US20120059181A1
公开(公告)日：2012-03-08
申请号：US13254999
申请日：2010-02-25
申请人： Giuseppe Bellussi , Angela Carati , Mariangela Cozzolino , Caterina Rizzo , Stefano Zanardi
发明人： Giuseppe Bellussi , Angela Carati , Mariangela Cozzolino , Caterina Rizzo , Stefano Zanardi
IPC分类号： C07F7/08 , C07F9/08 , C07F15/02
CPC分类号： C01B37/00 , C01P2002/72
摘要： The present invention relates to new hybrid, organic-inorganic hybrid silicates and metal-silicates characterized by a crystalline structure containing structural units having formula (a), wherein R is an organic group possibly containing one or more element T selected from Group IIIB, IVB, VB and from transition metals. A process starting from cyclic trisilanes for the preparation of said materials, is also described. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the area of nanotechnology.
摘要翻译：本发明涉及新型混合有机 - 无机杂化硅酸盐和金属硅酸盐，其特征在于含有具有式（a）的结构单元的晶体结构，其中R是可能含有一种或多种选自IIIB族，IVB族元素的有机基团，VB和过渡金属。还描述了从用于制备所述材料的环状三硅烷开始的方法。这些材料可用作催化领域的分子筛，吸附剂，电子领域，传感器领域，纳米技术领域。

3. 发明申请

US20100191009A1 ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE 有权
标题翻译：有机无机混合硅酸盐和具有订购结构的金属硅酸盐
公开(公告)号：US20100191009A1
公开(公告)日：2010-07-29
申请号：US12376704
申请日：2007-08-03
申请人： Giuseppe Bellussi , Angela Carati , Caterina Rizzo , Urbano Diaz Morales , Stefano Zanardi , Wallace O'Neil Parker , Roberto Millini
发明人： Giuseppe Bellussi , Angela Carati , Caterina Rizzo , Urbano Diaz Morales , Stefano Zanardi , Wallace O'Neil Parker , Roberto Millini
IPC分类号： C07F7/08
CPC分类号： C09C1/3081 , C01B33/44 , C01B37/00 , C01B39/00 , C01B39/02 , C01P2002/72 , C01P2002/74 , C01P2002/86 , C01P2006/17 , C07F7/1804
摘要： The present invention relates to new organic-inorganic hybrid silicates and metal-silicates called ECS, characterized by an X-ray powder diffraction pattern with reflections exclusively at angular values higher than 4.0° of 2Θ, preferably at angular values higher than 4.7°, and an ordered structure containing structural units having formula (a) wherein R is an organic group: Formula (a) and possibly containing one or more elements T selected from groups III B, IV B, V B and transition metals, with a Si/(Si+T) molar ratio in said structure higher than 0.3 and lower than or equal to 1, wherein Si is the silicon contained in the structural unit (a). A process is also described, starting from disilanes, for the preparation of these materials, which does not include the use of templates or surfactants. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the field of nanotechnologies.
摘要翻译：本发明涉及称为ECS的新的有机 - 无机杂化硅酸盐和金属硅酸盐，其特征在于具有专门在高于4.0°的角度值为2θ，优选高于4.7°的角度值的反射的X射线粉末衍射图，以及含有具有式（a）的结构单元的有序结构，其中R是有机基团：式（a）并且可能含有选自IIIB，IVB，VB族和过渡金属的一种或多种元素T，其中Si /（Si + T）的摩尔比高于0.3且小于或等于1，其中Si是结构单元（a）中所含的硅。还描述了从二硅烷开始制备这些材料的方法，其不包括使用模板或表面活性剂。这些材料可用作纳米技术领域的电子领域，传感器领域的催化剂领域的分子筛，吸附剂。

4. 发明授权

US08110692B2 Organic-inorganic hybrid silicates and metal-silicates having an ordered structure 有权
标题翻译：有机 - 无机杂化硅酸盐和具有有序结构的金属硅酸盐
公开(公告)号：US08110692B2
公开(公告)日：2012-02-07
申请号：US12376704
申请日：2007-08-03
申请人： Giuseppe Bellussi , Angela Carati , Caterina Rizzo , Urbano Diaz Morales , Stefano Zanardi , Wallace O'Neil Parker , Roberto Millini
发明人： Giuseppe Bellussi , Angela Carati , Caterina Rizzo , Urbano Diaz Morales , Stefano Zanardi , Wallace O'Neil Parker , Roberto Millini
IPC分类号： C07F7/18 , C07F7/02
CPC分类号： C09C1/3081 , C01B33/44 , C01B37/00 , C01B39/00 , C01B39/02 , C01P2002/72 , C01P2002/74 , C01P2002/86 , C01P2006/17 , C07F7/1804
摘要： The present invention relates to new organic-inorganic hybrid silicates and metal-silicates called ECS, characterized by an X-ray powder diffraction pattern with reflections exclusively at angular values higher than 4.0° of 2θ, preferably at angular values higher than 4.7°, and an ordered structure containing structural units having formula (a) wherein R is an organic group: Formula (a) and possibly containing one or more elements T selected from groups III B, IV B, V B and transition metals, with a Si/(Si +T) molar ratio in said structure higher than 0.3 and lower than or equal to 1, wherein Si is the silicon contained in the structural unit (a). A process is also described, starting from disilanes, for the preparation of these materials, which does not include the use of templates or surfactants. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the field of nanotechnologies.
摘要翻译：本发明涉及新的有机 - 无机杂化硅酸盐和称为ECS的金属硅酸盐，其特征在于X-射线粉末衍射图，其特征在于高于4.0°的角度值的反射，优选高于4.7°的角度值，和具有式（a）的结构单元的有序结构，其中R是有机基团：式（a）并且可能含有选自IIIB，IVB，VB族和过渡金属的一种或多种元素T，其中Si /（ Si + T）摩尔比高于0.3且小于或等于1，其中Si是包含在结构单元（a）中的硅。还描述了从二硅烷开始制备这些材料的方法，其不包括使用模板或表面活性剂。这些材料可用作纳米技术领域的电子领域，传感器领域的催化剂领域的分子筛，吸附剂。

5. 发明授权

US09278339B2 Mixed oxides of transition metals, hydrotreatment catalysts obtained therefrom, and preparation process comprising sol-gel processes 有权
公开(公告)号：US09278339B2
公开(公告)日：2016-03-08
申请号：US13499452
申请日：2010-09-23
申请人： Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
发明人： Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
IPC分类号： B01J21/00 , B01J23/00 , B01J29/00 , B01J31/00 , B01J27/049 , B01J27/051 , B01J35/10 , B01J37/03 , B01J37/20 , C10G45/08
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

6. 发明申请

US20120261311A1 MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL-GEL PROCESSES 有权
公开(公告)号：US20120261311A1
公开(公告)日：2012-10-18
申请号：US13499452
申请日：2010-09-23
申请人： Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
发明人： Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
IPC分类号： B01J21/08 , C10G29/16 , C10G29/20 , B01J27/051 , C10G45/00
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

7. 发明授权

US09522394B2 Mixed oxides of transition metals, hydrotreatment catalysts obtained therefrom and preparation process 有权
标题翻译：过渡金属的混合氧化物，由此获得的加氢处理催化剂及其制备方法
公开(公告)号：US09522394B2
公开(公告)日：2016-12-20
申请号：US14007913
申请日：2012-03-22
申请人： Angela Carati , Maria Frederica Gagliardi , Marco Massimo Ferrari , Stefano Zanardi , Marcello Marella , Michele Tomaselli
发明人： Angela Carati , Maria Frederica Gagliardi , Marco Massimo Ferrari , Stefano Zanardi , Marcello Marella , Michele Tomaselli
IPC分类号： B01J31/34 , B01J23/00 , B01J23/888 , B01J37/20 , B01J37/03 , B01J37/10 , B01J35/00 , B01J35/10 , B01J37/00 , C10G45/08 , C10G45/50
CPC分类号： B01J23/8885 , B01J23/002 , B01J31/34 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/031 , B01J37/04 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G45/50 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/41
摘要： New sulfide metal catalysts are described, containing Ni, Mo and W, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by sulfidation of mixed oxide precursors, also new, characterized in that they comprise an amorphous phase and a wolframite isostructural crystalline phase, the crystallinity degree of said mixed oxides being higher than 0 and lower than 100%, preferably higher than 0 and lower than 70%. The catalysts of the invention are useful as hydrotreatment catalysts, and in particular as hydrodesulfurization, hydrodenitrogenation and/or hydrodearomatization catalysts.
摘要翻译：描述了新的硫化物金属催化剂，其包含Ni，Mo和W，选自Si，Al及其混合物的元素Z，以及可能的通过混合氧化物前体的硫化获得的有机残基，其也是新的，其特征在于它们包含无定形所述混合氧化物的结晶度高于0且低于100％，优选高于0且低于70％。本发明的催化剂可用作加氢处理催化剂，特别是加氢脱硫，加氢脱氮和/或加氢脱芳构化催化剂。

8. 发明申请

US20140323291A1 MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM AND PREPARATION PROCESS 有权
标题翻译：过渡金属的混合氧化物，由其获得的加氢催化剂和制备方法
公开(公告)号：US20140323291A1
公开(公告)日：2014-10-30
申请号：US14007913
申请日：2012-03-22
申请人： Angela Carati , Maria Frederica Gagliardi , Marco Massimo Ferrari , Stefano Zanardi , Marcello Marella , Michele Tomaselli
发明人： Angela Carati , Maria Frederica Gagliardi , Marco Massimo Ferrari , Stefano Zanardi , Marcello Marella , Michele Tomaselli
IPC分类号： B01J31/34
CPC分类号： B01J23/8885 , B01J23/002 , B01J31/34 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/031 , B01J37/04 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G45/50 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/41
摘要： New sulfide metal catalysts are described, containing Ni, Mo and W, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by sulfidation of mixed oxide precursors, also new, characterized in that they comprise an amorphous phase and a wolframite iso structural crystalline phase, the crystallinity degree of said mixed oxides being higher than 0 and lower than 100%, preferably higher than 0 and lower than 70%. The catalysts of the invention are useful as hydrotreatment catalysts, and in particular as hydrodesulfurization, hydrodenitrogenation and/or hydrodearomatization catalysts.
摘要翻译：描述了新的硫化物金属催化剂，其包含Ni，Mo和W，选自Si，Al及其混合物的元素Z，以及可能的通过混合氧化物前体的硫化获得的有机残基，其也是新的，其特征在于它们包含无定形所述混合氧化物的结晶度高于0且低于100％，优选高于0且低于70％。本发明的催化剂可用作加氢处理催化剂，特别是加氢脱硫，加氢脱氮和/或加氢脱芳构化催化剂。

9. 发明授权

US07567456B2 Page buffer circuit and method for a programmable memory device 有权
标题翻译：页面缓冲电路和可编程存储器件的方法
公开(公告)号：US07567456B2
公开(公告)日：2009-07-28
申请号：US11166354
申请日：2005-06-24
申请人： Stefano Zanardi , Giulio Martinozzi
发明人： Stefano Zanardi , Giulio Martinozzi
IPC分类号： G11C11/34 , G11C16/04 , G11C7/10
CPC分类号： G11C16/26 , G11C16/10 , G11C2216/14
摘要： A page buffer for an electrically programmable memory includes a plurality of storage units, each comprising a first latch and a second latch. Input switching means loads into the latch the data bit to be written and to be temporarily stored. The input switching means has an input terminal connected to the respective data line for receiving a set voltage provided therethrough. The input switching means provides the set voltage to the first or second input/output terminals of the latch depending on the data bit to be written. An output switch device transfers onto the respective data line the read data bit temporarily stored into the latch and has a first terminal coupled to one among the first and second input/output terminals of the latch, a second terminal connected to the respective data line and a control terminal receiving the output control signal.
摘要翻译：用于电可编程存储器的页面缓冲器包括多个存储单元，每个存储单元包括第一锁存器和第二锁存器。输入切换意味着将要写入并临时存储的数据位加载到锁存器中。输入切换装置具有连接到相应数据线的输入端，用于接收从其提供的设定电压。输入切换装置根据要写入的数据位来向锁存器的第一或第二输入/输出端提供设定电压。输出开关装置将相应的数据线传送到临时存储到锁存器中的读数据位，并且具有耦合到锁存器的第一和第二输入/输出端之一的第一端，连接到相应数据线的第二端和接收输出控制信号的控制终端。

10. 发明授权

US07298650B2 Page buffer for a programmable memory device 有权
标题翻译：用于可编程存储器件的页缓冲器
公开(公告)号：US07298650B2
公开(公告)日：2007-11-20
申请号：US11134158
申请日：2005-05-20
申请人： Osama Khouri , Stefano Zanardi , Giulio Martinozzi
发明人： Osama Khouri , Stefano Zanardi , Giulio Martinozzi
IPC分类号： G11C16/04 , G11C7/10 , G11C7/00 , G11C8/00
CPC分类号： G11C16/26
摘要： A page buffer is provided for an electrically programmable memory that includes multiple memory cells forming multiple memory pages. The page buffer includes a register for at least temporarily storing data read from or to be written to the memory cells of a selected memory page. The register includes multiple latches and multiple buffer elements. Each of the latches is coupled to at least one signal line for transferring the data bit that is stored in the latch. Each of the buffer elements decouples an output of a corresponding one of the latches from the signal line, with the buffer element driving the signal line according to the data bit stored in the corresponding latch. Also provided is a method of transferring data from a register to signal lines in an electrically programmable memory.
摘要翻译：提供了一种用于电可编程存储器的页面缓冲器，其包括形成多个存储器页面的多个存储器单元。页面缓冲器包括用于至少临时存储从或将要写入所选存储器页的存储器单元的数据的寄存器。寄存器包括多个锁存器和多个缓冲器元件。每个锁存器耦合到至少一个信号线，用于传送存储在锁存器中的数据位。每个缓冲元件将锁存器中相应一个的输出与信号线分离，缓冲元件根据存储在相应锁存器中的数据位来驱动信号线。还提供了一种将数据从寄存器传送到电可编程存储器中的信号线的方法。

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