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    • 3. 发明授权
    • Chemical amplification photoresist monomers, polymers therefrom and photoresist compositions containing the same
    • 化学扩增光致抗蚀剂单体,聚合物和含有它们的光致抗蚀剂组合物
    • US06749990B2
    • 2004-06-15
    • US10054095
    • 2002-01-22
    • Jae Chang JungGeun Su LeeKi Soo Shin
    • Jae Chang JungGeun Su LeeKi Soo Shin
    • G03F7004
    • G03F7/0395G03F7/0046Y10S430/108
    • A chemical amplification photoresist monomer, a photoresist polymer prepared thereof, and a photoresist composition using the polymer. More specifically, a chemical amplification photoresist polymer comprising a fluorine-containing monomer represented by Chemical Formula 1, and a composition comprising the polymer. The photoresist composition has excellent etching resistance, heat resistance and adhesiveness, and is developable in aqueous tetramethylammonium hydroxide (TMAH) solution. As the composition has low light absorbance at 193 nm and 157 nm wavelength, it is very useful for forming ultramicro pattern in the process using a light source of far ultraviolet, especially of VUV (157 nm). In the Formula, R1, R2, R3 and R4 is defined in the specification.
    • 化学扩增光致抗蚀剂单体,其制备的光致抗蚀剂聚合物和使用该聚合物的光致抗蚀剂组合物。 更具体地说,包括由化学式1表示的含氟单体的化学扩增光致抗蚀剂聚合物和包含该聚合物的组合物。光致抗蚀剂组合物具有优异的耐蚀刻性,耐热性和粘合性,并且可在四甲基氢氧化铵(TMAH) 解。 由于组合物在193nm和157nm波长处具有低吸光度,因此在使用远紫外光源(尤其是VUV(157nm))的方法中形成超微图案非常有用。在式中,R1,R2, R3和R4在本说明书中定义。
    • 4. 发明授权
    • Photoresist monomers containing fluorine-substituted benzylcarboxylate and photoresist polymers comprising the same
    • 含有氟取代的苄基羧酸酯的光致抗蚀剂单体和包含其的光致抗蚀剂聚合物
    • US06653047B2
    • 2003-11-25
    • US10107650
    • 2002-03-27
    • Geun Su LeeJae Chang JungKi Soo Shin
    • Geun Su LeeJae Chang JungKi Soo Shin
    • G03F7004
    • G03F7/0395G03F7/0046Y10S430/106
    • Photoresist monomers, photoresist polymers prepared therefrom, and photoresist compositions using the polymers are disclosed. More specifically, photoresist polymers comprising a photoresist monomer containing fluorine-substituted benzylcarboxylate represented by Formula 1, and a composition comprising the polymer are disclosed. The photoresist composition has excellent etching resistance, heat resistance and adhesiveness, and can be developed in aqueous tetramethylammonium hydroxide (TMAH) solution. And, the present photoresist composition is suitable to form a fine pattern using deep ultraviolet light source such as VUV (157 nm), since the composition has low light absorbance at 193 nm and 157 nm wavelength. wherein, X1, X2, R1, l and m are defined in the specification.
    • 公开了光阻单体,由其制备的光致抗蚀剂聚合物和使用该聚合物的光致抗蚀剂组合物。 更具体地,公开了包含由式1表示的含氟取代的苄基羧酸酯的光致抗蚀剂单体的光致抗蚀剂聚合物和包含该聚合物的组合物。 光致抗蚀剂组合物具有优异的耐蚀刻性,耐热性和粘合性,并且可以在四甲基氢氧化铵(TMAH)水溶液中显影。 并且,本发明的光致抗蚀剂组合物适合于使用深紫外光源如VUV(157nm)形成精细图案,因为该组合物在193nm和157nm波长处具有低吸光度。其中X1,X2,R1,l 和m在说明书中定义。
    • 5. 发明授权
    • Photoresist polymer and composition having nitro groups
    • 光致抗蚀剂聚合物和具有硝基的组合物
    • US06613493B2
    • 2003-09-02
    • US10037515
    • 2002-01-04
    • Geun Su LeeJae Chang JungKi Soo Shin
    • Geun Su LeeJae Chang JungKi Soo Shin
    • G03F7004
    • G03F7/0392Y10S430/106
    • Photoresist polymers having nitro groups (—NO2), and photoresist compositions containing the same. A photoresist pattern having excellent endurance, etching resistance, reproducibility and resolution can be formed by the use of the photoresist copolymer comprising polymerization repeating units represented by Chemical Formula 1a or 1b: wherein, R1, a, b, c, d, e, f, g and h is defined in the specification. Having nitro groups in the polymer, the photoresist polymer results in a low absorbance in the range of 157 nm wavelength, so that it is extremely useful for a photolithography process using, in particular, VUV light source.
    • 具有硝基(-NO 2)的光致抗蚀剂聚合物和含有它们的光致抗蚀剂组合物。 可以通过使用由化学式1a或1b表示的聚合重复单元的光致抗蚀剂共聚物形成具有优异的耐久性,耐蚀刻性,再现性和分辨率的光致抗蚀剂图案:其中,R1,a,b,c,d,e,f g和h在本说明书中定义。在聚合物中具有硝基,光致抗蚀剂聚合物在157nm波长范围内导致低吸光度,因此其对于使用特别是VUV光的光刻工艺非常有用 资源。
    • 10. 发明授权
    • Photoresist monomers, polymers thereof and photoresist compositions containing the same
    • 光致抗蚀剂单体,其聚合物和含有它们的光致抗蚀剂组合物
    • US06849375B2
    • 2005-02-01
    • US10080319
    • 2002-02-21
    • Geun Su LeeJae Chang JungKi Soo Shin
    • Geun Su LeeJae Chang JungKi Soo Shin
    • G03F7/004G03F7/039
    • G03F7/0395G03F7/0046G03F7/0392G03F7/0397Y10S430/114
    • Photoresist monomers of following Formula 1, photoresist polymers thereof, and photoresist compositions containing the same. The photoresist polymers include a repeating unit comprising the photoresist monomer of Formula 1 as a comonomer and the photoresist compositions containing the same have excellent etching resistance, heat resistance and adhesiveness to a wafer, and are developable in aqueous tetramethylammonium hydroxide (TMAH) solutions. In addition, the photoresist compositions have a low light absorbance at 157 nm wavelength, and thus are suitable for a photolithography process using ultraviolet light sources such as VUV (157 nm) in fabricating a minute circuit for a high integration semiconductor device. wherein Y1, Y2, Y3, Y4, Y5, Y6, Z1, Z2 and m are defined in the specification.
    • 下列通式1的光致抗蚀剂单体,其光致抗蚀剂聚合物和含有它们的光致抗蚀剂组合物。 光致抗蚀剂聚合物包括包含作为共聚单体的式1的光致抗蚀剂单体的重复单元,并且含有该光致抗蚀剂组合物的光致抗蚀剂组合物具有优异的耐蚀刻性,耐热性和与晶片的粘合性,并且可在四甲基氢氧化铵(TMAH)水溶液中显影。 此外,光致抗蚀剂组合物在157nm波长处具有低吸光度,因此适用于在制造用于高集成度半导体器件的微小电路中使用诸如VUV(157nm)的紫外光源的光刻工艺。在Y1, Y2,Y3,Y4,Y5,Y6,Z1,Z2和m在本说明书中定义。