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1. 发明授权

US4584343A Crosslinkable fluorine-containing copolymers, surface-coatings based on these copolymers, and the use thereof 失效
标题翻译：可交联的含氟共聚物，基于这些共聚物的表面涂料及其用途
公开(公告)号：US4584343A
公开(公告)日：1986-04-22
申请号：US686727
申请日：1984-12-27
申请人： Gernot Lohr , Josef Mondt , Hans Graff
发明人： Gernot Lohr , Josef Mondt , Hans Graff
IPC分类号： C08F18/00 , C08F8/12 , C08F14/18 , C08F16/02 , C08F18/02 , C08F214/18 , C08F214/26 , C08F216/06 , C08F218/04 , C09D127/12 , C09D129/04 , C09D131/02 , C09D131/04 , C08F218/10
CPC分类号： C08F218/04 , C08F214/186 , C08F8/12 , C08F2800/10 , C08F2810/50 , Y10T428/31935
摘要： Crosslinkable fluorine-containing copolymers comprising copolymerized units of(a) a vinyl ester of a heavily branched carboxylic acid,(b) a vinyl ester of a short-chain carboxylic acid and(c) of a fluoroolefin, the vinyl ester groups of component (b) having been converted into OH groups by solvolysis of the copolymer. The copolymers are suitable for coating purposes of any type, in particular as binders in surface-coating systems for industrial surface-coatings.
摘要翻译：包含（a）重支链羧酸的乙烯基酯，（b）短链羧酸的乙烯基酯和（c）氟烯烃的共聚单元的交联的含氟共聚物，组分的乙烯基酯基（ b）通过共聚物的溶剂分解已经转化成OH基团。共聚物适用于任何类型的涂料目的，特别是作为工业表面涂料表面涂料体系的粘合剂。

2. 发明授权

US5008155A Aqueous dispersions for the preparation of crosslinkable coatings 失效
标题翻译：用于制备可交联涂料的水分散体
公开(公告)号：US5008155A
公开(公告)日：1991-04-16
申请号：US409082
申请日：1989-09-19
申请人： Dieter Engel , Josef Mondt , Klaus Zimmerschied
发明人： Dieter Engel , Josef Mondt , Klaus Zimmerschied
IPC分类号： C09D5/02 , B05D3/02 , B05D5/06 , B05D7/26 , C09D5/00 , C09D5/03 , C09D5/38 , C09D5/46 , C09D157/06 , C09D201/00
CPC分类号： C09D157/06 , B05D3/0209 , B05D3/0254 , Y10T428/31699 , Y10T428/31855
摘要： Aqueous dispersion for the production of crosslinkable surface coatings, containing, as the binder, a crosslinkable dispersion copolymer formed from olefinically unsaturated monomers and, if appropriate, further customary formulation constituents of lacquers, the dispersed particles of copolymer having average particle diameters from 0.5 to 10 .mu.m and the proportion in the dispersion copolymer of comonomer units carrying crosslinkable groups being greater than 10% by weight, relative to the dispersion copolymer.The preparation of the dispersion by emulsion or suspension copolymerization, in particular with the addition of free radical chain transfer substances, and also the use of the dispersion as a constituent of baking lacquers, hydrofillers, metallic paints and EPC paints.Also a process for the bake-coating of surfaces of solid substrates using the abovementioned aqueous dispersion, wherein the required amount of dispersion is applied to the surface to be coated and is dried at a temperature below its minimum film-forming temperature, and the dried coating is crosslinked by baking at a temperature above the glass transition temperature.
摘要翻译：用于制备可交联表面涂层的水分散体，其含有由烯属不饱和单体形成的可交联分散体共聚物作为粘合剂，如果合适的话，其含有更多的常规配方成分，共聚物的分散颗粒的平均粒径为0.5-10 相对于分散共聚物，携带可交联基团的共聚单体单元的分散共聚物中的比例大于10重量％。通过乳液或悬浮共聚法制备分散体，特别是加入自由基链转移物质，以及使用分散体作为烘烤漆，水溶性填料，金属涂料和EPC涂料的组分。还有一种使用上述水性分散体对固体基质的表面进行烘烤涂覆的方法，其中将所需量的分散体施加到待涂覆的表面上，并在低于其最低成膜温度的温度下干燥，并干燥涂层通过在高于玻璃化转变温度的温度下烘烤而交联。

3. 发明授权

US4522972A Process for the preparation of an aqueous copolymer dispersion 失效
标题翻译：制备含水共聚物分散体的方法
公开(公告)号：US4522972A
公开(公告)日：1985-06-11
申请号：US398415
申请日：1982-07-14
申请人： Josef Mondt , Thaddaus Wirth
发明人： Josef Mondt , Thaddaus Wirth
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F18/00 , C08F18/02 , C08F20/00 , C08F20/32 , C08F220/00 , C08F220/04 , C08F220/08 , C08F220/10 , C08F220/14 , C08L61/20 , C09D125/14 , C09D133/04 , C09D133/06 , C08L37/00 , C08L39/00
CPC分类号： C09D125/14 , C08F220/08 , C08F220/14 , C09D133/066 , C08L61/20
摘要： An aqueous copolymer dispersion can be prepared, with a particular choice of the monomers and the ratios of their amounts, from styrene, esters of acrylic or methacrylic acid, vinyl esters, monomers containing hydroxyl groups, acrylic and/or methacrylic acid, acrylamide or methacrylamide and addition compounds of glycidyl esters of branched monocarboxylic acids with unsaturated carboxylic acids, by polymerization in the presence of an anionic emulsifier and a radical initiator and, if appropriate, a non-ionic emulsifier, which dispersion, in combination with an aminoplast resin, provides thermosetting coatings with excellent properties. These coatings provide highly elastic, weather-resistant, water-resistant surface coatings, which have high adhesion and are free of flaws, on metallic substrates.
摘要翻译：可以制备水性共聚物分散体，具体选择单体及其用量，苯乙烯，丙烯酸或甲基丙烯酸的酯，乙烯基酯，含羟基的单体，丙烯酸和/或甲基丙烯酸，丙烯酰胺或甲基丙烯酰胺以及通过在阴离子乳化剂和自由基引发剂的存在下聚合并且如果合适的话，将非离子乳化剂与氨基塑料树脂组合提供的非离子乳化剂，通过在不饱和羧酸的缩合物中加成化合物，热固性涂料具有优异的性能。这些涂层在金属基材上提供高弹性，耐候性，耐水性表面涂层，其具有高粘合性并且没有缺陷。

4. 发明授权

US4089999A Impregnation and primer coating of absorptive substrates with plastics dispersions 失效
标题翻译：用塑料分散体浸渍和底漆涂覆吸收性基材
公开(公告)号：US4089999A
公开(公告)日：1978-05-16
申请号：US705447
申请日：1976-07-15
申请人： Josef Mondt , Karl Josef Rauterkus , Heinz Lehmann , Werner Stelzel , Hans Vitzthum
发明人： Josef Mondt , Karl Josef Rauterkus , Heinz Lehmann , Werner Stelzel , Hans Vitzthum
IPC分类号： C04B41/63 , B05D7/00 , B28B11/04 , C04B41/00 , C09D5/00 , C09D5/02 , B05D7/26 , B32B3/26
CPC分类号： C09D5/002 , B05D7/08 , B28B11/04 , B32B13/00 , B32B13/04 , B32B13/12 , B32B21/00 , B32B21/04 , B32B21/08 , B32B27/00 , B32B27/06 , B32B27/08 , B32B27/30 , B32B27/32 , B32B3/26 , C04B41/00 , C04B41/009 , C04B41/483 , C04B41/63 , C08F2/24 , C09D5/02 , B32B2255/00 , C04B2111/00491 , Y10T428/249994
摘要： Absorptive substrates, such as asbestos cement, concrete plaster work, can be impregnated to lock the pores and to consolidate the substrate, especially old and weathered plaster work, with aqueous plastics dispersions, if dispersions are used which have an average particle size of about 0.02 to at most 0.1.mu.m, and preferably from 0.036 to 0.080.mu.m. As opposed to conventional dispersions with larger particle sizes, the penetration of dispersions according to the invention reaches the same values as that of the solvent-based impregnating and priming compositions hitherto used. Aqueous dispersions are easier to handle and permit relatively high solids contents at a moderate viscosity.
摘要翻译：吸收性基材，例如石棉水泥，混凝土石膏作业，可以浸渍以锁定孔隙，并且使用水性塑料分散体来固化基材，特别是旧的和风化的石膏作业，如果使用平均粒度为约0.02的分散体至多0.1μm，优选0.036-0.080μm。与具有较大粒度的常规分散体相反，根据本发明的分散体的渗透达到与迄今使用的溶剂基浸渍和起泡组合物相同的值。水性分散体更容易处理，并允许中等粘度的相对较高的固体含量。

5. 发明授权

US4610898A Process for bake coating the surfaces of solid substances 失效
标题翻译：烘烤涂布固体物质表面的工艺
公开(公告)号：US4610898A
公开(公告)日：1986-09-09
申请号：US714043
申请日：1985-03-19
申请人： Dieter Engel , Josef Mondt , Helmut Rinno
发明人： Dieter Engel , Josef Mondt , Helmut Rinno
IPC分类号： B05D7/14 , B05D3/02 , B05D7/24 , B05D7/26 , C09D5/00 , C09D5/02 , C09D201/00
CPC分类号： C09D5/02
摘要： Process for bake coating the surfaces of solid materials by applying the required amount of an aqueous dispersion to the surface to be coated, the dispersion containing, as the binder, a coarse-grained, crosslinkable dispersion copolymer formed from olefinically unsaturated monomers and, if appropriate, further customary lacquer formulation constituents, and the crosslinkable dispersion copolymer being composed of a mixture of at least 2 components which can contain identical or different monomer units, of which at least one component A, which is coarse-grained, has a relatively low average molecular weight, and at least one component B, which can be coarse-grained or fine-grained, has a relatively high average high molecular weight, and the ratio by weight of the components A:B being preferably within the range from 99:1 to 1:1, drying the applied amount of dispersion at a temperature below its minimum film-formation temperature and cross-linking the dried coating by baking at a temperature above the glass transition temperature of the copolymer.
摘要翻译：通过将所需量的水分散体施加到待涂覆的表面上来烘烤涂覆固体材料的表面的方法，该分散体含有作为粘合剂的由烯属不饱和单体形成的粗粒度可交联的分散体共聚物，如果合适，进一步的常规漆配方组分，以及可交联分散共聚物由至少两种可以含有相同或不同单体单元的组分的混合物组成，其中至少一种粗粒度的组分A具有相对较低的平均值分子量和至少一种可以是粗粒度或细粒度的组分B具有相对高的平均高分子量，并且组分A:B的重量比优选在99:1的范围内至1：1，在低于其最低成膜温度的温度下干燥所施加的分散体量，并通过在温度下烘烤使干燥的涂层交联高于共聚物的玻璃化转变温度。

6. 发明授权

US4411955A Reactive hardenable binder mixture, process for preparing hardened products and use of the mixture for the preparation of coatings 失效
标题翻译：活性可硬化粘合剂混合物，制备硬化产品的方法和使用该混合物制备涂料
公开(公告)号：US4411955A
公开(公告)日：1983-10-25
申请号：US316806
申请日：1981-11-02
申请人： Josef Mondt , Gerd Walz , Thaddaus Wirth
发明人： Josef Mondt , Gerd Walz , Thaddaus Wirth
IPC分类号： C08G59/00 , C08G59/14 , C08G59/24 , C08G59/34 , C08G59/42 , C08G59/48 , C08G59/68 , C08L33/00 , C08L33/02 , C08L63/00 , C08L67/00 , C09D163/00 , C09J163/00 , B32B27/28
CPC分类号： C08G59/027 , C08G59/145 , C08G59/24 , C08G59/42 , C08G59/4246 , C08G59/685 , C09D163/00 , Y10T428/31511
摘要： A reactive hardenable binder composition based on(A) at least one aliphatic, cycloaliphatic or aliphatic-cycloaliphatic polyepoxide wherein at least 2 epoxidized cycloaliphatic radicals are bound via an aliphatic bridge,(B) at least one polycarboxylic acid unit of formula ##STR1## having an acid number between 30 and 400 whereinR.sup.1 is a radical of an at least oligomer product selected from the group consisting of polyesters and polymers having initially free OH-groups,R.sup.2 is a radical of a dicarboxylic carbocyclic acid having a COOH-group in ortho-position to its ester bond and(C) a catalyst component of the formula ##STR2## wherein R.sup.3 is a radical of a homo- or copolymer or combination of both of an unsaturated carboxylic acid with a statistically distributed number of COOH side groups or the radical of a polyester having initially free COOH-groups andMe is one equivalent of an alkaline or an alkaline earth metal, thus being present in its salt form, a process for the preparation of hardened products from said composition and a coated article having a coating based on said composition.
摘要翻译：一种基于（A）至少一种脂肪族，脂环族或脂族 - 脂环族聚环氧化物的反应性可硬化粘合剂组合物，其中至少2个环氧化脂环族基团通过脂族桥键合，（B）至少一种式（IMAGE）的多元羧酸单元 I），其酸值在30和400之间，其中R1是选自具有起始游离OH-基团的聚酯和聚合物的至少低聚物产物的基团，R 2是具有COOH- （C）催化剂组分，其中R 3是具有统计分布数的不饱和羧酸的均聚物或共聚物或两者的组合的基团的COOH侧基或具有起始游离COOH基团的聚酯的基团，Me为1当量碱金属或碱土金属，因此以其盐形式存在，制备方法所述组合物的硬化产物的定量和具有基于所述组合物的涂层的涂覆制品。

7. 发明授权

US4357455A Process for the preparation of copolymers containing hydroxyl groups and the use thereof 失效
标题翻译：制备含羟基的共聚物的方法及其用途
公开(公告)号：US4357455A
公开(公告)日：1982-11-02
申请号：US265793
申请日：1981-05-21
申请人： Josef Mondt , Helmut Rinno
发明人： Josef Mondt , Helmut Rinno
IPC分类号： C08F2/00 , C08F2/06 , C08F8/00 , C08F8/14 , C08F220/00 , C08F220/04 , C08G18/62 , C08F220/28 , C08F246/00
CPC分类号： C08F8/14
摘要： Process for preparing copolymers soluble in organic solvents and containing hydroxyl groups, by the polymerization and esterification of (a) at least one .alpha.,.beta.-olefinically unsaturated carboxylic acid with (b) at least one olefinically unsaturated copolymerizable monomer and (c) at least one epoxy group-containing compound, at an elevated temperature, in the presence of a polymerization catalyst and, advantageously, a polymerization modifier, characterized in that glycidol, ##STR1## is used as component (c), either alone or in admixture with one or more glycidyl esters with 12 to 19 carbon atoms and derived from saturated fatty acids, the number of epoxy groups being at least equivalent to the number of carboxyl groups, and in mixtures of glycidol with glycidyl esters, the number of equivalents of glycidyl esters is at most twice as great as the number of equivalents of glycidol. The invention further relates to the use of the products obtained for the preparation of air- or oven-drying coating compositions.
摘要翻译：通过（a）至少一种α，β-烯属不饱和羧酸与（b）至少一种烯属不饱和可共聚单体的聚合和酯化制备用于制备可溶于有机溶剂并含有羟基的共聚物的方法，（c）至少一种含环氧基团的化合物，在升高的温度下，在聚合催化剂和有利地，聚合改性剂存在下，其特征在于将缩水甘油作为组分（c），单独使用或与一种或更多的具有12至19个碳原子并且衍生自饱和脂肪酸的缩水甘油酯，环氧基的数目至少等于羧基数，并且在缩水甘油与缩水甘油酯的混合物中，缩水甘油酯的当量数为至少是缩水甘油的当量数的两倍。本发明还涉及获得用于制备空气或烘干涂料组合物的产品的用途。

8. 发明授权

US4193902A Finely particulate plastics dispersions prepared by metering a mixture containing four monomers into an aqueous liquor containing an anionic emulsifier 失效
标题翻译：通过将含有四种单体的混合物计量到含有阴离子乳化剂的含水液体中制备的细颗粒塑料分散体
公开(公告)号：US4193902A
公开(公告)日：1980-03-18
申请号：US866836
申请日：1978-01-04
申请人： Josef Mondt , Karl J. Rauterkus , Helmut Rinno
发明人： Josef Mondt , Karl J. Rauterkus , Helmut Rinno
IPC分类号： C08F212/08 , C08F220/12 , C09D125/14 , C09D133/06 , C09D133/12 , C08L33/08
CPC分类号： C09D133/12 , C08F212/08 , C08F220/12 , C09D125/14 , C09D133/064
摘要： A process is described by which plastics dispersions of high water and saponification resistance are obtained which, due to their small average particle size diameter of 0.01 to 0.06 microns are especially useful as primers for porous substrates. In their penetration characteristics, the present dispersions can be compared with conventional solvent-based primers at comparable solids content. The dispersions are obtained in a one-step polymerization process.
摘要翻译：通过这种方法描述了获得高水和抗皂化性的塑料分散体，由于其平均粒度直径为0.01至0.06微米，特别适用于多孔基材的底漆。在它们的渗透特性中，可以将现有的分散体与常规的溶剂型底漆进行比较，其含量相当。分散体是在一步聚合过程中获得的。

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