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    • 4. 发明授权
    • Latent cross-linking aqueous dispersions containing polyurethane
    • 含聚氨酯的潜在交联水性分散体
    • US06552119B1
    • 2003-04-22
    • US09744977
    • 2001-02-15
    • Ulrike LichtKarl HäberleEckehardt Wistuba
    • Ulrike LichtKarl HäberleEckehardt Wistuba
    • C08J300
    • C08G18/10C08G18/0828C08L75/04C08G18/73C08G18/797C08L33/00
    • A latent-crosslinking aqueous polyurethane dispersion comprises I) a disperse phase (P.I) including Ia) a polyurethane (Ia) which has hydrophilic groups which make it dispersible in water and also has carbodiimide groups but essentially no carboxyl groups or Ib) a physical mixture of Ibi) a polyurethane (Ibi) which has hydrophilic-groups which make it dispersible in water but has essentially no carbodiimide or carboxyl groups and Ibii) a carbodiimide (Ibii) which has essentially no hydrophilic groups which make it dispersible in water II) a coherent aqueous phase (P.II) including in dissolved form a polycarboxylic acid II which has no carbodiimide groups but has a solubility of at least 1 g/l at 25° C. in the coherent aqueous phase P.II.
    • 潜交联水性聚氨酯分散体包括I)包含I)分散相(PI)的聚氨酯(Ia),其具有使其分散在水中并且还具有碳二亚胺基团但基本上不含羧基的亲水基团,或Ib)Ibi)的物理混合物 具有亲水基团的聚氨酯(Ibi),其使其分散在水中但基本上不含碳二亚胺或羧基,并且具有基本上不具有使其在水中分散的亲水基团的碳二亚胺(Ibii)II)相干水相(P. II)包括溶解形式的聚羧酸II,其不具有碳二亚胺基团,但在25℃下在相干水相P.II中具有至少1g / l的溶解度。
    • 9. 发明授权
    • Polymer-coated precast concrete
    • 聚合物涂层预制混凝土
    • US5215827A
    • 1993-06-01
    • US802397
    • 1991-12-04
    • Bernhard DotzauerEckehardt WistubaManfred SchwartzRolf PetriBertold BechertHans-Juergen Denu
    • Bernhard DotzauerEckehardt WistubaManfred SchwartzRolf PetriBertold BechertHans-Juergen Denu
    • C04B41/48C04B41/63C09D133/06
    • C04B41/009C04B41/483C04B41/63C09D133/062C04B2111/00586C04B2111/21Y10T428/31855
    • Precast concrete which is coated with a copolymer A with a glass transition temperature of rom -25.degree. to +30.degree. C. and composed ofa) from 0.1 to 10% by weight of a monomer of the formula I ##STR1## where R.sup.1 and R.sup.2 are each --H or C.sub.1 -C.sub.4 -alkyl, R.sup.3 is a bridge of from 1 to 20 carbons,R.sup.4 is --C(O)R.sup.6, --C(O)OR.sup.6 or -CNR.sup.5 is --H, --C(OR)R.sup.9, --C(O)OR.sup.9 or --CNX is --O-- or --NR.sup.7 --,Z is a single bond, --CH.sub.2 --, --O--, --NR.sup.8 -- or --O--C(O)-- andR.sup.6, R.sup.7, R.sup.8 and R.sup.9 are each --H, alkyl, aryl, alkaryl or aralkyl of up to 12 carbons,b) from 85 to 99.9% by weight of at least two monomers selected from the group comprising esters of acrylic and methacrylic acid with alcohols containing from 1 to 24 carbons, vinyl esters of carboxylic acids containing from 1 to 20 carbons, vinylaromatic compounds containing up to 20 carbons, ethylenically unsaturated nitriles containing from 3 to 6 carbons, vinyl halides, non-aromatic hydrocarbons containing from 2 to 8 carbons and at least one olefinic double bond andc) from 0 to 10% by weight of other copolymerizable tin-free monomers,is produced as described.
    • 涂有共聚物A的预制混凝土,其玻璃化转变温度为-25℃至+ 30℃,并由a)0.1至10重量%的式I的单体组成,其中R 1 且R 2为-C(O)R 6,-C(O)OR 6或-CN R 5为-H,-C(O) 或)R 9,-C(O)OR 9或-CN X为-O-或-NR 7 - ,Z为单键,-CH 2 - , - O - , - NR 8 - 或-OC(O) R 7,R 8和R 9各自为至多12个碳的-H,烷基,芳基,烷芳基或芳烷基,b)85至99.9重量%的至少两种选自丙烯酸和甲基丙烯酸的酯与含有醇的组的单体 1至24个碳原子,含有1-20个碳原子的羧酸乙烯基酯,含有至多20个碳的乙烯基芳族化合物,含有3-6个碳原子的烯键式不饱和腈,卤代乙烯,含有2-8个碳原子的非芳族烃,和 至少一个烯属双键和c)0至10 其他可共聚的无锡单体的重量%如上所述制备。