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    • 3. 发明授权
    • N-Methyl-N-(sulphonic acid amide-n'-sulphenyl)-carbamic acid esters
    • N-甲基-N-(磺酰胺 - 正 - 硫苯基) - 氨基甲酸酯
    • US4212887A
    • 1980-07-15
    • US948190
    • 1978-10-02
    • Alfons HartmannEngelbert KuhleIngeborg HammannWolfgang BehrenzBernhard Homeyer
    • Alfons HartmannEngelbert KuhleIngeborg HammannWolfgang BehrenzBernhard Homeyer
    • A01N47/24A01P5/00A01P7/02A01P7/04C07C67/00C07C325/00C07C381/08C07D307/86C07D317/08C07D317/24C07D317/46C07D339/06A01N9/16A01N57/06C07C119/18C07F9/02
    • C07D317/24A01N47/24C07D307/86C07D339/06
    • N-Methyl-N-(sulphonic acid amide-N'-sulphenyl)-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1 to 4 carbon atoms in each alkyl radical, phenyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trihalogenomethyl substituent,R.sup.2 is alkyl with 2 to 8 carbon atoms, cycloalkyl, phenyl or cycloalkyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trifluoromethyl substituent, andR.sup.3 is phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl; phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl substituted at least once by trihalogenomethyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto, alkynylmercapto or dialkylamino, each with up to 4 carbon atoms per aliphatic moiety, or an oxime radical of the formula ##STR2## R.sup.4 and R.sup.5 each independently is cyano or alkyl, alkoxy, alkylthio, alkoxycarbonyl, dialkylcarbamoyl or dialkoxyphosphoryl with up to 4 carbon atoms per alkyl moiety, orR.sup.4 and R.sup.5, conjointly with the adjacent carbon atom, form an optionally methyl- or phenyl-substituted dithiolane, dithiane, oxathiolane or oxathiane ring.
    • 具有式(I)的N-甲基-N-(磺酰胺-N'-硫苯基) - 氨基甲酸酯,其中R 1是每个烷基中具有1至4个碳原子的二烷基氨基,苯基或苯基 至少一个卤素,具有1至4个碳原子的烷基,硝基或三卤代甲基取代基,R 2是具有2至8个碳原子的烷基,环烷基,苯基或环烷基或带有至少一个卤素的苯基,具有1至4个碳原子的烷基,硝基或 三氟甲基取代基,R 3为苯基,萘基,苯并二恶烷基,二氢苯并呋喃基或茚满基; 苯基,萘基,苯并二氧杂环戊烷基,二氢苯并呋喃基或茚满烷基,其被三卤代甲基,卤素,硝基,氰基,环烷基,甲酰氨基,二烷基或二氧戊环,或烷基,烯基,炔基,烷氧基,链烯氧基,炔氧基,烷基巯基,烯基巯基,炔基巯基或 每个脂族部分具有至多4个碳原子的二烷基氨基,或下式的肟基团R 4和R 5各自独立地为氰基或烷基,烷氧基,烷硫基,烷氧基羰基,二烷基氨基甲酰基或每烷基具有至多4个碳原子的二烷氧基磷酰基 部分,或R 4和R 5与相邻的碳原子一起形成任选的甲基 - 或苯基取代的二硫戊环,二噻烷,氧硫杂环戊烷或氧硫杂环。
    • 4. 发明授权
    • N-Methyl-N-(sulphonic acid amide-n'-sulphenyl)-carbamic acid esters
    • N-甲基-N-(磺酸酰胺-n {40-磺苯基) - 氨基甲酸酯
    • US4148910A
    • 1979-04-10
    • US756049
    • 1976-12-30
    • Alfons HartmannEngelbert KuhleIngeborg HammannWolfgang BehrenzBernhard Homeyer
    • Alfons HartmannEngelbert KuhleIngeborg HammannWolfgang BehrenzBernhard Homeyer
    • A01N47/24A01P5/00A01P7/02A01P7/04C07C67/00C07C325/00C07C381/08C07D307/86C07D317/08C07D317/24C07D317/46C07D339/06
    • C07D317/24A01N47/24C07D307/86C07D339/06
    • N-Methyl-N-(sulphonic acid amide-N'-sulphenyl)-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1 to 4 carbon atoms in each alkyl radical, phenyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trihalogenomethyl substituent,R.sup.2 is alkyl with 2 to 8 carbon atoms, cycloalkyl, phenyl or cycloalkyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trifluoromethyl substituent, andR.sup.3 is phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl; phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl substituted at least once by trihalogenomethyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto, alkynylmercapto or dialkylamino, each with up to 4 carbon atoms per aliphatic moiety, or an oxime radical of the formula ##STR2## R.sup.4 and R.sup.5 each independently is cyano or alkyl, alkoxy, alkylthio, alkoxycarbonyl, dialkylcarbamoyl or dialkoxyphosphoryl with up to 4 carbon atoms per alkyl moiety, orR.sup.4 and R.sup.5, conjointly with the adjacent carbon atom, form an optionally methyl- or phenyl-substituted dithiolane, dithiane, oxathiolane or oxathiane ring.
    • 具有式(I)的N-甲基-N-(磺酰胺-N'-硫苯基) - 氨基甲酸酯,其中R 1是每个烷基中具有1至4个碳原子的二烷基氨基,苯基或苯基 至少一个卤素,具有1至4个碳原子的烷基,硝基或三卤代甲基取代基,R 2是具有2至8个碳原子的烷基,环烷基,苯基或环烷基或带有至少一个卤素的苯基,具有1至4个碳原子的烷基,硝基或 三氟甲基取代基,R 3为苯基,萘基,苯并二恶烷基,二氢苯并呋喃基或茚满基; 苯基,萘基,苯并二氧杂环戊烷基,二氢苯并呋喃基或茚满烷基,其被三卤代甲基,卤素,硝基,氰基,环烷基,甲酰氨基,二烷基或二氧戊环,或烷基,烯基,炔基,烷氧基,链烯氧基,炔氧基,烷基巯基,烯基巯基,炔基巯基或 每个脂族部分具有至多4个碳原子的二烷基氨基,或下式的肟基团R 4和R 5各自独立地为氰基或烷基,烷氧基,烷硫基,烷氧基羰基,二烷基氨基甲酰基或每烷基具有至多4个碳原子的二烷氧基磷酰基 部分,或R 4和R 5与相邻的碳原子一起形成任选的甲基 - 或苯基取代的二硫戊环,二噻烷,氧硫杂环戊烷或氧硫杂环。
    • 8. 发明授权
    • Sulfonic acid-N'-methylamido-N'-sulfenyl-N-methyl-carbamic acid esters
    • 磺酸-N'-甲基酰氨基-N'-磺酰基-N-甲基 - 氨基甲酸酯
    • US4212883A
    • 1980-07-15
    • US900386
    • 1978-04-24
    • Peter SiegelEngelbert KuhleIngeborg HammannBernhard HomeyerWolfgang Behrenz
    • Peter SiegelEngelbert KuhleIngeborg HammannBernhard HomeyerWolfgang Behrenz
    • A01N47/24C07D317/24C07D317/46A01N9/16C07D339/02
    • C07D317/24A01N47/24C07D317/46
    • Sulfonic acid-N'-methylamide-N'-sulfenyl-N-methyl-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1-4 carbon atoms in each alkyl group, phenyl substituted in the o- or m-position by halogen or by alkyl with 1-4 carbon atoms, or phenyl substituted in the o-, m- or p-position by NO.sub.2, CF.sub.3 or CN, andR.sup.2 is phenyl, naphthyl, benzodioxolanyl or indanyl; phenyl, naphthyl, benzodioxolanyl or indanyl substituted by trihalogenomethyl, halogen, nitro, cyano, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto or dialkylamino wherein each hydrocarbon portion has 1-4 carbon atoms; cycloalkyl of 5-7 carbon atoms, or ##STR2## in which R .sup.3 and R.sup.4 each independently is cyano or alkyl, alkoxy, alkylthio or alkoxycarbonyl with 1-4 carbon atoms in each alkyl group, or R.sup.3 and R.sup.4 together form a ring, or, provided that R.sup.1 is a NO.sub.2 -substituted phenyl, R.sup.3 and R.sup.4 may be dihydrobenzofuranyl or dihydrobenzofuranyl substituted by alkyl of 1-4 carbon atoms,which possess insecticidal, acaricidal, nematicidal, fungicidal and herbicidal properties.
    • 其中R 1是每个烷基中具有1-4个碳原子的二烷基氨基,在o取代的苯基的磺酸-N'-甲酰胺-N'-磺酰基-N-甲基 - 氨基甲酸酯 - 或 - 位置被卤素或具有1-4个碳原子的烷基取代,或在由O-,m-或p-位置被NO 2,CF 3或CN取代的苯基,R 2是苯基,萘基,苯并二恶烷基或茚满基; 苯基,萘基,苯并二氧杂环戊烷基或被三卤甲基,卤素,硝基,氰基,甲酰氨基,二烷基或二氧戊环基取代的茚满基,或被烷基,烯基,炔基,烷氧基,链烯氧基,炔氧基,烷基巯基,烯基巯基或二烷基氨基取代, 碳原子 或者其中R 3和R 4各自独立地为氰基或烷基,烷氧基,烷硫基或烷基中具有1-4个碳原子的烷氧基羰基,或者R 3和R 4一起形成环, 或者如果R 1是NO 2取代的苯基,则R 3和R 4可以是被1-4个碳原子的烷基取代的二氢苯并呋喃基或二氢苯并呋喃基,其具有杀虫,杀螨,杀线虫,杀真菌和除草性质。