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1. 发明授权

US6037504A Process for producing aliphatic diols 失效
标题翻译：脂肪族二醇的制造方法
公开(公告)号：US6037504A
公开(公告)日：2000-03-14
申请号：US204903
申请日：1998-12-03
申请人： Gerhard Darsow , Wolfgang Dummer , Wilfried Niemeier
发明人： Gerhard Darsow , Wolfgang Dummer , Wilfried Niemeier
IPC分类号： B01J23/86 , B01J23/88 , B01J23/889 , C07B61/00 , C07C29/149 , C07C31/20 , C07C67/08 , C07C29/14
CPC分类号： C07C29/149 , B01J23/8892 , Y02P20/52
摘要： In a process for producing aliphatic .alpha.,.omega.-diols comprising 4 to 12 C atoms from aliphatic .alpha.,.omega.-dicarboxylic acids comprising 4 to 12 C atoms, an oligoester of average chain length n=3 to n=4.5 and with an acid number of 40 to 60 mg KOH/g reaction mixture is first formed from a diol and a dicarboxylic acid, which oligoester is thereafter catalytically hydrogenated in the liquid phase. Hydrogenation is carried out continuously at 180 to 250.degree. C. and at an H.sub.2 pressure of 100 to 400 bar, over a pelletised catalyst which is free from Zn oxide and which comprises pressed powders of Cu, Mn and Al oxides with a content of at least one oxide of metals of subgroup VI of the periodic table of the elements (Mendeleev). The amount of H.sub.2 is 20 to 100 times the amount required stoichiometrically.
摘要翻译：在由4-12个碳原子的脂肪族α，ω-二羧酸组成的含有4-12个碳原子的脂肪族α，ω-二醇的制备方法中，平均链长n = 3〜n = 4.5，酸值为 40至60mg KOH / g反应混合物首先由二醇和二羧酸形成，然后将低聚酯在液相中催化氢化。在180-250℃，在100-400巴的H 2压力下，在不含Zn氧化物的颗粒状催化剂上连续进行氢化，其包含Cu，Mn和Al氧化物的压制粉末，其含量为元素周期表第VI族金属的最少一种金属（Mendeleev）。 H2的量为化学计量所需量的20-100倍。

2. 发明授权

US5705700A Process for preparing a mixture of cyclohexylamine and dicyclohexylamine 失效
标题翻译：制备环己胺和二环己胺的混合物的方法
公开(公告)号：US5705700A
公开(公告)日：1998-01-06
申请号：US755512
申请日：1996-11-22
申请人： Gerhard Darsow , Gerd-Michael Petruck , Wilfried Niemeier
发明人： Gerhard Darsow , Gerd-Michael Petruck , Wilfried Niemeier
IPC分类号： B01J23/889 , C07B61/00 , C07C209/72 , C07C211/35
CPC分类号： C07C209/72
摘要： To prepare a mixture of cyclohexylamine and dicyclohexylamine by catalytic hydrogenation of aniline at elevated temperature and elevated H.sub.2 pressure, the catalyst system used comprises two reduced, unsupported catalysts A and B which are prepared from pressed element (hydr)oxide powders. Catalyst A comprises one or more of Fe, Co, Ni, also Mn, Cu and one or more of Ca, Sr, Ba. Catalyst B comprises one or more of Fe, Co, Ni, also Mn, Si and Mg.
摘要翻译：为了通过在升高的温度和升高的H 2压力下苯胺的催化氢化来制备环己胺和二环己胺的混合物，所用的催化剂体系包括由压制元素（氢氧化物）粉末制备的两种还原的未负载的催化剂A和B. 催化剂A包含Fe，Co，Ni中的一种或多种，也包括Mn，Cu和Ca，Sr，Ba中的一种或多种。催化剂B包含Fe，Co，Ni中的一种或多种，Mn还包括Mn，Si和Mg。

3. 发明授权

US5625097A Process for preparing diphenylamines and catalysts usable for this purpose 失效
标题翻译：制备可用于此目的的二苯胺和催化剂的方法
公开(公告)号：US5625097A
公开(公告)日：1997-04-29
申请号：US524556
申请日：1995-09-07
申请人： Hans-Josef Buysch , Christine Mendoza-Frohn , J urgen Scharschmidt , Ulrich Notheis , Rudolf J. Klee , Gerhard Darsow
发明人： Hans-Josef Buysch , Christine Mendoza-Frohn , J urgen Scharschmidt , Ulrich Notheis , Rudolf J. Klee , Gerhard Darsow
IPC分类号： B01J23/40 , B01J23/46 , B01J23/54 , B01J23/58 , B01J23/656 , B01J27/02 , B01J27/053 , B01J27/055 , B01J27/25 , C07B61/00 , C07C209/24 , C07C209/28 , C07C211/55 , C07C209/22
CPC分类号： C07C209/28 , B01J23/464 , B01J23/6562 , B01J27/055
摘要： The preparation of optionally substituted diphenylamine by reaction of optionally substituted aniline with optionally substituted cyclohexanone using a supported Rh catalyst containing rhodium or a combination of rhodium with another platinum metal from the group of palladium, platinum, ruthenium or iridium and which can additionally contain chromium, manganese, alkali metal and a sulphur compound is described. The catalyst of the invention is prepared from halide-free starting materials. The Rh catalyst is distinguished by a low dependence of the initial selectivity, the selectivity in the run-in state and the running-in time on the conditions of the reductive pretreatment and requires only short running-in times to the optimum state.
摘要翻译：通过任选取代的苯胺与任选取代的环己酮的反应制备任选取代的二苯胺，使用含有铑的负载Rh催化剂或铑与钯，铂，钌或铱的另一种铂金属的组合，并可另外含有铬，描述了锰，碱金属和硫化合物。本发明的催化剂由无卤素起始原料制备。 Rh催化剂的特征在于初始选择性的低依赖性，导入状态下的选择性和还原预处理条件下的进入时间，并且仅需要短时间进入最佳状态。

4. 发明授权

US5371294A Process for the preparation of a mixture of cyclohexylamine and dicyclohexylamine 失效
标题翻译：制备环己胺和二环己胺的混合物的方法
公开(公告)号：US5371294A
公开(公告)日：1994-12-06
申请号：US955957
申请日：1992-10-02
申请人： Otto Immel , Hans-Josef Buysch , Gerhard Darsow
发明人： Otto Immel , Hans-Josef Buysch , Gerhard Darsow
IPC分类号： B01J23/648 , C07B61/00 , C07C209/16 , C07C209/72 , C07C211/35 , C07C209/18
CPC分类号： C07C209/72 , C07C209/16
摘要： Cyclohexylamine and dicyclohexylamine can be prepared as a mixture with one another by reaction of phenol with aniline, ammonia or a mixture of aniline and ammonia in the presence of hydrogen over a catalyst, the reaction being carried out according to the invention over a palladium catalyst which has a support of niobic acid or tantalic acid or a mixture of niobic acid and tantalic acid or a support containing such acids. The reaction is carried out at 100.degree.-220.degree. C. under an H.sub.2 partial pressure of 0.5-500 bar.
摘要翻译：环己胺和二环己基胺可以通过在氢气存在下在催化剂上与苯胺，氨或苯胺和氨的混合物的反应彼此混合来制备，该反应根据本发明通过钯催化剂进行具有铌酸或钽酸或铌酸和钽酸的混合物或含有这些酸的载体的载体。反应在100-220℃，0.5-500巴的H 2分压下进行。

5. 发明授权

US5344987A Process for preparing diphenylamines 失效
标题翻译：二苯胺制备方法
公开(公告)号：US5344987A
公开(公告)日：1994-09-06
申请号：US092735
申请日：1993-07-16
申请人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
发明人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
IPC分类号： B01J27/053 , C07B61/00 , C07C209/24 , C07C209/26 , C07C209/60 , C07C211/55 , C07C213/02 , C07C217/92 , C07C209/72
CPC分类号： C07C209/26
摘要： Optionally substituted diphenylamines can be obtained by reacting optionally substituted anilines with optionally substituted cyclohexanones over a supported catalyst at 200.degree.-450.degree. C. and 0.1-20 bar, the supported catalyst containing one or more metals having a dehydrogenating action selected from the group Ru, Pd, Os, Ir, Pt, Fe, Co, Ni, Re, Mn, Cu, Ag, Cr and Ce.
摘要翻译：任选取代的二苯胺可以通过使任选取代的苯胺与任选取代的环己酮在200-450℃和0.1-20巴的负载催化剂上反应，所述载体催化剂含有一种或多种具有脱氢作用的金属选自Ru ，Pd，Os，Ir，Pt，Fe，Co，Ni，Re，Mn，Cu，Ag，Cr和Ce。

6. 发明授权

US5300706A Process for the preparation of d,1-menthol 失效
标题翻译：制备d，1-薄荷醇的方法
公开(公告)号：US5300706A
公开(公告)日：1994-04-05
申请号：US28850
申请日：1993-03-10
申请人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
发明人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
IPC分类号： B01J23/656 , B01J27/055 , C07B61/00 , C07C29/20 , C07C35/12 , C07C29/00 , C07C29/17
CPC分类号： C07C35/12
摘要： A process for the preparation of d,l-menthol by catalytic hydrogenation of aromatic or partly hydrogenated cyclic compounds which have the carbon skeleton of menthol having at least one double bond and are substituted by oxygen in the 3-position relative to the methyl group, with simultaneous rearrangement of optically active or inactive stereoisomers of menthol at elevated temperature and under pressure is described. The hydrogenation, which is to be carried out continuously, is carried out on a fixed bed catalyst which comprises, as active constituents, palladium, ruthenium or rhodium or a mixture of these elements, and comprises alkali metal hydroxides and/or alkali metal sulphates as promoters; the support for this catalyst is doped with a rare earth metal and manganese.
摘要翻译：一种通过芳香族或部分氢化的环状化合物的催化氢化制备d，l-薄荷醇的方法，其具有至少一个双键的薄荷醇的碳骨架并相对于甲基在3-位上被氧取代，描述了在升高的温度和压力下同时重新配置薄荷醇的光学活性或无活性立体异构体。要连续进行的氢化在固定床催化剂上进行，固定床催化剂包含作为活性组分的钯，钌或铑或这些元素的混合物，并且包括碱金属氢氧化物和/或碱金属硫酸盐作为发起人; 该催化剂的载体掺杂有稀土金属和锰。

7. 发明授权

US5162517A Process for the preparation of epimer-free sugar alcohols from the group consisting of xylitol, sorbitol (D-glucitol), 4-O-.beta.-D-galactopyranosyl-D-glucitol and 4-O-.alpha.-D-glucopyranosyl-D-sorbitol 失效
标题翻译：由XYLITOL，SORBITOL（D-GLUCITOL），4-O-（BETA）-D-葡萄糖醛酸-D-GLUCITOL和4-O-（ALPHA）-D-葡萄糖苷组合的组中制备无无糖酒精的方法，葡萄糖醛酸-D-SORBITOL
公开(公告)号：US5162517A
公开(公告)日：1992-11-10
申请号：US585747
申请日：1990-09-20
申请人： Gerhard Darsow
发明人： Gerhard Darsow
IPC分类号： C07H15/04 , B01J23/74 , C07B61/00 , C07C29/132 , C07C29/145 , C07C31/18 , C07C31/26
CPC分类号： C07C31/26
摘要： The sugar alcohols given in the title can be prepared in epimer-free form from the corresponding sugars by catalytic hydrogenation in aqueous solution using hydrogen, the hydrogenation being carried out continuously at 100-500 bar of H.sub.2 and 60.degree.-125.degree. C. on a fixed bed of carrier-free mouldings composed of pressed powders of the elements of the iron group of the periodic table. The mouldings have a compressive strength of above 50 N and an internal surface of 10-90 m.sup.2 /g.
摘要翻译：标题中给出的糖醇可以通过使用氢气的水溶液中的催化氢化从相应的糖制备为无差向异构体形式，氢化在100-500巴的H 2和60°-125℃下连续进行由周期表铁基元素的压粉组成的无载体模制品的固定床。模制品的抗压强度高于50N，内表面为10-90m2 / g。

8. 发明授权

US6031140A Process for producing isocamphyl cyclohexanoles 失效
标题翻译：异柠檬环己醇的制备方法
公开(公告)号：US6031140A
公开(公告)日：2000-02-29
申请号：US194635
申请日：1998-11-30
申请人： Gerhard Darsow , Wilfried Niemeier
发明人： Gerhard Darsow , Wilfried Niemeier
IPC分类号： B01J23/889 , C07C29/20 , C07C35/21 , C07C35/08
CPC分类号： C07C29/20 , C07C2101/14 , C07C2102/42
摘要： A continuous process for preparing isocamphyl-cyclohexanols from isocamphy-guaiacol or isocamphyl-phenol compounds by hydrogenating one of said compounds with hydrogen at elevated temperature and elevated pressure, comprising the use of support-free molded bodies which serve as catalysts and which are obtainable by reduction of molded bodies made of compressed powders of cobalt, manganese and copper (hydr)oxides and optionally of (hydr)oxides of the alkaline earth metals are used.
摘要翻译： PCT No.PCT / EP97 / 02870 Sec。 371日期：1998年11月30日 102（e）1998年11月30日日期PCT 1997年6月3日PCT公布。公开号WO97 / 46505 PCT 日期1997年12月11日通过在升高的温度和升高的压力下用氢气氢化所述化合物之一来制备异孔衣康愈醇或异山梨醇酚化合物的邻苯二甲酰 - 环己醇的连续方法，包括使用用作催化剂的无支撑体模塑体并且可以通过还原由钴，锰和铜（氢氧化物）氧化物和任选的碱土金属的（hydr）氧化物的压缩粉末制成的成型体而获得。

9. 发明授权

US5874648A Process for preparing isocamphylcyclohexanols 失效
标题翻译：异柠檬酰环己醇的制备方法
公开(公告)号：US5874648A
公开(公告)日：1999-02-23
申请号：US928103
申请日：1997-09-12
申请人： Gerhard Darsow
发明人： Gerhard Darsow
IPC分类号： B01J23/755 , B01J23/88 , C07B61/00 , C07C29/20 , C07C35/21 , C07C35/22
CPC分类号： C07C29/20 , C07C2101/14 , C07C2102/42
摘要： To prepare isocamphylcyclohexanols by hydrogenating compounds containing the carbon skeleton of the isocamphylguaiacols or isocamphylphenols, oxygen-free and support-free molded bodies disposed in a fixed bed and made of compacted powders of the elements of the ferrous subgroup of group VIII of the periodic system or their mutual alloys or their alloys with elements of group VIB are used as catalysts; in addition, hydrogenationally inert elements may be present. The molded bodies have a compressive strength of 20 to 250N and an internal surface area of 10 to 90 m.sup.2 /g.
摘要翻译：通过氢化含有异烟酰焦醇或异柠檬酚的碳骨架的化合物来制备异柠檬酸环己醇，其是无氧的和无支撑的成型体，其设置在固定床中并由周期性系统的第VIII族的亚铁亚族元素的压实粉末制成，它们的相互合金或其与VIB族元素的合金用作催化剂; 此外，可能存在氢化惰性元素。成型体的抗压强度为20〜250N，内表面积为10〜90m2 / g。

10. 发明授权

US5739404A Process for preparing a mixture of amino-methyl-cyclohexanes and diamino-methyl-cyclohexanes 失效
标题翻译：制备氨基甲基 - 环己烷和二氨基 - 甲基 - 环己烷混合物的方法
公开(公告)号：US5739404A
公开(公告)日：1998-04-14
申请号：US822253
申请日：1997-03-20
申请人： Gerhard Darsow , Gerd-Michael Petruck
发明人： Gerhard Darsow , Gerd-Michael Petruck
IPC分类号： B01J23/889 , C07B61/00 , C07C209/72 , C07C211/35 , C07C211/36
CPC分类号： C07C209/72 , C07C2101/08
摘要： For the continuous preparation of a mixture of amino-methyl-cyclohexanes and diamino-methyl-cyclohexanes by catalytic hydrogenation of diamino-toluenes with hydrogen at temperatures of from 150.degree. to 260.degree. C. and an H.sub.2 pressure of from 20 to 500 bar, use is made of reduced support-free catalysts which are produced from pressed powders of cobalt, manganese, copper and alkaline earth metal (hydr)oxides, with or without a content of at least one (hydr)oxide of metals of transition group V and/or VI of the Periodic Table of the Elements (Mendeleev).
摘要翻译：为了连续制备氨基甲基 - 环己烷和二氨基 - 甲基 - 环己烷的混合物，通过二氧化二甲苯与氢气在150°至260℃的温度和20至500巴的H 2压力下进行催化氢化，使用由具有或不具有过渡族V的金属的至少一种（氢）氧化物的含量的钴，锰，铜和碱土金属（氢））氧化物的压制粉末制备的还原的无载体催化剂，以及 /或元素周期表VI（Mendeleev）。

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