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1. 发明授权

US4524205A Process for the preparation of 1-amino-1,3,5-triazine-2,4(1H,3H)-diones 失效
标题翻译： 1-氨基-1,3,5-三嗪-2,4（1H，3H） - 二酮的制备方法
公开(公告)号：US4524205A
公开(公告)日：1985-06-18
申请号：US544334
申请日：1983-10-21
申请人： Gerhard Bonse , Reinhard Lantzsch , Henning Dorr , Wolfgang Kreiss , Karlfried Dickore , Klaus Ditgens , Eckart Kranz
发明人： Gerhard Bonse , Reinhard Lantzsch , Henning Dorr , Wolfgang Kreiss , Karlfried Dickore , Klaus Ditgens , Eckart Kranz
IPC分类号： A01N43/64 , C07D213/20 , C07D251/38 , C07D251/26
CPC分类号： C07D213/20 , A01N43/64 , C07D251/38
摘要： A process for the preparation of a herbicidally active 1-amino-1,3,5-triazone-2,4 (1H,3H)-dione of the formula ##STR1## comprising in a first stage at a temperature from about 0.degree. to 100.degree. C. reacting an isocyanate of the formulaR.sup.1 - NCO (II)with an isothio semicarbazone of the tautomeric formulas ##STR2## in which R.sup.3 and R.sup.4 each independently is hydrogen, alkyl, cycloalkyl, aralkyl o alkyl, cycloalkyl, aralkyl or aryl,thereby to form a urea derivative of the tautomeric formulas ##STR3## in a second stage at a temperature between about -50.degree. and 0.degree. C. reacting the urea derivative with phosgene (COCl.sub.2) in the presence of an auxiliary organic base and in the presence of a diluent, at least about 2 mols of phosgene and at least about 2 mols of the auxiliary base being used per mol of urea derivative, thereby to form a 1-alkylideneamino-1,3,5-triazine-2,4(1H,3H)-dione of the formula V ##STR4## and in a third stage converting the 1-alkylideneamino group to a 1-amino group.
摘要翻译：制备式（I）的除草活性1-氨基-1,3,5-三嗪-2,4（1H，3H） - 二酮的方法，其包含在第一阶段中在约使式R 1 -NCO（II）的异氰酸酯与互变异构结构式（III）的异噻唑烷酮反应，其中R 3和R 4各自独立地为氢，烷基，环烷基，芳烷基烷基，环烷基，芳烷基或芳基，从而在约-50℃至0℃的温度下在第二阶段中形成互变异构体式（IV）的脲衍生物。将脲衍生物与光气（COCl 2）在辅助有机碱的存在和在稀释剂存在下，每摩尔脲衍生物使用至少约2摩尔的光气和至少约2摩尔的辅助碱，从而形成1-亚烷基氨基-1，（V）的3,5-三嗪-2,4（1H，3H） - 二酮，在第一阶段将1-亚烷基氨基转化为1-氨基没有组。

2. 发明授权

US4386953A Herbicidally active substituted 6-halogeno-tert.-butyl-1,2,4-triazin-5-ones 失效
标题翻译：除草活性的取代的6-卤代叔丁基-1,2,4-三嗪-5-酮
公开(公告)号：US4386953A
公开(公告)日：1983-06-07
申请号：US299919
申请日：1981-09-08
申请人： Eckart Kranz , Kurt Findeisen , Robert Schmidt , Ludwig Eue
发明人： Eckart Kranz , Kurt Findeisen , Robert Schmidt , Ludwig Eue
IPC分类号： C07D253/06 , A01N43/707 , C07D253/075 , A01N43/64
CPC分类号： C07D253/075 , A01N43/707
摘要： A substituted 6-halogeno-tert.-butyl-1,2,4-triazin-5-one of the formula ##STR1## in which R.sup.1 is an amino or methyl group,R.sup.2 is an alkylmercapto, alkylamino or dialkylamino group,X is a halogen atom, andY and Z each independently is a hydrogen or halogen atom,which possesses selective herbicidal activity. A synthesis involving the novel intermediates ##STR2## in which X, Y and Z have the above-mentioned meaning andQ is CN, CONH.sub.2 or COOH,is also shown.
摘要翻译： R 1为氨基或甲基的取代的6-卤代叔丁基-1,2,4-三嗪-5-酮，其中R 1为烷基巯基，烷基氨基或二烷基氨基，X为卤素原子，Y和Z各自独立地为具有选择性除草活性的氢或卤素原子。涉及其中X，Y和Z具有上述含义且Q为CN，CONH 2或COOH的新中间体“IMAGE”的合成也显示。

3. 发明授权

US4162280A Preparation of phosphorylated amidines 失效
标题翻译：磷酸化脒的制备
公开(公告)号：US4162280A
公开(公告)日：1979-07-24
申请号：US887899
申请日：1978-03-17
申请人： Eckart Kranz
发明人： Eckart Kranz
IPC分类号： A01N57/26 , B01J27/00 , B01J31/00 , C07F9/24 , C07F9/44
CPC分类号： A01N57/26 , C07F9/2458
摘要： Preparation of a phosphorylated amidine of the formula ##STR1## wherein X is oxygen or sulfur and R, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are various organic radicals, which comprises reacting a phosphoric acid ester-amide of the formula ##STR2## with a carboxamide of the formula ##STR3## at a temperature between about 0.degree. and 50.degree. C., and then reacting the mixture with a base. Advantageously the reaction is effected at about 0.degree. to 15.degree. C. in the presence of an aliphatic or aromatic optionally chlorinated hydrocarbon or an alcohol as an inert solvent, and in the presence of a catalyst.
摘要翻译：制备式IMAMA的磷酸化脒，其中X是氧或硫，R，R 1，R 2，R 3和R 4是各种有机基团，其包括使下式的磷酸酯 - 酰胺与羧酰胺在约0℃至50℃之间的温度下，使式“IMAGE”进行反应，然后使该混合物与碱反应。有利地，反应在约0℃至15℃下在脂族或芳族任选氯化烃或作为惰性溶剂的醇存在下进行，并在催化剂存在下进行。

4. 发明授权

US4132736A Preparation of 4-alkylthiosemicarbazides 失效
标题翻译： 4-烷基硫代氨基脲的制备
公开(公告)号：US4132736A
公开(公告)日：1979-01-02
申请号：US729933
申请日：1976-10-06
申请人： Gunther Cramm , Eckart Kranz , Gunter Hellrung
发明人： Gunther Cramm , Eckart Kranz , Gunter Hellrung
IPC分类号： C07B61/00 , B01J27/00 , C07C67/00 , C07C325/00 , C07C337/06 , C07D285/12 , C07D285/135 , C07C159/00
CPC分类号： C07D285/135
摘要： 4-Alkylthiosemicarbazides of the formulaAlkyl--NH--CS--NH--NH.sub.2are produced by heating at about 40 to 90.degree. C the novel hydrazinium salts of N-alkyldithiocarbamic acids of the formulaAlkyl--NH--CS--S.sup.- + NH.sub.3 --NH.sub.2in a solvent while removing by-product H.sub.2 S as by use of vacuum or passage of an inert gas through the reaction mixture, advantageously in the presence of a catalytic amount of sulfur to speed up the reaction. Hydrazine hydrate may also be present. The hydrazinium salt starting material can be prepared by reacting the corresponding alkylamine, ammonia, carbon disulfide and hydrazine, and the reaction solution directly employed in the heating step of the present invention without isolation of the intermediate.
摘要翻译：通过在约40至90℃下加热式烷基-NH-CS-S-NH-NH 2的N-烷基二硫代氨基甲酸的新的肼鎓盐，制备式烷基-NH-CS-NH-NH 2的4-烷基硫代氨基脲在溶剂中，同时通过使用真空或通过惰性气体通过反应混合物除去副产物H 2 S，有利地在催化量的硫存在下加速反应。也可以存在水合肼。肼盐起始原料可以通过使相应的烷基胺，氨，二硫化碳和肼与本发明的加热步骤中直接使用的反应溶液反应而不分离中间体来制备。

5. 发明授权

US5081265A Microbicidal substituted dioxolanes 失效
标题翻译：微生物取代的二氧化物
公开(公告)号：US5081265A
公开(公告)日：1992-01-14
申请号：US582581
申请日：1990-09-14
申请人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
发明人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
IPC分类号： C07D317/26 , A01N43/50 , A01N43/653 , C07C45/00 , C07C45/75 , C07C49/245 , C07C49/255 , C07C49/84 , C07C67/00 , C07C323/22 , C07C323/65 , C07D405/00 , C07D407/04 , C07D409/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Fungicidal dioxolanes of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted arylsulphinyl, optionally substituted arylsulphonyl, optionally substituted arylalkyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted arylsulphinylalkyl, optionally substituted arylsulphonylalkyl, optionally substituted aralkyloxyalkyl, optionally substituted aralkylthioalkyl, optionally substituted aralkylsulphinylalkyl or optionally substituted aralkylsulphonylalkyl,R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl or cycloalkyl, orR.sup.3 and R.sup.4 together represent divalent alkanediyl and/orR.sup.5 and R.sup.6 together represent divalent alkanediyl andA represents nitrogen or a CH group,and addition products thereof with acids and metal salts. Also novel intermediates of the formulas ##STR2##

6. 发明授权

US5076833A Herbicidal and plant growth-regulating 6-(pent-3-yl)-1,2,4-triazin-5(4H)-ones 失效
标题翻译：除草剂和植物生长调节6-（PENT-3-YL）-1,2,4-三嗪-5（4H） - 酮
公开(公告)号：US5076833A
公开(公告)日：1991-12-31
申请号：US517262
申请日：1990-05-01
申请人： Eckart Kranz , Karl-Julius Reubke , Klaus Lurssen , Hans-Joachim Santel , Robert R. Schmidt , Birgit Krauskopf
发明人： Eckart Kranz , Karl-Julius Reubke , Klaus Lurssen , Hans-Joachim Santel , Robert R. Schmidt , Birgit Krauskopf
IPC分类号： C07D253/06 , A01N43/707 , C07D253/075
CPC分类号： C07D253/075 , A01N43/707
摘要： A herbicidal or plant growth-regulating 6-(pent-3-yl)-1,2,4-triazin-5(4H)-one of the formula ##STR1## in which R.sup.1 represents amino andR.sup.2 represents alkylthio having more than 1 carbon atom, alkylamino or dialkylamino,orR.sup.1 represents methylamino andR.sup.2 represents alkylthio.
摘要翻译：式（I）的除草或植物生长调节6-（戊-3-基）-1,2,4-三嗪-5（4H） - 酮，其中R 1表示氨基，R 2表示具有多于1个碳原子，烷基氨基或二烷基氨基，或R 1表示甲基氨基，R 2表示烷硫基。

7. 发明授权

US4988715A Microbicidal substituted dioxolanes 失效
标题翻译：杀菌剂取代二氧戊环
公开(公告)号：US4988715A
公开(公告)日：1991-01-29
申请号：US389032
申请日：1989-08-03
申请人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
发明人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
IPC分类号： C07D317/26 , A01N43/50 , A01N43/653 , C07C45/00 , C07C45/75 , C07C49/245 , C07C49/255 , C07C49/84 , C07C67/00 , C07C323/22 , C07C323/65 , C07D405/00 , C07D407/04 , C07D409/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Fungicidal dioxolanes of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, or other radicalsR.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl or cycloalkyl, orR.sup.3 and R.sup.4 together represent divalent alkanediyl and/orR.sup.5 and R.sup.6 together represent divalent alkanediyl andA represents nitrogen or a CH group,and addition products thereof with acids and metal salts. Also novel intermediates of the formulas ##STR2##
摘要翻译：其中R 1表示任选取代的烷基或其它基团R 2，R 3，R 4，R 5和R 6彼此独立地表示的式（I）的杀真菌二氧戊环代表氢，烷基或环烷基，或者R 3和R 4一起代表二价烷二基和/或R 5和R 6一起表示二价烷二基，A表示氮或CH基，并且其与酸和金属盐的加成产物。（VIa）（VIIa）（VIIa）（VIIa）（VIIa）（VIIa）中的新颖的中间体

8. 发明授权

US4530715A Cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones as fungicides and plant growth regulators 失效
标题翻译：环烷基（α-三唑基-β-羟基） - 酮作为杀真菌剂和植物生长调节剂
公开(公告)号：US4530715A
公开(公告)日：1985-07-23
申请号：US438448
申请日：1982-11-02
申请人： Eckart Kranz , Karl H. Buchel , Udo Kraatz , Erik Regel , Wilhelm Brandes , Paul-Ernst Frohberger , Klaus Lurssen
发明人： Eckart Kranz , Karl H. Buchel , Udo Kraatz , Erik Regel , Wilhelm Brandes , Paul-Ernst Frohberger , Klaus Lurssen
IPC分类号： A01N43/653 , C07C45/63 , C07D249/08 , C07D521/00 , A01N43/64 , A01N55/02 , C07F3/00
CPC分类号： C07D231/12 , A01N43/653 , C07C45/63 , C07D233/56 , C07D249/08
摘要： Cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones of the general formula ##STR1## in which R.sup.1 represents an optionally substituted cycloalkyl group, andR.sup.2 represents a halogenoalkyl, halogenoalkenyl or alkoxycarbonyl group,and their physiologically acceptable acid addition salts and metal salt complexes are new, are prepared as described and find use as fungicides and plant growth regulators.
摘要翻译：其中R 1表示任选取代的环烷基，R 2表示卤代烷基，卤代烯基或烷氧基羰基，以及它们的生理上可接受的酸加成盐（Ⅰ）所示的环烷基（α-三唑基-β-羟基） - 酮和金属盐络合物是新的，按照描述制备并用作杀真菌剂和植物生长调节剂。

9. 发明授权

US4455264A Preparation of acyl cyanides 失效
标题翻译：酰基氰的制备
公开(公告)号：US4455264A
公开(公告)日：1984-06-19
申请号：US436094
申请日：1982-10-22
申请人： Kurt Findeisen , Eckart Kranz
发明人： Kurt Findeisen , Eckart Kranz
IPC分类号： C07C20060101 , C07C255/45 , C07C255/56 , C07D253/06 , C07C120/00 , C07C121/34 , C07C121/76
CPC分类号： C07C253/16
摘要： Acyl cyanides of the formula ##STR1## in which R represents an optionally substituted alkyl group having 1 to 8 carbon atoms, an optionally substituted cycloalkyl group having 3 to 12 carbon atoms or an optionally substituted aryl group, or an optionally substituted 5-membered or 6-membered heterocyclic radical which additionally can be fused to a benzene ring,are obtained in high yields by reacting carboxylic acid anhydrides of the formula R--CO--O--CO--R (II) with trimethylsilyl cyanide, (CH.sub.3).sub.3 Si--CN (III), if appropriate in the presence of a catalyst and, if appropriate, in the presence of a diluent, at a temperature between 50.degree. and 250.degree. C. The acyl cyanides can be used as intermediate products, for example, for the preparation of certain herbicidally active compounds of the triazinone series.
摘要翻译：其中R表示任选取代的具有1至8个碳原子的烷基，任选取代的具有3至12个碳原子的环烷基或任选取代的芳基，或任选取代的5元或通过使式R-CO-O-CO-R（II）的羧酸酐与三甲基甲硅烷基氰化物，（CH 3）3 Si-CN（III）反应，可以高收率地获得另外可以与苯环稠合的6元杂环基（III），如果合适的话，在催化剂的存在下，如果合适的话，在稀释剂的存在下，在50℃和250℃之间的温度下。酰基氰可以用作中间产物，例如用于制备三嗪酮系列的某些除草活性化合物。

10. 发明授权

US4127728A Preparation of 1-phenyl-2,2,2-trihalogeno-ethanol esters 失效
标题翻译： 1-苯基-2,2,2-三卤代乙醇酯的制备
公开(公告)号：US4127728A
公开(公告)日：1978-11-28
申请号：US717302
申请日：1976-08-24
申请人： Thomas Schmidt , Wolfgang Kramer , Eckart Kranz
发明人： Thomas Schmidt , Wolfgang Kramer , Eckart Kranz
IPC分类号： C07C69/007 , C07C29/68 , C07C33/46 , C07C67/00 , C07C67/08 , C07C67/14 , C07C68/00 , C07C201/00 , C07C205/42 , C07C253/00 , C07C255/55 , C07C313/00 , C07C319/20 , C07C323/19 , C07C381/14 , C07D317/46 , C07D317/54
CPC分类号： C07C67/08 , C07C29/68 , C07C33/46 , C07C381/14 , C07C67/14
摘要： A process for the preparation of a substituted 1-phenyl-2,2,2-trihalo-ethanol ester of the formula ##STR1## in which R is alkyl, halogenoalkyl, alkoxy, cycloalkyl or optionally substituted phenyl, benzyl, phenoxy, or phenylsulfonyl,X is halogenoalkyl with 1-3 carbon atoms and 1-3 halogen atoms,Y is halogen, cyano, nitro, alkyl, alkoxy, alkylmercapto, sulfoalkoxy or optionally substituted methylenedioxy, andn is an integer from 0 to 3,Comprising reacting a compound of the formula ##STR2## WITH A HALOGENATED ALDEHYDE OF THE FORMULAX CHO in the presence of a Friedel-Crafts catalyst at a temperature of about -70 to +100.degree. C thereby to form a complex alcoholate, and reacting the complex alcoholate with an acid halide of the formula ##STR3## OR WITH A CORRESPONDING ACID ANHYDRIDE AT A TEMPERATURE OF ABOUT -70 TO +100.degree. C. The reaction with the acid halide or anhydride is preferably carried out in the presence of a solvent or diluent, sodium sulfate hydrate is added to the final reaction solution and the resulting mixture of sodium sulfate and basic aluminum halide is filtered off. The products are known insecticides.
摘要翻译：制备式“IMAGE”的取代的1-苯基-2,2,2-三卤代 - 乙醇酯的方法，其中R是烷基，卤代烷基，烷氧基，环烷基或任选取代的苯基，苄基，苯氧基或苯基磺酰基 X是具有1-3个碳原子和1-3个卤素原子的卤代烷基，Y是卤素，氰基，硝基，烷基，烷氧基，烷基巯基，磺基烷氧基或任选取代的亚甲二氧基，N是0至3的整数，包含反应A 在Fried-Crafts催化剂存在下，在约-70至+ 100℃的温度下，使用式（ⅩⅩⅩⅤ）化合物与式（ⅩⅤ）化合物反应，从而形成复合醇化物，并使复合醇化物与在-70至+ 100℃的温度下，与酰基卤或酸酐的反应优选在溶剂或稀释剂钠的存在下进行。将硫酸盐水合物加入到最终的反应物中并将所得的硫酸钠和碱式卤化铝的混合物滤出。产品是已知的杀虫剂。

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